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Results for “EVAPORATION”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 505 records · Page 28
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

Numerical modelling of evaporation in a ceramic layer in the tape casting process

Evaporation of water from a ceramic layer is a key phenomenon in the drying process for the manufacturing of tape cast ceramics. This process contains mass, momentum and energy exchange between the porous medium and the free–flow region. In order to analyze such interaction processes, a Representative Elementary Volume (REV)–scale model concept is presented for coupling non–isothermal multi–phase compositional porous–media flow and single–phase compositional laminar free–flow. The preliminary results show the typical expected evaporation behaviour from a porous medium initially saturated with water, and its transport to the free–flow region according to the existent results from the literature.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2016

Enhanced solar evaporation of water from porous media, through capillary mediated forces and surface treatment

The relative influence of the capillary, Marangoni, and hydrophobic forces in mediating the evaporation of water from carbon foam based porous media, in response to incident solar radiation, are investigated. It is indicated that inducing hydrophilic interactions on the surface, through nitric acid treatment of the foams, has a similar effect to reduced pore diameter and the ensuing capillary forces. The efficiency of water evaporation may be parameterized through the Capillary number (Ca), with a lower Ca being preferred. The proposed study is of much relevance to efficient solar energy utilization.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

Autodyne effect in a single-mode Er fibre laser and the possibility of its usage for recognising the evaporated biotissue type

The autodyne signal arising in an Er fibre laser in the course of evaporating biological models of different types is studied and the possibility of recognising the biotissue type using the method of autodyne detection of the backscattered Doppler signal is assessed. In the experiments we modelled the process of surgical intervention using the contact (hole perforation with the Er laser fibre) and noncontact (surface evaporation with the focused radiation) regimes of impact on different biological models. The amplitude – frequency characteristic of the autodyne detection for the Er fibre laser is measured and the initial spectra of the backscattered Doppler signal arising under the action of laser radiation on the samples of biological models are obtained. The experiments have shown that the spectra of the backscattered Doppler signal, arising in the course of the contact and noncontact action of the Er fibre laser on different biological models, demonstrate clear-cut distinctions. (control of laser radiation parameters)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2013

CHROMOSPHERIC EVAPORATION IN SOLAR FLARE LOOP STRANDS OBSERVED WITH THE EXTREME-ULTRAVIOLET IMAGING SPECTROMETER ON BOARD HINODE

The entire profile of the Fe XXIII line at 263.8 A, formed at temperature Almost-Equal-To 14 MK, was blueshifted by an upward velocity -122 {+-} 33 km s{sup -1} when it was first detected by the Extreme-ultraviolet Imaging Spectrometer operating in rapid cadence (11.18 s) stare mode during a C1 solar flare. The entire profile became even more blueshifted over the next two exposures, when the upward velocity reached its maximum of -208 {+-} 14 km s{sup -1} before decreasing to zero over the next 12 exposures. After that, a weak, secondary blueshifted component appeared for five exposures, reached a maximum upward velocity of -206 {+-} 33 km s{sup -1}, and disappeared after the maximum line intensity (stationary plus blueshifted) was achieved. Velocities were measured relative to the intense stationary profile observed near the flare's peak and early during its decline. The initial episode during which the entire profile was blueshifted lasted about 156 s, while the following episode during which a secondary blueshifted component was detected lasted about 56 s. The first episode likely corresponds to chromospheric evaporation in a single loop strand, while the second corresponds to evaporation in an additional strand, as described in multi-strand flare loop models proposed by Hori et al. and Warren and Doschek. Line emission from progressively cooler ions (Fe XVII, XVI, and XIV) brightened at successively later times, consistent with cooling of flare-heated plasma.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Multilayer formation and evaporation of deuterated ices in prestellar and protostellar cores

