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At least 505 records · Page 28

High-Fidelity Microstructural Characterization and Performance Modeling of Aluminized Composite Propellant

Image processing and stereological techniques were used to characterize the heterogeneity of composite propellant and inform a predictive burn rate model. Composite propellant samples made up of ammonium perchlorate (AP), hydroxyl-terminated polybutadiene (HTPB), and aluminum (Al) were faced with an ion mill and imaged with a scanning electron microscope (SEM) and x-ray tomography (micro-CT). Properties of both the bulk and individual components of the composite propellant were determined from a variety of image processing tools. An algebraic model, based on the improved Beckstead-Derr-Price model developed by Cohen and Strand, was used to predict the steady-state burning of the aluminized composite propellant. In the presented model the presence of aluminum particles within the propellant was introduced. The thermal effects of aluminum particles are accounted for at the solid-gas propellant surface interface and aluminum combustion is considered in the gas phase using a single global reaction. In conclusion, properties derived from image processing were used directly as model inputs, leading to a sample-specific predictive combustion model.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Performance Impacts to the NASA Artemis II Trajectory Correction Burn Placement

As NASA embarks to return humans to the lunar vicinity with the upcoming Artemis II mission, the selected free return trajectory taking the crew to the Moon in the Orion spacecraft is impacted by the execution of small trajectory correction burns to ensure the spacecraft stays on course for a successful return to Earth. The placement of these nominally zero translational maneuvers must account for the crew schedule, navigation tracking constraints, spacecraft venting, thermal and communication requirements, and a host of other programmatic factors. Understanding the influence the placement of these periodic burn corrections have on the integrated GN\&C performance can provide valuable insight to mission controllers and trajectory planning processes to untangle the complex trade space considered for both baseline and contingency scenarios. This sensitivity information can also be utilized to facilitate the optimized placement of these burns. This paper utilizes several techniques to systematically generate the performance impacts to the NASA Artemis II trajectory correction burn placement and demonstrate how to derive optimized locations that make the system robust to crew activity, maneuver execution errors, navigation uncertainty, orbit insertion errors, disturbance accelerations, and other system limitations.

GN&C↗

Processing and properties of a solid energy fuel from municipal solid waste (MSW) and recycled plastics

Highlights: • Briquetting was used to produce solid fuels from municipal solid waste and recycled plastics. • Optimal drying, processing temperature and pressure were found to produce stable briquettes. • Addition of waste plastics yielded heating values comparable with typical coal feedstocks. • This processing method improves utilization of paper and plastic diverted from landfills. - Abstract: Diversion of waste streams such as plastics, woods, papers and other solid trash from municipal landfills and extraction of useful materials from landfills is an area of increasing interest especially in densely populated areas. One promising technology for recycling municipal solid waste (MSW) is to burn the high-energy-content components in standard coal power plant. This research aims to reform wastes into briquettes that are compatible with typical coal combustion processes. In order to comply with the standards of coal-fired power plants, the feedstock must be mechanically robust, free of hazardous contaminants, and moisture resistant, while retaining high fuel value. This study aims to investigate the effects of processing conditions and added recyclable plastics on the properties of MSW solid fuels. A well-sorted waste stream high in paper and fiber content was combined with controlled levels of recyclable plastics PE, PP, PET and PS and formed into briquettes using a compression molding technique. The effect of added plastics and moisture content on binding attraction and energy efficiency were investigated. The stability of the briquettes to moisture exposure, the fuel composition by proximate analysis, briquette mechanical strength, and burning efficiency were evaluated. It was found that high processing temperature ensures better properties of the product addition of milled mixed plastic waste leads to better encapsulation as well as to greater calorific value. Also some moisture removal (but not complete) improves the compacting process and results in higher heating value. Analysis of the post-processing water uptake and compressive strength showed a correlation between density and stability to both mechanical stress and humid environment. Proximate analysis indicated heating values comparable to coal. The results showed that mechanical and moisture uptake stability were improved when the moisture and air contents were optimized. Moreover, the briquette sample composition was similar to biomass fuels but had significant advantages due to addition of waste plastics that have high energy content compared to other waste types. Addition of PP and HDPE presented better benefits than addition of PET due to lower softening temperature and lower oxygen content. It should be noted that while harmful emissions such as dioxins, furans and mercury can result from burning plastics, WTE facilities have been able to control these emissions to meet US EPA standards. This research provides a drop-in coal replacement that reduces demand on landfill space and replaces a significant fraction of fossil-derived fuel with a renewable alternative.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A new site for the astrophysical gamma-process

