Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “C”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 505 records · Page 28
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Gas-Phase Formation of 1,3,5,7-Cyclooctatetraene (C 8 H 8 ) through Ring Expansion via the Aromatic 1,3,5-Cyclooctatrien-7-yl Radical (C 8 H 9 • ) Transient

Gas-phase 1,3,5,7-cyclooctatetraene (C 8 H 8 ) and triplet aromatic 1,3,5,7-cyclooctatetraene (C 8 H 8 ) were formed for the first time through the bimolecular methylidyne radicals (CH) - 1,3,5-cycloheptatriene (C 7 H 8 ) reactions under single collision conditions on the doublet surface. The reaction involves methylidyne radical addition to the olefinic pi electron system of 1,3,5-cycloheptatriene followed by isomerization and ring expansion to aromatic 1,3,5-cyclooctatrien-7-yl radical (C 8 H 9 •). The chemically activated doublet radical intermediate undergoes unimolecular decomposition to 1,3,5,7-cyclooctatetraene. Substituted 1,3,5,7-cyclooctatetraene molecules can be prepared in the gas phase with hydrogen atom(s) in the 1,3,5-cycloheptatriene reactant being replaced by organic side groups. Furthermore, these findings are also of potential interest to organometallic chemists by expanding the synthesis of exotic transition metal complexes incorporating substituted 1,3,5,7-cyclooctatetraene dianion (C 8 H 8 2- ) ligands and to untangle the unimolecular decomposition of chemically activated and substituted 1,3,5-cyclooctatrien-7-yl radical eventually gaining a fundamental insight of their bonding chemistry, electronic structures, and stabilities.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Ni/Photoredox-Catalyzed C(sp 3 )–C(sp 3 ) Coupling between Aziridines and Acetals as Alcohol-Derived Alkyl Radical Precursors

Aziridines are readily available C(sp 3 ) precursors that afford valuable β-functionalized amines upon ring opening. In this article, we report a Ni/photoredox methodology for C(sp 3 )–C(sp 3 ) cross-coupling between aziridines and methyl/1°/2° aliphatic alcohols activated as benzaldehyde dialkyl acetals. Orthogonal activation modes of each alkyl coupling partner facilitate cross-selectivity in the C(sp 3 )–C(sp 3 ) bond-forming reaction: the benzaldehyde dialkyl acetal is activated via hydrogen atom abstraction and β-scission via a bromine radical (generated in situ from single-electron oxidation of bromide), whereas the aziridine is activated at the Ni center via reduction. Here, we demonstrate that an Ni(II) azametallacycle, conventionally proposed in aziridine cross-coupling, is not an intermediate in the productive cross-coupling. Rather, stoichiometric organometallic and linear free energy relationship studies indicate that aziridine activation proceeds via Ni(I) oxidative addition, a previously unexplored elementary step.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Deep mitigation of CO 2 and non-CO 2 greenhouse gases toward 1.5 °C and 2 °C futures

Stabilizing climate change well below 2 °C and towards 1.5 °C requires comprehensive mitigation of all greenhouse gases (GHG), including both CO 2 and non-CO 2 GHG emissions. Here we incorporate the latest global non-CO 2 emissions and mitigation data into a state-of-the-art integrated assessment model GCAM and examine 90 mitigation scenarios pairing different levels of CO 2 and non-CO 2 GHG abatement pathways. We estimate that when non-CO 2 mitigation contributions are not fully implemented, the timing of net-zero CO 2 must occur about two decades earlier. Conversely, comprehensive GHG abatement that fully integrates non-CO 2 mitigation measures in addition to a net-zero CO 2 commitment can help achieve 1.5 °C stabilization. While decarbonization-driven fuel switching mainly reduces non-CO 2 emissions from fuel extraction and end use, targeted non-CO 2 mitigation measures can significantly reduce fluorinated gas emissions from industrial processes and cooling sectors. Our integrated modeling provides direct insights in how system-wide all GHG mitigation can affect the timing of net-zero CO 2 for 1.5 °C and 2 °C climate change scenarios.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2014

Deep Co penetration and spin-polarization of C{sub 60} molecules at hybridized Co-C{sub 60} interfaces

