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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 505 records · Page 28
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NASA NTRS1977

Use of rate equations to describe laser excitation in flames

The region of validity of conventional rate equation formulations used to describe the excitation of flame gases for spectroscopic diagnostic purposes is examined by direct comparison with the density matrix formulation. The density matrix equations are formulated for an ensemble of atoms or molecules in the gas state. These equations are reduced to the steady-state limit for a two-level system under the effect of single-mode and multimode optical fields. The steady-state equations are shown to be valid only when the laser pulse rises slowly with respect to the collisional dephasing rate for single-mode excitation, and for certain special cases under multimode excitation.

Daily, J. W.↗
NASA NTRS1977

On the representation matrices of the spin permutation group

A method is presented for the determination of the representation matrices of the spin permutation group (symmetric group), a detailed knowledge of these matrices being required in the study of the electronic structure of atoms and molecules. The method is characterized by the use of two different coupling schemes. Unlike the Yamanouchi spin algebraic scheme, the method is not recursive. The matrices for the fundamental transpositions can be written down directly in one of the two bases. The method results in a computationally significant reduction in the number of matrix elements that have to be stored when compared with, say, the standard Young tableaux group theoretical approach.

Wilson, S.↗
NASA NTRS1978

Photon-scattering cross sections of H2 and He measured with synchrotron radiation

Total (elastic + inelastic) differential photon-scattering cross sections have been measured for H2 gas and for He, using an X-ray beam. Absolute measured cross sections agree with theory within the probable errors. Relative cross sections (normalized to theory at large S) agree to better than 1% with theoretical values calculated from wave functions that include the effect of electron-electron Coulomb correlation, but the data deviate significantly from theoretical independent-particle (e.g., Hartree-Fock) results. The ratios of measured absolute He cross sections to those of H2, at any given S, also agree to better than 1% with theoretical He-to-H2 cross-section ratios computed from correlated wave functions. It appears that photon scattering constitutes a very promising tool for probing electron correlation in light atoms and molecules. The degree of polarization of the synchrotron radiation beam has been measured by rotating the scattering plane about the beam axis; results are compared with theory.

Ice, G. E.↗
NASA NTRS1979

The physical basis for absorption of light

The effects of light absorption on the wave functions of gas-phase molecules and atoms are investigated by high resolution spectral measurements of radiation emerging from a sample. A Stark-modulated sample of methyl fluoride was irradiated at the 102 GHz rotational transition and the emergent radiation was resolved by means of a spectrum analyzer. For signal oscillator frequencies below or above the molecular resonance by one modulation frequency, the amplitudes of the upper and lower modulation sidebands are found to be of nonuniform intensity, which is inconsistent with amplitude modulation. Emission due to polarization is, however, calculated to be consistent with the results observed, indicating that light absorption should be considered as a subtractive stimulated emission.

Pickett, H. M.↗
NASA NTRS1979

Ionospheric chemistry

This report deals primarily with progress in the chemistry of minor neutrals and ionized constituents of the thermosphere. Significant progress was made over the last few years in quantitative studies of many chemical processes. This success was primarily due to the advent of multiparameter multisatellite programs which permitted accurate simultaneous measurements to be made of many important parameters. In many cases studies of chemical reactions were made with laboratory-like precision. Rate coefficients have been derived as functions of temperature for a number of important reactions. New information has been acquired on nearly every major process which occurs in the thermosphere, including the recombination rates of all major molecular ions, charge transfer reactions, ion atom interchange reactions, and reactions of neutral and ionized metastable atoms and molecules.

