Reaction rate of vibrationally excited hydroxyl with ozone
Reaction rate of vibrationally excited hydroxyl with ozone, obtaining hydroxyl emission spectra by Fourier transform spectroscopy
Coltharp, R. N.↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Neutral composition of the upper atmosphere of Mars as determined from the Mariner UV spectrometer experiments
Atomic oxygen and hydrogen identification in Mars upper atmospheric emission spectra by Mariner UV spectrometer, inferring carbon monoxide presence by self absorption
Thomas, G. E.↗
Composition of the upper clouds of Venus.
Recent developments have shed new light on the composition of the upper Venus clouds. An analysis of the Mariner 5 occultation data has led to improved temperature and pressure profiles. When these are combined with transit data, it is concluded that there is an optically thin cloud layer with a top at 81-km altitude where the temperature and pressure are, respectively, 175 K and 3 mb. The inclusion of temperatures derived from the near-infrared CO2 bands leads to the postulate of a second cloud deck with a top at 61-km altitude, where temperature and pressure are 260 K and 240 mb. Additional important constraints on cloud models are imposed by the measured abundances of HCl and H2O, by the polarization data, and by the reflection and emission spectra. It is concluded that the leading candidate for the uppermost clouds is liquid drops of HCl-H2O, that there is no recommended candidate for the second cloud deck, and that H2O ice is at most a minor component of these cloud systems.
Rea, D. G.↗
Study of dual-channel infrared spectroradiometer systems
A dual channel infrared spectroradiometer system was installed at a high altitude facility where spectral data were obtained from F2/H2, FLOX/CH4, FLOX/B2H6, OF2/CH4, and OF2/B2H6 propellant combinations. A good HF emission spectra was obtained for tests with the OF2B2H6 propellant combination. Subsequently, data were obtained on the LOX/GH2 propellant combination at sea level and altitude conditions that were inconsistent because the calculation of plume properties led to physically unrealistic results. The inconsistencies resulted from measurement accuracy not being within the narrow limits required by the data reduction scheme. Although the anticipated program results were not obtained, the data gathered are useful for guiding future experimental efforts and formulations of less sensitive analytical models.
Wrubel, J. A.↗
Compendium of marine luminescence signatures, part 2 (appendix C)
Chlorophyll and Gelbstoff excitation and emission spectra of sea water samples are assembled according to geographic sites from the Atlantic and Gulf coasts, the west coast, and a location north of Hawaii. Data were taken by fluorescent spectrophotometer and include also laboratory algal cultures for comparison with the sea water samples.
Hornig, A. W.↗
A study of lunar models based on Apollo and other data
The research concerned with the interpretation of lunar data developed during the Apollo Program is reported. The areas of research include: X-ray emission spectra and molecular orbitals of lunar materials, magnetic properties of lunar rock, lunar features, thermal history and evolution of the moon, and the internal constitution and evolution of the moon.
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Skylab experiments. Volume 1: Physical science, solar astronomy
The basic subject of this volume is the solar astronomy program conducted on Skylab. In addition to descriptions of the individual experiments and the principles involved in their performance, a brief description is included of the sun and the energy characteristics associated with each zone. Wherever possible, related classroom activities have been identified and discussed in some detail. It will be apparent that the relationships rest not only in the field of solar astronomy, but also in the following subjects: (1) physics - optics, electromagnetic spectrum, atomic structure, etc.; (2) chemistry - emission spectra, kinetic theory, X-ray absorption, etc.; (3) biology - radiation and dependence on the sun; (4) electronics - cathode ray tubes, detectors, photomultipliers, etc.; (5) photography; (6) astronomy; and (7) industrial arts.
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Atmospheric and surface properties of Mars obtained by infrared spectroscopy on Mariner 9.
During the almost 1-year operational lifetime of Mariner 9 the infrared spectroscopy experiment obtained data over a large portion of Mars. Between June and October 1972, improvements were made in the CO2 transmittances, which are necessary for the interpretation of the thermal emission spectra. Recently obtained spectra indicate that strong seasonal variations in the water vapor distribution occurred over both polar regions. The wettest atmospheric conditions observed so far contain 20 to 30 precipitable microns of water over the north polar cap during northern spring. A low-resolution pressure map is presented that covers that portion of the planet between latitudes -60 and +25 deg. A more detailed study of the Coprates canyon indicates that, at its lowest point, the canyon floor must be at least 5 km below the rim. Applications of tidal theory to temperature fields derived from the spectra indicate diurnal surface pressure fluctuations of as much as 12% during the Great Dust Storm of 1971-1972.
Conrath, B.↗
Long wavelength VLBI.
The application of very-long baseline interferometry (VLBI) techniques at meter and decameter wavelengths has proven to be a unique tool for studying a number of different phenomena. Because of the high angular resolution which we achieve with VLBI, candidate objects for study include the compact nuclei and 'jets' associated with quasars and radio galaxies, pulsars, small knots in galactic supernova remnants, and nonthermal planetary sources. Our investigations have been aimed at determining the emission spectra of these objects, measuring their apparent angular size, and mapping their structure. We expect that these properties will be interrelated, particularly at or below the frequencies at which their spectra peak.
