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NASA NTRS2017

Reduced Order Modeling of SLS Liquid Hydrogen Pre-Valve Flow Guide to Enable Rapid Transient Analysis

NASA is developing a new launch vehicle, called the Space Launch System (SLS), which is intended on taking humans out of low earth orbit to destinations including the moon, asteroids, and Mars. The propulsion system for the core stage of this vehicle includes four RS-25 Liquid Hydrogen/Oxygen rocket engines. These engines are upgraded versions of the Space Shuttle Main Engines (SSME); the upgrades include higher power levels and affordability enhancements. As with any new vehicle, the Main Propulsion System (MPS), which include the feedlines and ancillary hardware connecting the engines to the fuel and oxidizer tanks, had to be redesigned (figure 1 - export clearance in progress), as the previous MPS for the SSME's was inherently part of the Space Shuttle System, which had a completely different overall configuration.

Brown, Andrew M.↗

NASA NTRS2018

Exploration Medical Capability System Engineering Overview

Deep Space Gateway and Transport missions will change the way NASA currently practices medicine. The missions will require more autonomous capability compared to current low Earth orbit operations. For the medical system, lack of consumable resupply, evacuation opportunities, and real-time ground support are key drivers toward greater autonomy. Recognition of the limited mission and vehicle resources available to carry out exploration missions motivates the Exploration Medical Capability (ExMC) Element's approach to enabling the necessary autonomy. The ExMC Systems Engineering team's mission is to "Define, develop, validate, and manage the technical system design needed to implement exploration medical capabilities for Mars and test the design in a progression of proving grounds." The Element's work must integrate with the overall exploration mission and vehicle design efforts to successfully provide exploration medical capabilities. ExMC is using Model-Based System Engineering (MBSE) to accomplish its integrative goals. The MBSE approach to medical system design offers a paradigm shift toward greater integration between vehicle and the medical system, and directly supports the transition of Earth-reliant ISS operations to the Earth-independent operations envisioned for Mars. This talk will discuss how ExMC is using MBSE to define operational needs, decompose requirements and architecture, and identify medical capabilities needed to support human exploration. How MBSE is being used to integrate across disciplines and NASA Centers will also be described. The medical system being discussed in this talk is one system within larger habitat systems. Data generated within the medical system will be inputs to other systems and vice versa. This talk will also describe the next steps in model development that include: modeling the different systems that comprise the larger system and interact with the medical system, understanding how the various systems work together, and developing tools to support trade studies.

Mindock, J.↗

NASA NTRS2018

Exploration Medical Cap Ability System Engineering Overview

McGuire, K.↗

NASA NTRS1977

A real-time digital computer program for the simulation of automatic spacecraft reentries

The automatic reentry flight dynamics simulator, a nonlinear, six-degree-of-freedom simulation, digital computer program, has been developed. The program includes a rotating, oblate earth model for accurate navigation calculations and contains adjustable gains on the aerodynamic stability and control parameters. This program uses a real-time simulation system and is designed to examine entries of vehicles which have constant mass properties whose attitudes are controlled by both aerodynamic surfaces and reaction control thrusters, and which have automatic guidance and control systems. The program has been used to study the space shuttle orbiter entry. This report includes descriptions of the equations of motion used, the control and guidance schemes that were implemented, the program flow and operation, and the hardware involved.

Kaylor, J. T.↗

NASA NTRS2008

Pre-Launch Algorithms and Risk Reduction in Support of the Geostationary Lightning Mapper for GOES-R and Beyond

