Low-temperature thermionic emitter Interim scientific report, 9 Feb. 1968 - 8 Feb. 1969
Performance tests on alkaline earth oxide electron emitters at low temperatures
Dore, B. V.↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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A comparison of two methods of measuring particle size of Al sub 2 O sub 3 produced by a small rocket motor.
Tank collection and spectrophotometric tests in determining aluminum oxide particle size produced by small rocket engine
Dobbins, R. A.↗
A comparison of two methods of measuring particle size of Al2O3 produced by a small rocket motor
Tank collection and spectrophotometric tests in determining aluminum oxide particle size produced by small rocket engine
Dobbins, R. A.↗
Cyclic oxidation evaluation: Approaching application conditions
A survey is presented of the cyclic furnace and burner rig oxidation facilities at NASA-Lewis Research Center together with a review of selected test results and an initial interpretation of the data obtained. Cyclic furnace tests are used to conveniently screen alloy oxidation resistance and spall tendency; high velocity tests further indicate dynamic environmental resistance. Alloys which form scales predominantly of Cr2O3/chromite spinel spall much more than those forming alpha Al2O3/aluminate spinel scales. Weight changes due to scale spalling were used to estimate alloy depletion/thickness losses.
Barrett, C. A.↗
Time dependency of strainrange partitioning life relationships
The effect of exposure time (or creep rate) on the CP life relationship is established by conducting isothermal CP tests at varying exposure times on 316 Ss at 1300 and 1500 F. A reduction in the CP cycle life is observed with an increase in the exposure time of the CP test at a given inelastic strain-range. This phenomenon is characterized by modifying the Manson-Coffin type of CP relationship. Two new life relationships: (1) the Steady State Creep Rate (SSRC) Modified CP life relationship, and (2) the Failure Time (FT) Modified CP life relationship, are developed in this report. They account for the effect of creep rate and exposure time within the CP type of waveform. The reduction in CP cyclic life in the long exposure time tests is attributed to oxidation and the precipitation of carbides along the grain boundaries.
Kalluri, S.↗
Long-Term Tests of 38 Ball-Bearing Greases
Perfluoroalkylpolyether lubricants performed best. Final report in series presents results of program of long-term testing of ballbearing greases in vacuum, oxidizing, and otherwise hostile environments. Earlier reports in same series described in "Tests of 38 Ball-Bearing Greases," (MFS-25624) and "Further Tests of 38 Ball-Bearing Greases." (MFS-27043)
Mcmurtrey, E.↗
Stress Rupture Behavior of Silicon Carbide Coated, Low Modulus Carbon/Carbon Composites
The disadvantages of carbon-carbon composites, in addition to the oxidation problem, are low thermal expansion, expensive fabrication procedures, and poor off axis properties. The background of carbon-carbon composites, their fabrication, oxidation, oxidation protection and mechanical testing in flexure are discussed.
Rozak, Gary A.↗
Oxidation Kinetics of Cast TiAl3
The isothermal oxidation kinetics of the TiAl3 compound over a wide temperature range is documented, and these rates are related to exclusive alpha-Al2O3 scale growth. The specific weight change vs time curves are shown. Two abnormalities are immediately apparent. One is that a rapid initial uptake of oxygen occurs at times less than 5 h, followed by a lower oxidation rate at longer times, for tests at 900 C and below. The other is that the final weight changes for the 700, 800, and 900 C tests are not in the sequence expected with respect to temperature. Isothermal oxidation of drop cast TiAl above 1000 C was found to exhibit parabolic oxidation controlled by protective alpha-Al2O3 scale formation. TiAl is the only phase in the binary Ti-Al system that forms exclusive scales of alpha-Al2O3 in isothermal oxidation. High anomalous rates at short times and at temperatures below 1000 C resulted from the internal oxidation of a second phase of aluminum.
Smialek, J. L.↗
SXI prototype mirror mount
The purpose of this contract was to provide optomechanical engineering and fabrication support to the Solar X-ray Imager (SXI) program in the areas of mirror, optical bench and camera assemblies of the telescope. The Center for Applied Optics (CAO) worked closely with the Optics and S&E technical staff of MSFC to develop and investigate the most viable and economical options for the design and fabrication of a number of parts for the various telescope assemblies. All the tasks under this delivery order have been successfully completed within budget and schedule. A number of development hardware parts have been designed and fabricated jointly by MSFC and UAH for the engineering model of SXI. The major parts include a nickel electroformed mirror and a mirror mount, plating and coating of the ceramic spacers, and gold plating of the contact rings and fingers for the camera assembly. An aluminum model of the high accuracy sun sensor (HASS) was also designed and fabricated. A number of fiber optic tapers for the camera assembly were also coated with indium tin oxide and phosphor for testing and evaluation by MSFC. A large number of the SXI optical bench parts were also redesigned and simplified for a prototype telescope. These parts include the forward and rear support flanges, front aperture plate, the graphite epoxy optical bench and a test fixture for the prototype telescope. More than fifty (50) drawings were generated for various components of the prototype telescope. Some of these parts were subsequently fabricated at UAH machine shop or at MSFC or by the outside contractors. UAH also provide technical support to MSFC staff for a number of preliminary and critical design reviews. These design reviews included PDR and CDR for the mirror assembly by United Technologies Optical Systems (UTOS), and the program quarterly reviews, and SXI PDR and CDR. UAH staff also regularly attended the monthly status reviews, and made a significant number of suggestions to improve the design, assembly and alignment of the telescope. Finally, a high level assembly and alignment plan for the entire telescope was prepared by UAH. This plan addresses the sequence of assembly, the required assembly and alignment tolerances, and the methods to verify the alignment at each step during the assembly process. This assembly and alignment plan will be used to assemble and integrate the engineering model (EM) of the telescope. Later on, based on this plan more detailed assembly and alignment procedures will be developed for the lower-level assemblies of SXI.