The study suggests that the requisite thermodynamic conditions may occur when carbon-oxygen white dwarfs explode by deflagration or detonation. When these stars undergo such explosive disruption, there will be a region near the surface where the burning temperature lies in the 2.4-3.2 range. To examine this astrophysical site, calculations are performed for an s-process nucleosynthesis during helium shell flashes and the nuclear transmission taking place when such mass zones are heated by the deflagration or detonation wave, and the results are compared with the solar-system distribution of the p-isotopes. It is demonstrated that Type Ia supernovas provide a viable site for the gamma process, and that the same thermodynamic conditions would also exist in Type II-p powered supernovas, provided that they are powered by detonation.

Howard, W. Michael↗

Standardization of the carbon-phenolic materials and processes. Vol. 1: Experimental studies

Carbon-phenolic composite materials are used as ablative material in the solid rocket motor nozzle of the Space Shuttle. The nozzle is lined with carbon cloth-phenolic resin composites. The nominal effects of the completely consumed solid propellant on the carbon-phenolic material are given. The extreme heat and erosion of the burning propellant are controlled by the carbon-phenolic composite by ablation, the heat and mass transfer process in which a large amount of heat is absorbed by sacrificially removing material from the nozzle surface. Phenolic materials ablate with the initial formation of a char. The depth of the char is a function of the heat conduction coefficient of the composite. The char layer is a very poor heat conductor so it protects the underlying phenolic composite from the high heat of the burning propellant. The nozzle component ablative liners (carbon cloth-phenolic composites) are tape wrapped, hydroclave and/or autoclave cured, machined, and assembled. The tape consists of a prepreg broadcloth. The materials flow sheet for the nozzle ablative liners is shown. The prepreg is a three component system: phenolic resin, carbon cloth, and carbon filler. This is Volume 1 of two, Experimental Studies.

Hall, William B.↗

β-delayed α decay of {sup 16}N and the {sup 12}C(α,γ){sup 16}O cross section at astrophysical energies: A new experimental approach

The {sup 12}C(α,γ){sup 16}O reaction at energies corresponding to the quiescent helium burning in massive stars is regarded as one of the most important processes in nuclear astrophysics. Although this process has being studied for over four decades, our knowledge of its cross section at the energies of interest for astrophysics is still widely unsatisfactory. Indeed, no experimental data are available around 300 keV and in the energy region of astrophysical interest extrapolations are performed using some theoretical approaches, usually R-matrix calculations. Consequently, the published astrophysical factors range from 1 to 288 keVb for S{sub E1}(300) and 7 to 120 keVb for S{sub E2}(300), especially because of the unknown contribution coming from subthreshold resonances. To improve the reliability of these extrapolations, data from complementary experiments, such as elastic and quasi- elastic α scattering on {sup 12}C, α-transfer reactions to {sup 16}O, and {sup 16}N decay are usually included in the analysis. Here the β-delayed α decay of {sup 16}N is used to infer information on the {sup 12}C(α,γ){sup 16}O reaction and a new experimental technique is suggested.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

