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At least 505 records · Page 28

A study of the infrared emission from the O I (3d 3D0) and (4s 5S0) states produced by electron impact excitation of O2

The absolute emission cross section values for the O I(3p 3P-3d 3D0, lambda = 11,287 A) and the (3p 5P-4s 5S0, lambda = 11,299 A) multiplets excited by electron impact on O2 have been measured. These infrared oxygen emission features appear prominently in auroral spectra and were observed in electron bombardment of O2. The former cross section has a value of 3.05 x 10 to the -19th + or - 15 percent at 100 eV, while the latter's value is 4.14 x 10 to the -19th sq cm + or - 15 percent. The quintet emission at lambda = 11,299 A is the only deexcitation channel for the 4s 5S0 state and thus represents the total excitation cross section for that state. However, the lambda = 11,287 A branch from the O I (3d 3D0) state only constitutes about 25 percent of the total 3d 3D0 cross section, with the major branch from this state being the transition to the ground state observed at lambda = 1027 A. The branching ratio is in good agreement with the theoretical calculation of Padhan and Saraph (1977).

Erdman, P. W.↗

Determination of O2(a1Delta g) and O2(b1Sigma + g) yields in the reaction O + ClO yields Cl + O2 - Implications for photochemistry in the atmosphere of Venus

A discharge flow apparatus with a chemiluminescence detector was used to investigate the reaction O + ClO yields Cl + O2(asterisk), where O2(asterisk) = O2(a1Delta g) or O2(b1Sigma + g). It is found that the observed O2(a1Delta g) airglow of Venus cannot be explained in the framework of standard photochemistry using the experimental results obtained here and those reported in the recent literature. The possibility of an alternative source of O atoms derived from SO2 photolysis in the Venus mesosphere is suggested.

Leu, Ming-Taun↗

Pioneer Venus measurements of H, O, and C production in comet P/Halley near perihelion

The Pioneer Venus Orbiter Ultraviolet Spectrometer measured the production of H, O, and C in comet Halley from late December 1985 to early March 1986. Water production rates obtained from the H data rose from 3.3 x 10 to the 29th/s at 1 AU inbound to 1.2 x 10 to the 30th/s at perihelion; there was a further increase to 1.6 x 10 to the 30th/s followed by a slow decline to 1.4 x 10 to the 30th/s at the time of the Vega-1 encounter. The H measurements show a periodic behavior that imply variations in the water production rate having structure within a 7.4-day sidereal period, in phase with similar variations seen in radical and dust production in March and April. Average H:O:C ratios of 1.0:0.7:0.07 were measured from 10 to 26 days after perihelion.

Stewart, A. I. F.↗

The production of O(1D) from dissociative recombination of O2(+)

The results of large scale ab initio calculations of the rates for production of O(1D) by dissociative combination of O2(+) are presented for electron temperatures in the range 100 to 3000 K. A 1-delta-u state is the dominant dissociative route from v = 0 and a 3-sigma-u(-) state is the most important route from v = 1 and v = 2. The calculated total rate for O(1D) production from v = 0 is 2.21(+0.21, -0.24) x 10(-7) x (T sub e/300) exp -.46 near room temperature. The v = 1 and v = 2 rates are about 17 percent and 47 percent smaller respectively, than the v = 0 rate at 300 K.

Guberman, Steven L.↗

Making Reliable Large-Diameter O-Rings

Vacuum curing yields joint-free, voidless elastomer seals. Method for manufacturing large-diameter O-rings produces them in single pieces, without bonded joints. Reduces probability trapped gases form flaws. O-rings produced, having diameters as much as 144 in. (3.66m), reliable and of high quality. Nesting upper and lower halves of mold hold elastomer rings for curing. Oil flowing through upper and lower cavities heats elastomer to cure it.

Larsen, Glade L.↗

Vertical O(sub 3) distribution as a diagnostic for eddy diffusion profile

A model study of the distribution of ozone on Mars is presented. It is showed that knowledge of the vertical ozone distribution, such as could be obtained from ultraviolet measurements from an orbiter, could be used to infer vertical transport rates at various levels in the atmosphere. The dependence of the vertical distribution of O(sub 3) on the height variation of eddy diffusion coefficient is illustrated. Ozone abundance is a valuable diagnostic for other climatological parameters. In addition, the sensitivity of O(sub 3) distribution to eddy diffusion may aid in determining the role of surface oxidation and recombination processes and lead to a better understanding of the volatiles released or adsorbed cyclically in the Martian regolith.