Clark, T. A.↗
Radiative transitions involving the (2p2)(3 Pe) metastable autodetaching of H(-)
The absorption coefficient for the free-bound transition H (ls) + e(-)+ h omega yields H(-)(2 sq p,(3)P(e)) is calculated (together with the differential emission rate for the inverse process) using ls - 2s - 2p close coupling continuum wave functions and a Hylleraas bound state wave function. A maximum in the absorption and emission spectra is found to occur at a photon wavelength of 1219.5 A, which is 2 A closer to the Lyman alpha line than predicted by the calculations of Drake, and is in closer agreement with the stellar absorption feature identified by Heap and Stecher. The free-bound absorption process appears to be a significant source of continuous ultraviolet opacity.
Jacobs, V. L.↗
A calculational approach to electron impact excitation of ions in hot solar plasmas
The cross section requirements are presented for studying UV and X-ray emission spectra associated with active and flare-produced plasmas in the sun's corona. The general approach to the calculation of the distorted wave approximation problem is also given.
Temkin, A.↗
Are BL Lac-type objects nearby black holes
It is pointed out that isolated black holes accreting interstellar gas can account for the characteristic properties of the Lacertids. Emission spectra for various interstellar gas densities and black hole masses are compared with the data plotted by Strittmatter et al. (1972) for the BL Lac-type objects. Rough estimates indicate that there may indeed be a finite number of stellar-mass black holes close to the earth as required by the theory. If it is determined that the BL Lac-type objects lie outside of the galactic disk a black hole accretion model may still apply if certain conditions are satisfied.
Shapiro, S. L.↗
Effect of aerosol emission on the inference of trace gas concentrations from limb radiance data
This note reports on an analysis of atmospheric emission spectra in the 10-12 micron region measured with a limb-oriented balloon-borne spectrometer. Data clearly show the existence of an additional feature at 10.8 microns which is probably due to measurement contamination from aerosols. The 10.8 micron emitter has a strong reducing effect on the HNO3 mixing ratio profile as determined by application of a symmetrical band shape model to the 10.8 spectral feature.
Remsberg, E. E.↗
The interaction of hydrogen with Taurus-Littrow orange soil
A description is given of outgassing and gas interaction studies conducted with Taurus-Littrow orange soil. Scanning electron microscopy studies and X-ray emission spectra investigations are also considered. Data for the adjacent gray soil are included and compared with the results obtained for the orange soil. It is found that differences obtained for the two gases are not related to the nature of the gases evolved but only to the amounts of the gas.
Cadenhead, D. A.↗
Background
An analysis was made of the UF6 fueled gas core reactor as a function of cavity reactor criticality and fluid mechanics tests, investigations of uranium optical emission spectra, and radiant heat transfer power plant studies. Data are also given on nuclear and thermodynamic cycle analysis.
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Exciton coupling in molecular crystals
The implications of perfect exciton coupling and molecular vibrations were investigated, as well as the effect they have on the lifetime of singlet and triplet excitons coupled in a limiting geometry. Crystalline bibenzyl, Cl4Hl4, provided a situation in which these mechanisms involving exciton coupling can be studied in the limit of perfect coupling between units due to the crystal's geometry. This geometry leads to a coupling between the two halves of the molecule resulting in a splitting of the molecular excited states. The study reported involves an experimental spectroscopic approach and begins with the purification of the bibenzyl. The principal experimental apparatus was an emission spectrometer. A closed cycle cryogenic system was used to vary the temperature of the sample between 20 K and 300 K. The desired results are the temperature-dependent emission spectra of the bibenzyl; in addition, the lifetimes and quantum yields measured at each temperature reveal the effect of competing radiationless processes.
Ake, R. L.↗
Temperature sensing: The direct road to information
The retrievability of detailed temperature soundings from remote measurements of emission spectra depends not so much on how the data are treated as on what the data are. It is shown that the shape of the weighting functions depends on the nature of the pressure and temperature dependence of the transmittance, which differ from one part of the spectrum to another as well as with spectral resolution. It is shown that careful selection of channels results in much narrower weighting functions than those corresponding to channels that have actually been used.
Kaplan, L. D.↗
Theory of the intercluster medium
A set of computer models for the evolution of intercluster matter (ICM) in expanding cosmologies which includes processes of electron impact ionization/excitation, radiative and dielectronic recombination, thermal bremsstrahlung, Compton scattering, and photoionization is presented. The thermal, ionization, and excitation histories of major constituents were found as functions of time, and predictions of emission spectra, the possible distortions of the cosmic 3 K microwave background, and optical depths of absorption troughs in QSO continua at various redshifts were obtained. It is concluded that the present Friedmann cosmology can be dominated by hot intercluster matter which would contain H and He in their cosmic ratio and traces of heavier elements. For a narrow range of parameters it is possible to generate cosmologies with a closure density of ICM which do not exceed the diffuse X-ray measurements. In open cosmologies distortion of the 3 K microwave background occurs, while closed cases show negligible change from the unperturbed spectrum.
Sherman, R. D.↗