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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 505 records · Page 28

Regenerative Fuel Cell Test Rig Completed and Operational at Glenn Research Center

The NASA Glenn Research Center has completed construction of its first closed-cycle hydrogen-oxygen regenerative fuel cell (RFC). The RFC is an electrochemical system that collects and stores solar energy during the day then releases that energy at night, thus making the Sun's energy available all 24 hours. It consists of a dedicated hydrogen-oxygen fuel cell stack and an electrolyzer stack, the interconnecting plumbing and valves, cooling pumps, water transfer pumps, gas recirculation pumps, phase separators, storage tanks for oxygen (O2) and hydrogen (H2), heat exchangers, isolation valves, pressure regulators, nitrogen purge provisions, instrumentation, and other components. It includes all the equipment required to (1) absorb electrical power from an outside source and store it as pressurized hydrogen and oxygen and (2) make electrical power from the stored gases, saving the product water for reuse during the next cycle.

Bents, David J.↗

Low-Pt-Content Anode Catalyst for Direct Methanol Fuel Cells

Combinatorial experiments have led to the discovery that a nanophase alloy of Pt, Ru, Ni, and Zr is effective as an anode catalyst material for direct methanol fuel cells. This discovery has practical significance in that the electronic current densities achievable by use of this alloy are comparable or larger than those obtained by use of prior Pt/Ru catalyst alloys containing greater amounts of Pt. Heretofore, the high cost of Pt has impeded the commercialization of direct methanol fuel cells. By making it possible to obtain a given level of performance at reduced Pt content (and, hence, lower cost), the discovery may lead to reduction of the economic impediment to commercialization.

Narayanan, Sekharipuram↗

Fuel-Cell Power Systems Incorporating Mg-Based H2 Generators

Two hydrogen generators based on reactions involving magnesium and steam have been proposed as means for generating the fuel (hydrogen gas) for such fuel-cell power systems as those to be used in the drive systems of advanced motor vehicles. The hydrogen generators would make it unnecessary to rely on any of the hydrogen storage systems developed thus far that are, variously, too expensive, too heavy, too bulky, and/or too unsafe to be practical. The two proposed hydrogen generators are denoted basic and advanced, respectively. In the basic hydrogen generator (see figure), steam at a temperature greater than or equals 330 C would be fed into a reactor charged with magnesium, wherein hydrogen would be released in the exothermic reaction Mg + H2O yields MgO + H2. The steam would be made in a flash boiler. To initiate the reaction, the boiler could be heated electrically by energy borrowed from a storage battery that would be recharged during normal operation of the associated fuel-cell subsystem. Once the reaction was underway, heat from the reaction would be fed to the boiler. If the boiler were made an integral part of the hydrogen-generator reactor vessel, then the problem of transfer of heat from the reactor to the boiler would be greatly simplified. A pump would be used to feed water from a storage tank to the boiler.

Kindler, Andrew↗

Investigation of Ruthenium Dissolution in Advanced Membrane Electrode Assemblies for Direct Methanol Based Fuel Cells Stacks

This viewgraph presentation gives a detailed review of the Direct Methanol Based Fuel Cell (DMFC) stack and investigates the Ruthenium that was found at the exit of the stack. The topics include: 1) Motivation; 2) Pathways for Cell Degradation; 3) Cell Duration Testing; 4) Duration Testing, MEA Analysis; and 5) Stack Degradation Analysis.

Direct Methanol Fuel Cells, (DMFC)↗

Study of component technologies for fuel cell on-site integrated energy system. Volume 2: Appendices

This data base catalogue was compiled in order to facilitate the analysis of various on site integrated energy system with fuel cell power plants. The catalogue is divided into two sections. The first characterizes individual components in terms of their performance profiles as a function of design parameters. The second characterizes total heating and cooling systems in terms of energy output as a function of input and control variables. The integrated fuel cell systems diagrams and the computer analysis of systems are included as well as the cash flows series for baseline systems.

Lee, W. D.↗

Cathode catalysts for primary phosphoric acid fuel cells

Alkylation or carbon Vulcan XC-72, the support carbon, was shown to provide the most stable bond type for linking cobalt dehydrodibenzo tetraazannulene (CoTAA) to the surface of the carbon; this result is based on data obtained by cyclic voltammetry, pulse voltammetry and by release of 14C from bonded CoTAA. Half-cell tests at 100 C in 85% phosphoric acid showed that CoTAA bonded to the surface of carbon (Vulcan XC-72) via an alkylation procedure is a more active catalyst than is platinum based on a factor of two improvement in Tafel slope; dimeric CoTAA had catalytic activity equal to platinum. Half-cell tests also showed that bonded CoTAA catalysts do not suffer a loss in potential when air is used as a fuel rather than oxygen. Commercially available polytetrafluroethylene (PTFE) was shown to be unstable in the fuel cell environment with degradation occurring in 2000 hours or less. The PTFE was stressed at 200 C in concentrated phosphoric acid as well as electrochemically stressed in 150 C concentrated phosphoric acid; the surface chemistry of PTFE was observed to change significantly. Radiolabeled PTFE was prepared and used to verify that such chemical changes also occur in the primary fuel cell environment.

Source record↗

Evaluation Studies of Solid Oxide-Based Fuel Cells for Light-Weight Electrical Power in Aviation: Concepts and Opportunities for the Application of Additive Manufacturing

Currently NASA is investigating the feasibility of hybrid-electric, solid oxide fuel cell power (SOFC) systems for generating electrical power for airborne propulsion and secondary/auxiliary power. As part of this project, researchers are investigating the performance of SOFC hardware in aviation-like environments, to establish the barriers, and potential suitability, of this technology. Immediate findings indicate the unsuitability of current SOFC stack architectures with regards to ease of manufacture, specific energy, as well as environmental and mechanical durability. One possible solution is to create light-weight high specific energy density solid oxide fuel cells. The possibility may be achievable by the use of modern processing techniques such as additive manufacturing. Here I discuss the use additive manufacturing to fabricate ceramic anode, electrolytes, and cathode cells supported on various metal foams with predicted performance based upon variable porosities

Goldsby, Jon C.↗

Balloon Fuel Cell Power System

NASA Lewis Research Center's Electrochemical Technology Branch has teamed with the NASA Wallops Flight Facility to demonstrate the operation of a hydrogen-oxygen proton exchange membrane (PEM) fuel cell for application in the upper atmosphere. NASA Wallops' Balloon Programs Branch has a requirement for a high-power, long-duration power system for use on a scientific balloon platform. The current power system will not meet these needs. The objective of this program is to deliver a 200-W (minimum) fuel cell system that can deliver approximately 10 kWh of electrical energy.

Source record↗