Tyler, A. L.↗

O stars and Wolf-Rayet stars

Basic information is given about O and Wolf-Rayet stars indicating how these stars are defined and what their chief observable properties are. Part 2 of the volume discussed four related themes pertaining to the hottest and most luminous stars. Presented are: an observational overview of the spectroscopic classification and extrinsic properties of O and Wolf-Rayet stars; the intrinsic parameters of luminosity, effective temperature, mass, and composition of the stars, and a discussion of their viability; stellar wind properties; and the related issues concerning the efforts of stellar radiation and wind on the immediate interstellar environment are presented.

Conti, Peter S.↗

Fast O(sup +) ion flow observed around Venus at low altitudes

The Pioneer Venus Orbiter Neutral Mass Spectrometer (ONMS) has observed fast O(+) ions with an energy exceeding 40 eV in the spacecraft reference frame. The orbit of the spacecraft is nearly polar with periapsis near the equator. The ONMS is mounted at an angle to the spin axis which, in turn, is perpendicular to the ecliptic plane. From the spin modulated data the direction of the ion flow in that plane can be determined. Data from the first 11 diurnal cycles (orbits 1 to 2475) are vector averaged in order to display the general flow pattern. Plots of the averaged data are presented. On the dayside and near the terminators, where fast O(+) is observed near the ionopause, the directions are more or less parallel to the planet's surface with evidence of an asymmetry about the Sun-Venus line. On the nightside below 2000 km and near the equator there is a preferred dawn to dusk direction while at higher altitudes (lower solar zenith angles and higher latitudes) the flow direction is more antisunward. The averaged flux for this time period is 8x10 to the 5th/sq cm/s with a maximum of 5x10 to the 8th.

Kasprzak, W. T.↗

Alfven ion-cyclotron heating of ionospheric O(+) ions

Transversely heated ionospheric ions, in particular O(+) ions, are often observed flowing upward along auroral field lines. Currents observed in association with the transversely heated ions can drive shear Alfven waves and electrostatic ion-cyclotron waves unstable which can, in turn, be resonantly absorbed by the ions to produce the heating. Particle simulations are used to examine self-consistently the excitation of these waves and the associated heating. It is shown that the growth of the electrostatic ion-cyclotron waves quickly becomes suppressed as the ions become heated and the dominant wave fields are those of the shear Alfven wave. The resultant transverse ion heating is larger and faster than that produced by solely electrostatic ion-cyclotron wave heating. Due to trapping of ions by the shear Alfven wave, the temperature of the O(+) ions remains comparable to that of the H(+) ions.

Winglee, R. M.↗

Observations of a Greenstein effect in the O I 1302A emission of Comet Halley

Far-ultraviolet spectra of Comet Halley (1986 III) were obtained on February 26, 1986, 17 days after perihelion, and on March 13, 1986, 13 hr before the Giotto encounter, using an imaging spectrograph aboard a sounding rocket. A sunward-antisunward asymmetry observed in the brightness distribution of the O I 1302A emission is a result of the differential Swings effect first discussed by Greenstein (1958) for Fraunhofer structure in the solar continuum. The mean velocity of the O atoms in the coma at cometocentric radii greater than 10,000 km was 2.2 + or - 0.8 km/s based on model calculations which incorporate the Greenstein effect. This velocity is consistent with H2O as the principal source of oxygen.

Dymond, K. F.↗

Ground-based measurements of O 1D and the H2O production rate from comets

High spectral resolution 6300.3 A line profiles of Comet Halley are modeled to determine the relative contributions to the emission that can be expected from the distant O 1D daughters produced by photodissociation H2O, CO2, and CO. The results are compared with profiles measured with a single etalon Fabry-Perot interferometer interfaced with a 0.4-m telescopre. To accurately calculate Q O 1D using the 6300.3 A intensity, the line profile must be known. It is shown that the outflow velocity of the parent molecules from the nucleus can be determined using the interferometer profiles.

Kerr, R. B.↗

O-Ring-Testing Fixture

Fixture used to evalute properties of O-rings of various materials. Hydraulic actuator positions plug in housing, creating controlled, variable gap in O-ring glands formed by grooves in plug and by inner wall of housing. Creates controlled axial and radial gaps between sealing surfaces around ring so effectiveness of material in maintaining seal determined under dynamic conditions.