The Geostationary Lightning Mapper (GLM) is a single channel, near-IR imager/optical transient event detector, used to detect, locate and measure total lightning activity over the full-disk as part of a 3-axis stabilized, geostationary weather satellite system. The next generation NOAA Geostationary Operational Environmental Satellite (GOES-R) series with a planned launch in 2014 will carry a GLM that will provide continuous day and night observations of lightning from the west coast of Africa (GOES-E) to New Zealand (GOES-W) when the constellation is fUlly operational. The mission objectives for the GLM are to 1) provide continuous, full-disk lightning measurements for storm warning and nowcasting, 2) provide early warning of tornadic activity, and 3) accumulate a long-term database to track decadal changes of lightning. The GLM owes its heritage to the NASA Lightning Imaging Sensor (1997-Present) and the Optical Transient Detector (1995-2000), which were developed for the Earth Observing System and have produced a combined 13 year data record of global lightning activity. Instrument formulation studies were completed in March 2007 and the implementation phase to develop a prototype model and up to four flight models is expected to be underway in the latter part of 2007. In parallel with the instrument development, a GOES-R Risk Reduction Team and Algorithm Working Group Lightning Applications Team have begun to develop the Level 2 ground processing algorithms and applications. Proxy total lightning data from the NASA Lightning Imaging Sensor on the Tropical Rainfall Measuring Mission (TRMM) satellite and regional test beds (e.g., Lightning Mapping Arrays in North Alabama and the Washington DC Metropolitan area)

Goodman, Steven J.↗

NASA NTRS2008

Geostationary Lightning Mapper for GOES-R and Beyond

The Geostationary Lightning Mapper (GLM) is a single channel, near-IR imager/optical transient event detector, used to detect, locate and measure total lightning activity over the full-disk as part of a 3-axis stabilized, geostationary weather satellite system. The next generation NOAA Geostationary Operational Environmental Satellite (GOES-R) series with a planned launch readiness in December 2014 will carry a GLM that will provide continuous day and night observations of lightning from the west coast of Africa (GOES-E) to New Zealand (GOES-W) when the constellation is fUlly operational. The mission objectives for the GLM are to 1) provide continuous, full-disk lightning measurements for storm warning and nowcasting, 2) provide early warning of tornadic activity, and 3) accumulate a long-term database to track decadal changes of lightning. The GLM owes its heritage to the NASA Lightning Imaging Sensor (1997-Present) and the Optical Transient Detector (1995-2000), which were developed for the Earth Observing System and have produced a combined 13 year data record of global lightning activity. Instrument formulation studies were completed in March 2007 and the implementation phase to develop a prototype model and up to four flight models will be underway in the latter part of 2007. In parallel with the instrument development, a GOES-R Risk Reduction Team and Algorithm Working Group Lightning Applications Team have begun to develop the Level 2 algorithms and applications. Proxy total lightning data from the NASA Lightning Imaging Sensor on the Tropical Rainfall Measuring Mission (TRMM) satellite and regional test beds (e.g., Lightning Mapping Arrays in North Alabama and the Washington DC Metropolitan area) are being used to develop the pre-launch algorithms and applications, and also improve our knowledge of thunderstorm initiation and evolution. Real time lightning mapping data are being provided in an experimental mode to selected National Weather Service (NWS) forecast offices in Southern and Eastern Region. This effort is designed to help improve our understanding of the application of these data in operational settings.

Goodman, Steven J.↗

NASA NTRS2008

Pre-Launch Algorithms and Risk Reduction in Support of the Geostationary Lightning Mapper for GOES-R and Beyond

The Geostationary Lightning Mapper (GLM) is a single channel, near-IR optical transient event detector, used to detect, locate and measure total lightning activity over the full-disk as part of a 3-axis stabilized, geostationary weather satellite system. The next generation NOAA Geostationary Operational Environmental Satellite (GOES-R) series with a planned launch in 2014 will carry a GLM that will provide continuous day and night observations of lightning from the west coast of Africa (GOES-E) to New Zealand (GOES-W) when the constellation is fully operational. The mission objectives for the GLM are to 1) provide continuous,full-disk lightning measurements for storm warning and Nowcasting, 2) provide early warning of tornado activity, and 3) accumulate a long-term database to track decadal changes of lightning. The GLM owes its heritage to the NASA Lightning Imaging Sensor (1997-Present) and the Optical Transient Detector (1995-2000), which were developed for the Earth Observing System and have produced a combined 13 year data record of global lightning activity. Instrument formulation studies were completed in March 2007 and the implementation phase to develop a prototype model and up to four flight units is expected to begin in latter part of the year. In parallel with the instrument development, a GOES-R Risk Reduction Team and Algorithm Working Group Lightning Applications Team have begun to develop the Level 2B algorithms and applications. Proxy total lightning data from the NASA Lightning Imaging Sensor on the Tropical Rainfall Measuring Mission (TRMM) satellite and regional test beds (e.g., Lightning Mapping Arrays in North Alabama and the Washington DC Metropolitan area) are being used to develop the pre-launch algorithms and applications, and also improve our knowledge of thunderstorm initiation and evolution. Real time lightning mapping data provided to selected National Weather Service forecast offices in Southern and Eastern Region are also improving our understanding of the application of these data in the severe storm warning process and help to accelerate the development of the pre-launch algorithms and Nowcasting applications.

