The Limited Incorporation and Role of Fluorine in Mn-rich Disordered Rocksalt Cathodes
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25 ENERGY STORAGE↗
SEARCH · Engineering Papers
Results for “ELECTROMAGNETIC RADIATION”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Evolution of 4π-Periodic Supercurrent in the Presence of an In-Plane Magnetic Field
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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Isocorrole-Loaded Polymer Nanoparticles for Photothermal Therapy under 980 nm Light Excitation
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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Technoeconomic Analysis of a Novel Microwave Process to Produce Ethylene from Methane
Ethylene is a critical feedstock in industrial processes, serving as a raw material in the petrochemical industry to produce plastics and commodity chemicals. Conventional ethylene production routes are energy-intensive and contribute substantially to the carbon footprint of chemical manufacturing. In this study, an industrial-scale novel microwave process was simulated using ASPEN Plus to assess its economic viability. Technoeconomic analysis confirmed the economic competitiveness of the novel microwave process, with a levelized cost of ethylene of USD 0.51/kg compared to USD 0.56/kg for the conventional base case. Key economic drivers of the process were identified, and sensitivity analyses were conducted to evaluate their impact on project economics. Furthermore, 87.7% of the total utility consumption in the novel microwave process is electricity, highlighting its potential to contribute to the electrification of the chemical industry. The findings of this study confirm the economic feasibility of both industrial-scale microwave reactors and modular plant configurations for the production of ethylene from methane, offering a promising alternative to conventional processes.
electromagnetic radiation↗
π-Extended Porphyrin–Phthalocyanine Heterojunction Devices Exhibiting High Ammonia Sensitivity with a Remarkable Light Effect
π-Extended porphyrins represent an attractive class of organic compounds because of their unique photophysical, optoelectronic, and physicochemical properties. Herein, cross-conjugated (Ace-PQ-Ni) and linear-conjugated (AM6) porphyrins are used to build double-layer heterojunction devices by combining them with a lutetium bisphthalocyanine complex (LuPc 2 ). The heterojunction effect at the porphyrin–phthalocyanine interface plays a key role in the charge transport properties. Both devices exhibit exceptionally high ammonia sensitivity at room temperature and under ambient relative humidity, with limit of detection values of 156 and 115 ppb for Ace-PQ-Ni/LuPc 2 and AM6/LuPc 2 sensors, respectively. Interestingly, the Ace-PQ-Ni/LuPc 2 and AM6/LuPc 2 sensors display opposite effects upon light illumination. While the former sensors show largely decreased ammonia sensitivity under light illumination, the current variation of the latter under ammonia is remarkably enhanced with a multiplication factor of 13 and a limit of detection (LOD) of 83 ppb. Here, the striking difference in their sensing properties upon light illumination is attributed to their different π-conjugation pathways (cross-conjugation versus linear conjugation).
