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At least 487 records · Page 27

Polymer solution phase separation: Microgravity simulation

In many multicomponent systems, a transition from a single phase of uniform composition to a multiphase state with separated regions of different composition can be induced by changes in temperature and shear. The density difference between the phase and thermal and/or shear gradients within the system results in buoyancy driven convection. These differences affect kinetics of the phase separation if the system has a sufficiently low viscosity. This investigation presents more preliminary developments of a theoretical model in order to describe effects of the buoyancy driven convection in phase separation kinetics. Polymer solutions were employed as model systems because of the ease with which density differences can be systematically varied and because of the importance of phase separation in the processing and properties of polymeric materials. The results indicate that the kinetics of the phase separation can be performed viscometrically using laser light scattering as a principle means of following the process quantitatively. Isopycnic polymer solutions were used to determine the viscosity and density difference limits for polymer phase separation.

Cerny, Lawrence C.↗

DNS and LES of a Shear-Free Mixing Layer

The purpose of this work is twofold. First, given the computational resources available today, it is possible to reach, using DNS, higher Reynolds numbers than in Briggs et al.. In the present study, the microscale Reynolds numbers reached in the low- and high-energy homogeneous regions are, respectively, 32 and 69. The results reported earlier can thus be complemented and their robustness in the presence of increased turbulence studied. The second aim of this work is to perform a detailed and documented LES of the shear-free mixing layer. In that respect, the creation of a DNS database at higher Reynolds number is necessary in order to make meaningful LES assessments. From the point of view of LES, the shear-free mixing-layer is interesting since it allows one to test how traditional LES models perform in the presence of an inhomogeneity without having to deal with difficult numerical issues. Indeed, as argued in Briggs et al., it is possible to use a spectral code to study the shear-free mixing layer and one can thus focus on the accuracy of the modelling while avoiding contamination of the results by commutation errors etc. This paper is organized as follows. First we detail the initialization procedure used in the simulation. Since the flow is not statistically stationary, this initialization procedure has a fairly strong influence on the evolution. Although we will focus here on the shear-free mixing layer, the method proposed in the present work can easily be used for other flows with one inhomogeneous direction. The next section of the article is devoted to the description of the DNS. All the relevant parameters are listed and comparison with the Veeravalli & Warhaft experiment is performed. The section on the LES of the shear-free mixing layer follows. A detailed comparison between the filtered DNS data and the LES predictions is presented. It is shown that simple eddy viscosity models perform very well for the present test case, most probably because the flow seems to be almost isotropic in the small-scale range that is not resolved by the LES.

Knaepen, B.↗

New instability modes for bounded, free shear flows

A class of highly amplified supersonic disturbances are found for high-speed, bounded mixing layers at high values of streamwise wavenumber. Their amplification is an order of magnitude greater than the most amplified modes, which occur at 60-65 deg at low streamwise wavenumber. These disturbances are stabilized by increasing Mach number, viscosity, and sweep; however, the effect of sweep on the most amplified mode is not significant until the wave propagation angle reaches 30 deg. The maximum growth rate of the unstable disturbances decreases as the temperature of the higher Mach number stream is increased. The structure of these disturbances is such that the phase speed with respect to the mean flow is subsonic in a small region in the center of the shear layer, and supersonic on either side of this region.

Macaraeg, Michele G.↗

Solvent-Dependent Dynamics of Cellulose Nanocrystals in Process-Relevant Flow Fields

Flow-assisted alignment of anisotropic nanoparticles is a promising route for the bottom-up assembly of advanced materials with tunable properties. While aligning processes could be optimized by controlling factors such as solvent viscosity, flow deformation, and the structure of the particles themselves, it is necessary to understand the relationship between these factors and their effect on the final orientation. In this study, we investigated the flow of surface-charged cellulose nanocrystals (CNCs) with the shape of a rigid rod dispersed in water and propylene glycol (PG) in an isotropic tactoid state. In situ scanning small-angle X-ray scattering (SAXS) and rheo-optical flow-stop experiments were used to quantify the dynamics, orientation, and structure of the assigned system at the nanometer scale. The effects of both shear and extensional flow fields were revealed in a single experiment by using a flow-focusing channel geometry, which was used as a model flow for nanomaterial assembly. Due to the higher solvent viscosity, CNCs in PG showed much slower Brownian dynamics than CNCs in water and thus could be aligned at lower deformation rates. Moreover, CNCs in PG also formed a characteristic tactoid structure but with less ordering than CNCs in water owing to weaker electrostatic interactions. The results indicate that CNCs in water stay assembled in the mesoscale structure at moderate deformation rates but are broken up at higher flow rates, enhancing rotary diffusion and leading to lower overall alignment. Albeit being a study of cellulose nanoparticles, the fundamental interplay between imposed flow fields, Brownian motion, and electrostatic interactions likely apply to many other anisotropic colloidal systems.

