A surface-wave investigation of the rupture mechanism of the Gobi-Altai /December 4, 1957/ earthquake
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The possible role of spallation on the free surfaces of target bodies in asteroid surface evolution in the presence of colliding bodies is considered. The ease of impact melt formation is discussed based on the results of shock recovery experiments, and a difference between collisions with dense, nonporous targets and with porous, particulate powders is demonstrated. It is shown that agglutinate-type glasses can be produced at impact velocities of 5 km/sec, but only in highly comminuted, porous targets and not in dense rocks. The apparent lack of agglutinate-type glasses on asteroid surfaces is explained in terms of coarse-grained asteroidal surfaces acting as dense, nonporous bedrock. It is argued that a possible mechanism inhibiting asteroidal surface comminution so as to inhibit melt formation and the effects of micrometeoroid impacts can be represented by collision processes with finite-sized targets rather than with a semi-infinite half-space as in the case of the moon, which give rise to spallation products rather than crater ejecta.
This paper describes the novel method used for supporting the thermally controlled panel on the uncontrolled structure. The method described allows for large magnitude thermally induced relative motion between the panels while it simultaneously provides a controlled thermal resistivity between the two panels. The resulting design is also capable of withstanding the accelerations of atmospheric entry and provides sufficient stiffness to ensure its motion is significantly de-coupled from that of the launch vehicle.
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Understanding the radiolytic reactivity of aluminum oxyhydroxide phases widely present in stored nuclear wastes is essential to develop reliable processing approaches. Recent experiments using vibrational sum frequency generation (VSFG), a surface sensitive technique, have shown that rehydration of γ-irradiated boehmite (010) and gibbsite (001) surfaces does not recover the initial hydroxyl density prior to irradiation. In this study, using density functional theory and nudged elastic band calculations, we examine dehydration and rehydration of these surfaces and attendant proton transfer mechanisms. While dehydration of both surfaces is predicted to be energetically unfavorable, rehydration of boehmite (010) is favorable after overcoming an energy barrier of 0.52 eV that relates to the orientation of surface hydroxyls controlling the hydrogen bonding network of adsorbed water. In the case of gibbsite (001), for which the experimental results suggest that rehydration mainly involves the reformation of interlayer hydroxyls, we found that a two-proton transfer mechanism is more likely than a one-proton transfer mechanism, and that it prevents the reorientation of interlayer hydroxyls into intralayer hydroxyls consistent with experimental VSFG findings. A detailed analysis of the effect of surface hydrogen vacancy on the strength of hydrogen bond interactions was performed, which indicates that H 2 and H 2 O are the energetically most favorable product species to form from radiation-induced surface H and/or OH defects.
The basic pulse tube refrigerator produces cooling by a mechanism known as surface heat pumping. Cyclical compression and expansion of a gas within an enclosed tube produces large temperature gradients. The purpose of the tube is to act as 'nodal regenerator'. Heat is stored at node positions along the tube wall and is transported between nodes by moving gas parcels. This process gives rise to refrigeration, with hot temperatures at the closed end and cold temperatures at the open end. Unfortunately, much of the available refrigeration is not realized because the closed end of the basic pulse tube restricts gas movement - gas at the extreme temperatures does not come in contact with the heat exchangers. The orifice pulse tube overcomes this limitation by using a valve and surge volume assembly at the warm, closed end. This allows for a residual gas velocity to remain present during the heat transfer process, thereby permitting more gas to exchange heat at the heat exchangers. This paper describes the pulse tube as a nodal regenerator and the effect residual gas velocity has on the heat transfer mechanism of the orifice pulse tube.
Quantum mechanical methods have been used to compute potential energy surfaces for chemical reactions. The reactions studied were among those believed to be important to the NASP and HSR programs and included the recombination of two H atoms with several different third bodies; the reactions in the thermal Zeldovich mechanism; the reactions of H atom with O2, N2, and NO; reactions involved in the thermal De-NO(x) process; and the reaction of CH(squared Pi) with N2 (leading to 'prompt NO'). These potential energy surfaces have been used to compute reaction rate constants and rates of unimolecular decomposition. An additional application was the calculation of transport properties of gases using a semiclassical approximation (and in the case of interactions involving hydrogen inclusion of quantum mechanical effects).