Goodman, Steven↗

NASA NTRS2008

Pre-Launch Algorithms and Risk Reduction in Support of the Geostationary Lightning Mapper for GOES-R and Beyond

The Geostationary Lightning Mapper (GLM) is a single channel, near-IR optical transient event detector, used to detect, locate and measure total lightning activity over the full-disk as part of a 3-axis stabilized, geostationary weather satellite system. The next generation NOAA Geostationary Operational Environmental Satellite (GOES-R) series with a planned launch in 2014 will carry a GLM that will provide continuous day and night observations of lightning from the west coast of Africa (GOES-E) to New Zealand (GOES-W) when the constellation is fully operational.The mission objectives for the GLM are to 1) provide continuous,full-disk lightning measurements for storm warning and Nowcasting, 2) provide early warning of tornadic activity, and 3) accumulate a long-term database to track decadal changes of lightning. The GLM owes its heritage to the NASA Lightning Imaging Sensor (1997-Present) and the Optical Transient Detector (1995-2000), which were developed for the Earth Observing System and have produced a combined 13 year data record of global lightning activity. Instrument formulation studies were completed in March 2007 and the implementation phase to develop a prototype model and up to four flight units is expected to begin in latter part of the year. In parallel with the instrument development, a GOES-R Risk Reduction Team and Algorithm Working Group Lightning Applications Team have begun to develop the Level 2B algorithms and applications. Proxy total lightning data from the NASA Lightning Imaging Sensor on the Tropical Rainfall Measuring Mission (TRMM) sate]lite and regional test beds (e.g., Lightning Mapping Arrays in North Alabama and the Washington DC Metropolitan area) are being used to develop the pre-launch algorithms and applications, and also improve our knowledge of thunderstorm initiation and evolution. Real time lightning mapping data provided to selected National Weather Service forecast offices in Southern and Eastern Region are also improving our understanding of the application of these data in the severe storm warning process and help to accelerate the development of the pre-launch algorithms and Nowcasting applications. Abstract for the 3 rd Conference on Meteorological

Goodman, Steven↗

NASA NTRS2016

Lighting Condition Analysis for Mars Moon Phobos

A manned mission to Phobos may be an important precursor and catalyst for the human exploration of Mars, as it will fully demonstrate the technologies for a successful Mars mission. A comprehensive understanding of Phobos' environment such as lighting condition and gravitational acceleration are essential to the mission success. The lighting condition is one of many critical factors for landing zone selection, vehicle power subsystem design, and surface mobility vehicle path planning. Due to the orbital characteristic of Phobos, the lighting condition will change dramatically from one Martian season to another. This study uses high fidelity computer simulation to investigate the lighting conditions, specifically the solar radiation flux over the surface, on Phobos. Ephemeris data from the Jet Propulsion Laboratory (JPL) DE405 model was used to model the state of the Sun, the Earth, and Mars. An occultation model was developed to simulate Phobos' self-shadowing and its solar eclipses by Mars. The propagated Phobos' state was compared with data from JPL's Horizon system to ensure the accuracy of the result. Results for Phobos lighting condition over one Martian year are presented in this paper, which include length of solar eclipse, average solar radiation intensity, surface exposure time, total maximum solar energy, and total surface solar energy (constrained by incident angle). The results show that Phobos' solar eclipse time changes throughout the Martian year with the maximum eclipse time occurring during the Martian spring and fall equinox and no solar eclipse during the Martian summer and winter solstice. Solar radiation intensity is close to minimum at the summer solstice and close to maximum at the winter solstice. Total surface exposure time is longer near the north pole and around the anti- Mars point. Total maximum solar energy is larger around the anti-Mars point. Total surface solar energy is higher around the anti-Mars point near the equator. The results from this study and others like it will be important in determining landing site selection, vehicle system design and mission operations for the human exploration of Phobos and subsequently Mars.