Torr, D. G.↗
NASA NTRS1981

Submillimeter, millimeter, and microwave spectral line catalogue

A computer accessible catalogue of submillimeter, millimeter and microwave spectral lines in the frequency range between 0 and 3000 GHZ (i.e., wavelengths longer than 100 mu m) is presented which can be used a planning guide or as an aid in the identification and analysis of observed spectral lines. The information listed for each spectral line includes the frequency and its estimated error, the intensity, lower state energy, and quantum number assignment. The catalogue was constructed by using theoretical least squares fits of published spectral lines to accepted molecular models. The associated predictions and their estimated errors are based upon the resultant fitted parameters and their covariances. Future versions of this catalogue will add more atoms and molecules and update the present listings (133 species) as new data appear. The catalogue is available as a magnetic tape recorded in card images and as a set of microfiche records.

Poynter, R. L.↗
NASA NTRS1980

The effect of solar-cycle ultraviolet flux variations on cometary gas

The effects on comet gas of variations in the solar ultraviolet flux during solar cycle 21 are discussed. The photoionization, photodissociation, and resonance fluorescence and scattering rates of individual atoms and molecules increase by factors ranging up to 4, leading to potential order of magnitude variations in emission-line fluxes between minimum and maximum solar activity. These effects are illustrated for H2O and CO. Recent observations of comet Bradfield (1979) are discussed, and it is suggested that comets appearing near solar maximum be extensively observed to provide information on the response of cometary gas to solar flux variations, which can be used to discriminate between cometary models.

Oppenheimer, M.↗
NASA NTRS1981

Reactions of ground-state and metastable O/2+/ ions with He, O2, N2, and CO2 at thermal energies

Evidence is presented that some previous studies of reactions of O(2+) ions with various atoms and molecules referred to ion samples composed in part of ions in metastable (1D and/or 1S) states. This finding resolves the 3 orders of magnitude discrepancy between previous experimental and calculated rate coefficients for the O(2+)(3P) + He charge transfer process. Using a drift tube to distinguish, via arrival time differences, groundstate O(+)(3P) and metastable ions, a rate coefficient of (3.5 plus or minus 1.5) x 10 to the -11th cu cm/sec is obtained for the reaction, in good agreement with that obtained from ab initio theoretical calculations. Previous conclusions concerning reactions of O(2+) with O2 and N2, however, remain valid since the difference in reactivity of ground-state and metastable O(2+) ions appears to be negligible in this case. The rate coefficient for the reaction O(2+) + CO2 has been determined to be (2 plus or minus 0.5) x 10 to the -9th cu cm/sec for ions either in the ground-state or in metastable states.

Johnsen, R.↗
NASA NTRS1981

Excited ozone is a possible source of atmospheric N2O

Consideration is given to the possibility that internally excited ozone formed in the three-body recombination reaction between oxygen atoms and molecules may be a potential source of atmospheric N2O through a gas-phase reaction with nitrogen molecules. Determinations of the wavelength dependence of the quantum yield for N2O formation from the photolysis of dilute solutions of O3 in liquid N2 and of the O(1D) quantum yield in the gas-phase photolysis of O3 are interpreted as suggesting the possibility of the excited ozone reaction, and a new expression for N2O quantum yield is derived. An expression for the production rate of N2O through the proposed reaction is then obtained and used to calculate atmospheric concentrations and fluxes of N2O. The theoretical profile obtained is found to agree better with experimental data than that obtained without the excited ozone reaction taken into account and to demonstrate a wide variability in N2O mixing ratios. In addition, the existence of the new N2O source is noted to imply a significantly smaller flux of N2O from surface microbiological activities, and provide a possible physical basis for latitudinal and temporal N2O variations and an additional stability for the ozone layer.

Prasad, S. S.↗
NASA NTRS1981

The Jovian hydrogen bulge - Evidence for co-rotating magnetospheric convection

The Jovian hydrogen bulge is located 180 deg away in the System II longitude from the active sector identified as the source region for Jupiter's decametric radio emission and release of energetic electrons into interplanetary space. The sector results from the large magnetic anomaly in the Jovian northern hemisphere; it is expected that a two-cell magnetospheric convection pattern is found in the Jovian atmosphere. The magnetic anomaly of the active sector produces a convection which brings the magnetospheric plasma to the upper atmosphere at the longitudes below the hydrogen bulge; the hot plasma contains electrons with energies of about 100 keV which dissociate atmospheric molecules into atomic hydrogen creating longitudinal symmetry in hydrogen Lyman alpha emission.