conductometric transducer↗
Compartmentalization and Photo-Regulating Pathways for Incompatible Tandem Catalysis
This contribution describes an advanced compartmentalized micellar nanoreactor that possesses a reversible photoresponsive feature and its application towards photo-regulating reaction pathways for incompatible tandem catalysis under aqueous conditions. The smart nanoreactor is based on multi-functional amphiphilic poly(2-oxazoline)s and covalently crosslinked with spiropyran upon micelle formation in water. It responds to light irradiation in a wavelength-selective manner switching its morphology as confirmed by dynamic light scattering and cryo-transition electron microscopy. The compartmental structure renders distinct nanoconfinements for two incompatible enantioselective transformations: a rhodium-diene complex-catalyzed asymmetric 1,4-addition occurs in the hydrophilic corona while a Rh-TsDPEN-catalyzed asymmetric transfer hydrogenation proceeds in the hydrophobic core. Control experiments and kinetic studies showed that the gated behavior induced by the photo-triggered reversible spiropyran to merocyanine transition in the cross-linking layer is key to discriminate among substrates/reagents during the catalysis. Here, the smart nanoreactor realized photo-regulation to direct the reaction pathway to give a multi-chiral product with high conversions and perfect enantioselectivities in aqueous media. Our SCM catalytic system, on a basic level, mimics the concepts of compartmentalization and responsiveness Nature uses to coordinate thousands of incompatible chemical transformations into streamlined metabolic processes.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
A Donor–Acceptor [2]Catenane for Visible Light Photocatalysis
Colored charge-transfer complexes can be formed by the association between electron-rich donor and electron-deficient acceptor molecules, bringing about the narrowing of HOMO–LUMO energy gaps so that they become capable of harnessing visible light. In an effort to facilitate the use of these widespread, but nonetheless weak, interactions for visible light photocatalysis, it is important to render the interactions strong and robust. Furthermore, we employ a well-known donor–acceptor [2]catenane—formed by the mechanical interlocking of cyclobis(paraquat-p-phenylene) and 1,5-dinaphtho[38]crown-10—in which the charge-transfer interactions between two 4,4'-bipyridinium and two 1,5-dioxynaphthalene units are enhanced by mechanical bonding, leading to increased absorption of visible light, even at low concentrations in solution. As a result, since this [2]catenane can generate persistent bipyridinium radical cations under continuous visible-light irradiation without the need for additional photosensitizers, it can display good catalytic activity in both photo-reductions and -oxidations, as demonstrated by hydrogen production—in the presence of platinum nanoparticles—and aerobic oxidation of organic sulfides, such as l-methionine, respectively. This research, which highlights the usefulness of nanoconfinement present in mechanically interlocked molecules for the reinforcement of weak interactions, can not only expand the potential of charge-transfer interactions in solar energy conversion and synthetic photocatalysis but also open up new possibilities for the development of active artificial molecular shuttles, switches, and machines.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Confinement of 1D Chain and 2D Layered CuI Modules in K-INA-R Frameworks via Coordination Assembly: Structure Regulation and Semiconductivity Tuning
Herein, we present a new series of CuI-based hybrid materials with tunable structures and semiconducting properties. Furthermore, the CuI inorganic modules can be tailored into a one-dimensional (1D) chain and two-dimensional (2D) layer and confined/stabilized in coordination frameworks of potassium isonicotinic acid (HINA) and its derivatives (HINA-R, R = OH, NO 2 , and COOH). The resulting CuI-based hybrid materials exhibit interesting semiconducting behaviors associated with the dimensionality of the inorganic module; for instance, the structures containing the 2D-CuI module demonstrate significantly enhanced photoconductivity with a maximum increase of five orders of magnitude compared to that of the structures containing the 1D-CuI module. They also represent the first CuI-bearing hybrid chemiresistive gas sensors for NO 2 with boosted sensing performance and sensitivity at multiple orders of magnitude over that of the pristine CuI. Particularly, the sensing ability of CuI-K-INA containing both 1D- and 2D-CuI modules is comparable to those of the best NO 2 chemiresistors reported thus far.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Robust Miniemulsion PhotoATRP Driven by Red and Near-Infrared Light
Not Available
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Mechanistic Investigation of the Ce(III) Chloride Photoredox Catalysis System: Understanding the Role of Alcohols as Additives