We used near-edge x-ray absorption fine structure spectroscopy to identify the interplays at organic semiconductor-ferromagnet interfaces. When monitoring the L-edge intensity of 0.36 nm Co depositing on C{sub 60} films of various thicknesses, we detected weaker Co signal from structures with larger C{sub 60} thicknesses. Having determined that the electron mean escape depth in C{sub 60} is 4.9 nm, further model analysis indicates that the decline of spectral intensity is due to deep penetration of Co clusters. Finally, C K-edge spectra reveal clear evidences of orbital hybridization between Co and C{sub 60} as well as a visible dichroic effect at 125 K.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2014

Experimental and ab initio studies of the reactive processes in gas phase i-C{sub 3}H{sub 7}Br and i-C{sub 3}H{sub 7}OH collisions with potassium ions

Collisions between potassium ions and neutral i-C{sub 3}H{sub 7}Br and i-C{sub 3}H{sub 7}OH, all in their electronic ground state, have been studied in the 0.10–10.00 eV center of mass (CM) collision energy range, using the radiofrequency-guided ion beam technique. In K{sup +} + i-C{sub 3}H{sub 7}Br collisions KHBr{sup +} formation was observed and quantified, while the analogous KH{sub 2}O{sup +} formation in K{sup +} + i-C{sub 3}H{sub 7}OH was hardly detected. Moreover, formation of the ion-molecule adducts and their decomposition leading to C{sub 3}H{sub 7}{sup +} and either KBr or KOH, respectively, have been observed. For all these processes, absolute cross-sections were measured as a function of the CM collision energy. Ab initio structure calculations at the MP2 level have given information about the potential energy surfaces (PESs) involved. In these, different stationary points have been characterized using the reaction coordinate method, their connectivity being ensured by using the intrinsic-reaction-coordinate method. From the measured excitation function for KHBr{sup +} formation the corresponding thermal rate constant at 303 K has been calculated. The topology of the calculated PESs allows an interpretation of the main features of the reaction dynamics of both systems, and in particular evidence the important role played by the potential energy wells in controlling the reactivity for the different reaction channels.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

The first potential energy surfaces for the C{sub 6}H{sup −}–H{sub 2} and C{sub 6}H{sup −}–He collisional systems and their corresponding inelastic cross sections

Molecular anions have recently been detected in the interstellar and circumstellar media. Accurate modeling of their abundance requires calculations of collisional data with the most abundant species that are usually He atoms and H{sub 2} molecules. In this paper, we focus on the collisional excitation of the first observed molecular anion, C{sub 6}H{sup −}, by He and H{sub 2}. Theoretical calculations of collisional cross sections rely generally on ab initio interaction potential energy surfaces (PESs). Hence, we present here the first PESs for the C{sub 6}H{sup −}–H{sub 2} and C{sub 6}H{sup −}–He van der Waals systems. The ab initio energy data for the surfaces were computed at the explicitly correlated coupled cluster with single, double, and scaled perturbative triple excitations level of theory. The method of interpolating moving least squares was used to construct 4D and 2D analytical PESs from these data. Both surfaces are characterized by deep wells and large anisotropies. Analytical models of the PESs were used in scattering calculations to obtain cross sections for low-lying rotational transitions. As could have been anticipated, important differences exist between the He and H{sub 2} cross sections. Conversely, no significant differences exist between the collisions of C{sub 6}H{sup −} with the two species of H{sub 2} (para- and ortho-H{sub 2}). We expect that these new data will help in accurately determining the abundance of the C{sub 6}H{sup −} anions in space.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2017

Heat wave exposure in India in current, 1.5 °C, and 2.0 °C worlds

Heatwaves with large impacts have increased in the recent past and will continue to increase under future warming. However, the implication for population exposure to severe heatwaves remains unexplored. Here, we characterize maximum potential human exposure (without passive/active reduction measures) to severe heatwaves in India. We show that if the global mean temperature is limited to 2.0 °C above pre-industrial conditions, the frequency of severe heatwaves will rise by 30 times the current climate by the end-21st century. In contrast, the frequency is projected to be about 2.5 times more (than the low-warming scenario of 2 °C) under conditions expected if the RCP8.5 'business-as-usual' emissions scenario is followed. Under the 2.0 °C low-warming target, population exposure to severe heatwaves is projected to increase by about 15 and 92 times the current level by the mid and end-21st century respectively. Strategies to reduce population growth in India during the 21st century may provide only limited mitigation of heatwave exposure mostly late in the century. Limiting global temperatures to 1.5 °C above preindustrial would reduce the exposure by half relative to RCP8.5 by the mid-21st century. If global temperatures are to exceed 1.5 °C then substantial measures will be required to offset the large increase in exposure to severe heatwaves in India.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Increased bundle‐sheath leakiness of CO 2 during photosynthetic induction shows a lack of coordination between the C 4 and C 3 cycles