KamLAND SENSITIVITY TO NEUTRINOS FROM PRE-SUPERNOVA STARS

In the late stages of nuclear burning for massive stars (M > 8 M{sub ⊙}), the production of neutrino–antineutrino pairs through various processes becomes the dominant stellar cooling mechanism. As the star evolves, the energy of these neutrinos increases and in the days preceding the supernova a significant fraction of emitted electron anti-neutrinos exceeds the energy threshold for inverse beta decay on free hydrogen. This is the golden channel for liquid scintillator detectors because the coincidence signature allows for significant reductions in background signals. We find that the kiloton-scale liquid scintillator detector KamLAND can detect these pre-supernova neutrinos from a star with a mass of 25 M{sub ⊙} at a distance less than 690 pc with 3σ significance before the supernova. This limit is dependent on the neutrino mass ordering and background levels. KamLAND takes data continuously and can provide a supernova alert to the community.

79 ASTRONOMY AND ASTROPHYSICS↗

Coupling Experiments and Simulations to Understand Metallic Fuel Behavior

The development of metal alloy fuels for minor actinide transmutation in fast reactor systems is of high importance. However, it faces numerous technical challenges such as: i) fuel behavior has to be benign during core off-normal events; ii) fuel has to maintain integrity to high burnup; iii) low minor actinide fabrication loss under remote handling conditions; and iv) fuel has to lend itself to low-loss recycling process. Limited experimental fuel performance data is currently available to support the selection of a fuel type for a transmutation system. Metallic fuels are being considered for application in fast reactor environment due to the high burn-up, high fissile and fertile density capability, inherent safety characteristics, favorable thermal response, and relatively easy recycling process. The uranium-plutonium-zirconium (U-Pu- Zr) based alloys are considered as one of the most promising metallic fuels for such application. In this work, we present results of microstructural characterization of Pu-Zr and U-Pu-Zr alloys and provide much needed linkage between thermal properties and microscopic scale observation. A firm understanding of microstructural evolution in reactor materials is imperative and will lead to deeper understanding of in-reactor degradation behavior, creating a new generation of radiation-resistant materials and fuels with the potential for significant increases in burn-up.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

On the Importance of the Convective Urca Process in 3D Simulations of a Simmering White Dwarf

Type Ia supernovae are bright thermonuclear explosions that are important to numerous areas of astronomy. However, the origins of these events are poorly understood. One proposed setting is that of a near Chandrasekhar mass white dwarf that undergoes runaway carbon burning in the core. During the thousand years leading up to the explosion, the white dwarf undergoes a simmering phase where slow carbon burning heats the core and drives convection. A poorly understood aspect of this phase is the convective Urca process, which links convection with weak nuclear reactions. We use the low Mach number code MAESTROeX to perform full 3D simulations as is required to accurately capture the turbulent convection. We present simulations with and without the A=23 convective Urca process, which have relaxed to a steady state. We characterize the effects of the convective Urca process on the neutrino losses, the nuclear energy generation, and the convective boundary. We find that the size of the convection zone is substantially reduced by the convective Urca process, though convection still extends past the Urca shell. Our findings on the structure of the convective zone and the compositional changes can be used to inform 1D stellar models that track the longer-timescale evolution.

