Spin-state effects on the thermal dihydrogen release from solid-state [MH(η2-H2)dppe2]+ (M = Fe, Ru, Os) organometallic complexes for hydrogen storage applications
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This study evaluates the latest Global Precipitation Measurement (GPM) Integrated Multi-satellitE Retrievals for GPM (IMERG V07B) against its predecessor V06B, for studying mesoscale convective systems (MCSs). Both versions are compared using ground-based radar and rain gauge data from five meteorologically diverse regions: the contiguous United States (including eastern coastlines), Amazon rainforest, central Argentina mountains, equatorial Indian Ocean, and northern Australia across multiple temporal (0.5–6 hours) and spatial scales (0.1°–0.25°). An updated global MCS tracking dataset is developed by integrating satellite-observed infrared brightness temperature with IMERG V07B. Comparation of IMERG against radar observations reveals that IMERG demonstrates better performance in capturing the probability distribution and quantitative contributions of rainfall (from no-rain to intense-rain conditions) over tropical oceans than over land, with marked improvements in IMERG V07B for heavy-to-intense rain (> 10 mm h-1). Over land, systematic biases persist: IMERG tends to overestimate light-to-moderate rain (1–10 mm h-1) while underestimating heavy-to-intense rain. Additionally, aggregating IMERG to coarser resolutions (3-hourly or 0.25°) improves consistency with radar observations, outperforming the 1-hourly/0.1° resolution. The new IMERG V07B-based global MCS dataset exhibits consistent statistical characteristics with the V06B-based dataset, despite lower mean rain rates and reduced heavy precipitation contributions. These findings offer valuable insights for utilizing IMERG V07B in global precipitation studies, MCS characterization, and model evaluation.
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Traditional processes of making contacts (metallization layer) onto bulk crystalline Bi 2 Te 3 -based materials do not work for nanostructured thermoelectric materials either because of weak bonding strength or an unstable contact interface at temperatures higher than 200 °C. Hot pressing of nickel contact onto nanostructured thermoelectric legs in a one-step process leads to strong bonding. However, such a process results in large contact resistance in n-type Ni/Bi 2 Te 2.7 Se 0.3 /Ni legs, although not in p-type Ni/Bi 0.4 Sb 1.6 Te 3 /Ni legs. A systematic study was carried out here to investigate the detailed reaction and diffusion at the interface of the nickel layer and n-type Bi 2 Te 3 -based thermoelectric material layer. We found that a p-type region formed within the n-type Bi 2 Te 2.7 Se 0.3 during hot pressing due to Te deficiency and Ni doping, leading to a large contact resistance.
Enantioselectivity is examined in the addition of allyl groups to fluorinated ketones.
We demonstrate that shadow nanosphere lithography (SNL) is an auspicious tool to systematically create three-dimensional electrocatalyst nanostructures on the semiconductor photoelectrode through controlling their morphology and optical properties.
Lanthanide complexes are firstly applied for in vivo NIR-II high resolution whole body bioimaging.
The transport of charge carriers throughout an active conjugated polymer (CP) host, characterized by a heterogeneous morphology of locally varying degrees of order and disorder, profoundly influences the performance of CP-based electronic devices.
The structure of π-Ti 2 O(PO 4 ) 2 ·2H 2 O was determined by the SR-PXRD method. The proton conductivity of chitosan/π-TiP membranes reached 4.5 × 10 −3 S cm −1 at 95%-RH.
A facile and universal route for synthesizing transition metal borides has been developed by reaction of boron triiodide (BI 3 ) with elemental transition metals.