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At least 505 records · Page 28
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Krypton Concentration using HZ-PAN

Idaho National Laboratory (INL) has developed and tested engineered sorbents to separate and capture volatile fission products such iodine, xenon (Xe), and krypton (Kr) from off-gas streams. As noble gases, Xe and Kr can be difficult to capture and separate. Historically, cryogenic distillation has been used to execute the separation. However, performing this separation from bulk air streams is expensive and can pose significant hazards. INL has successfully developed two different sorbents for Xe and Kr capture, silver mordenite polyacrylonitrile and hydrogen mordenite polyacrylonitrile (HZ-PAN). Adsorption studies to date successfully separated and captured Kr from carrier gas streams, but those studies focused primarily on initial separation and capture. Successful utilization in a used nuclear fuel (UNF) reprocessing facility, however, requires further concentration of the Kr to minimize long term storage volumes. This study focuses on the concentration of Kr utilizing HZ PAN as the concentrating media. Concentrating Kr during desorption is ideal for two reasons: one, to produce Kr that can be used for commercial and research applications, or two, to minimize the volume of the radioactive gaseous waste stream for disposal. This report investigates the Kr concentrating potential of HZ-PAN by running multiple Kr adsorption-desorption cycles, collecting the desorbed effluent from a saturated HZ-PAN column, and loading it onto a fresh column. This study demonstrates that four adsorption-desorption cycles can transform a 150 ppmv Kr stream into a 37.5% Kr stream, an overall concentration factor of 2497. Each concentration step results in successively smaller volumes desorbed, reducing volume by a factor of approximately 40,000. Depending on the operational goals, during desorption one could collect smaller volume fractions of high concentration Kr (~ 67%). This demonstration should be considered proof-of-concept. Further refinement is necessary to develop optimum operating schemes to integrate into UNF off-gas treatment.

12 - MGMT OF RADIOACTIVE AND NON-RADIOACTIVE WASTE↗
DOE OSTI2020

Ammonia Permeation Through Inorganic Membranes

Moisture probes are used in the tritium facility to measure the moisture content of the gas stream. When tritium reacts with nitrogen to form ammonia, the ammonia gas damages the sensitive moisture probe. The gas stream tested during this experiment for moisture probe protection is composed of nitrogen and argon gas in conjunction with ammonia and water vapor. The gas stream is filtered through an inorganic membrane due to the high reactivity of tritium and a residual gas analyzer (RGA) is used to measure the ammonia and water vapor in the gas stream, as well as the permeability of nitrogen and argon through the inorganic membranes. The membranes tested were boron nitride and silver. The permeability was compared for each membrane at different pressures and flow rates. Fourier-transformed infrared spectroscopy (FT-IR) was used to compare the membranes before and after ammonia permeation. Ammonia gas is a byproduct formed from tritium gas reacting with nitrogen in the gas stream, similar to the Haber Process which occurs when hydrogen reacts with nitrogen [2]. The corrosive nature of ammonia damages metals and sensitive instruments such as moisture probes. Moisture probes are essential in various gas and liquid processes for measuring the moisture content of a gas. Membrane research has found that graphene oxide membranes successfully uptake ammonia from the gas stream at a humidity of approximately 30% at which point the pores pin closed, preventing gas permeation. Further research is being conducted to find an inorganic membrane that will prevent ammonia permeation thus circumventing damage to the sensitive moisture probe. The permeation measurements for argon and nitrogen gas and water and ammonia vapor were measured at various pressures of 800, 1000, 1200, 1500, 1800, and 2000 torr. The permeability average (PA) was calculated for each filter using a Barrer calculation. The average permeations for each filter were then compared. The gas composition was measured using the RGA Nitrogen was permeated through the membranes after ammonia permeation and a FT-IR spectrum was obtained. Boron Nitride: As the nitrogen pressure increased, the permeability of the membrane decreased from 800-1200 torr and remained relatively unchanged from 1200-2000 torr. The membrane exhibited a slight decrease in argon permeability from 800-1200 torr and a slight increase from 1500-2000 torr. The boron nitride membrane when permeated with ammonia and nitrogen prevented less ammonia permeation compared to the blank filter. The boron nitride filter demonstrated a decrease in permeability after ammonia permeation. Silver Membrane: When permeated with nitrogen alone, the membrane permeability decreased from 800 torr to 1200 torr. The permeability of the membrane showed little difference as pressure increased from 1200 torr. When permeated with argon, the same phenomenon occurred but on a much smaller scale. When compared to the blank and the boron nitride membranes the silver membrane exhibited significantly lower permeability. This may be in part due to the coating on the silver membrane and differences in pore size of the membranes. During permeation with ammonium hydroxide vapor and nitrogen, the partial pressure of the ammonia increased as compared to the blank membrane. The permeability before and after permeation with ammonia and nitrogen were compared. Permeability values suggested that after being permeated with the ammonia that the permeability for lower pressures increased slightly. There was no significant change in the FT-IR spectrums before and after permeation. Future work: Continue testing various inorganic membranes for ammonia permeation. Further research chemical separation of ammonia from the gas stream, which may prove difficult due to the high reactivity of tritium.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