Photocatalytic C–H activation is an emerging area of research. While cerium chloride photocatalysts have been extensively studied, the role of alcohol additives in these systems remains a subject of ongoing discussion. It was demonstrated that the photocatalyst [NEt 4 ] 2 [Ce IV Cl 6 ] ( 1 ) produces •Cl and added alcohols exhibit zero-order kinetics. Prior studies by other researchers suggested that 1 and alcohols lead to cerium alkoxide [Ce–OR] and alkoxy radical intermediates. Here, to understand these seemingly divergent mechanistic proposals, an expanded investigation comparing cerium(IV) catalyst 1 and cerium(III) complex [NEt 4 ] 3 [Ce III Cl 6 ] ( 2 ), which exhibit markedly different reactivity and C–H selectivity, is disclosed. Our findings reveal that alcohol additives accelerate the conversion of cerium(III) to cerium(IV) catalysts, forming key intermediates such as [NEt 4 ] 2 [Ce III Cl 5 (HOCH 3 )] ( 5 ) and [NEt 4 ] 2 [Ce IV Cl 5 (OCH 3 )] ( 6 ), driven by excited-state di-tert-butyl azodicarboxylate under blue light irradiation. The active complex 6 releases the •OCH 3 radical, in sharp contrast to •Cl radicals initiated by cerium(IV) photoredox catalyst 1 . These different reactivity and selectivity profiles can be understood in the context of complex 5 generation and in situ formation of base to afford complex 6 . Experimental validation shows enhanced selectivity toward C–H bonds with different reactivity with catalyst 1 and methanol upon the addition of base and decreased selectivity with catalyst 2 and methanol upon the addition of acid. These findings unify the previously contrasting observations of cerium halide/alkoxide photocatalytic systems and provide a comprehensive understanding on the essential role of base/acid and alcohol in selectivity and reactivity.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Modulating Noncovalent Cross-links with Molecular Switches
Spiropyran molecular switches, in conjunction with transition metal ions, are shown to operate as reversible polymer cross-linkers. Solutions containing a spiropyran-functionalized polymer and transition metal ions underwent reversible thermally triggered (light-triggered) transient network formation (disruption) driven by the association (dissociation) of metal-ligand cross-links. Heat triggers metal-ion-mediated cross-linking via thermal isomerization of spiropyran to its open, merocyanine form, and exposure to visible light triggers dissociation of polymer cross-links. Cross-linking is found to depend on both the valence of the ion as well as the molar ratio of spiropyran to metal salt. We envision this to be a starting point for the design of many types of reversible, stimuli responsive polymers, utilizing the fact that spiropyrans have been shown to respond to a variety of stimuli including heat, light, pH, and mechanical force.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Turning on Visible-Light Photocatalytic C-H Oxidation over Metal-Organic Frameworks by Introducing Metal-to-Cluster Charge Transfer
The tailorable structure and electronic structure of metal–organic frameworks (MOFs) greatly facilitate their modulated light harvesting, redox power, and consequently photocatalysis. In this work, a representative MOF, UiO-66, was furnished by installing Fe 3+ onto the Zr-oxo clusters, to give Fe-UiO-66, which features extended visible light harvesting, based on metal-to-cluster charge transfer (MCCT). The Fe-UiO-66 with unique electronic structure and strong oxidizing power exhibits visible light-driven water oxidation, which is impossible for pristine UiO-66. More strikingly, under visible irradiation, the generated holes over Fe-UiO-66 are able to exclusively convert H 2 O to hydroxide radicals, initiating and driving the activation of stubborn C-H bond, such as toluene oxidation. The electrons reduce O 2 to O 2 •- radicals that further promote the oxidation reaction. The related catalytic mechanism and the structure–activity relationship have been investigated in detail. As far as we know, this is not only an unprecedented report on activating “inert” MOFs for photocatalytic C-H activation but also the first work on extended light harvesting and enhanced photocatalysis for MOFs by introducing an MCCT process.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Operation of the CAPRICE electron cyclotron resonance ion source applying frequency tuning and double frequency heating
The properties of the electromagnetic waves heating the electrons of the ECR ion sources (ECRIS) plasma affect the features of the extracted ion beams such as the emittance, the shape, and the current, in particular for higher charge states. The electron heating methods such as the frequency tuning effect and the double frequency heating are widely used for enhancing the performances of ECRIS or even for the routine operation during the beam production. In order to better investigate these effects the CAPRICE ECRIS has been operated using these techniques. The ion beam properties for highly charged ions have been measured with beam diagnostic tools. The reason of the observed variations of this performance can be related to the different electromagnetic field patterns, which are changing inside the plasma chamber when the frequency is varying.