Extremely large deuteration of several molecules has been observed toward prestellar cores and low-mass protostars for a decade. New observations performed toward low-mass protostars suggest that water presents a lower deuteration in the warm inner gas than in the cold external envelope. We coupled a gas-grain astrochemical model with a one-dimensional model of a collapsing core to properly follow the formation and the deuteration of interstellar ices as well as their subsequent evaporation in the low-mass protostellar envelopes with the aim of interpreting the spatial and temporal evolutions of their deuteration. The astrochemical model follows the formation and the evaporation of ices with a multilayer approach and also includes a state-of-the-art deuterated chemical network by taking the spin states of H{sub 2} and light ions into account. Because of their slow formation, interstellar ices are chemically heterogeneous and show an increase of their deuterium fractionation toward the surface. The differentiation of the deuteration in ices induces an evolution of the deuteration within protostellar envelopes. The warm inner region is poorly deuterated because it includes the whole molecular content of ices, while the deuteration predicted in the cold external envelope scales with the highly deuterated surface of ices. We are able to reproduce the observed evolution of water deuteration within protostellar envelopes, but we are still unable to predict the super-high deuteration observed for formaldehyde and methanol. Finally, the extension of this study to the deuteration of complex organics, important for the prebiotic chemistry, shows good agreement with the observations, suggesting that we can use the deuteration to retrace their mechanisms and their moments of formation.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

PROPERTIES OF CHROMOSPHERIC EVAPORATION AND PLASMA DYNAMICS OF A SOLAR FLARE FROM IRIS OBSERVATIONS

The dynamics of hot chromospheric plasma of solar flares is a key to understanding the mechanisms of flare energy release and particle acceleration. A moderate M1.0 class flare of 2014 June 12, (SOL2014-06-12T21:12) was simultaneously observed by NASA's Interface Region Imaging Spectrograph (IRIS) and other spacecraft, and also by the New Solar Telescope at the BBSO. This paper presents the first part of our investigation focused on analysis of the IRIS data. Our analysis of the IRIS data in different spectral lines reveals a strong redshifted jet-like flow with a speed of ∼100 km s{sup −1} of the chromospheric material before the flare. Strong nonthermal emission of the C ii k 1334.5 Å line, formed in the chromosphere–corona transition region, is observed at the beginning of the impulsive phase in several small (with a size of ∼1″) points. It is also found that the C ii k line is redshifted across the flaring region before, during, and after the impulsive phase. A peak of integrated emission of the hot (1.1 · 10{sup 7} K) plasma in the Fe xxi 1354.1 Å line is detected approximately five minutes after the integrated emission peak of the lower temperature C ii k. A strong blueshift of the Fe xxi line across the flaring region corresponds to evaporation flows of the hot chromospheric plasma with a speed of 50 km s{sup −1}. Additional analysis of the RHESSI data supports the idea that the upper chromospheric dynamics observed by IRIS has features of “gentle” evaporation driven by heating of the solar chromosphere by accelerated electrons and by a heat flux from the flare energy release site.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

EVIDENCE FOR EVAPORATION-INCOMPLETE CONDENSATION CYCLES IN WARM SOLAR CORONAL LOOPS

Quasi-constant heating at the footpoints of loops leads to evaporation and condensation cycles of the plasma: thermal non-equilibrium (TNE). This phenomenon is believed to play a role in the formation of prominences and coronal rain. However, it is often discounted as being involved in the heating of warm loops because the models do not reproduce observations. Recent simulations have shown that these inconsistencies with observations may be due to oversimplifications of the geometries of the models. In addition, our recent observations reveal that long-period intensity pulsations (several hours) are common in solar coronal loops. These periods are consistent with those expected from TNE. The aim of this paper is to derive characteristic physical properties of the plasma for some of these events to test the potential role of TNE in loop heating. We analyzed three events in detail using the six EUV coronal channels of the Solar Dynamics Observatory/Atmospheric Imaging Assembly. We performed both a differential emission measure (DEM) and a time-lag analysis, including a new method to isolate the relevant signal from the foreground and background emission. For the three events, the DEM undergoes long-period pulsations, which is a signature of periodic heating even though the loops are captured in their cooling phase, as is the bulk of the active regions. We link long-period intensity pulsations to new signatures of loop heating with strong evidence for evaporation and condensation cycles. We thus simultaneously witness widespread cooling and TNE. Finally, we discuss the implications of our new observations for both static and impulsive heating models.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