A Membrane Contactor Enabling Energy-Efficient CO 2 Capture from Point Sources with Deep Eutectic Solvents

We demonstrate a scalable and energy-efficient hollow fiber membrane contactor (HFMC)-based process using a green solvent for CO 2 capture. This process uses a deep eutectic solvent (DES) in an HFMC to provide close interfacial interactions and contact between the DES and CO 2 . This approach overcomes disadvantages associated with direct absorption in DES and could potentially be applied to a variety of solvent-based CO 2 capture methods. Commercial low-cost polymer hollow fiber membranes (e.g., microporous polypropylene) were evaluated for CO 2 capture with reline, a prototypical DES. Single-gas measurements showed that the DES-based polypropylene HFMC can capture and separate CO 2 while rejecting N2. From a mixed gas containing 50 mol % N 2 and 50 mol % CO ν , the DES-based HFMC separated CO 2 with a purity of 96.9 mol %. The effect of several process parameters including solvent flow rate, pressure, and temperature on the CO 2 separation performance was studied. The flux of the recovered CO 2 was 67.43 mmole/m 2 /h at a feed pressure of 4 bar. In situ Fourier transform infrared (FTIR) measurements combined with density functional theory (DFT)-based molecular dynamics simulations revealed that reline absorbs CO 2 by physical absorption without forming a new chemical compound, and CO 2 separation by reline occurs via the pressure swing mechanism. This research provides fundamental insights about physical solvent-based separation processes and a pathway toward practical deployment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

ASC Poster - Concentration of Xe from Simulated Dissolver Off-gas Streams Utilizing a Solid Sorbent, AgZ-PAN

Idaho National Laboratory (INL) has developed and tested engineered sorbents to separate and capture volatile fission products such iodine (I), xenon (Xe), and krypton (Kr) from off-gas streams. As noble gases, Xe and Kr can be difficult to capture and separate. Historically, cryogenic distillation has been used to execute the separation, but this method can pose significant hazards. INL has successfully developed two sorbents for Xe and Kr capture, silver mordenite polyacrylonitrile (AgZ-PAN) and hydrogen mordenite polyacrylonitrile (HZ-PAN). Adsorption studies to date successfully separated and captured Xe from carrier gas streams, but those studies focused primarily on initial separation and capture. In addition, the ability to concentrate Xe through multiple adsorption and desorption cycles has not been studied and therefore is the focus on this presentation. Concentrating Xe during desorption is ideal to produce Xe that can be used for commercial and research applications.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2021

Engineering Permanent Porosity into Liquids

The possibility of engineering well-defined pores into liquid materials is fascinating from both a conceptual and an applications point of view. Although the concept of porous liquids was proposed in 2007, these materials had remained hypothetical due to the technical challenges associated with their synthesis. Over the past five years, however, reports of the successful construction of porous liquids based on existing porous scaffolds, such as coordination cages, organic cages, metal–organic frameworks, porous carbons, zeolites, and porous polymers, have started to emerge. Here, the focus is on these early reports of porous liquids as prototypes in the field, classified according to the previously defined types of porous liquids. Particular attention will be paid to design strategies and structure–property relationships. Porous liquids have already exhibited promising applications in gas storage, transportation, and chemical separations. Furthermore, they show great potential for use in the chemical industry. The challenges of preparation, scale-up, volatility, thermal and chemical stability, and competition with porous solids will also be discussed.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Graphitic Aza-Fused π-Conjugated Networks: Construction, Engineering, and Task-Specific Applications