Dessler, A. J.↗
NASA NTRS1982

Modeling of thin-film GaAs growth

A model of crystal growth is discussed that takes into account the processes of nucleation on the growing surface and also considers the processes of surface migration and desorption of adatoms. The solid on solid (SOS) model of crystal growth is represented by a rectangular array of integers where each integer represents the number of adatoms in a column perpendicular to some reference frame. The adatoms can represent atoms or molecules that are being stacked. This SOS method is used to simulate epitaxial growth of crystals. Output of the computer program developed can be graphic or quantitative.

Heinbockel, J. H.↗
NASA NTRS1982

Science and technology results from the OSS-1 Payload on the Space Shuttle

The OSS-1 Payload of nine experiments was carried on the STS-3 Space Shuttle flight in March of 1982. The OSS-1 Payload contained four instruments that evaluated specific aspects of the Orbiter's environment, including the levels of particulate, gaseous and electromagnetic emissions given off by the Orbiter, and the interactions between the Orbiter and the surrounding plasma. In addition to these environmental observations, these instruments performed scientific investigations in astronomy and in space plasma physics, including active experiments in electron beam propagation. Other experiments were in the areas of solar physics, plant growth, micrometeorite studies and the technology of actively controlled heat pipes. A description is given of the initial results from these experiments, with some implications of these results for future operation of space experiments from the Shuttle payload bay. One major result was the unexpected discovery of a faint surface-induced optical glow created near the Shuttle surfaces by impacts of ambient atmospheric atoms and molecules.

Chipman, E.↗
NASA NTRS1982

The far-infrared disk of M51

Far-infrared maps and multifrequency photometry are presented for M51 and its companion galaxy NGC 5195. Dust reradiates about half the starlight of the M51 + NGC 5195 system to produce the observed far-infrared (80-200 microns) luminosity of 3 x 10 to the 10th solar luminosities. Observed with 49-arcsec resolution and covering 37 arcmin-squared, the maps show that roughly 70% of this luminosity is produced by the 5 arcmin (approximately 15 kpc) wide far-infrared disk of M51. Comparable luminosities emitted from the central regions (diameters = 49 arcsec or 2.3 kpc) of M51 and NGC 5195 contribute the remaining 30% (approximately 1 x 10 to the 10th solar luminosities). The photometry reveals a difference in energetics at the galactic scale; dust producing the central luminosity of NGC 5195 classified as Ip-Ep, Irr II or SBa(r) is much less abundant and considerably warmer than the approximately 20 K dust producing the central luminosity of M51 (Sc I). Far-infrared properties are given for several galactic scale complexes of star formation in M51. Relationships are discussed for selected maps of optical starlight and emissions from these components of M51's interstellar medium: dust grains, CO molecules, hydrogen atoms, electrons, and H II regions.

Smith, J.↗
NASA NTRS1982

On charge exchange and knock-on processes in the exosphere of Io

One direct consequence of magnetospheric interaction of Io is the strong dynamical coupling of its neutral atmosphere with the corotating plasma. The absorption of the thermal ions and the associated neutral injection is an improtant issue not yet explored. As far as nonthermal escape of the neutral atmosphere is concerned, three processes stand out. That is, apart from sputtering, exospheric interactions like atom-ion knock-on collision and charge exchange recombination could be a significant source of the neutral clouds in the Jovian system. Using a current electrodynamic model of Io, both the absorption rate of the corotating thermal plasma and the production rates of new exospheric ions and the fast neutrals are considered. It is found that the source strength of the neutral atoms and molecules with speeds of about 100 km/sec could amount to 10 to the 26th/sec whereas exospheric neutrals emitted at lower speed (of about 10 km/sec) amounts to 4 x 10 to the 25th/sec. The generation of the new ions in connection with the streaming of the magnetospheric plasma around Io could also produce an asymmetric sputtering with a neutral flux of about 10 to the 27th/sec emitted from the region of Io which faces Jupiter. These results may be related to a number of sodium observations.

