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At least 487 records · Page 27

Ray-tracing image simulations of transparent objects with complex shape and inhomogeneous refractive index

Optical images of transparent three-dimensional objects can be different from a replica of the object’s cross section in the image plane, due to refraction at the surface or in the body of the object. Simulations of the object’s image are thus needed for the visualization and validation of physical models. We report ray tracing image simulations that achieved high physical fidelity, reproducing optical behaviors and image features not rendered in previous studies. We replicated brightfield microscopy images of drops with complex shapes, and images of pressure and shock waves traveling inside them. For high physical fidelity, the simulations must replicate the spatial and angular distribution of illumination rays, and both the experiment and the simulation must be designed for accurate optical modeling. The simulations are highly sensitive to the properties of the drops and can be used to diagnose and refine fluid dynamics models. The simulated images can also be optimized to extract multiple 3D properties from experimental images. Compared to specialized single-shot 3D imaging methods, this approach has the advantage that it preserves the experimental simplicity, the high resolution, and the visual interpretability characteristic to basic optical imaging. The techniques introduced here are directly applicable to optical microscopy, so they can be used in other fields, such as microfluidics and biology, to expand the type and the accuracy of three-dimensional information that can be extracted from basic optical images.

Cavitation↗

Resonant nonlinear refraction of 4 – 5 - μ m light in CO and C O 2 gas

The resonant nonlinear refraction of 4–5-μm light in CO and CO 2 gas at a peak intensity of 15MW/cm 2 was demonstrated using time- and frequency-resolved measurements of self-focusing and self-defocusing. The nonlinearity of these molecular gases exhibits intensity-dependent sign reversals and a <4-ns response time. A change from self-focusing to self-defocusing or vice versa was observed to occur for Rabi frequencies that are comparable to the collisional linewidth. A density matrix model for the nonlinear susceptibility of a strongly driven two-level system provides a qualitative explanation for these results.

74 ATOMIC AND MOLECULAR PHYSICS↗

Benchmarking density functional perturbation theory to enable high-throughput screening of materials for dielectric constant and refractive index

We demonstrate a high-throughput density functional perturbation theory (DFPT) methodology capable of screening compounds for their dielectric properties. The electronic and ionic dielectric tensors are calculated for 88 compounds, where the eigenvalues of the total dielectric tensors are compared with single crystal and polycrystalline experimental values reported in the literature. We find that GGA/PBE has a smaller mean average deviation from experiments (MARD=16.2%) when compared to LDA. The prediction accuracy of DFPT is lowest for compounds that exhibit complex structural relaxation effects (e.g., octahedra rotation in perovskites) and/or strong anharmonicity. Despite some discrepancies between DFPT results and reported experimental values, the high-throughput methodology is found to be useful in identifying interesting compounds by ranking. This is demonstrated by the high Spearman correlation factor (ρ=0.92). Finally, we demonstrate that DFPT provides a good estimate for the refractive index of a compound without calculating the frequency dependence of the dielectric matrix (MARD=5.7%).

36 MATERIALS SCIENCE↗

Negative Refraction in Time-Varying Strongly Coupled Plasmonic-Antenna–Epsilon-Near-Zero Systems

Time-varying metasurfaces are emerging as a powerful instrument for the dynamical control of the electromagnetic properties of a propagating wave. Here we demonstrate an efficient time-varying metasurface based on plasmonic nano-antennas strongly coupled to an epsilon-near-zero (ENZ) deeply subwavelength film. The plasmonic resonance of the metal resonators strongly interacts with the optical ENZ modes, providing a Rabi level spitting of ~30%. Optical pumping at frequency ω induces a nonlinear polarization oscillating at 2ω responsible for an efficient generation of a phase conjugate and a negative refracted beam with a conversion efficiency that is more than 4 orders of magnitude greater compared to the bare ENZ film. In this work, the introduction of a strongly coupled plasmonic system therefore provides a simple and effective route towards the implementation of ENZ physics at the nanoscale.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Refractive Guide Switching a Regenerative Amplifier Free-Electron Laser for High Peak and Average Power Hard X Rays

In this work, we present an x-ray regenerative amplifier free-electron laser design capable of producing fully coherent hard x-ray pulses across a broad tuning range at a high steady state repetition rate. The scheme leverages a strong undulator taper and an apertured diamond output-coupling cavity crystal to produce both high peak and average spectral brightness radiation that is 2 to 3 orders of magnitude greater than conventional single-pass self-amplified spontaneous emission free-electron laser amplifiers. Refractive guiding in the postsaturation regime is found to play a key role in passively controlling the stored cavity power. The scheme is explored both analytically and numerically in the context of the Linac Coherent Light Source II High Energy upgrade.