2D π-conjugated networks linked by aza-fused units represent a pivotal category of graphitic materials with stacked nanosheet architectures. Extensive efforts have been directed at their fabrication and application since the discovery of covalent triazine frameworks (CTFs). Besides the triazine cores, tricycloquinazoline and hexaazatriphenylene linkages are further introduced to tailor the structures and properties. Diverse related materials have been developed rapidly, and a thorough outlook is necessitated to unveil the structure–property–application relationships across multiple subcategories, which is pivotal to guide the design and fabrication toward enhanced task-specific performance. Herein, the structure types and development of related materials including CTFs, covalent quinazoline networks, and hexaazatriphenylene networks, are introduced. Advanced synthetic strategies coupled with characterization techniques provide powerful tools to engineer the properties and tune the associated behaviors in corresponding applications. Case studies in the areas of gas adsorption, membrane-based separation, thermo-/electro-/photocatalysis, and energy storage are then addressed, focusing on the correlation between structure/property engineering and optimization of the corresponding performance, particularly the preferred features and strategies in each specific field. In the last section, the underlying challenges and opportunities in construction and application of this emerging and promising material category are discussed.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Quantitative Decoupling of Oxygen-Redox and Manganese-Redox Voltage Hysteresis in a Cation-Disordered Rock Salt Cathode

Pronounced voltage hysteresis in Li-excess cathode materials is commonly thought to be associated with oxygen redox. However, these materials often possess overlapping oxygen and transition-metal redox, whose contributions to hysteresis between charge and discharge are challenging to distinguish. In this work, a two-step aqueous redox titration is developed with the aid of mass spectrometry (MS) to quantify oxidized lattice oxygen and Mn 3+/4+ redox in a representative Li-excess cation-disordered rock salt—Li 1.2 Mn 0.4 Ti 0.4 O 2 (LMTO). Two MS-countable gas molecules evolve from two separate titrant-analyte reactions, thereby allowing Mn and O redox capacities to be decoupled. The decoupled O and Mn redox coulombic efficiencies are close to 100% for the LMTO cathode, indicating high charge-compensation reversibility. As incremental Mn and O redox capacities are quantitatively decoupled, each redox voltage hysteresis is further evaluated. Overall, LMTO voltage hysteresis arises not only from an intrinsic charge-discharge voltage mismatch related to O redox, but also from asymmetric Mn-redox overvoltages. The results reveal that O and Mn redox both contribute substantially to voltage hysteresis. In conclusion, this work further shows the potential of designing new analytical workflows to experimentally quantify key properties, even in a disordered material having complex local coordination environments.

25 ENERGY STORAGE↗
DOE OSTI2024

THD-C Sheet: A Novel Nonbenzenoid Carbon Allotrope with Tetra-, Hexa-, and Dodeca-Membered Rings

Here, we propose a novel two-dimensional carbon-based structure with tetra-, hexa-, and dodeca-membered rings, which we refer to by the abbreviated name, THD-C. The structure presents a mixture of sp–sp 2 hybridization and can potentially be synthesized by the topological assembly of 4-ethynyldiphenylacetylene molecules. By employing first-principles calculations, the stability and ease of synthesis of the sheet are investigated and compared with various C-allotropes. We predict its metallic behavior and excellent kinetic and dynamic stability. Due to the crystal structure of the sheet, a strong mechanical anisotropy is observed. The effects of functionalization on the electronic properties of the material are also studied, and different semiconducting systems are obtained. The potential of THD-C for energy storage in metal-based batteries, hydrogen storage, and catalysis is also investigated, and we find a superior performance in comparison to graphite and other allotropes. The quantum confinement effect is investigated by constructing nanoribbons and nanotubes of various sizes. For ribbons, we find that tailor-made electronic and magnetic properties can be obtained and explored in potential spintronic devices. Additionally, we observe that nanotubes are conducting irrespective of their chirality and can potentially be used for capture, storage, and separation of industrially relevant small gas molecules.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Evaluation of a Reference-Free Collision Cross Section Calibration Strategy for Proteomics Using SLIM-Based High-Resolution Ion Mobility Spectrometry–Mass Spectrometry

