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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 487 records · Page 27
All sourcesNASA NTRSDOE OSTI
DOE OSTI2013

Fracture-Permeability Relationships of Utica Shale: Early Results

In October 2013, we will begin a Los Alamos Lab-funded project on the hydraulic fracturing of shale. The goal is to use unique LANL microfluidic and triaxial core flood experiments integrated with state-of-the-art numerical simulation to reveal fundamental dynamics of fracture-fluid interactions. Our particular focus is on the development of CO 2 -based fracturing fluids and fracturing techniques to enhance production, greatly reduce wastewater, while simultaneously sequestering CO 2 . Our more general goal is to determine fundamental fracture aperture-permeability relationships and the efficiency of hydrocarbon extraction as a function of fracture characteristics.

02 PETROLEUM↗
DOE OSTI2022

Using Al 3+ to Tailor Graphene Oxide Nanochannels: Impact on Membrane Stability and Permeability

Graphene oxide (GO) membranes, which form from the lamination of GO sheets, attract much attention due to their unique nanochannels. There is much interest in controlling the nanochannel structures and improving the aqueous stability of GO membranes so they can be effectively used in separation and filtration applications. This study employed a simple yet effective method of introducing trivalent aluminum cations to a GO sheet solution through the oxidation of aluminum foil, which modifies the nanochannels in the self-assembled GO membrane by increasing the inter-sheet distance while decreasing intra-sheet spacing. The Al 3+ modification resulted in an increase in membrane stability in water, methanol, ethanol, and propanol, yet decreased membrane permeability to water and propanol. These changes were attributed to strong interactions between Al 3+ and the membrane oxygenated functional groups, which resulted in an increase in membrane hydrophobicity and a decrease in the intra-sheet spacing as supported by surface tension, contact angle, atomic force microscopy, and X-ray photoelectron spectroscopy measurements. Our approach for forming Al 3+ modified GO membranes provides a method for improving the aqueous stability and tailoring the permeation selectivity of GO membranes, which have the potential to be implemented in vapor separation and fuel purification applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2002

Formation of ferrihydrite and associated iron corrosion products in permeable reactive barriers of zero-valent iron

Ferrihydrite, which is known to form in the presence of oxygen and to be stabilized by the adsorption of Si, PO4 and SO4, is ubiquitous in the fine-grained fractions of permeable reactive barrier (PRB) samples from the U.S. Coast Guard Support Center (Elizabeth City, NC) and the Denver Federal Center (Lakewood, CO) studied by high-resolution transmission electron microscopy and selected area electron diffraction. The concurrent energy-dispersive X-ray data indicate a strong association between ferrihydrite and metals such as Si, Ca, and Cr. Magnetite, green rust 1, aragonite, calcite, mackinawite, greigite and lepidocrocite were also present, indicative of a geochemical environment that is temporally and spatially heterogeneous. Whereas magnetite, which is known to form due to anaerobic Fe0 corrosion, passivates the Fe0 surface, ferrihydrite precipitation occurs away from the immediate Fe0 surface, forming small (<0.1 microm) discrete clusters. Consequently, Fe0-PRBs may remain effective for a longer period of time in slightly oxidized groundwater systems where ferrihydrite formation occurs compared to oxygen-depleted systems where magnetite passivation occurs. The ubiquitous presence of ferrihydrite suggests that the use of Fe0-PRBs may be extended to applications that require contaminant adsorption rather than, or in addition to, redox-promoted contaminant degradation.