36 MATERIALS SCIENCE↗

Numerical solution of three-dimensional free turbulent shear flows

Numerical results are presented for three-dimensional compressible turbulent jet and wake flows. An alternating direction implicit numerical procedure is used to solve the finite-difference form of the parabolic elliptic Navier-Stokes equations. A coordinate transformation maps the boundaries at infinity into a finite computational domain in order to properly specify infinity boundary conditions as well as contain the downstream growth of the viscous flow field in a fixed computational grid. Turbulence closure is achieved through an algebraic mixing length eddy viscosity model. Numerical results for supersonic flow are presented for an axisymmetric jet, an elliptical jet, an elliptical wake, and two interacting rectangular jets. Experimental data were not available for comparison with the numerical results. However, the results compare well with empirical results for free shear flows.

Oh, Y. H.↗

Measurement of viscosity and elasticity of lubricants at high pressures

The oscillating quartz crystal viscometer has been used to investigate possible viscoelastic behavior in synthetic lubricating fluids and to obtain viscosity-pressure-temperature data for these fluids at temperatures to 300 F and pressures to 40,000 psig. The effect of pressure and temperature on the density of the test fluids was measured concurrently with the viscosity measurements. Viscoelastic behavior of one fluid, di-(2-ethylhexyl) sebacate, was observed over a range of pressures. These data were used to compute the reduced shear elastic (storage) modulus and reduced loss modulus for this fluid at atmospheric pressure and 100 F as functions of reduced frequency.

Rein, R. G., Jr.↗

A potential-flow/boundary-layer method for calculating subsonic and transonic airfoil flow with trailing-edge separation

The development of a potential-flow/boundary-layer method for calculating subsonic and transonic turbulent flow past airfoils with trailing-edge separation is reported. A moment-of-momentum integral boundary-layer method is used which employs the law-of-the-wall/law-of-the-wake velocity profile and a two-layer eddy-viscosity model and ignores the laminar sublayer. All integrals across the boundary layer are obtained in closed form. Separation is assumed to occur when the shearing-stress velocity vanishes. A closed-form solution is derived for separated-flow regions where the shearing stress is negligible. In the potential-flow method, the exact form of the airfoil boundary condition is used, but it is applied at the chord line rather than the airfoil surface. This allows the accurate computation of flow about airfoils at large angles of attack but permits the use of body-oriented Cartesian computational grids. The governing equation for the perturbation velocity potential contains several terms in addition to the classical small-disturbance terms.

Barnwell, R. W.↗

A new readily processable polyimide

As part of an effort to develop tough solvent resistance thermoplastics for potential use as structural resins on aerospace vehicles, a new processable polyimide was evaluated. The synthesis involved the reaction of a new diamine, 1,3-bis 2-(3-aminophenoxy)ethyl ether, with 3,3',4,4'-benzophenonetetracarboxylic dianhydride to form the polyamic acid and subsequent conversion of it to the polyimide. Various physical properties such as thermal stability, solvent resistance, glass transition temperature, crystalline melt temperature, melt viscosity and mechanical properties such as fracture toughness, adhesive, film and composite properties are reported. Of particular interest is the extremely high titanium to titanium tensile shear strength obtained for this polyimide.

Harris, F. W.↗

A new readily processable polyimide

As part of an effort to develop tough solvent resistance thermoplastics for potential use as structural resins on aerospace vehicles, a new processable polyimide was evaluated. The synthesis involved the reaction of a new diamine, 1,3-bis 2-(3-aminophenoxy)ethyl ether, with 3,3',4,4'-benzophenonetetracarboxylic dianhydride to form the polyamic acid and subsequent conversion of it to the polyimide. Various physical properties such as thermal stability, solvent resistance, glass transition temperature, crystalline melt temperature, melt viscosity and mechanical properties such as fracture toughness, adhesive, film and composite properties are reported. Of particular interest is the extremely high titanium to titanium tensile shear strength obtained for this polyimide.