Introduction: “I think dust is probably one of our greatest inhibitors to a nominal operation on the Moon. I think we can overcome other physio-logical or physical or mechanical problems except dust.”– Gene Cernan, Apollo 17 Technical Debrief The Apollo missions revealed the impact of lu-nar dust on mechanisms. Lunar dust particles are jagged and electrostatically charged, giving them the ability to bind or damage mechanisms and alter thermal properties. Reports documented clogged equipment and jammed mechanisms in every mission, regardless of surface duration, as well as clogged mechanisms in the Extravehicular Mobility Suit (EMS), including zippers, wrist and hose locks, faceplates, and sunshades [1-2]. Several astronauts remarked they could not have sustained surface activity much longer because clogged joints would have frozen up completely [2]. Effective dust mitigation strategies are need-ed to support longer duration stays on the lunar surface [3-4]. State of the Art: Technology for mechanisms able to operate in dusty enviroments is advancing rapidly due to the needs of both Mars rovers and the Artemis program. Vacuum-tight connectors are essential for spacesuits and habitats, and their performance can be dependent on cleaning technologies, which have proven difficult on the lunar surface. Several TRL 3-5 technologies are undergoing tests with the expectation to reach TRL 6 within 1-2 years. Some mechanisms will be infused and tested on the VIPER (Volatiles Inves-tigating Polar Exploration Rover) mission planned for mid-2020s. NASA Funded Efforts: NASA has recognized the need for dust tolerant mechanisms, and has partnered with industry to advance the state-of-the-art. At NASA GRC, KSC, and JSC, the Dust Tolerant Mechanisms Project is working to devel-op advanced actuator seals for rotary joints and rotary bearing technologies for long-term sus-tained operation in lunar dust environments. An-other NASA project at NASA GRC, partnered with GSFC, JPL, and KSC is Motors for Dusty & Ex-treme Cold Environments (MDECE). MDECE is developing an unheated magnetically-geared mo-tor that can operate continuously for a long dura-tion at an ambient temperature of -243 ºC (33 K). NASA GRC has the capability to characterize the effects of dust on seals, mechanisms, and other mating surfaces and components under lunar conditions [5]. Through the SBIR/STTR program, NASA has funded several companies to advance dust toler-ant mechanisms via the Dust Tolerant Mecha-nisms sub-topic with applications in surface mobil-ity, spacesuits, connectors, joints, and more. LSIC and Community Efforts: The Lunar Surface Innovation Consortium (LSIC) Dust Miti-gation focus group has fostered collaborations across NASA, industry, and academia to develop solutions that minimizes the impact of lunar dust on robotic and human systems. Community ef-forts have included topical meetings on dust tol-erant mechanisms, featured technology presenta-tions, and feedback to NASA on potential gaps and needs. Testing: In 2021, NASA released NASA-STD-1008 [6]. This NASA Technical Standard estab-lishes minimum requirements and provides guid-ance for testing systems and hardware to be ex-posed to dust in planetary environments. The standard has specific sections dedicated to Mechanisms Testing (e.g. bearings, gears) as well as Seals and Mating Surfaces Testing (e.g. hatches, docking systems). Gaps and Needs: NASA is tracking dust tol-erant mechanisms as a gap in a cross-directorate analysis of capability areas needed to enable fu-ture human space-flight architectures. Two high-priority gap areas include additional facilities for testing mechanisms in lunar-surface conditions, and a better understanding of vulnerabilities to the smallest, nanometer-scale dust particles. Conclusion: Understanding and mitigating lu-nar dust is critical to successful, sustained opera-tions on the lunar surface – whether autonomous or otherwise. This presentation will discuss both the state-of-the-art and open needs in lunar dust tolerant mechanisms, technology impacts, mitiga-tion approaches, testing, LSIC community efforts, and more. References: [1] Gaier, J. R. (2020). The Im-pact of Dust on Lunar Surface Equipment During Apollo. Lunar Dust 2020. [2] GRC, & Gaier, J. R. (2005). The Effects of Lunar Dust on EVA Sys-tems During the Apollo Missions. [3] Johansen, M. R. (2020). An Update on NASA’s Lunar Dust Mitigation Strategy. Lunar Dust 2020. [4] ASI, CSA, ESA, JAXA, & NASA. (2016). Dust Mitiga-tion Gap Assessment Report. [5] Jimenez, N. et al (2022), LPSC Abstract 2572. [6] NASA-STD-1008, 2021.
For apertures above 50 meters, the high structural stiffness and compact packaging of tetrahedral truss make this concept an attractive candidate for the reflector support structure. Various features of a deployable, foldable, doubly curved tetrahedral truss structure are presented as well as methods used to design the truss geometry and to synchronize deployment of the folding elements. An arc division method for distributing truss nodal locations over a doubly curved reflector surface is shown to decrease differences in surface strut lengths and to increase the geometric similarity of all node condigurations in each strut surface. These features enhance the design of a single node and strut synchronizer mechanism for each surface examined. The folding error resulting from using this approach is minimal.