FOS: Physical sciences↗

A Comparison Between Orion Automated and Space Shuttle Rendezvous Techniques

The Orion spacecraft will replace the space shuttle and will be the first human spacecraft since the Apollo program to leave low earth orbit. This vehicle will serve as the cornerstone of a complete space transportation system with a myriad of mission requirements necessitating rendezvous to multiple vehicles in earth orbit, around the moon and eventually beyond . These goals will require a complex and robust vehicle that is, significantly different from both the space shuttle and the command module of the Apollo program. Historically, orbit operations have been accomplished with heavy reliance on ground support and manual crew reconfiguration and monitoring. One major difference with Orion is that automation will be incorporated as a key element of the man-vehicle system. The automated system will consist of software devoted to transitioning between events based on a master timeline. This effectively adds a layer of high level sequencing that moves control of the vehicle from one phase to the next. This type of automated control is not entirely new to spacecraft since the shuttle uses a version of this during ascent and entry operations. During shuttle orbit operations however many of the software modes and hardware switches must be manually configured through the use of printed procedures and instructions voiced from the ground. The goal of the automation scheme on Orion is to extend high level automation to all flight phases. The move towards automation represents a large shift from current space shuttle operations, and so these new systems will be adopted gradually via various safeguards. These include features such as authority-to-proceed, manual down modes, and functional inhibits. This paper describes the contrast between the manual and ground approach of the space shuttle and the proposed automation of the Orion vehicle. I will introduce typical orbit operations that are common to all rendezvous missions and go on to describe the current Orion automation architecture and contrast it with shuttle rendezvous techniques and circumstances. The shuttle rendezvous profile is timed to take approximately 3 days from orbit insertion to docking at the International Space Station (ISS). This process can be divided into 3 phases: far-field, mid-field and proximity operations. The far-field stage is characterized as the most quiescent phase. The spacecraft is usually too far to navigate using relative sensors and uses the Inertial Measurement Units (IMU s) to numerically solve for its position. The maneuvers are infrequent, roughly twice per day, and are larger than other burns in the profile. The shuttle uses this opportunity to take extensive ground based radar updates and keep high fidelity orbit states on the ground. This state is then periodically uplinked to the shuttle computers. The targeting solutions for burn maneuvers are also computed on the ground and uplinked. During the burn the crew is responsible for setting the shuttle attitude and configuring the propulsion system for ignition. Again this entire process is manually driven by both crew and ground activity. The only automatic processes that occur are associated with the real-time execution of the burn. The Orion automated functionality will seek to relieve the workload of both the crew and ground during this phase

Ruiz, Jose O,↗

The nu-process

As the core of a massive star collapses to form a neutron star, the flux of neutrinos in the overlying shells of heavy elements becomes so great that, despite the small cross section, substantial nuclear transmutation is induced. Neutrinos excite heavy elements and even helium to particle unbound levels. The evaporation of a single neutron or proton, and the back reaction of these nucleons on other species present, significantly alters the outcome of traditional nucleosynthesis calculations leading to a new process: nu-nucleosynthesis. Modifications to traditional hydrostatic and explosive varieties of helium, carbon, neon, oxygen, and silicon burning are considered. The results show that a large number of rare isotopes, including many of the odd-Z nuclei from boron through copper, owe much of their present abundance in nature to this process.

Woosley, S. E.↗

Analysis of stress corrosion cracking in alloy 718 following commercial reactor exposure

Alloy 718 is generally considered a highly corrosion-resistant material but can still be susceptible to stress corrosion cracking (SCC). The combination of factors leading to SCC susceptibility in the alloy is not always clear enough. In this paper, alloy 718 leaf spring (LS) materials that suffered stress corrosion damage during two 24-month cycles in pressurized water reactor service, operated to >45 MWd/mtU burn-up, was investigated. Compared to archival samples fabricated through the same processing conditions, little microstructural and property changes occurred in the material with in-service irradiation, contrary to high dose rate laboratory-based experiments reported in literature. Though the lack of delta phase formation along grain boundaries would suggest a more SCC resistant microstructure, grain boundary cracking in the material was extensive. Crack propagation routes were explored through focused ion beam milling of specimens near the crack tip for transmission electron microscopy as well as in polished plan view and cross-sectional samples for electron backscatter diffraction analysis. It has been shown in this study that cracks propagated mainly along random high-angle grain boundaries, with the material around cracks displaying a high local density of dislocations. The slip lines were produced through the local deformation of the leaf spring material above their yield strength. Also, the cause for local SCC appears to be related to oxidation of both slip lines and grain boundaries, which under the high in-service stresses resulted in crack development in the material.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Combustion time in the engine cylinder and its effect on engine performance