Harris, F. W.↗

Numerical simulation of turbulence in the presence of shear

The numerical calculations are presented of the large eddy structure of turbulent flows, by use of the averaged Navier-Stokes equations, where averages are taken over spatial regions small compared to the size of the computational grid. The subgrid components of motion are modeled by a local eddy-viscosity model. A new finite-difference scheme is proposed to represent the nonlinear average advective term which has fourth-order accuracy. This scheme exhibits several advantages over existing schemes with regard to the following: (1) the scheme is compact as it extends only one point away in each direction from the point to which it is applied; (2) it gives better resolution for high wave-number waves in the solution of Poisson equation, and (3) it reduces programming complexity and computation time. Examples worked out in detail are the decay of isotropic turbulence, homogeneous turbulent shear flow, and homogeneous turbulent shear flow with system rotation.

Shaanan, S.↗

Calculation of wall and free turbulent-shear flows at supersonic speeds

Supersonic turbulent flows are simulated numerically by solving the Reynolds-averaged full Navier-Stokes equations by an implicit finite-volume method. This flux-vector-split upwind scheme uses approximate factorization followed by line-Gauss-Seidel relaxations. The effects of turbulence are modeled by two eddy viscosity models. High-Reynolds-number form of the k-epsilon model is coupled with a wall-function to avoid excessive refinement of the grid in the low-Reynolds number regions. The k-epsilon equations are solved by the explicit-implicit MacCormack method. The algebraic Baldwin-Lomax model is also being used as an inexpensive alternative for the cases which do not experience massive separation. Several examples of two-dimensional solutions are given to illustrate both wall and free turbulent shear flows which include fluid dynamic phenomena, such as shocks, boundary layers, shear layers, wakes, separations and recirculations. The results compared with experimental data show good agreeent.

Baysal, O.↗

Initial development of a hypersonic free mixing layer

A preliminary experimental investigation to establish some of the characteristics and further the understanding of the initial development of a turbulent free mixing layer for hypersonic speeds has been conducted. Mean profile data at about 6 inches downstream of the exit of a hypersonic nozzle have been obtained in nitrogen for a nominal Mach number of 19.5, total temperature of about 1670 K and Reynolds number range from about 50,000 to 110,000 per foot and have been compared with profiles upstream of the nozzle exit. Static pressure varied across the shear layer for the present tests. The outer 80 percent of the high-velocity portion of the free shear layer can be calculated by a rotational method of characteristics. However, turbulent mixing is evidently important in the low-velocity region, and effects of eddy viscosity and eddy conductivity should be included in a theoretical analysis.

Harvey, W. D.↗

Block Polyelectrolyte Additives That Modulate the Viscoelasticity and Enhance the Printability of Gelatin Inks at Physiological Temperatures

We demonstrate the utility of block polyelectrolyte (bPE) additives to enhance viscosity and resolve challenges with the three-dimensional (3D) printability of extrusion-based biopolymer inks. The addition of oppositely charged bPEs to solutions of photocurable gelatin methacryloyl (GelMA) results in complexation-driven self-assembly of the bPEs, leading to GelMA/bPE inks that are printable at physiological temperatures, representing stark improvements over GelMA inks that suffer from low viscosity at 37 °C, leading to low printability and poor structural stability. The hierarchical microstructure of the self-assemblies (either jammed micelles or 3D networks) formed by the oppositely charged bPEs, confirmed by small-angle X-ray scattering, is attributed to the enhancements in the shear strength and printability of the GelMA/bPE inks. Varying bPE concentration in the inks is shown to enable tunability of the rheological properties to meet the criteria of pre- and postextrusion flow characteristics for 3D printing, including prominent yielding behavior, strong shear thinning, and rapid recovery upon flow cessation. Moreover, the bPE self-assemblies also contribute to the robustness of the photo-cross-linked hydrogels; photo-cross-linked GelMA/bPE hydrogels are shown to exhibit higher shear strength than photo-cross-linked GelMA hydrogels. Last, the assessment of the printability of GelMA/bPE inks indicates excellent printing performance, including minimal swelling postextrusion, satisfactory retention of the filament shape upon deposition, and satisfactory shape fidelity of the various printed constructs. We envision this study to serve as a practical guide for the printing of bespoke extrusion inks where bPEs are used as scaffolds and viscosity enhancers that can be emulated in a range of photocurable precursors.