Li, Zu Qun↗

NASA NTRSDate not supplied

From CMS to the U.S. Greenhouse Gas Center – Improved Tracking of Recent Changes in Co 2 and Ch 4 From NASA’s Quasi-Operational Modeling Systems

Reliable, low latency delivery of high quality global flux and concentration information is a growing but still unmet need to advance expanding measurement, monitoring, reporting, and verification efforts that underpin federal climate mitigation strategies. Here we present on progress toward developing space-based greenhouse gas (GHG) monitoring systems that can provide comprehensive information trailing real time by a matter of weeks to a few months. Through support from its Carbon Monitoring System (CMS) program, NASA has developed the capability to assimilate XCO 2 retrievals from the Orbiting Carbon Observatory, 2 (OCO 2 ) into the Goddard Earth Observing System (GEOS) Constituent Data Assimilation System (CoDAS) to create gap-filled, three-dimensional (3D) estimates of CO 2 mixing ratio. When observations are unavailable, concentration fields are further informed by observationally-informed bottom-up flux packages that incorporate remotely sensed fire, nighttime lights, and vegetation observations combined with estimates of atmospheric growth rate based on surface in situ data. The 3D nature of these datasets supports evaluation with independent aircraft data to improve confidence in satellite data, development of new regional modeling approaches, and quantification of the climate impacts of GHGs. The system has recently been expanded to assimilate XCH 4 from ESA’s TROPOspheric Monitoring Instrument (TROPOMI) instrument and is supported by companion efforts to improve delivery of estimates of bottom-up land and ocean fluxes. The quasi-operational GEOS-GHG system is contributing to the recently announced U.S. Greenhouse Gas Center (GHG Center) by delivering information on recent changes in CO 2 and CH 4 emissions and concentrations to support stakeholder and research communities. In this presentation, we provide an overview of the current system configured to support the GHG Center. We highlight examples of how this data contributes to broader NASA initiatives including the Earth Information Center, an innovative virtual and physical exhibit designed to show how NASA data helps the nation combat climate change. We conclude by discussing how innovations in CMS research can address remaining data gaps and modeling challenges to advance operational GHG monitoring in the future.

Lesley Ott↗

NASA NTRSDate not supplied

Progress Toward Evaluating Roughness-Resolved Aerothermodynamic Simulations for the Mars Sample Return Earth Entry System

This work pursues the efficient Navier-Stokes simulation, using NASA’s standard LAURA and DPLR simulation tools, of the flowfield and convective heating resulting from the patterned-roughness surface of the Mars Sample Return (MSR) Earth Entry System (EES). This type of simulation has been infeasible for past NASA missions. However, for EES, the combination of a patterned roughness heatshield approximated with a sinusoidal pattern, the zero degrees angle of attack nominal flow, and the supersonic boundary layer edge Mach number, all combine to make these roughness resolved grid simulations feasible. The patterned roughness and zero degrees angle of attack nominal flow allow the simulation domain to be reduced to a thin axial flowfield slice that captures a minimum of single period of the roughness pattern. With a periodic boundary condition applied along the boundaries of this slice, simulation on the reduced domain is identical to the full domain but with significant cost saving. The supersonic boundary layer edge Mach number prevents the upstream influence, which allows the smooth stagnation region to be frozen. This freezing of the stagnation region flow is required because of the numerical instability resulting from the tight spacing of the grid in the axial direction as the stagnation point is approached. Applying the developed analysis approach to a peak heating EES case results in a roughness augmentation factor for the convective heating of 1.32, which agrees well with correlations that predict values between 1.30 and 1.37. Analysis approach developed in this work provides the framework for future studies of turbulence modeling impacts and the influence of an ablating surface.