47 OTHER INSTRUMENTATION↗

Shock compression of diamond single crystals to 120 GPa: Refractive index and nonlinear photoelasticity

The optical response of transparent solids at extreme conditions is important for both fundamental science and many applications. Strong transparent solids are of particular interest for use as optical windows in dynamic compression experiments. Due to diamond’s exceptional strength and optical properties, laser-driven shock experiments and plate impact experiments were carried out to examine the diamond optical response for shock wave compression along two different crystal orientations. Using laser interferometry at 532 nm and 1550 nm wavelengths, optical transparency was observed and refractive indices were determined for [100] diamond at stresses up to 119 GPa and for [111] diamond at stresses up to 87 GPa. From these results, the nonlinear photoelastic response for [100] and [111] diamond was determined, revealing significant dependence on both crystal orientation and laser wavelength. To enable [100] diamond as an interferometry window in dynamic compression experiments, the requisite window corrections were determined for 532 nm and 1550 nm wavelengths. Because of diamond’s excellent x-ray transparency, the present findings will be particularly useful for incorporating [100] diamonds as windows in dynamic compression experiments involving x-ray diffraction or other x-ray diagnostics.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Assessing the Impact of Corneal Refraction and Iris Tissue Non-planarity on Iris Recognition

Assumptions regarding eye morphology are implicit in iris recognition algorithms. The cornea is assumed to have little to no effect on the view of the iris texture when the eye gaze is non-frontal, the iris is assumed flat, and the eye is assumed to be imaged via an orthographic projection. If these assumptions hold, affine transformations may be used to rectify non-frontally posed images to a frontal view and the rubber sheet model may be accurately used to normalize the iris annulus to a rectangular image. This work examines how iris recognition performance degrades when the first two assumptions are violated. Using a computer renderable eye model, a data set is created varying the presence of the cornea and a parameterized non-planarity of the iris shape across a large range of eye gaze angles. Matching scores are created using a commercial matcher. Thus, when comparing the relative impact of each assumption violation, it is observed that iris non-planarity presents a more significant problem than corneal refractive distortion with regard to iris recognition accuracy in non-frontal images.

59 BASIC BIOLOGICAL SCIENCES↗

Modeling the refraction of microbaroms by the winds of a large maritime storm

Continuous infrasonic signals produced by the ocean surface interacting with the atmosphere, termed microbaroms, are known to be generated by a number of phenomena including large maritime storms. Storm generated microbaroms exhibit axial asymmetry when observed at locations far from the storm due to the source location being offset from the storm center. Because of this offset, a portion of the microbarom energy will radiate towards the storm center and interact with the winds in the region. Detailed here are predictions for the propagation of microbaroms through an axisymmetric, three-dimensional model storm. Geometric propagation methods have been utilized and the predicted horizontal refraction is found to produce signals that appear to emanate from a virtual source near the storm center when observed far from the storm. This virtual source near the storm center is expected to be observed only from a limited arc around the storm system with increased extent associated with more intense wind fields. This result implies that identifying the extent of the arc observing signal from the virtual source could provide a means to estimate the wind structure using infrasonic observations far from the storm system.

