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At least 487 records · Page 27

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NASA NTRS1977

CO2 and humidity removal system for extended Shuttle missions - CO2, H2O, and trace contaminant equilibrium testing

The equilibrium relationships for the co-adsorption of CO2 and H2O on an amine coated acrylic ester are presented. The equilibrium data collection and reduction techniques are discussed. Based on the equilibrium relationship, other modes of operation of systems containing HS-C are discussed and specific space applications for HS-C are presented. Equilibrium data for 10 compounds which are found as trace contaminants in closed environments are also presented.

Davis, S. H.↗

NASA NTRS1977

Volatile/mobile trace elements in Karoonda /C4/ chondrite

Concentrations of ten volatile/mobile trace elements and of nonvolatile Co in the Karoonda (C4) meteorite were determined, and the atomic abundances relative to C1 are compared with values for the Murchison (C2) and Allende (C3) meteorites. Empirical Bi, In, and Tl data for Karoonda and heated Allende and Murchison are compared with theoretical curves for condensation from a gas of cosmic composition at low pressures. It is suggested that Karoonda might derive from low-temperature open-system metamorphism of pristine C3-like material.

Matza, S. D.↗

NASA NTRS1978

Low-background trace-gas detector

Spectrophone detects very small concentrations of trace gases. With gas in sample cell, laser is tuned to absorption line of interest. Molecular absorption in cell produces pulsed acoustical pressure at chopper frequency. Two optical paths with very different absorption lengths are used to pretune cell to balance out background absorption by cell windows.

Rosengren, L.↗

NASA NTRS1977

Spacelab baseline ECS trace contaminant removal test program

An estimate of the Spacelab Baseline Environmental Control System's contaminated removal capability was required to allow determination of the need for a supplemental trace contaminant removal system. Results from a test program to determine this removal capability are presented.

Ray, C. D.↗

NASA NTRS1978

The capability of satellite borne remote sensors to measure stratospheric trace constituents. Volume 1: Background and requirements

Volume 1 of a three volume report issued as MITRE/METREX Technical Report is presented. This volume contains a synthesis of the results of two previous MITRE/METREX studies and an update of the information. These studies deal with a comprehensive review of stratospheric trace constituent measurement requirements. The scope of the study was restricted to those contituents which fall into the general category of air pollutants.

Keitz, E. L.↗

NASA NTRS1978

The capability of satellite borne remote sensors to measure stratospheric trace constituents. Volume 2: Ozone and aerosol related missions

Stratospheric trace constituent measurement requirements are separated into two somewhat overlapping areas. In the first area, it is assumed that the only problem of interest is ozone; its chemistry chain, environmental effects and measurement requirements. In like manner, in the second area it is assumed that the only problem of interest is stratospheric aerosols; their chemistry, effects and measurement requirements.

Keitz, E. L.↗

NASA NTRS1977

Trace elements in the Allende meteorite. III - Coarse-grained inclusions revisited

Radiochemical neutron activation analytic determinations of several elements in coarse-grained inclusions of the Allende meteorite are reported. The condensation and fractionation behavior of these and other elements are described. Evidence was found for a post-accretion thermal event which redistributed some trace elements. The solar system ratio of Zr/Hf is computed on the basis of the minimum variation in the inclusion, and the percentage of high-temperature condensates in the earth and moon are calculated on the basis of the mean U content of the inclusions. The mean value of the enrichment factors of 21 refractory elements relative to C1 chondrites is provided, and the elements that did or did not condense in a solid solution of melilite are listed.

Grossman, L.↗

NASA NTRS1978

Ray tracing of gravity waves as a possible warning system for tornadic storms and hurricanes

Gravity waves with wave periods of 13 to 15 min and horizontal phase velocities of 90 to 220 m/sec were present in ground-based observations of the upper atmosphere during time periods when tornadoes were occurring and gravity waves with wave periods of 20 to 25 min and horizontal phase velocities of 100 to 200 m/sec were detected when a hurricane was present. Combinations of available neutral atmosphere data and model parameter values were used with a group ray tracing technique in an attempt to locate the sources of these waves. Computed sources of the waves with periods of 13 to 15 min were located within 50 km of the locations where tornadoes touched down from 2 to 4 h later. In the case of the waves with periods of 20 to 25 min it was found that the computed location of the source was roughly where the hurricane would be located 3 h after the waves were excited. The applicability of the present study to a tornado and hurricane warning system is noted.

Hung, R. J.↗

NASA NTRS1978

A review of experimental studies of crystal/liquid trace element partitioning

Experimental techniques for examining trace-element behavior are reviewed. Applications of these techniques are described for a variety of partition coefficients including: olivine/liquid, subcalcic pyroxene/liquid, calcic pyroxene/liquid, amphibole/liquid, plagioclase/liquid, alkali feldspar/liquid, garnet/liquid, apatite/liquid and whitlockite/liquid, ilmenite/liquid, armalcolite/liquid and pseudobrookite/liquid, magnetite/liquid and spinel/liquid, perovskite/liquid, and melilite/liquid partition coefficients. Partition coefficients between immiscible liquids are discussed and suggestions for further work are noted. A detailed bibliography is included.

Irving, A. J.↗

NASA NTRS1978

Ray tracing evaluation of a technique for correcting the refraction errors in satellite tracking data

Errors may be introduced in satellite laser ranging data by atmospheric refractivity. Ray tracing data have indicated that horizontal refractivity gradients may introduce nearly 3-cm rms error when satellites are near 10-degree elevation. A correction formula to compensate for the horizontal gradients has been developed. Its accuracy is evaluated by comparing it to refractivity profiles. It is found that if both spherical and gradient correction formulas are employed in conjunction with meteorological measurements, a range resolution of one cm or less is feasible for satellite elevation angles above 10 degrees.