Summary Use of a complete dynamic model of NADP‐malic enzyme C 4 photosynthesis indicated that, during transitions from dark or shade to high light, induction of the C 4 pathway was more rapid than that of C 3 , resulting in a predicted transient increase in bundle‐sheath CO 2 leakiness ( ϕ ). Previously, ϕ has been measured at steady state; here we developed a new method, coupling a tunable diode laser absorption spectroscope with a gas‐exchange system to track ϕ in sorghum and maize through the nonsteady‐state condition of photosynthetic induction. In both species, ϕ showed a transient increase to > 0.35 before declining to a steady state of 0.2 by 1500 s after illumination. Average ϕ was 60% higher than at steady state over the first 600 s of induction and 30% higher over the first 1500 s. The transient increase in ϕ , which was consistent with model prediction, indicated that capacity to assimilate CO 2 into the C 3 cycle in the bundle sheath failed to keep pace with the rate of dicarboxylate delivery by the C 4 cycle. Because nonsteady‐state light conditions are the norm in field canopies, the results suggest that ϕ in these major crops in the field is significantly higher and energy conversion efficiency lower than previous measured values under steady‐state conditions.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2022

T cells discriminate between groups C1 and C2 HLA-C

Dimorphic amino acids at positions 77 and 80 delineate HLA-C allotypes into two groups, C1 and C2, which associate with disease through interactions with C1 and C2-specific natural killer cell receptors. How the C1/C2 dimorphism affects T cell recognition is unknown. Using HLA-C allotypes that differ only by the C1/C2-defining residues, we found that KRAS-G12D neoantigen-specific T cell receptors (TCRs) discriminated between C1 and C2 presenting the same KRAS-G12D peptides. Structural and functional experiments, and immunopeptidomics analysis revealed that Ser77 in C1 and Asn77 in C2 influence amino acid preference near the peptide C-terminus (pΩ), including the pΩ-1 position, in which C1 favors small and C2 prefers large residues. This resulted in weaker TCR affinity for KRAS-G12D-bound C2-HLA-C despite conserved TCR contacts. Thus, the C1/C2 dimorphism on its own impacts peptide presentation and HLA-C-restricted T cell responses, with implications in disease, including adoptive T cell therapy targeting KRAS-G12D-induced cancers.

Sim, Malcolm J. W. (ORCID:0000000334079661)↗
NASA NTRS1974

C-band station coordinate determination for the GEOS-C altimeter calibration area

Dynamical orbital techniques were employed to estimate the center-of-mass station coordinates of six C-band radars located in the designated primary GEOS-C radar altimeter calibration area. This work was performed in support of the planned GEOS-C mission (December, 1974 launch). The sites included Bermuda, Grand Turk, Antigua, Wallops Island (Virginia), and Merritt Island (Florida). Two sites were estimated independently at Wallops Island yielding better than 40 cm relative height recovery, with better than 10 cm and 1 m (relative) recovery for phi and gamma respectively. Error analysis and comparisons with other investigators indicate that better than 2 m relative recovery was achieved at all sites. The data used were exclusively that from the estimated sites and included 18 orbital arcs which were less than two orbital revolutions in length, having successive tracks over the area. The techniques employed here, given their independence of global tracking support, can be effectively employed to improve various geodetic datums by providing very long and accurate baselines. The C-band data taken on GEOS-C should be employed to improve such geodetic datums as the European-1950 using similar techniques.