36 MATERIALS SCIENCE↗

Turbulence processes and simple closure schemes

The closure problem in turbulence is briefly reviewed, and some simple closure schemes are introduced. Processes occurring in turbulent flow are discussed on the basis of solutions for some elementary flows such as homogeneous turbulence with and without uniform shear. Closure by specification of initial conditions, and finally practical closure schemes for more complicated flows (e.g., pipe flows) are considered briefly. The latter include Reynolds stress, eddy viscosity, and mixing-length closures.

Deissler, R. G.↗

A free surface vortex method with weak viscous effects

The advantage of vortex methods for inviscid flows of several fluids separated by interfaces is that problems of this kind may be posed and solved numerically entirely on the interface surface. For free surface problems, where one of the fluids has negligible inertia, a small amount of viscosity produces a thin, weak rotational layer adjacent to the potential flow vortex sheet. Here, a method is described for including this weak viscous effect as a modification of the boundary conditions for the potential part of the flow, thus allowing this slightly viscous flow to be formulated as a vortex method on the free surface. This is important for unsupported free drops where the viscosity at the free surface is the only source of damping for oscillations, and for gas-filled bubbles, where it provides both drag and damping. Small applied shear stresses from aerodynamic, electrostatic, or other sources may be included provided they are of the same order as the potential flow shear stress or smaller.

Lundgren, T. S.↗

Effective Inflow Conditions for Turbulence Models in Aerodynamic Calculations

The selection of inflow values at boundaries far upstream of an aircraft is considered, for one- and two-equation turbulence models. Inflow values are distinguished from the ambient values near the aircraft, which may be much smaller. Ambient values should be selected first, and inflow values that will lead to them after the decay second; this is not always possible, especially for the time scale. The two-equation decay during the approach to the aircraft is shown; often, the time scale has been set too short for this decay to be calculated accurately on typical grids. A simple remedy for both issues is to impose floor values for the turbulence variables, outside the viscous sublayer, and it is argued that overriding the equations in this manner is physically justified. Selecting laminar ambient values is easy, if the boundary layers are to be tripped, but a more common practice is to seek ambient values that will cause immediate transition in boundary layers. This opens up a wide range of values, and selection criteria are discussed. The turbulent Reynolds number, or ratio of eddy viscosity to laminar viscosity has a huge dynamic range that makes it unwieldy; it has been widely mis-used, particularly by codes that set upper limits on it. The value of turbulent kinetic energy in a wind tunnel or the atmosphere is also of dubious value as an input to the model. Concretely, the ambient eddy viscosity must be small enough to preserve potential cores in small geometry features, such as flap gaps. The ambient frequency scale should also be small enough, compared with shear rates in the boundary layer. Specific values are recommended and demonstrated for airfoil flows

Spalart, Philippe R.↗

A Laboratory Assessment and Optimization of Nanoparticle-Stabilized CO2 Foams for Hydraulic Fracturing Applications

In this research, we have conducted a comprehensive assessment and optimization of aqueous CO2 foams for fracturing applications. The performance of CO2 foams is evaluated using three major matrices: foam stability, foam apparent viscosity, and leakoff. The response of these performance matrices to different internal factors and external conditions is evaluated. These factors and conditions include foam quality, nanoparticle concentration, salinity, shear rate, surfactant type and concentration, polymer concentration, and temperature. Before foam generation, the colloidal stability of the nanosilica dispersion is evaluated at different types of electrolytes and under high temperatures. With a good salinity resistance and thermal stability, the nanosilica is then used for the entire set of foam generation experiments. The foam configuration with optimized parameters is used for the leakoff test, which serves as a supplementary section to further demonstrate the advantages of the proposed foam system. Then the final commercialization section provides a general view of what should be considered to commercialize the research results. In general, it is found that the aqueous CO2 foam system has demonstrated a good potential to be used as a fracturing fluid. The design of the foam system needs to consider formations properties and formation fluid properties etc. to realize the optimal performance of the system on a laboratory scale.

02 PETROLEUM↗

Comment on: The present state and future direction of eddy viscosity models

Two turbulence models are compared under various flow conditions. Presented first is a k-omega model which is best suited for wall bounded flows. Presented second is a k-epsilon model which is best suited for free shear flow. Generalizations of the k-omega model are discussed, and various aerodynamic parameters such as skin friction, velocity distribution, and hypersonic cylinder-flare, are compared for the different models. All results are presented in viewgraph format.

Coakley, T. J.↗