A mooring latch includes a passive foundation portion and a latching portion. The latching portion includes a mechanism, a conical surface shaped to mate with a conical surface of the passive portion, a connector for connection to a mooring structure and permitting rotation about a horizontal axis. The mechanism has a latched configuration that mates the conical surfaces and permits rotations about a shared vertical axis of the conical surfaces. A mooring line threaded through the passive and latching portions and equipped with one or more stops may be used to guide the latching portion to or from the passive portion and to actuate latching or unlatching or the mooring latch.
The technical results from near-field testing of the 15-meter model of the hoop column antenna at the Martin Marietta Denver Aerospace facility are documented. The antenna consists of a deployable central column and a 15 meter hoop, stiffened by cables into a structure with a high tolerance repeatable surface and offset feed location. The surface has been configured to have four offset parabolic apertures, each about 6 meters in diameter, and is made of gold plated molybdenum wire mesh. Pattern measurements were made with feed systems radiating at frequencies of 7.73, 11.60, 2.27, 2.225, and 4.26 (all in GHz). This report (Volume 1) covers the testing from an overall viewpoint and contains information of generalized interest for testing large antennas. This volume discusses the deployment of the antenna in the Martin Facility and the measurements to determine mechanical stability and trueness of the reflector surface, gives the test program outline, and gives a synopsis of antenna electromagnetic performance. Three techniques for measuring surface mechanical tolerances were used (theodolites, metric cameras, and near-field phase), but only the near-field phase approach is included. The report also includes an error analysis. A detailed listing of the antenna patterns are provided for the 2.225 Ghz feed in Volume 3 of this report, and for all other feeds in Volume 2.
The specification of greater than 45kW of disposable power available on the JIMO spacecraft raises the possibility of a new class of instrumentation that has utility at such power levels. In this presentation we discuss the concept of an electromagnetic mass driver that can launch projectiles from orbit around one of the Galilean satellites directed on a trajectory that will impact the satellite surface. The resulting impact will create a crater that will provide information on the mechanical properties of surface and near-surface materials, expose subsurface materials for remote spectral identification, and form a vapor cloud that can be sensed for composition either remotely or in-situ. An analog for such a controlled cratering experiment is Deep Impact, a mission to observe the crater and ensuing ejecta cloud formed by a ballistic projectile into a comet surface in July, 2005.
Miniaturization of microelectronic devices necessitates atomic precision in manufacturing techniques, particularly in the deposition of thin films. Atomic layer deposition (ALD) is recognized for its precision in controlling film thickness and composition on intricate three-dimensional structures. This study focuses on the ALD nucleation and growth mechanisms of ruthenium (Ru), a metal that has significant future implications for microelectronics. Despite its advantages, the deposition of a high surface-free energy material like Ru on a low surface-free energy material such as an oxide often faces challenges of large nucleation delays and non-uniform growth. To address these challenges, we explored the effectiveness of organometallic surface pretreatments using trimethylaluminum (TMA) or diethylzinc (DEZ) to enhance Ru film nucleation and growth. Our study employed a less-studied Ru precursor, cyclopentadienylethyl(dicarbonyl)ruthenium [RuCpEt(CO)2], which demonstrated promising results in terms of reduced nucleation delay and increased film continuity. Ru ALD was performed on silicon substrates with native oxide, using RuCpEt(CO)2 and O2 as coreactants. Our findings reveal that surface pretreatment significantly improves nucleation density and film thickness within the initial 60 ALD cycles, achieving up to a 3.2-fold increase in Ru surface coverage compared to nonpretreated substrates. Supported by density functional theory calculations, we propose that the enhanced nucleation observed with RuCpEt(CO)2 compared to previously-studied Ru(Cp)2 is due to two key mechanisms: the facilitated removal of CO ligands during deposition, which enhances the reactivity of the precursor, and a hydrogen-abstraction reaction involving the ethyl ligand of RuCpEt(CO)2 and the metal-alkyl groups on the surface. This study not only advances our understanding of Ru ALD processes but also highlights the significant impact of precursor chemistry and surface treatments in optimizing ALD for advanced microelectronic applications.
The primary mechanism by which dust is inserted into the Martian atmosphere is the interaction of low-level atmospheric motions with the planet's surface. Near-surface winds exert a shear stress upon dust particles resting on the Martian surface, and at some lower threshold limit of stress magnitude, approximately 0.04 N-m(exp -2), particles are set into motion. Wind tunnel studies indicate that the first particles are too large to remain in suspension in the Martian atmosphere, but their impact back upon the surface can set smaller suspendable particles into motion. This process is termed saltation. Numerical simulations of Martian dust storms were carried out via the interactive coupling of the NASA Ames Mars general circulation Model with an aerosol transport/microphysical model.