As part of a general program to study combustion in the engine cylinder and to correlate the phenomena of combustion with the observed performance of actual engines, this paper presents a sketchy outline of what may happen in the engine cylinder during the burning of a charge. It also suggests the type of information needed to supply the details of the picture and points out how combustion time and rate affect the performance of the engine. A theoretical concept of a flame front which is assumed to advance radially from the point of ignition is presented, and calculations based on the area and velocity of this flame and the density of the unburned gases are made to determine the mass rate of combustion. From this rate the mass which has been burned and the pressure at any instant during combustion are computed. This process is then reversed in an effort to determine actual rates of combustion and flame velocities from the pressures as recorded on indicator diagrams. The effects of different rates of combustion on engine performance are then discussed and the importance of proper spark advance is emphasized.

Marvin, Charles F , Jr↗

Fingerprints of carbon, nitrogen, and silicon isotopes in small interstellar SiC grains from the Murchison meteorite

We report ion microprobe determinations of the carbon, nitrogen, and silicon isotopic compositions of small SiC grains from the Murchison CM2 chondrite. Analyses were made on samples containing variable numbers of grains and on 14 individual grains. In some cases the multiple-grain sample compositions were probably dominated by only one or two grains. Total ranges observed are given. Only a few grains show values near the range limits. Both the total ranges of carbon and nitrogen isotopic compositions, and even the narrower ranges typical for the majority of the grains, are similar to those observed for larger SiC grains. Two rare components appear to be present in the smaller-size fraction, one characterized by C-12/C-13 about 12-16 and the other by very heavy nitrogen. The carbon and nitrogen isotopic compositions qualitatively may reflect hydrostatic H-burning via the CNO cycle and He-burning in red giants, as well as explosive H-burning in novae. The silicon isotopic compositions of most grains qualitatively show what is the signature of He-burning. The silicon isotopic composition of one grain, however, suggests a different process.

Hoppe, Peter↗

Preliminary Results of Field Emission Cathode Tests

Preliminary screening tests of field emission cathodes such as chemical vapor deposited (CVD) diamond, textured pyrolytic graphite, and textured copper were conducted at background pressures typical of electric thruster test facilities to assess cathode performance and stability. Very low power electric thrusters which provide tens to hundreds micronewtons of thrust may need field emission neutralizers that have a capability of tens to hundreds of microamperes. From current voltage characteristics, it was found that the CVD diamond and textured metals cathodes clearly satisfied the Fowler-Nordheim emission relation. The CVD diamond and a textured copper cathode had average current densities of 270 and 380 mA/sq cm, respectively, at the beginning-of-life. After a few hours of operation the cathode emission currents degraded by 40 to 75% at background pressures in the 10(exp -5) Pa to 10(exp -4) Pa range. The textured pyrolytic graphite had a modest current density at beginning-of-life of 84 mA/sq cm, but this cathode was the most stable of all. Extended testing of the most promising cathodes is warranted to determine if current degradation is a burn-in effect or whether it is a long-term degradation process. Preliminary experiments with ferroelectric emission cathodes, which are ceramics with spontaneous electric polarization, were conducted. Peak current densities of 30 to 120 mA/sq cm were obtained for pulse durations of about 500 ns in the 10(exp -4) Pa pressure range.

Sovey, James S.↗

Vacuum Ultraviolet Radiation Desorption of Molecular Contaminants Deposited on Quartz Crystal Microbalances

Recent quartz crystal microbalance measurements made in the Marshall Space Flight Center, Photo-Deposition Facility, for several materials, recorded a significant loss of deposited contaminants when the deposition surface of the microbalance was illuminated by a deuterium lamp. These measurements differ from observations made by other investigators in which the rate of deposition increased significantly when the deposition surface was illuminated with vacuum ultraviolet radiation. These observations suggest that the accelerated deposition of molecular contaminants on optically sensitive surfaces is dependant upon the contaminant being deposited and must be addressed during the materials selection process by common material screening techniques.

Albyn, Keith↗