54 ENVIRONMENTAL SCIENCES↗

A Holographic Prism Based on Photo-Thermo-Refractive Glass: Requirements and Possibilities

A technology for multivalued holographic measurement of a plane angle—a holographic prism, which serves as the basis for a device for calibrating the testing tools for navigational equipment under rolling— has been developed. The holographic prism is a miniature sample of photosensitive material, which contains a system of superimposed holographic gratings, and a laser the radiation of which passes through gratings to form a fan of diffracted beams. The fan in a prism based on a calcium fluoride (fluorite) crystal with color centers contained six out-of-plane beams radiating from a region with a hard-to-localize center. This fact hindered calibration of the measure and its application in the testing device. The use of photothermo-refractive glass as a material for preparing a sample and recording a system of holograms in it makes it possible to eliminate the drawbacks of fluorite-based prism. The number of holograms rises up to 21, the fan becomes in-plane, and its center is localized in a small region, with a size of several tenths of the sample thickness (1–2 mm). The fan beams are energetically homogeneous, and each can be identified when using the fan in a testing device.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Extension of Complex Refractive Index Measurements to the Near-Infrared for Liquids: Methodology and Uncertainty Analysis

Optical identification of liquid droplets, aerosols, or thin films is important for many applications. While reference spectra are sometimes available for such measurements, they are not always applicable to the observed spectrum or the given sample morphology. Reference spectra for many forms can be modeled, however, if the n/k vectors (real and imaginary refractive indices) are available. In previous work we have reported protocols to determine the n/k vectors for dozens of liquids, primarily in the mid-infrared (MIR) spectral range from 7500 to 400 cm –1 . In this work we extend the spectral range into the near-infrared (NIR) region, demonstrating a method to measure and merge the data sets to create composite n/k data ranging from 10 000 to 400 cm –1 (1.0 to 25 µm) with absorbance fidelity spanning over four orders of magnitude, and vastly improved signal-to-noise in the NIR. The precision of the composite data is evaluated for three different liquids, focusing primarily on the steps for converting the raw absorbance spectra to k values. The variability in both MIR and NIR data as well as in the final n/k vectors is also investigated for several liquids. For typical liquids, the overall variability (reported as 2σ) in the final n and k-vectors is determined to be ∼0.4% and 3%, respectively. Finally, the derived n/k data are used to calculate absorbance spectra for aerosol droplets, showing marginal variability due to the typical measurement errors in the final n/k vectors.

47 OTHER INSTRUMENTATION↗

Real-time measurement of parametric influences on the refractive index and length changes in silica optical fibers

In this paper, we present a simple cascaded Fabry-Perot interferometer (FPI) that can be used to measure in real-time the refractive index (RI) and length variation in silica optical fibers caused due to external physical parameters, such as temperature, strain, and radiation. As a proof-of-concept, we experimentally demonstrate real-time monitoring of temperature effects on the RI and length and measure the thermo-optic coefficient (TOC) and thermal expansion coefficient (TEC) by using the cascaded FPI within a temperature range of 21–486°C. The experimental results provide a TEC of 5.53 × 10 −7 /°C and TOC of 4.28 × 10 −6 /°C within the specified temperature range. Such a simple cascaded FPI structure will enable the design of optical sensors to correct for measurement errors by understanding the change in RI and length of optical fiber caused by environment parameters.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Refractive axicon for X-ray microscopy applications: design, optimization, and experiment

In a full-field transmission X-ray microscopy (TXM) setup, a condenser X-ray optical element is used to illuminate the sample by condensing the X-ray beam delivered by the synchrotron storage ring. On-going and future upgrades of synchrotron facilities to diffraction-limited storage rings will pose new challenges to these TXM setups, such as much smaller X-ray beams on the condenser. Here, we demonstrate that a refractive axicon can be used as an X-ray beam shaper to match the ring-shaped aperture of the condenser. Aiming at more efficient use of the incoming X-ray intensity, we explore several axicon designs both analytically and with numerical simulations. The axicons were produced by two-photon polymerization 3D printing on thin silicon nitride membrane substrates. The first characterization of the axicon was carried out at the TOMCAT beamline of the Swiss Light Source (Switzerland).

47 OTHER INSTRUMENTATION↗

Nonlinear refraction and absorption properties of optical materials for high-peak-power long-wave-infrared lasers

Optical materials transparent in the CO 2 laser wavelength range have been evaluated regarding their suitability for components in ultrashort-pulse (≤ a few ps), high-peak-power (≥ a few TW) long-wave infrared (LWIR) lasers. We provide values for the nonlinear refractive index ( n 2 ) for seventeen materials, and onsets for nonlinear absorption for eleven materials. Characterizations were performed using a 2 ps laser pulse at λ =9.2 μ m. This paper methodically presents the newly acquired data in conjunction with existing literature on linear optical properties, establishing it as a comprehensive reference for designing high-peak-power LWIR laser systems.