Krabill, W. B.↗
NASA NTRS1982

Thermal annealing of radiation damage in CMOS ICs in the temperature range -140 C to +375 C

Annealing of radiation damage was investigated in the commercial, Z- and J-processes of the RCA CD4007A ICs in the temperature range from -140 C to +375 C. Tempering curves were analyzed for activation energies of thermal annealing, following irradiation at -140 C. It was found that at -140 C, the radiation-induced shifts in the threshold potentials were similar for all three processes. The radiation hardness of the Z- and J-process is primarily due to rapid annealing of radiation damage at room temperature. In the region -140 to 20 C, no dopant-dependent charge trapping is seen, similar to that observed at higher temperatures. In the unbiased Z-process n-channels, after 1 MeV electron irradiation, considerable negative charge remains in the gate oxide.

Danchenko, V.↗
NASA NTRS1990

Analysis and interpretation of Wide Field Planetary Camera outgas data collected in the temperature range from -20 C to -100 C

The data from the Wide Field Planetary Camera (WFPC) are analyzed to determine the absolute source-emission parameters and contaminant reemission parameters of outgassing mass accumulation. The data correspond to the mass accumulated on a -100 C quartz crystal microbalance and then desorbed at -50 C as a function of time. The parameters investigated include contaminant mass, first-order rate constants, and characteristic energies. The data are modeled in terms of a minimum number of species characterized by source-rate and reemission-rate parameters. The modeling technique is found to produce adequate fits, and the contaminants that accumulate at -100 C and desorb at -50 C do not accumulate at -50 C. The data analysis is found to be an adequate technique for assessing outgassing parameters for the prediction of WFPC internal contamination.

Barengoltz, Jack B.↗
NASA NTRS1992

An alternate method for achieving temperature control in the -130 C to 75 C range

Thermal vacuum testing often requires temperature control of chamber shrouds and heat exchangers within the -130 C to 75 C range. There are two conventional methods which are normally employed to achieve control through this intermediate temperature range: (1) single-pass flow where control is achieved by alternately pulsing hot gaseous nitrogen (GN2) and cold LN2 into the feed line to yield the setpoint temperature; and (2) closed-loop circulation where control is achieved by either electrically heating or LN2 cooling the circulating GN2 to yield the setpoint temperature. A third method, using a mass flow ratio controller along with modulating control valves on GN2 and LN2 lines, provides excellent control but equipment for this method is expensive and cost-prohibitive for all but long-term continuous processes. The single-pass method provides marginal control and can result in unexpected overcooling of the test article from even a short pulse of LN2. The closed-loop circulation method provides excellent control but requires an expensive blower capable of operating at elevated pressures and cryogenic temperatures. Where precise control is needed (plus or minus 2 C), single-pass flow systems typically have not provided the precision required, primarily because of overcooling temperature excursions. Where several individual circuits are to be controlled at different temperatures, the use of expensive cryogenic blowers for each circuit is also cost-prohibitive, especially for short duration of one-of-a-kind tests. At JPL, a variant of the single-pass method was developed that was shown to provide precise temperature control in the -130 C to 75 C range while exhibiting minimal setpoint overshoot during temperature transitions. This alternate method uses a commercially available temperature controller along with a GN2/LN2 mixer to dampen the amplitude of cold temperature spikes caused by LN2 pulsing. The design of the GN2/LN2 mixer, the overall control system configuration, the operational procedure, and the prototype system test results are described.

Johnson, Kenneth R.↗
NASA NTRS1993

New low-Ni (igneous?) particles among the C and C? types of cosmic dust

Low-Ni particles with major element abundances, optical properties, and morphologies sufficiently similar to chondritic interplanetery dust particles (IDP's) to receive JSC Cosmic Dust Catalog classifications of C or C?-types were shown to have trace element contents and mineralogies similar to igneous material. Examination of the JSC Catalog EDX spectra by Cooke et al. has shown that 13 percent of the C-type and 38 percent of the C?-type particles are potentially low-Ni particles. Two new low-Ni particles were identified, and it was shown that an additional fragment from the L2002*C cluster has an igneous composition. A newly analyzed fragment of the W7066*A cluster has a chondritic composition. The W7066*A cluster is important because it has yielded a fragment of igneous composition and another fragment having high concentrations of He and Ne suggesting an extraterrestrial origin.