TEMPORAL EVOLUTION OF CHROMOSPHERIC EVAPORATION: CASE STUDIES OF THE M1.1 FLARE ON 2014 SEPTEMBER 6 AND X1.6 FLARE ON 2014 SEPTEMBER 10

With observations from the Interface Region Imaging Spectrograph, we track the complete evolution of ∼11 MK evaporation flows in an M1.1 flare on 2014 September 6 and an X1.6 flare on 2014 September 10. These hot flows, as indicated by the blueshifted Fe xxi 1354.08 Å line, evolve smoothly with a velocity decreasing exponentially from ∼200 km s{sup −1} to almost stationary within a few minutes. We find a good correlation between the flow velocity and energy deposition rate as represented by the hard X-ray flux observed with the Reuven Ramaty High Energy Solar Spectroscopic Imager, or time derivative of the soft X-ray flux observed with the Geostationary Operational Environmental Satellites and the HINODE X-ray Telescope, which is in general agreement with models of nonthermal electron heating. The maximum blueshift of Fe xxi appears approximately at the same time as or slightly after the impulsive enhancement of the ultraviolet continuum and the Mg ii 2798.8 Å line emission, demonstrating that the evaporation flow is closely related to heating of the lower chromosphere. Finally, while the hot Fe xxi 1354.08 Å line is entirely blueshifted with no obvious rest component, cool chromospheric and transition region lines like Si iv 1402.77 Å are often not entirely redshifted but just reveal an obvious red wing enhancement at the ribbons, suggesting that the speed of chromospheric condensation might be larger than previously thought.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

Black hole evaporation in conformal gravity

We study the formation and the evaporation of a spherically symmetric black hole in conformal gravity. From the collapse of a spherically symmetric thin shell of radiation, we find a singularity-free non-rotating black hole. This black hole has the same Hawking temperature as a Schwarzschild black hole with the same mass, and it completely evaporates either in a finite or in an infinite time, depending on the ensemble. We consider the analysis both in the canonical and in the micro-canonical statistical ensembles. Last, we discuss the corresponding Penrose diagram of this physical process.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

STARSPOTS-TRANSIT DEPTH RELATION OF THE EVAPORATING PLANET CANDIDATE KIC 12557548b

Violent variation of transit depths and an ingress-egress asymmetry of the transit light curve discovered in KIC 12557548 have been interpreted as evidence of a catastrophic evaporation of atmosphere with dust ( M-dot {sub p}∼>1 M{sub ⊕} Gyr{sup –1}) from a close-in small planet. To explore what drives the anomalous atmospheric escape, we perform time-series analysis of the transit depth variation of Kepler archival data for ∼3.5 yr. We find a ∼30% periodic variation of the transit depth with P {sub 1} = 22.83 ± 0.21 days, which is within the error of the rotation period of the host star estimated using the light curve modulation, P {sub rot} = 22.91 ± 0.24 days. We interpret the results as evidence that the atmospheric escape of KIC 12557548b correlates with stellar activity. We consider possible scenarios that account for both the mass loss rate and the correlation with stellar activity. X-ray and ultraviolet (XUV)-driven evaporation is possible if one accepts a relatively high XUV flux and a high efficiency for converting the input energy to the kinetic energy of the atmosphere. Star-planet magnetic interaction is another possible scenario, though huge uncertainty remains for the mass loss rate.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2024

Improving tubular protonic ceramic fuel cell performance by compensating Ba evaporation via a Ba-excess optimized proton conducting electrolyte synthesis strategy