Earth Entry System↗

NASA NTRS2023

Overview of the NASA Spacecraft Trade Modeling System (NSTRDMS), A Rapid Mission Analysis Tool

A rapid mission analysis tool is developed to support the ongoing design of the Lunar Transit trajectory of the Power and Propulsion Element (PPE). A 50-kW class electric propulsion system is envisioned to transit a massive vehicle be-tween a Medium Earth Orbit (MEO) parking orbit and a lunar L2 southern Near Rectilinear Halo Orbit (NRHO). A parameterization is developed by which the Lunar Transit can be analyzed in the context of varying vehicle mass, solar elec-tric propulsion (SEP) configurations, and solar array power output. A rapid and novel mission analysis tool enables a wide array of these trade analyses to be completed without the need for extensive computing resources or time. This tool is shown to be useful in the analysis of a reference trajectory, where changes to the baseline vehicle architecture or off-nominal operational scenarios (such as electric thruster failures) can be rapidly assessed by the mission designer.

Low thrust↗

NASA NTRS1981

Integrated propulsion for near-Earth space missions. Volume 1: Executive summary

Tradeoffs between electric propulsion system mass ratio and transfer time from LEO to GEO were conducted parametrically for various thruster efficiency, specific impulse, and other propulsion parameters. A computer model was developed for performing orbit transfer calculations which included the effects of aerodynamic drag, radiation degradation, and occultation. The tradeoff results showed that thruster technology areas for integrated propulsion should be directed towards improving primary thruster efficiency in the range from 1500 to 2500 seconds, and be continued towards reducing specific mass. Comparison of auxiliary propulsion systems showed large total propellant mass savings with integrated electric auxiliary propulsion. Stationkeeping is the most demanding on orbit propulsion requirement. At area densities above 0.5 sq m/kg, East-West stationkeeping requirements from solar pressure exceed North-South stationkeeping requirements from gravitational forces. A solar array pointing strategy was developed to minimize the effects of atmospheric drag at low altitude, enabling electric propulsion to initiate orbit transfer at Shuttle's maximum cargo carrying altitude. Gravity gradient torques are used during ascent to sustain the spacecraft roll motion required for optimum solar array illumination. A near optimum cover glass thickness of 6 mils was established for LEO to GEO transfer.

Dailey, C. L.↗

NASA NTRS1993

LDEF materials overview

The flight and retrieval of the National Aeronautics and Space Administration's Long Duration Exposure Facility (LDEF) provided an opportunity for the study of the low-Earth orbit (LEO) environment and long-duration space environmental effects (SEE) on materials that is unparalleled in the history of the U.S. Space Program. The 5-year, 9-month flight of LDEF greatly enhanced the potential value of all materials on LDEF to the international SEE community, compared to that of the original 1-year flight plan. The remarkable flight attitude stability of LDEF enables specific analyses of individual and combined effects of LEO environmental parameters on identical materials on the same space vehicle. NASA recognized this potential by forming the LDEF Space Environmental Effects on Materials Special Investigation Group (MSIG) to address the greatly expanded materials and LEO space environment analysis opportunities available in the LDEF structure, experiment trays, and corollary measurements so that the combined value of all LDEF materials data to current and future space missions will be addressed and documented. An overview of the interim LDEF materials findings of the principal investigators and the Materials Special Investigation Group is provided. These revelations are based on observations of LEO environmental effects on materials made in space during LDEF retrieval and during LDEF tray deintegration at the Kennedy Space Center, and on findings of approximately 1.5 years of laboratory analyses of LDEF materials by the LDEF materials scientists. These findings were extensively reviewed and discussed at the MSIG-sponsored LDEF Materials Workshop '91. The results are presented in a format that categorizes the revelations as 'clear findings' or 'obscure preliminary findings' (and progress toward their resolution), plus resultant needs for new space materials developments and ground simulation testing/analytical modeling, in seven categories: materials/environmental parameters and data bases; LDEF contamination; thermal control coatings and protective treatments; polymers and films; polymer-matrix composites; metals, ceramics, and optical materials; and systems-related materials. The utilization of LDEF materials data for future low-Earth orbit missions is also discussed, concentrating on Space Station Freedom. In general, the LDEF data is remarkably consistent; LDEF will provide a 'benchmark' for materials design data bases for satellites in low-Earth orbit. Some materials were identified to be encouragingly resistant to LEO SEE for 5.8-years; other 'space qualified' materials displayed significant environmental degradation. General contamination levels on LDEF were low, but molecular contamination was widespread; LDEF offers an unprecedented opportunity to provide a unified perspective of unmanned LEO spacecraft contamination mechanisms. New material development requirements for long-term LEO missions were identified and current ground simulation testing methods/data for new, durable materials concepts can be validated with LDEF results. LDEF findings are already being integrated into the design of Space Station Freedom.