Ip, W.-H.↗
NASA NTRS1983

Space radiation interaction mechanisms in materials

Models of charged-particle impact under conditions typical of the space environment are reported, with a focus on impact excitation and nuclear reactions, especially for heavy ions. Impact excitation is studied by using a global model for electronic excitation based on formal relations through the classical dielectric function to derive an approximation related to the local plasma (electron density distribution) within the atoms and molecules; and corrections to the model resulting from the nonfluid nature of this plasma are discussed. Nuclear reactions are studied by reducing quantum-mechanical treatment of this general N-body problem to an equivalent two-body problem that is solvable, and by comparing the results with experimental data. The equations for heavy-charged-particle transport are derived and solution techniques demonstrated. Finally, these methods of analysis are applied to study the change in the electrical properties of a GaAs semiconductor for photovoltaic applications; proton damage to GaAs crystals is found to arise from stable replacement defects and to be nonannealable, in contrast to electron-induced damage.

Wilson, J. W.↗
NASA NTRS1983

Radiation energy receiver for laser and solar propulsion systems

The concept of remotely heating a rocket propellant with a high intensity radiant energy flux is especially attractive due to its high specific impulse and large payload mass capabilities. In this paper, a radiation receiver-thruster which is especially suited to the particular thermodynamic and spectral characteristics of highly concentrated solar energy is proposed. In this receiver, radiant energy is volumetrically absorbed within a hydrogen gas seeded with alkali metal vapors. The alkali atoms and molecules absorb the radiant flux and, subsequently, transfer their internal excitation to hydrogen molecules through collisional quenching. It is shown that such a radiation receiver would outperform a blackbody cavity type receiver in both efficiency and maximum operating temperatures. A solar rocket equipped with such a receiver-thruster would deliver thrusts of several hundred newtons at a specific impulse of 1000 seconds.

Rault, D. F. G.↗
NASA NTRS1983

Explicit Hilbert-space representations of atomic and molecular photoabsorption spectra - Computational studies of Stieltjes-Tchebycheff functions

Computational methods are reported for construction of discrete and continuum Schroedinger states in atoms and molecules employing explicit Hilbert space procedures familiar from bound state studies. As theoretical development, the Schroedinger problem of interest is described, the Cauchy-Lanczos bases and orthonormal polynomials used in constructing L-squared Stieltjes-Tchebycheff (ST) approximations to the discrete and continuum states are defined, and certain properties of these functions are indicated. Advantages and limitations of the ST approach to spectral studies relative to more conventional calculations are discussed, and aspects of the approach in single-channel approximations to larger molecules are described. Procedures are indicated for construction of photoejection anisotropies and for performing coupled-channel calculations employing the ST formalism. Finally, explicit descriptive intercomparisons are made of the nature and diagnostic value of ST functions with more conventional scattering functions.

Hermann, M. R.↗
NASA NTRS1983

Comments on laser-excited fluorescence of the hydroxyl radical: Relaxation coefficients at atmospheric pressure, appendix 5

The lifetime of the excited state of a atom or molecule is often determined from the rate of fluorescence decay originating as a function of buffer gas pressure, an accurate determination is made of the rates of collision induced transitions away from the excited state. Deconvolution can in principle be employed to resolve fluorescence times shorter than the response times of the system. However, attainable reproducibility and accuracy in actual experiments usually set a limit beyond which no meaningful results are expected. Prudence thus dictates that the results of deconvolution be viewed with extreme caution whenever fluorescence time much shorter than the response of times of the system are indicated.

Wang, C. C.↗