Protonic ceramic fuel cells (PCFCs) are emerging as a promising technology for reduced temperature ceramic energy conversion devices. The BaCe 0.4 Zr 0.4 Y 0.1 Yb 0.1 O 3–δ (BCZYYb4411) electrolyte is notable for its high proton conductivity. However, the tendency of barium to volatilize in BCZYYb4411 during high-temperature sintering compromises its chemical stability and performance. This study investigates the effects of intentionally incorporating excess barium into BCZYYb4411, formulated as Ba 1+x Ce 0.4 Zr 0.4 Y0.1Yb 0.1 O 3–δ (where x = 0, 0.1, 0.2, and 0.3), with the aim of compensating barium evaporation and enhancing the physical and chemical properties. We find that excess barium results in a greater shrinkage rate, facilitating a denser electrolyte structure. This barium-enriched electrolyte demonstrates improved electrochemical performance by effectively counteracting the deleterious effects of barium evaporation. Applying this strategy to tubular PCFCs, we achieved a peak power density of 480 mW•cm –2 at 600 °C. This unique approach provides a simple, tunable, and easy-to-implement processing modification to achieve high-performance tubular PCFC.

25 ENERGY STORAGE↗
DOE OSTI2021

Evaporation and propagation of liquid drop streams at vacuum pressures: Experiments and modeling

Evaporation of streams of liquid droplets in environments at vacuum pressures below the vapor pressure has not been widely studied. Here, experiments and simulations are reported that quantify the change in droplet diameter when a steady stream of ≈100 μm diameter drops is injected into a chamber initially evacuated to <10 –8 bar. In experiments, droplets fall through the center of a 0.8 m long liquid nitrogen cooled shroud, simulating infinity radiation and vapor mass flux boundary conditions. Furthermore, experimentally measured changes in drop diameters vary from ≈0 to 6 μm when the initial vapor pressure is increased from 10 –6 to 10 –3 bar by heating the liquid. Measured diameter changes are predicted by a model based on the Hertz-Knudsen equation. One uncertainty in the calculation is the “sticking coefficient” β. Assuming a constant β for all conditions studied here, predicted diameter changes best match measurements with β≈0.3. This value falls within the range of β reported in the literature for organic liquids. Finally, at the higher vapor pressure conditions considered here, the drop stream disperses transverse to the main flow direction. This spread is attributed to forces imparted by an absolute pressure gradient produced by the evaporating stream.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2012

Evaporation-assisted high-power impulse magnetron sputtering: The deposition of tungsten oxide as a case study

The deposition rate during the synthesis of tungsten trioxide thin films by reactive high-power impulse magnetron sputtering (HiPIMS) of a tungsten target increases, above the dc threshold, as a result of the appropriate combination of the target voltage, the pulse duration, and the amount of oxygen in the reactive atmosphere. This behavior is likely to be caused by the evaporation of the low melting point tungsten trioxide layer covering the metallic target in such working conditions. The HiPIMS process is therefore assisted by thermal evaporation of the target material.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Estimation of Evaporation Rate from Gold-Silicon Alloy Based on the Nucleation Time and Nanowire Length Distributions

Abstract—: Nanowires are one of the most promising building blocks for various nanoelectronic devices. Nanowires are usually grown via the so-called vapor-liquid-solid mechanism on the surfaces activated by the droplets of a catalyst (e.g., Au). Here we theoretically studied the impact of the evaporation from the droplet on the nucleation statistics. Within the semi-analyticalapproach, we obtain the relation between the nucleation time distributions and the evaporation rate of atoms from the droplet. We analyze the Si NW length-time dependences to estimate theeffective lifetime of a silicon atom in a gold-silicon alloy at 550°C is about 5 s.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2018

Charge Separation at the Evaporation (Condensation) Front of Water and Ice. Charging of Spherical Droplets