Metals/chemistry↗
NASA NTRS2023

Estimates of Permeability of Water in Rare Earth Silicates Using the Modified Theory of Deal and Grove

The salient elements of the theory of oxide growth under an environmental barrier are reviewed. In addition, the results from steam oxidation tests recently conducted on environmental barrier coated specimens are reported. The oxide thickness between the coating and substrate are reported as a function of time. Also, the results from previously conducted steam oxidation tests are reviewed. An approach to estimate the permeability of water through the various coating systems using the oxide thickness versus time measurements and the theory of oxide growth is demonstrated. Although the steam oxidation tests may have been performed under disparate conditions, the approach allows one to rank the protection efficiency of the various coating systems against substrate oxidation on an equivalent basis.

environmental barrier coatings↗
DOE OSTI2017

INDUCED MICROEARTHQUAKES AND SEISMICITY-PERMEABILITY RELATIONSHIPS IN FRACTURES

In the past several years, induced microearthquakes (MEQs) related to energy development projects have garnered public attention. Large-scale fluid injection in geoengineering activities, such as enhanced geothermal reservoir stimulation, geological storage of CO2, shale reservoir stimulation, and deep disposal of wastewater can generate significant fluid overpressures and induce microearthquakes by reactivating preexisting faults and fractures that are widely distributed throughout the upper crust. The monitoring of fluid-injection-induced microearthquakes can provide significant information (e.g., timing, special distribution, and moment magnitude) in evaluating reservoir development (e.g., fracture distribution and reservoir hydraulic conductivity evolution), in informing production strategies (e.g., accommodation of production wells), and in assessing the risks of fluid injection activities (e.g., caprock integrity of CO2 reservoir). The following questions are addressed in this study: (1) what are the mechanisms and implications of in-situ feedbacks (e.g., monitored fluid-injection-induced MEQs distribution, seismic moment magnitudes, and fracture behaviors) in geothermal stimulation? (2) What information can be derived from MEQs to inform geothermal reservoir stimulation strategies? (3) Are there any potential relationships between induced seismic or aseismic slip and permeability evolution of fractures in such unconventional reservoirs and caprocks? (4) What factors play an important role in controlling these relationships? These questions are addressed in the five individual chapters of this thesis.

58 GEOSCIENCES↗
DOE OSTI2016

Flow in and Permeability of Porous Media for Turbulent Flow - 16117

The turbulent flow of an incompressible fluid in a porous medium with irregularly shaped grains is analyzed by adopting the k-ε model and making use of ANSYS. The effective permeability is dominantly in the longitudinal direction with negligibly small transverse component due to anisotropic arrangement of the grains. It is observed that the turbulent kinetic energy is large in the central region of pores, but the turbulent dissipation appears to be quite uniform. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2018

Cake Permeability of Waste Simulants found in the Highly Active Storage Tanks at Sellafield - 18676

Caesium Phosphomolybdate (CPM) and Zirconium Molybdate (ZM) are two compounds causing issues within the Highly Active Storage Tanks (HASTs) at Sellafield. CPM has the potential to cause 'hot spots' possibly affecting the integrity of the tanks due to its settling and radioactive properties. ZM is thought to cause mobility issues when it is re-suspended by the jet ballasts in the HASTs. CPM and ZM were synthesised following the method published by Paul. The permeability method followed was published by Loginov. Conclusions: CPM has a higher overall cake resistance; Suggests a more open network for the ZM bed than the CPM bed; Cubes would be expected to pack tighter than spheres, suggesting the orientation of the cubes has some effect on the packing; In future the use of 2 M nitric acid instead of water will be explored as this is the natural conditions found in the HASTs.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2015

Impact of viscous fingering and permeability heterogeneity on fluid mixing in porous media

Fluid mixing plays a fundamental role in many natural and engineered processes, including groundwater flows in porous media, enhanced oil recovery, and microfluidic lab-on-a-chip systems. Recent developments have explored the effect of viscosity contrast on mixing, suggesting that the unstable displacement of fluids with different viscosities, or viscous fingering, provides a powerful mechanism to increase fluid-fluid interfacial area and enhance mixing. However, existing studies have not incorporated the effect of medium heterogeneity on the mixing rate. Here, we characterize the evolution of mixing between two fluids of different viscosity in heterogeneous porous media. We focus on a practical scenario of divergent-convergent flow in a quarter five spot geometry prototypical of well-driven groundwater flows. We study by means of numerical simulations the impact of permeability heterogeneity and viscosity contrast on the breakthrough curves and mixing efficiency, and we rationalize the nontrivial mixing behavior that emerges from the competition between the creation of fluid-fluid interfacial area and channeling.