43 PARTICLE ACCELERATORS↗

High speed laser-induced refractive index change in ophthalmic HEMA hydrogel using a line focus

Laser-induced refractive index change (LIRIC) techniques typically focus femtosecond laser pulses to a tight spot to achieve the high intensities required to alter ophthalmic materials. A line-focus implementation using 800 nm pulses at 1 kHz repetition rate has been shown to greatly increase the effective writing speed of the process, but the high pulse energies used led to nonlinear propagation effects, presenting challenges for the fabrication of ophthalmic correctors. By taking advantage of the lower effective order of multiphoton absorption for 514 nm pulses, power levels may be reduced, allowing overlapped pulse writing. We demonstrate that this allows high-quality phase bars and devices to be made at high speeds.

Manning, Zachary A. [University of Rochester, NY (↗

Temperature dependent index of refraction compensation and radiation resistance in monolithic optical systems

Monolithic catadioptric optical systems are susceptible to defocus errors caused by inhomogeneous temperature within the glass material due to temperature dependent index of refraction. This invention discloses methods to mitigate these errors using tuned materials in its optical design coupled with active optical radiative heating to provide optimal performance and includes methods to enhance radiation resistance.

36 MATERIALS SCIENCE↗

Computational Determination of the Refractive Index of TATB, LLM-105, β-HMX, & α-RDX

In this study, we use Materials Studio CASTEP, an ab initio quantum mechanical (QM) program employing density functional theory (DFT), to compute the refractive index (RI) of solid energetic materials, specifically, PETN (tetragonal phase), TATB, LLM-105, β-HMX, and α-RDX. The use of quantum mechanical DFT methods affords the investigation of the optical mate rial properties of a system without the need for any experimental input. The RI values of PETN and TATB have been experimentally determined previously and are compared here to the QM derived RI values as validation of the theoretical approach in determining material optical proper ties. To date, experimental measurements to determine the RI values for LLM-105 have yet to be determined. This fact obviates the need to determine LLM-105 RI values using quantum mechanical means.

36 MATERIALS SCIENCE↗

Liquid Chromatography Coupled to Refractive Index or Mass Spectrometric Detection for Metabolite Profiling in Lysate-based Cell-free Systems

Engineering cellular metabolism for targeted biosynthesis can require extensive design-build-test-learn (DBTL) cycles as the engineer works around the cell's survival requirements. Alternatively, carrying out DBTL cycles in cell-free environments can accelerate this process and alleviate concerns with host compatibility. A promising approach to cell-free metabolic engineering (CFME) leverages metabolically active crude cell extracts as platforms for biomanufacturing and for rapidly discovering and prototyping modified proteins and pathways. Realizing these capabilities and optimizing CFME performance requires methods to characterize the metabolome of lysate-based cell-free platforms. That is, analytical tools are necessary for monitoring improvements in targeted metabolite conversions and in elucidating alterations to metabolite flux when manipulating lysate metabolism. In this work, metabolite analyses using high-performance liquid chromatography (HPLC) coupled with either optical or mass spectrometric detection were applied to characterize metabolite production and flux in E. coli S30 lysates. Specifically, this report describes the preparation of samples from CFME lysates for HPLC analyses using refractive index detection (RID) to quantify the generation of central metabolic intermediates and by-products in the conversion of low-cost substrates (i.e., glucose) to various high-value products. The analysis of metabolite conversion in CFME reactions fed with 13 C-labeled glucose through reversed-phase liquid chromatography coupled to tandem mass spectrometry (MS/MS), a powerful tool for characterizing specific metabolite yields and lysate metabolic flux from starting materials, is also presented. Altogether, applying these analytical methods to CFME lysate metabolism enables the advancement of these systems as alternative platforms for executing faster or novel metabolic engineering tasks.

59 BASIC BIOLOGICAL SCIENCES↗