Charge separation at evaporation (condensation) front of water and ice is analyzed. Relatively low distribution coefficient of protons and hydroxide ions between vapor and condensed phase that is less than the distribution coefficient of water molecules leads to accumulation of protons and hydroxide ions at the phase front upon evaporation and a decrease in the amount of such species upon condensation. Interphase charge separation is caused by the subsequent diffusion of nonequilibrium protons and hydroxide ions. The charge separation is also affected by the double electric layer generated by orientation defects at the water and ice surfaces. Dependences of electric field at a plane surface of water and ice on the rate of phase transformation are calculated. Electric charges of spherical water droplets are estimated at different field strengths and droplet radii.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2013

Analysis Of 2H-Evaporator Scale Wall [HTF-13-82] And Pot Bottom [HTF-13-77] Samples

Savannah River Remediation (SRR) is planning to remove a buildup of sodium aluminosilicate scale from the 2H-evaporator pot by loading and soaking the pot with heated 1.5 M nitric acid solution. Sampling and analysis of the scale material has been performed so that uranium and plutonium isotopic analysis can be input into a Nuclear Criticality Safety Assessment (NCSA) for scale removal by chemical cleaning. Historically, since the operation of the Defense Waste Processing Facility (DWPF), silicon in the DWPF recycle stream combines with aluminum in the typical tank farm supernate to form sodium aluminosilicate scale mineral deposits in the 2H-evaporator pot and gravity drain line.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2015

Analysis of Tank 4 (FTF-4-15-22, 23) Surface and Subsurface Supernatant Samples in Support of Enrichment Control, Corrosion Control and Evaporator Feed Qualification Programs

This report provides the results of analyses on Savannah River Site Tank 4 surface and subsurface supernatant liquid samples in support of the Enrichment Control Program (ECP), the Corrosion Control Program (CCP) and the Evaporator Feed Qualification (EFQ) Program. The purpose of the ECP sample taken from Tank 4 in August 2015 was to determine if the supernatant liquid would be “acceptable feed” to the 2H and 3H evaporator systems.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2017

Enhancing Electrophoretic Display Lifetime: Thiol-Polybutadiene Evaporation Barrier Property Response to Network Microstructure

An evaporation barrier is required to enhance the lifetime of electrophoretic deposition (EPD) displays. As EPD functions on the basis of reversible deposition and resuspension of colloids suspended in a solvent, evaporation of the solvent ultimately leads to device failure. Incorporation of a thiol-polybutadiene elastomer into EPD displays enabled display lifetime surpassing six months in counting and catalyzed rigid display transition into a flexible package. Final flexible display transition to mass production compels an electronic-ink approach to encapsulate display suspension within an elastomer shell. Final thiol-polybutadiene photosensitive resin network microstructure was idealized to be dense, homogeneous, and expose an elastic response to deformation. Research at hand details an approach to understanding microstructural change within display elastomers. Polybutadiene-based resin properties are modified via polymer chain structure, with and without added aromatic urethane methacrylate difunctionality, and in measuring network response to variation in thiol and initiator concentration. Dynamic mechanical analysis results signify that cross-linked segments within a difunctionalized polybutadiene network were on average eight times more elastically active than that of linked segments within a non-functionalized polybutadiene network. Difunctionalized polybutadiene samples also showed a 2.5 times greater maximum elastic modulus than non-functionalized samples. Hybrid polymer composed of both polybutadiene chains encompassed TE-2000 stiffness and B-1000 elasticity for use in encapsulating display suspension. Later experiments measured kinetic and rheological response due to alteration in dithiol cross-linker chain length via real time Fourier transform infrared spectroscopy and real-time dynamic rheology. Distinct differences were discovered between dithiol resin systems, as maximum thiol conversion achieved in short and long chain length dithiols was 86% and 11%, respectively. Oscillatory real-time rheological experiments confirmed a more uniform network to better dissipate applied shear in short chain length dithiol systems, as long chain length dithiols relayed a steep internal stress build-up due to less cross-links and chain entanglements. Thorough understanding of network formation aids the production of a stronger and impermeable elastomeric barrier for preservation of EPD displays.

36 MATERIALS SCIENCE↗