43 PARTICLE ACCELERATORS↗
A 3D Monte Carlo code for the modeling of plasma dynamics and beam formation mechanism in electron cyclotron resonance ion sources
The code here presented is the first part of a Monte Carlo (MC) self-consistent 3D plasma simulator. It is yet able to solve the equation of motion for thousands of independent charged particles. The procedure allows to understand the consequences of each phenomenon introduced in the evolution steps of the code. MC random selection of starting parameters is used for each particles; the environmental conditions enclosed in the simulation are ECRIS magnetic field, resonant electromagnetic wave, initial plasma density distribution and MC calculation of Spitzer collision. The results of the first simulations explain some typical effects as the hollow beam formation and the main plasma deconfinement mechanism.
43 PARTICLE ACCELERATORS↗
Photonic band structures of two-dimensional magnetized plasma photonic crystals
By using modified plane wave method, photonic band structures of the transverse electric polarization for two types of two-dimensional magnetized plasma photonic crystals are obtained, and influences of the external magnetic field, plasma density, and dielectric materials on the dispersion curves are studied, respectively. Results show that two areas of flat bands appear in the dispersion curves due to the role of external magnetic field, and the higher frequencies of the up and down flat bands are corresponding to the right-circled and left-circled cutoff frequencies, respectively. Adjusting external magnetic field and plasma density can not only control positions of the flat bands, but also can control the location and width of the local gap; increasing relative dielectric constant of the dielectric materials makes omni-direction gaps appear.
36 MATERIALS SCIENCE↗
Comment on ''Electron acceleration by a short laser beam in the presence of a long-wavelength electromagnetic wave'' [J. Appl. Phys. 102, 056106 (2007)]
Gupta et al.[J. Appl. Phys. 102, 056106 (2007)] investigated vacuum electron acceleration by a short laser beam in the presence of a long-wavelength electromagnetic wave. However, we consider that their simulation results to be questionable. We have investigated their simulation in detail and present our own simulation results, which do not match the good acceleration as theirs given in the original paper.
43 PARTICLE ACCELERATORS↗
Nonlinear propagation of coherent electromagnetic waves in a dense magnetized plasma
We present an investigation of the nonlinear propagation of high-frequency coherent electromagnetic waves in a uniform quantum magnetoplasma. Specifically, we consider nonlinear couplings of right-hand circularly polarized electromagnetic-electron-cyclotron (CPEM-EC) waves with dispersive shear Alfven (DSA) and dispersive compressional Alfven (DCA) perturbations in plasmas composed of degenerate electron fluids and non-degenerate ion fluids. Such interactions lead to amplitude modulation of the CPEM-EC wave packets, the dynamics of which is governed by a three-dimensional nonlinear Schroedinger equation (NLSE) with the frequency shift arising from the relativistic electron mass increase in the CPEM-EC fields and density perturbations associated with the DSA and DCA perturbations. Accounting for the electromagnetic and quantum forces, we derive the evolution equation for the DSA and DCA waves in the presence of the magnetic field-aligned ponderomotive force of the CPEM-EC waves. The NLSE and the driven DSA and DCA equations are then used to investigate the modulational instability. The relevance of our investigation to laser-plasma interaction experiments and the cores of white dwarf stars is pointed out.
70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
Effect of electron density profile on power absorption of high frequency electromagnetic waves in plasma
Considering different typical electron density profiles, a multi slab approximation model is built up to study the power absorption of broadband (0.75-30 GHz) electromagnetic waves in a partially ionized nonuniform magnetized plasma layer. Based on the model, the power absorption spectra for six cases are numerically calculated and analyzed. It is shown that the absorption strongly depends on the electron density fluctuant profile, the background electron number density, and the collision frequency. A potential optimum profile is also analyzed and studied with some particular parameters.
70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