58 GEOSCIENCES↗
DOE OSTI2015

Multiporosity flow in fractured low-permeability rocks: Extension to shale hydrocarbon reservoirs

We presented a multiporosity extension of classical double and triple-porosity fractured rock flow models for slightly compressible fluids. The multiporosity model is an adaptation of the multirate solute transport model of Haggerty and Gorelick (1995) to viscous flow in fractured rock reservoirs. It is a generalization of both pseudo steady state and transient interporosity flow double-porosity models. The model includes a fracture continuum and an overlapping distribution of multiple rock matrix continua, whose fracture-matrix exchange coefficients are specified through a discrete probability mass function. Semianalytical cylindrically symmetric solutions to the multiporosity mathematical model are developed using the Laplace transform to illustrate its behavior. Furthermore, the multiporosity model presented here is conceptually simple, yet flexible enough to simulate common conceptualizations of double and triple-porosity flow. This combination of generality and simplicity makes the multiporosity model a good choice for flow modelling in low-permeability fractured rocks.

58 GEOSCIENCES↗
DOE OSTI2017

Effective Pressure Law for the Intrinsic Formation Factor in Low Permeability Sandstones: EPL law for the formation factor

The effective pressure law for the intrinsic formation factor of low permeability sandstones from the Ordos Basin (northwest of China) was studied experimentally by measuring the electrical resistivity of brine saturated rock samples while cycling the pore and confining pressures, p p and p c . We used a 100,000 ppm NaCl solution so that the results could be directly interpreted in terms of the intrinsic formation factor F. The Response Surface method was used to construct a quadratic function of pp and pc fitting the experimental data, from which the coefficient α of the effective pressure law, p eff = p c – αp p , was determined. We found that the coefficient α generally had low values, mainly from 0.2 to 0.4, thus contradicting the theoretical prediction that α should be equal to 1 for scale-invariant properties, such as F, in linear elastic materials having a homogeneous solid matrix. Since the two underlying assumptions, linear elasticity and homogeneity of the solid matrix, are likely violated in reservoir rocks, we tried to assess their effects on α using simple analytical models, based on idealized geometries of the pore and solid phases. Analysis of these models suggests that non-linear elasticity associated with the formation of solid–solid contacts in the compressed rocks (e.g., during closure of rough cracks or crack-like pores along the grain boundaries), may be more effective in producing the low α values observed than inhomogeneity of the solid matrix.

58 GEOSCIENCES↗
DOE OSTI2019

Response surface modeling of CO 2 dynamic storage efficiency factor in high permeability thick sandstones

In order to utilize as much of the pore space for CO 2 storage in high permeability thick saline aquifers, it is vital to investigate the interactions of injected CO 2 with formation brine and rock. In order to quantify the displacement process, we investigate the dynamic storage efficiency factor (DSEF) for saline aquifers where pressure increase is minimal during the injection phase. Dimensionless numbers are derived from basic governing equations, constitutive equations, initial and boundary conditions using the inspection analysis. Then using the Hammersley sequence sampling, 178 numerical experiments are designed, and a compositional reservoir simulator is used to perform these simulations. In the next step, response surface regression analysis is used to establish a relationship between DSEF obtained from the numerical simulations and the corresponding dimensionless numbers. The simulation results show that for the studied conditions the underground dynamics is mostly influenced by the gravity number, followed by effective aspect ratio and dip numbers. The results from the response surface regression analysis are used to develop a correlation, which can be used to estimate the dynamic CO 2 storage capacity of relevant zones. This study provides quantitative measures for the different competing mechanisms involved in underground displacement of fluids in CO 2 geological storage, which can serve as a useful tool during planning phase of storage projects.

02 PETROLEUM↗