Ion mobility spectrometry (IMS) is a gas-phase analytical technique that separates ions with different sizes and shapes and is compatible with mass spectrometry (MS) to provide an additional separation dimension. The rapid nature of the IMS separation combined with the high sensitivity of MS-based detection and the ability to derive structural information on analytes in the form of the property collision cross section (CCS) makes IMS particularly well-suited for characterizing complex samples in -omics applications. In such applications, the quality of CCS from IMS measurements is critical to confident annotation of the detected components in the complex -omics samples. However, most IMS instrumentation in mainstream use requires calibration to calculate CCS from measured arrival times, with the most notable exception being drift tube IMS measurements using multifield methods. The strategy for calibrating CCS values, particularly selection of appropriate calibrants, has important implications for CCS accuracy, reproducibility, and transferability between laboratories. The conventional approach to CCS calibration involves explicitly defining calibrants ahead of data acquisition and crucially relies upon availability of reference CCS values. In this work, we present a novel reference-free approach to CCS calibration which leverages trends among putatively identified features and computational CCS prediction to conduct calibrations post-data acquisition and without relying on explicitly defined calibrants. We demonstrated the utility of this reference-free CCS calibration strategy for proteomics application using high-resolution structures for lossless ion manipulations (SLIM)-based IMS-MS. In conclusion, we first validated the accuracy of CCS values using a set of synthetic peptides and then demonstrated using a complex peptide sample from cell lysate.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2024

Comparison of reduced model predictions for divertor detachment onset and reattachment timescales in ASDEX Upgrade and JET experiments

Building on prior analysis of ASDEX Upgrade (AUG) experiments (Henderson et al 2023 Nucl. Fusion63 086024), this study compares simple analytical formula predictions for divertor detachment onset and reattachment timescales in JET experiments. Detachment onset primarily scales with divertor neutral pressure, impurity concentration, power directed to the targets, machine size, and integral perpendicular power decay length. JET experiments, focusing on seeding mixtures of Ne and Ar, align with the detachment onset predictions. Radiation efficiencies among the impurities show good agreement with the model predictions, contrasting with AUG observations which suggested higher efficiency for Ar and lower efficiency for Ne. The time taken to re-ionise the neutral volume in front of the outer target in fully detached divertor conditions was measured following both abrupt increases in injected neutral beam power and, separately, cutting of the impurity gas flow. Re-ionisation of the neutrals occurs within approximately 1 s on JET, which aligns with the simple model prediction derived from AUG data. While the AUG results are not new, their comparison with the JET results enhances understanding, reinforcing confidence in using simple models to predict future reactor scenarios.

JET↗
DOE OSTI2022

Nature of the galaxies on top of quasars producing Mg ii absorption

ABSTRACT Quasar–galaxy pairs at small separations are important probes of gas flows in the disc–halo interface in galaxies. We study host galaxies of 198 Mg ii absorbers at 0.39 ≤ zabs ≤ 1.05 that show detectable nebular emission lines in the Sloan Digital Sky Survey (SDSS) spectra. We report measurements of impact parameter (5.9 ≤ D [kpc] ≤ 16.9) and absolute B-band magnitude (−18.7 ≤ MB ≤ −22.3 mag) of host galaxies of 74 of these absorbers using multiband images from the Dark Energy Spectroscopic Instrument (DESI) Legacy Imaging Survey, more than doubling the number of known host galaxies with D ≤ 17 kpc. This has allowed us to quantify the relationship between Mg ii rest equivalent width (W2796) and D, with best-fitting parameters of W2796 (D = 0) = 3.44 ± 0.20 Å and an exponential scale length of 21.6$^{+2.41}_{-1.97}\, \mathrm{ kpc}$. We find a significant anticorrelation between MB and D, and MB and W2796, consistent with the brighter galaxies producing stronger Mg ii absorption. We use stacked images to detect average emissions from galaxies in the full sample. Using these images and stacked spectra, we derive the mean stellar mass (9.4 ≤ log(M*/M⊙) ≤ 9.8), star formation rate (2.3 ≤ SFR [M⊙ yr−1] ≤ 4.5), age (2.5–4 Gyr), metallicity (12 + log(O/H) ∼ 8.3), and ionization parameter (log q [cm s−1] ∼ 7.7) for these galaxies. The average M* found is less than that of Mg ii absorbers studied in the literature. The average SFR and metallicity inferred are consistent with that expected in the main sequence and the known stellar mass–metallicity relation, respectively. High spatial resolution follow-up spectroscopic and imaging observations of this sample are imperative for probing gas flows close to the star-forming regions of high-z galaxies.