Source record↗
Plume diagnostics of SRM static firings for pressure perturbation studies
During the shuttle launches, the solid rocket motors (SRM) occasionally experience pressure perturbations (8-13 psi) between 65 and 75 seconds into the motor burn time. The magnitudes of these perturbations are very small in comparison with the operating motor chamber pressure, which is over 600 psi during this time frame. These SRM pressure perturbations are believed to be caused primarily by the expulsion of slag (aluminum oxide). Two SRM static tests, TEM-11 and FSM-4, were instrumented extensive]y for the study of the phenomenon associated with pressure perturbations. The test instrumentation used included nonintrusive optical and infrared diagnostics of the plume, such as high-speed photography, radiometers, and thermal image cameras. Results from all these nonintrusive observations strongly support the scenario that the pressure perturbation event in the shuttle SRM is caused primarily by the expulsion of molten slag. The slag was also expelled preferentially near the bottom of the nozzle due to slag accumulation at the bottom of the aft end of the horizontally oriented motor.
Sambamurthi, J. K.↗
Correlation of Slag Expulsion with Ballistic Anomalies in Shuttle Solid Rocket Motors
During the Shuttle launches, the solid rocket motors (SRM) occasionally experience pressure perturbations (8-13 psi) between 65-75 s into the motor burn time. The magnitudes of these perturbations are very small in comparison with the operating motor chamber pressure, which is over 600 psi during this time frame. These SRM pressure perturbations are believed to he caused primarily by the expulsion of slag (aluminum oxide). Two SRM static tests, TEM-11 and FSM-4, were instrumented extensively for the study of the phenomena associated with pressure perturbations. The test instrumentation used included nonintrusive optical and infrared diagnostics of the plume, such as high-speed photography, radiometers, and thermal image cameras. Results from all of these nonintrusive observations provide substantial circumstantial evidence to support the scenario that the pressure perturbation event in the Shuttle SRM is caused primarily by the expulsion of molten slag. In the static motor tests, the slag was also expelled preferentially near the bottom of the nozzle because of slag accumulation at the bottom of the aft end of the horizontally oriented motor.
Sambamurthi, Jay K.↗
Moisture-Induced Delayed Spallation and Interfacial Hydrogen Embrittlement of Alumina Scales
While interfacial sulfur is the primary chemical factor affecting Al2O3 scale adhesion, moisture-induced delayed spallation appears as a secondary, but impressive, mechanistic detail. Similarities with bulk metallic phenomena suggest that hydrogen embrittlement from ambient humidity, resulting from the reaction Al(sub alloy)+3(H2O)(sub air) = Al(OH)(-) (sub 3) +3H(+) may be the operative mechanism. This proposal was tested on pre-oxidized Rene N5 by standard cathodic hydrogen charging in 1N H2SO4, as monitored by weight change, induced current, and microstructure. Cathodic polarization at -2.0 V abruptly stripped mature Al2O3 scales at the oxide-metal interface. Anodic polarization at +2.0 V, however, produced alloy dissolution. Finally, with no applied voltage, the acid electrolyte produced neither scale spallation nor alloy dissolution. Thus, hydrogen charging was detrimental to alumina scale adhesion. Moisture-induced interfacial hydrogen embrittlement is concluded to be the cause of delayed scale spallation and desktop thermal barrier coating failures.
Smialek, James L.↗
Experimental Waterflow Determination of the Dynamic Hydraulic Transfer Function for the J-2X Oxidizer Turbopump: Results and Interpretation - Part Two
Experimental results describing the hydraulic dynamic pump transfer matrix (Yp) for a cavitating J-2X oxidizer turbopump inducer+impeller tested in subscale waterflow are presented. The transfer function is required for integrated vehicle pogo stability analysis as well as optimization of local inducer pumping stability. Dynamic transfer functions across widely varying pump hydrodynamic inlet conditions are extracted from measured data in conjunction with 1D-model based corrections. Derived Dynamic transfer functions are initially interpreted relative to traditional Pogo pump equations. Water-to-liquid oxygen scaling of measured cavitation characteristics are discussed. Comparison of key dynamic transfer matrix terms derived from waterflow testing are made with those implemented in preliminary Ares Upper Stage Pogo stability modeling. Alternate cavitating pump hydraulic dynamic equations are suggested which better reflect frequency dependencies of measured transfer matrices.