Abstract The Lower Mississippi River basin (LMRB) has experienced significant changes in land cover and is one of the most vulnerable regions to hurricanes in the United States. Here, we study the impacts of land-cover change on the hydrologic response to Hurricane Ida in LMRB. By using an integrated surface–subsurface hydrologic model, Energy Exascale Earth System Model (E3SM) Land Model coupled with the three-dimensional ParFlow subsurface flow model (ELM-ParFlow), we simulate the effects of land-cover change on the flood volume and peak timing induced by rainfall from Hurricane Ida. The results show that land-cover changes from 1850 to 2015, which resulted in a smoother surface and less vegetation, exacerbated both flood peak time and volume induced by Hurricane Ida. The effects of land-cover changes can be decomposed into two mechanisms: a smoother surface routes more water faster to a watershed outlet and less vegetation allows more water to contribute to surface runoff. By comparing scenarios in which the two mechanisms were isolated, we found that changes in soil moisture due to vegetation cover change have more dominant effects on floods in the southern part and changes in Manning’s coefficient have the largest effect on floods in the northern part of the LMRB. The study provides important insights into the complex relationship between land-use, land-cover, and hydrologic processes in coastal regions.
Reducing protein adhesion is a critical strategy in fouling-resistant material innovation, with broad applications spanning biomedical and healthcare devices, biosensors, industrial and environmental systems, and other important technological domains. Here, in this study, we elucidated protein adhesion behavior on polystyrene-based thin films by neutron reflectometry (NR) and quartz crystal microbalance with dissipation (QCM-D), using both lysozyme and bovine serum albumin (BSA) as model proteins. To this end, semifluorinated polystyrene thin films with gradient wettability and surface energy were fabricated through dry processing using plasma oxidation and gas-phase deposition. Although it is believed that a fully fluorinated alkyl chain offers extremely low surface energy, thus rejecting foulants, and has been used in many fouling-resistant surface designs, enhanced protein–surface interactions were observed consistently in NR and QCM-D results, due to the combined effects of surface morphology and chemistry. On the contrary, depositing shorter fluorinated silane onto a hydrophilic PS surface contributed to a more homogeneous nanoscale fluorine coating, resulting in less initial protein adsorption and improved surface recovery. Comparative analysis of proteins with different sizes on the nanopatterned semifluorinated surface revealed the influence of molecular characteristics on surface interactions. Lysozyme, being smaller and more compact, showed faster adsorption kinetics and higher surface coverage but largely reversible binding, whereas BSA, with its larger and more flexible structure, formed broader and more stable interfacial layers. This study fills the gap in understanding protein adhesion within the range of hydrophobicity (water contact angle ∼90°), as current strategies often associate with extreme hydrophilic and superhydrophobic surfaces due to hydration or low-surface-energy rejection mechanisms, respectively. It also provides in-depth insights into current combinatorial fouling-resistant surface design.
A test method is described for predicting the long-time survivability of elastomers in hydrazine under dynamic stressing conditions. The method selected is based upon the existence and approximate invariance of a 'physical property surface' relating the mechanical response of the elastomer in terms of stress, strain, time, and temperature. The property surface was generated for two selected elastomers (EPT-10 and AF-E-332). A novel carousel testing tank was designed to allow sequential testing of eight tensile specimens immersed in liquid hydrazine within a constant-temperature water bath. The test procedure and data reduction methods used to generate the property surface are described. The utility and validity of these results applied to fatigue and flexure loading to these elastomeric materials over long-time periods are discussed.
Mass spectra of products emerging from identical samples of a C-13-enriched polyimide polymer (chemically equivalent to Kapton) under atomic oxygen bombardment in space and in the laboratory were collected. Reaction products unambiguously detected in space were CO-13, NO, (12)CO2, and (13)CO2. These reaction products and two others, H2O and CO-12, were detected in the laboratory, along with inelastically scattered atomic and molecular oxygen. Qualitative agreement was seen in the mass spectra taken in space and in the laboratory; the agreement may be improved by reducing the fraction of O2 in the laboratory molecular beam. Both laboratory and space data indicated that CO and CO2 products come preferentially from reaction with the imide component of the polymer chain, raising the possibility that the either component may degrade in part by the 'evaporation' of higher molecular weight fragments. Laboratory time-of-flight distributions showed: (1) incomplete energy accommodation of impinging O and O2 species that do not react with the surface; and (2) both hyperthermal and thermal CO and CO2 products, suggesting two distinct reaction mechanisms with the surface.