Astronomy & Astrophysics↗
DOE OSTI2022

Pilot Test of a Nanoporous, Super-hydrophobic Membrane Contactor Process for Post-combustion CO 2 Capture

GTI Energy and Air Liquide Advanced Separations (ALaS) have been developing a novel hollow fiber membrane contactor (HFMC) technology for post-combustion CO 2 capture. The process combines advantageous features of both absorption and membrane-based separation processes to separate CO 2 from flue gas cost-effectively. The key component of the HFMC technology is the super-hydrophobic, porous hollow fiber, which is made from polyether ether ketone (PEEK). Compared to conventional absorption/desorption technologies, the critical advantage of the HFMC process is the high contact surface area provided by the hollow fibers enabling an increased volumetric mass-transfer rate. In the PEEK HFMC process, the specific surface area has been increased by an order of magnitude over structurally packed or trayed columns, resulting in compact systems with small footprints.

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2024

Are Marine Low Cloud Droplet Concentrations Buffered by Entrained Aitken‐Mode Aerosol (Final Technical Report)

During the summertime, the high-latitude oceans come to life with green phytoplankton, which gain their energy from sunlight and are food for sea creatures small and large. When the phytoplankton are eaten or die, sulfur-rich gases are released under the ocean surface and mix into the air. Observations suggest that, over the Southern Ocean, frequent storms lift this air high into the atmosphere while raining out particulates like salt. As a result, the sulfur-rich air then spawns high concentrations of small ‘Aitken-mode’ aerosol particles. We hypothesize that these particles work their way down into the marine boundary layer, where they can replenish the supply of cloud-condensation nuclei scavenged by frequent precipitation. Further, this process maintains high concentrations of liquid cloud droplets in austral summer, promoting more sunlight to be reflected to space. We call this ‘Aitken buffering’. The primary objective of this project has been to document and test what role Aitken-mode aerosols play in clouds over the Southern Ocean and elsewhere. This effort has included three main components: 1) developing a computer model that realistically simulates the aerosol processes and the small-scale turbulent air motions that move aerosols around and create the clouds, 2) using that model to interpret and extend these observations for process understanding, by allowing different factors that contribute to the aerosol budget, such as surface wind speed, precipitation, surface gas exchange, etc. to be separated, and 3) studying Aitken-mode aerosol and its variability with a focus over the Southern Ocean and Antarctica, using data from Atmospheric Radiation Measurement (ARM) sites and other available observations. Initial computer studies in more idealized conditions found that elevated concentrations of Aitken-mode aerosols above the clouds could help prevent the breakup of those clouds by acting as cloud-condensation nuclei after they were entrained into the cloudy boundary layer. Simulations of a day during the ACE-ENA field campaign showed that Aitken-mode aerosols could also prevent cloud breakup under more realistic conditions. A new method that extracts information about Aitken-mode aerosols from measurements of aerosols onto which cloud droplets can form finds that Aitken-mode aerosols do vary seasonally over the Southern Ocean, with a peak in summertime, as described above. Other work during this project has focused on understanding how patterns of water vapor, clouds and precipitation are coupled within low-lying clouds over the oceans, and also on how cloud droplets cluster within clouds and how the distribution of cloud droplet sizes change as dry air is mixed into clouds, with the latter studies also using observations from ACE-ENA.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Simulated moving bed system for CO2 separation, and method of same

A system and method for separating and/or purification of CO2 gas from a CO2 feed stream is described. The system and method include a plurality of fixed sorbent beds, adsorption zones and desorption zones, where the sorbent beds are connected via valve and lines to create a simulated moving bed system, where the sorbent beds move from one adsorption position to another adsorption position, and then into one regeneration position to another regeneration position, and optionally back to an adsorption position. The system and method operate by concentration swing adsorption/desorption and by adsorptive/desorptive displacement.