Gardner, C. S.↗

NASA NTRS1980

Extracting trace substances from biological fluids

Apparatus is used as aid in extraction of trace amounts of volatile organics from biological fluids. "Transervaporator" makes it possible to prepare violate fraction for analysis by high-resolution gas chromatography.

Zlatkis, A.↗

NASA NTRS1979

Theoretical simulation of solar spectra in the middle ultraviolet and visible for atmospheric trace constituent measurements

The data compiled during the study allowed a detailed examination of the attenuation of the solar radiance by the combined effect of the atmospheric trace gases and the SAGE filters. The case of the 0.44 microns channel is presented. The amounts of NO2, NO2, O3 and the airmass were chosen to closely simulate a low sun spectral scan from a 9 February 1977 balloon flight. The solar radiance outside the earth's atmosphere was determined from the AFGL Sacramento Peak Observatory spectral data tape degraded to 2.0A resolution and normalized to Thekaekara's absolute intensities. The spectral absorption coefficients used for NO2 and O3 were tabulated previously.

Goldman, A.↗

NASA NTRS1979

Measurement techniques for trace metals in coal-plant effluents: A brief review

The strong features and limitations of techniques for determining trace elements in aerosols emitted from coal plants are discussed. Techniques reviewed include atomic absorption spectroscopy, charged particle scattering and activation, instrumental neutron activation analysis, gas/liquid chromatography, gas chromatographic/mass spectrometric methods, X-ray fluorescence, and charged-particle-induced X-ray emission. The latter two methods are emphasized. They provide simultaneous, sensitive multielement analyses and lend themselves readily to depth profiling. It is recommended that whenever feasible, two or more complementary techniques should be used for analyzing environmental samples.

Singh, J. J.↗

NASA NTRS1978

Lidar remote sensing of tropospheric pollutants and trace gases - Programs of NASA Langley Research Center

NASA Langley Research Center is engaged in a number of in-house and contracted programs to develop, evaluate, and apply lidar techniques to remote measurements of pollutant gases, trace molecules, and aerosols. The differential absorption lidar (DIAL) research programs include the development and evaluation of a UV DIAL system for remote measurements of SO2 and O3 concentrations and aerosol dispersion in urban and power-plant stack plumes, a near-IR DIAL system for vertical measurements of water vapor concentrations, and a high-power tunable IR DIAL system which will measure the concentration of gas species that have absorption features in the 1.4- to 4.4-micron wavelength range. The lidar programs which deal with aerosol measurements include the evaluation of a mobile ruby lidar system for use in plume dispersion model verification and the development of a high-spectral-resolution lidar system for measurement of aerosol extinction and backscattering coefficients. System characteristics and measurement sensitivities are discussed, and comparisons are made between simulations and experimental results.

Browell, E. V.↗

NASA NTRS1978

The airborne Laser Absorption Spectrometer - A new instrument of remote measurement of atmospheric trace gases

The Laser Absorption Spectrometer is a portable instrument developed by JPL for remote measurement of trace gases from an aircraft platform. It contains two carbon dioxide lasers, two optical heterodyne receivers, appropriate optics to aim the lasers at the ground and detect the backscattered energy, and signal processing and recording electronics. Operating in the differential-absorption mode, it is possible to monitor one atmospheric gas at a time and record the data in real time. The system can presently measure ozone, ethylene, water vapor, and chlorofluoromethanes with high sensitivity. Airborne measurements were made in early 1977 from the NASA/JPL twin-engine Beechcraft and in May 1977 from the NASA Convair 990 during the ASSESS-II Shuttle Simulation Study. These flights resulted in measurements of ozone concentrations in the lower troposphere which were compared with ground-based values provided by the Air Pollution Control District. This paper describes the details of the instrument and results of the airborne measurements.

Shumate, M. S.↗

NASA NTRS1978

Millimeter wavelength spectroscopy of trace atmospheric constituents from the Five College Radio Astronomy Observatory

The Five College Radio Astronomy Observatory system, located in western Massachusetts, is described. It is suggested that high sensitivity in the three-millimeter wavelength band facilitates detection and monitoring of a number of trace molecules in the earth's atmosphere as well as astonomical observation at radio wavelengths. Line formation and radiative transfer in the earth's atmosphere are discussed, and the receiver sensitivity is considered.

Huguenin, G. R.↗

NASA NTRS1978

Stratospheric trace gas sampling with chemical absorption filters

Recent interest in stratospheric chemistry, sparked in part by the suggested roles of atomic chlorine (Cl) and nitrogen oxides (NOx) in the catalytic destruction of ozone (O3), has made sampling and measurement of trace constituents above the tropopause highly desirable. An ongoing research program in the In Situ Studies Project at the National Center for Atmospheric Research carries out aircraft and balloon-borne stratospheric chemical sampling at regular intervals by using chemically impregnated filters to collect particles and reactive gases.

Bonelli, J. E.↗

NASA NTRS1978

Major and trace element chemistry of Luna 24 samples from Mare Crisium

Atomic absorption spectrometry and instrumental neutron activation analysis were employed to analyze six Luna 24 soils for major and trace elements. The analysis revealed well-mixed soils, though size fractions of each of the soils showed quite dissimilar compositions. Thus the regolith apparently has not been extensively reworked. Noritic breccia admixed preferentially to the finest size fractions and differential comminution of one or more other soil components accounted for the observed elemental distributions as a function of grain size. The ferrobasalt composition and one or more components with higher MgO contents have been identified in the samples.

Blanchard, D. P.↗