Zoladz, Tom↗
Study of Anti-Vortex Baffle Effect in Suppressing Swirling Flow in LOX Tank
Experimental results describing the hydraulic dynamic pump transfer matrix (Yp) for a cavitating J-2X oxidizer turbopump inducer+impeller tested in subscale waterflow are presented. The transfer function is required for integrated vehicle pogo stability analysis as well as optimization of local inducer pumping stability. Dynamic transfer functions across widely varying pump hydrodynamic inlet conditions are extracted from measured data in conjunction with 1D-model based corrections. Derived Dynamic transfer functions are initially interpreted relative to traditional Pogo pump equations. Water-to-liquid oxygen scaling of measured cavitation characteristics are discussed. Comparison of key dynamic transfer matrix terms derived from waterflow testing are made with those implemented in preliminary Ares Upper Stage Pogo stability modeling. Alternate cavitating pump hydraulic dynamic equations are suggested which better reflect frequency dependencies of measured transfer matrices.
Yang, H. Q.↗
Advanced CMOS Radiation Effects Testing and Analysis
Presentation at the annual NASA Electronic Parts and Packaging (NEPP) Program Electronic Technology Workshop (ETW). The material includes an update of progress in this NEPP task area over the past year, which includes testing, evaluation, and analysis of radiation effects data on the IBM 32 nm silicon-on-insulator (SOI) complementary metal oxide semiconductor (CMOS) process. The testing was conducted using test vehicles supplied by directly by IBM.
cmos↗
Creep Behavior and Durability of Cracked CMC
To understand failure mechanisms and durability of cracked Ceramic matrix composites (CMCs), Melt Infiltration (MI) SiCSiC composites with Sylramic-iBN fibers and full Chemical vapour infiltration SiCSiC composites with Sylramic-ion bombarded BN (iBN) and Hi-Nicalon -S fibers were pre-cracked between 150 to 200 megapascal and then creep and Sustained Peak Low Cycle Fatigue (SPLCF) tested at 13150 C at stress levels from 35 to 103 megapascal for up to 200 hours under furnace and burner rig conditions. In addition creep testing was also conducted on pre-cracked full Chemical vapour infiltration SiCSiC composites at 14500 C between 35 and 103 megapascal for up to 200 hours under furnace conditions. If the specimens survived the 200 hour durability tests, then they were tensile tested at room temperature to determine their residual tensile properties. The failed specimens were examined by Scanning electron microscope (SEM) to determine the failure modes and mechanisms. The influence of crack healing matrix, fiber types, crack density, testing modes and interface oxidation on durability of cracked Ceramic matrix composites (CMCs) will be discussed.
Creep↗
The Combustion Product Monitor instrument for the spacecraft fire safety demonstration project
The Combustion Product Monitor (CPM) instrument is a six-channel tunable laser absorption spectrometer capable of measuring ambient gas-phase concentrations of CO, HCl, HCN, HF, CO2, and O2 in spacecraft environments. Monitoring of these compounds can provide early warning detection of combustion events and can also facilitate safe post-fire cleanup. Here, we will describe the development of a CPM instrument optimized for operation as part of the Spacecraft Fire Safety Demonstration (Saffire) Project. As part of Saffire, the CPM instrument will measure concentrations of the target gases during low-gravity, reduced pressure oxidative pyrolysis of relevant test materials aboard a transfer vehicle returning from low Earth orbit. We will describe the CPM instrument design, absorption line selection,theoretical and experimental detection limits, and environmental testing.
Briggs, Ryan M.↗
Calcined Polyethyleneimine-Coated Optical Fibers for Distributed pH Monitoring at High Pressures and Temperatures
In the oil and gas, CO2 sequestration, H2 subsurface storage, and geothermal energy sectors, subsurface pH measurements are critical for monitoring the geochemical conditions and estimating potential corrosion rates of wellbore systems. Real-time pH measurements in these conditions are vital for detecting and predicting corrosion deterioration of wellbore components that may jeopardize the safety and continued operation of wellbore systems. Previous tests using metal oxide-based coatings (TiO2) provided strong responses at elevated temperatures and moderate pressure stability but provided poor differentiation between acidic and alkaline solutions. Building off the pH responsiveness of the TiO2 surface and known pH sensitivity of amine-based polymers, a coating based on the secondary amine polymer polyethyleneimine (PEI) was developed. As the polymer itself is highly water soluble and easily removed by aqueous solutions, the sensor coating was treated with a high temperature (500 °C) calcination procedure in air to convert it into a more stable oxidized coating capable of withstanding hot aqueous solutions without dissolving while retaining linear pH sensitivity from pH values between 2 and 11. The sensor performance was measured using optical transmission measurements in solutions of various pHs and using optical backscatter reflectometry for distributed pH sensing demonstration in wellbore-relevant pressures (up to 1,000 psi) and temperatures (80 °C).
Shumski, Alexander↗