Flynn, G. J.↗
NASA NTRS1996

Science Results from the Spaceborne Imaging Radar-C/X-Band Synthetic Aperture Radar (SIR-C/X-SAR): Progress Report

The Spaceborne Imaging Radar-C/X-band Synthetic Aperture Radar (SIR-C/X-SAR) is the most advanced imaging radar system to fly in Earth orbit. Carried in the cargo bay of the Space Shuttle Endeavour in April and October of 1994, SIR-C/X-SAR simultaneously recorded SAR data at three wavelengths (L-, C-, and X-bands; 23.5, 5.8, and 3.1 cm, respectively). The SIR-C/X-SAR Science Team consists of 53 investigator teams from more than a dozen countries. Science investigations were undertaken in the fields of ecology, hydrology, ecology, and oceanography. This report contains 44 investigator team reports and several additional reports from coinvestigators and other researchers.

Diane L Evans↗
NASA NTRS1995

The MCH2+ Systems: Do ScCH2+ and TiCH2+ Have C(sub s) or C(sub 2v) Symmetry and A Comparison of the B3LYP Method to Other Approaches

ScCH2(+) and TiCH2(+) are found to have C(sub s) symmetry, while the remaining systems have the expected C(sub 2v) symmetry. The C(sub s) symmetry structure is favored for ScCH2(+) and TiCH2(+) because it allows donation from one of the CH bonds into an empty 3d orbital. This distortion stabilizes the systems by less than 2 kcal/mol at the B3LYP, CASSCF, and CCSD(T) levels of theory. The SCF and B3LYP approaches find the C2(sub v) structure to be a saddle point, while the CASSCF approach finds the C(sub 2v) structure to be a stationary point. For V-Cu there are no empty 3d orbitals of the correct symmetry, and therefore the distortion to C(sub s), is unfavorable. The B3LYP binding energies are in good agreement with experiment and our previous best estimates.

Ricca, Alessandra↗
DOE OSTI2013

Angular analysis of B 0 → φ K * decays and search for C P violation at Belle

Here, we report the measurements of branching fractions and C P violation asymmetries in B 0 → φ K * decays obtained in an angular analysis using the full data sample of 772 × 10 6 B B ¯ pairs collected at the Υ ( 4 S ) resonance with the Belle detector at the KEKB asymmetric-energy e + e - collider. Furthermore, we perform a partial wave analysis to distinguish among scalar [ B 0 → φ ( K π ) 0 * ], vector [ B 0 → φ K * ( 892 ) 0 ] and tensor [ B 0 → φ K 2 * ( 1430 ) 0 ] components, and determine the corresponding branching fractions to be B [ B 0 → φ ( K π ) 0 * ] = ( 4.3 ± 0.4 ± 0.4 ) × 10 - 6 , B [ B 0 → φ K * ( 892 ) 0 ] = ( 10.4 ± 0.5 ± 0.6 ) × 10 - 6 and B [ B 0 → φ K 2 * ( 1430 ) 0 ] = ( 5.5 - 0.7 + 0.9 ± 1.0 ) × 10 - 6 . We also measure the longitudinal polarization fraction f L in B 0 → φ K * ( 892 ) 0 and B 0 → φ K 2 * ( 1430 ) 0 decays to be 0.499 ± 0.030 ± 0.018 and 0.918 - 0.060 + 0.029 ± 0.012 , respectively. The first quoted uncertainties are statistical and the second are systematic. In total, we measure 26 parameters related to branching fractions, polarization and C P violation in the B 0 → φ K * system. No evidence for C P violation is found.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2017

Search for C P Violation and Measurement of the Branching Fraction in the Decay D 0 → K S 0 K S 0

In this work we study the decay D 0 → K S 0 K S 0 using 921 fb - 1 of data collected at or near the Υ ( 4 S ) and Υ ( 5 S ) resonances with the Belle detector at the KEKB asymmetric energy e + e - collider. The measured time-integrated C P asymmetry is A C P ( D 0 → K S 0 K S 0 ) = ( - 0.02 ± 1.53 ± 0.02 ± 0.17 ) % , and the branching fraction is B ( D 0 → K S 0 K S 0 ) = ( 1.321 ± 0.023 ± 0.036 ± 0.044 ) × 10 - 4 , where the first uncertainty is statistical, the second is systematic, and the third is due to the normalization mode ( D 0 → K S 0 π 0 ). These results are furthermore more precise than previous measurements available for this mode. The A C P measurement is consistent with the standard model expectation.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