Turner, James E.↗

Optical and microwave detection using Bi-Sr-Ca-Cu-O thin films

Recent progress at the Johns Hopkins University Applied Physics Laboratory (JHU/APL) in the development of optical and microwave detectors using high temperature superconducting thin films is described. Several objectives of this work have been accomplished, including: deposition of Bi-Sr-Ca-Cu-O thin films by laser abation processing (LAP); development of thin film patterning techniques, including in situ masking, wet chemical etching and laser patterning; measurements of bolometric and non-bolometric signatures in patterned Bi-Sr-Ca-Cu-O films using optical and microwave sources, respectively; analysis and design of an optimized bolometer through computer simulation, and investigation of its use in a Fourier transform spectrometer. The focus here is primarily on results from the measurement of the bolometric and non-bolometric response.

Grabow, B. E.↗

Stratospheric H2(O-18) distribution from far infrared observations

The stratospheric distribution of H2(O-18) in the 22 to 37 km altitude range has been obtained from balloon-based measurement of far infrared thermal emission spectra with an unapodized spectral resolution of 0.0033/cm. The analysis is based on the observed spectra of 9 isolated spectral lines in the 46 to 72/cm region obtained from four complete limb sequences. Comparison of the results with the statistically expected values indicates enhancement in the H2(O-18) concentrations increasing from 27 + or - 14 percent at 29 km to 40 + or - 23 percent at 37 km. No significant enhancement at lower altitudes was observed.

Guo, J.↗

An analysis of the effects of N2 absorption on the O(+) 834-A emission from rocket observations

Altitude profiles of the O(+) 834-A emission, obtained from rocket observations at moderate and high solar conditions, are compared with model calculations. The model showed that when viewing the atmosphere horizontally at altitudes below the F2 layer, the 834-A intensity was virtually independent of the O(+) density. The 834-A intensity was found to be highly sensitive to the N2 absorption cross section. Comparisons with model calculations suggest that absorption by N2 is a factor of 10 lower than the currently accepted values.

Cleary, D. D.↗

Yttrium enrichment and improved magnetic properties in partially melted Y-Ba-Cu-O materials

The yttrium-rich compositions in the Y-Ba-Cu-O system were mapped out in a systematic manner to quantify their magnetic properties and to correlate them with the microstructure and phase composition as determined by scanning electron microscopy and X-ray diffraction analysis. It is found that the microstructure of Y-Ba-Cu-O compositions is a sensitive function of both their composition and processing conditions. Measurements of magnetic susceptibility and maximum (low-field) and remanent magnetization for the system Y:Ba:Cu = x:2:3 show highest values for x = 2. The corresponding structures involve numerous small crystals of Y2BaCuO5 (211) embedded in highly ordered assemblages of continous YBa2Cu3O(7-y) (123) layers.

Alterescu, Sidney↗

Calculating climate attractor dimension from delta O-18 records by the Grassberger-Procaccia algorithm

The Grassberger-Procaccia method of calculating dimension from a time series is applied to 14 late Pleistocene delta O-18 records. A step-by-step sequence leading from data to the Grassberger-Procaccia dimension is outlined, and the problems encountered when dealing with observed (as opposed to theoretical) data are discussed; for the climatic proxy data these problems include situations where the time series is not very long, is noisy and/or smoothed, and is not sampled at a constant time interval. The delta O-18 records to be used are described, and the results are presented and compared with previously published dimension calculations. New dimension interpretations are assessed, and an example using a synthetic time series that illustrates the possible error due to inconsistencies in the time scale is analyzed.

Maasch, Kirk A.↗

Shocked forbidden O I 63 micron line emission from the supernova remnant IC 443

Observations of the fine-structure emission from the forbidden O I 63 micron line in the SNR IC 443 are presented. It is shown that the emission correlates well with the distribution of line emission from shock-excited molecular hydrogen, which leads to the conclusion that the line is shock-excited. X-ray heating as well as UV-heating from a photodissociation region is ruled out as a possible excitation mechanism for the emission. It is shown that the forbidden O I 63 micron line is an important contributor to the total emission in the IRAS 60 micron band, estimated as approximately 40-75 percent of the total band flux. An attempt to shock model the line emission from IC 443 is made; however, to match the observational evidence, it has to be assumed that the shock is J-type, and that the oxygen chemistry is suppressed so that oxygen remains in atomic form and does not get converted into H2O. However, no theoretical rationale for these assumptions can be provided.

Burton, Michael G.↗