Elliott, Jeannine Elizabeth↗
DOE OSTI2021

Understanding Gas Solubility of Pure Component and Binary Mixtures within Multivalent Ionic Liquids from Molecular Simulations

Understanding the molecular-level solubility of CO 2 and its mixtures is essential to the progress of gas treating technologies. Herein, we use grand canonical Monte Carlo simulations to study the single component gas absorption of SO 2 , N 2 , CH 4 , and H 2 , and binary mixtures of CO 2 /SO 2 , CO 2 /N 2 , CO 2 /CH 4 , and CO 2 /H 2 of varying mole fractions within multivalent ionic liquids (ILs). Our results highlight the importance of the free volume effect and the anion effect when interpreting the absorption behavior of these mixtures, similar to the behavior of CO 2 found in our previous study. The deviation of the gas solubility between the pure component absorption versus the binary absorption, as well as the solubility selectivity, highlight the importance of the relative affinity of gas species within a mixture to the different anions. Further, the absorption selectivity within a specific IL system can be predicted based on the relative gas affinity to the anion.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Ammonia separation from N 2 and H 2 over LTA zeolitic imidazolate framework membranes

LTA type zeolitic imidazolate framework membranes denoted as ZIF-21 were synthesized and evaluated for the separation of a commodity chemical, ammonia, from nitrogen and hydrogen. Membranes were grown using secondary seeded growth. Ammonia permeances were as high as 1727 GPU, with NH 3 /N 2 , and NH 3 /H 2 ideal selectivities of 35, and 12 respectively. ZIF-21 membranes were also evaluated for gas mixtures composed of 13.8:86.2 NH 3 /N 2 and NH 3 /H 2 , with mixture separation selectivities as high as 7.6 for NH 3 /N 2 . Differences in adsorption, and diffusivities were identified as the key separation mechanisms. Specifically, for both gas pairs the polar-polar interaction between ammonia and the linker polar channels, led to the preferential adsorption of ammonia, and therefore favored thermodynamically the separation of ammonia from nitrogen and hydrogen. In addition, for NH 3 /N 2 gas pair, differences in diffusivities was a contributing separation mechanism. For NH 3 /H 2 gas pair, due to the faster hydrogen diffusivity, the kinetic contribution was a strong competing separation mechanism.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Self-Adjusting Metal–Organic Framework for Efficient Capture of Trace Xenon and Krypton

The capture of the xenon and krypton from nuclear reprocessing off-gas is essential to the treatment of radioactive waste. Although various porous materials have been employed to capture Xe and Kr, the development of high-performance adsorbents capable of trapping Xe/Kr at very low partial pressure as in the nuclear reprocessing off-gas conditions remains challenging. Herein, we report a self-adjusting metal-organic framework based on multiple weak binding interactions to capture trace Xe and Kr from the nuclear reprocessing off-gas. The self-adjusting behavior of ATC-Cu and its mechanism have been visualized by the in-situ single-crystal X-ray diffraction studies and theoretical calculations. The self-adjusting behavior endows ATC-Cu unprecedented uptake capacities of 2.65 and 0.52 mmol g -1 for Xe and Kr respectively at 0.1 bar and 298 K, as well as the record Xe capture capability from the nuclear reprocessing off-gas. Further, our work not only provides a benchmark Xe adsorbent but proposes a new route to construct smart materials for efficient separations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Polymeric membranes for CO 2 separation and capture

Over the past decade, CO 2 separation and capture have become the new bandwagon for polymer science and membrane research. This review presents the fundamentals of CO 2 /gas separation in polymeric membranes and discusses how these principles underpin opportunities and challenges for post-combustion carbon capture (CO 2 /N 2 ), hydrogen purification (CO 2 /H 2 ), and natural gas and biogas sweetening (CO 2 /CH 4 ). Emerging polymeric membrane materials are discussed, including a few polymers containing a high content of polar functional groups (i.e., ether oxygen-rich polymers and polymeric ionic liquids), shape-persisting glassy polymers (i.e., perfluoropolymers, thermally rearranged polymers, iptycene-containing polymers), and reactive polymers featuring facilitated transport. Moreover, the promising candidates for each CO 2 separation application are highlighted. Lastly, the permeability-selectivity data reviewed were plotted against their 2008 and 2019 upper bounds.

08 HYDROGEN↗