Stein, Bland A.↗

NASA NTRS2009

A Multiscale Modeling System: Developments, Applications, and Critical Issues

The foremost challenge in parameterizing convective clouds and cloud systems in large-scale models are the many coupled dynamical and physical processes that interact over a wide range of scales, from microphysical scales to the synoptic and planetary scales. This makes the comprehension and representation of convective clouds and cloud systems one of the most complex scientific problems in Earth science. During the past decade, the Global Energy and Water Cycle Experiment (GEWEX) Cloud System Study (GCSS) has pioneered the use of single-column models (SCMs) and cloud-resolving models (CRMs) for the evaluation of the cloud and radiation parameterizations in general circulation models (GCMs; e.g., GEWEX Cloud System Science Team 1993). These activities have uncovered many systematic biases in the radiation, cloud and convection parameterizations of GCMs and have led to the development of new schemes (e.g., Zhang 2002; Pincus et al, 2003; Zhang and Wu 2003; Wu et al. 2003; Liang and Wu 2005; Wu and Liang 2005, and others). Comparisons between SCMs and CRMs using the same large-scale forcing derived from field campaigns have demonstrated that CRMs are superior to SCMs in the prediction of temperature and moisture tendencies (e.g., Das et al. 1999; Randall et al 2003b; Xie et al. 2005).

Tao, Wei-Kuo↗

NASA NTRS2002

Thermal Examination of an Orbiting Cryogenic Fuel Depot

For many years NASA has been interested in the storage and transfer of cryogenic fuels in space. Lunar, L2 and other chemical propulsive space vehicle missions now have staged refueling needs that a fuel depot would satisfy. The depot considered is located in lower earth orbit. Many considerations must go into designing and building such a station. Multi-layer insulation systems, thermal shielding and low conductive structural supports are the principal means of protecting the system from excessive heat loss due to boiloff. This study focuses on the thermal losses associated with storing LH2 in a passively cooled fuel depot in a lower earth equatorial orbit. The corresponding examination looks at several configurations of the fuel depot. An analytical model has been developed to determine the thermal advantages and disadvantages of three different fuel depot configurations. Each of the systems consists of three Boeing rocket bodies arranged in various configurations. The first two configurations are gravity gradient stabilized while the third one is a spin-stabilized concept. Each concept was chosen for self-righting capabilities as well as the fuel settling capabilities, however the purpose of this paper is to prove which of the three concepts is the most efficient passively cooled system. The specific areas to be discussed are the heating time from the fusion temperature to the vaporization temperature and the amount of boiloff for a specific number of orbits. Each of the previous points is compared using various sun exposed surface areas of the tanks.

Hull, Patrick V.↗

NASA NTRS1995

Ca-Rich Carbonate Melts: A Regular-Solution Model, with Applications to Carbonatite Magma + Vapor Equilibria and Carbonate Lavas on Venus

A thermochemical model of the activities of species in carbonate-rich melts would be useful in quantifying chemical equilibria between carbonatite magmas and vapors and in extrapolating liquidus equilibria to unexplored PTX. A regular-solution model of Ca-rich carbonate melts is developed here, using the fact that they are ionic liquids, and can be treated (to a first approximation) as interpenetrating regular solutions of cations and of anions. Thermochemical data on systems of alkali metal cations with carbonate and other anions are drawn from the literature; data on systems with alkaline earth (and other) cations and carbonate (and other) anions are derived here from liquidus phase equilibria. The model is validated in that all available data (at 1 kbar) are consistent with single values for the melting temperature and heat of fusion for calcite, and all liquidi are consistent with the liquids acting as regular solutions. At 1 kbar, the metastable congruent melting temperature of calcite (CaCO3) is inferred to be 1596 K, with (Delta)bar-H(sub fus)(calcite) = 31.5 +/- 1 kJ/mol. Regular solution interaction parameters (W) for Ca(2+) and alkali metal cations are in the range -3 to -12 kJ/sq mol; W for Ca(2+)-Ba(2+) is approximately -11 kJ/sq mol; W for Ca(2+)-Mg(2+) is approximately -40 kJ/sq mol, and W for Ca(2+)-La(3+) is approximately +85 kJ/sq mol. Solutions of carbonate and most anions (including OH(-), F(-), and SO4(2-)) are nearly ideal, with W between 0(ideal) and -2.5 kJ/sq mol. The interaction of carbonate and phosphate ions is strongly nonideal, which is consistent with the suggestion of carbonate-phosphate liquid immiscibility. Interaction of carbonate and sulfide ions is also nonideal and suggestive of carbonate-sulfide liquid immiscibility. Solution of H2O, for all but the most H2O-rich compositions, can be modeled as a disproportionation to hydronium (H3O(+)) and hydroxyl (OH(-)) ions with W for Ca(2+)-H3O(+) (approximately) equals 33 kJ/sq mol. The regular-solution model of carbonate melts can be applied to problems of carbonatite magma + vapor equilibria and of extrapolating liquidus equilibria to unstudied systems. Calculations on one carbonatite (the Husereau dike, Oka complex, Quebec, Canada) show that the anion solution of its magma contained an OH mole fraction of (approximately) 0.07, although the vapor in equilibrium with the magma had P(H2O) = 8.5 x P(CO2). F in carbonatite systems is calculated to be strongly partitioned into the magma (as F(-)) relative to coexisting vapor. In the Husereau carbonatite magma, the anion solution contained an F(-) mole fraction of (approximately) 6 x 10(exp -5).

Treiman, Allan H.↗

NASA NTRS2022

The Earth's Exosphere and Its Response to Space Weather

Neutral-Plasma charge exchange is a fundamental physical process that occurs ubiquitously across the universe. In geospace, charge exchange occurs in the Earth’s topside ionosphere, polar wind, plasmasphere, inner magnetosphere, and magnetosheath. Past and current space missions have profiled plasma and electromagnetic characteristics in various parts of the Earth’s magnetospheric system. However, observations of the exosphere, i.e., neutrals above 500 km altitude, are still sparse and, in some regions, non-existent, which limits our understanding of the neutral contribution to the overall dynamics of the geospace environment. Cold exospheric neutrals (< 10 eV) play an important role in the Sun-Earth interaction. Variability of exospheric density provides key information of the Earth’s atmospheric loss under dynamic space environment conditions. Various neutral species and their density variations in the polar wind can alter ion outflow patterns, modifying global magnetospheric dynamics. Exospheric neutrals also provide an energy sink for the inner magnetosphere by creating Energetic Neutral Atoms (ENAs) through charge exchange with high-energy ring current ions, which subsequently leave our geospace system unimpeded by magnetic fields. Exospheric neutrals also provide a means to observe the global interaction of the solar wind – magnetosphere, through global imaging of the system via ENAs (e.g., the TWINS and IMAGE missions) and soft X-rays (e.g., the upcoming LEXI and SMILE missions), the byproducts of neutral-plasma charge exchange. In the coming decade, we advocate that our community needs to increase our exploration of the neutral populations in the outermost reaches of the Earth’s atmosphere. It is imperative that we improve both in-situ and remote-sensing technologies for measuring key neutral species in our exosphere. We also encourage dedicated exosphere missions and to stimulate model developments of our exosphere and its interaction with the co-located magnetospheric system and neighboring Ionosphere - Thermosphere - Mesosphere system.

Hyunju Connor↗