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At least 487 records · Page 27
All sourcesNASA NTRSDOE OSTI
NASA NTRS2020

A 60 kpc Galactic Wind Cone in NGC 3079

Galactic winds are associated with intense star formation and active galactic nuclei. Depending on their formation mechanism and velocity, they may remove a significant fraction of gas from their host galaxies, thus suppressing star formation, enriching the intergalactic medium, and shaping the circumgalactic gas. However, the long-term evolution of these winds remains mostly unknown. We report the detection of a wind from NGC 3079 to at least 60 kpc from the galaxy. We detect the wind in far-ultraviolet (FUV) line emission to 60 kpc (as inferred from the broad FUV filter in the Galaxy Evolution Explorer) and X-rays to at least 30 kpc. The morphology, luminosities, temperatures, and densities indicate that the emission comes from shocked material, and the O/Fe ratio implies that the X-ray-emitting gas is enriched by Type II supernovae. If so, the speed inferred from simple shock models is about 500 km s−1, which is sufficient to escape the galaxy. However, the inferred kinetic energy in the wind from visible components is substantially smaller than canonical hot superwind models.

Edmund J. Hodges-Kluck↗
NASA NTRS1990

Morphological type correlation between nearest neighbor pairs of galaxies

Although the morphological type of galaxies is one of the most fundamental properties of galaxies, its origin and evolutionary processes, if any, are not yet fully understood. It has been established that the galaxy morphology strongly depends on the environment in which the galaxy resides (e.g., Dressler 1980). Galaxy pairs correspond to the smallest scales of galaxy clustering and may provide important clues to how the environment influences the formation and evolution of galaxies. Several investigators pointed out that there is a tendency for pair galaxies to have similar morphological types (Karachentsev and Karachentseva 1974, Page 1975, Noerdlinger 1979). Here, researchers analyze morphological type correlation for 18,364 nearest neighbor pairs of galaxies identified in the magnetic tape version of the Center for Astrophysics Redshift Catalogue.

Yamagata, Tomohiko↗
NASA NTRS1994

Post-Gondwana geomorphic evolution of southwestern Africa: Implications for hte controls on landscape development from observations and numerical experiments

The relationship between morphology and surficial geology is used to quantify the denudation that has occurred across southwestern Africa sicne the fragmentation of Gondwana during the Early Mesozoic. Two main points emerge. Signficant denudation, of the order of kilometers, is widespread except in the Kalahari region of the continental interior. The denudation is systematically distributed so that the continental exterior catchment, draining directly to the Cape basin, is denuded to a greater depth than the interior catchment inland of the Great Escarpment. The analysis also implies tha the majority of the denudation occurred before the beginning of the Cenozoic for both teh exerior and interior catchments. Existing models of landscape development are reviewed, and implications of the denudation chronology are incorporated into a revised conceptual model. This revision implies tha thte primary effect of rifting on the subsequent landscape evolution is that it generates two distinct drainage regimes. A marginal upwarp, or rift flank uplift, separates rejuvenated rivers that drain into the subsiding rift from rivers in the continetal interior that are deflected but not rejuvenated. The two catchments evolve independently unless they are integrated by breaching of hte marginal upwarp. If this occurs, the exterior baselevel is communicated to the interior catchment that is denuded accordingly. Denudation rates generally decrease as the margin evolves, and this decrease is reinforced by the exposure of substrate that is resistant to denudation and/or a change to a more arid climate. The observations do not reveal a particular style of smaller-scale landscape evolution, sucha s escarpment retreat, that is responsible for the differential denudation across the region. It is proposed that numerical model experiments, which reflect the observational insights at the large scale, may identify the smaller-scale controls on escarpment development if the model and natural systems are analogous. Four numerical experiments are presented in which the roles of antecedent topography, resistant substrate, climte change, and lowering the baselevel of the interior catchment are investigated for an initially high elevation margin bordered by an escarpment. The model results suggest several styles of landscape evolution that are compatible with the observations. Escarpments may retreat in a regular manner, but they also degrade and are destroyed, only to reform at the drainage divide between exterior and interior catchments.

Gilchrist, Alan R.↗
DOE OSTI2025

Discharge Rate‐Driven Li 2 O 2 Growth Exhibits Unconventional Morphology Trends in Solid‐State Li‐O 2 Batteries

Solid-state lithium oxygen batteries (LOBs) are known for their enhanced safety, higher electrochemical stability, and improved energy density compared to liquid-state LOBs. However, the investigation of solid-state LOBs is limited with little understanding of their discharge and charge processes. In this work, a polymer-based solid-state LOB is used to investigate the effect of discharge rate on lithium peroxide (Li 2 O 2 ) formation, the oxygen evolution reaction (OER), and cycle performance. Notably, we observe a counterintuitive trend: Li 2 O 2 particle size increases with increasing discharge current density, in contrast to liquid systems. This behavior arises from inherent space charge layers that restrict Li⁺ transport under high current, and spatially heterogeneous active sites at the solid electrolyte–cathode interface, directly evidenced by small angle X-ray scattering (SAXS), which govern nucleation accessibility and promote site-selective Li 2 O 2 growth. Furthermore, higher current densities improve ORR and OER efficiency but accelerate anode degradation, while lower currents promote side reactions. These opposing effects result in a trade-off that defines an optimal discharge rate (0.1 mA cm -2 ) for maximizing cycle life. This study provides a new mechanistic perspective on discharge-driven processes in solid-state LOBs and offers practical guidelines for performance optimization in future high-energy battery systems.

Discharge current density↗
DOE OSTI2026

A trait syndrome ties cell morphology to glycolysis across the yeast subphylum

Co-variation of traits provides fundamental insights into constraints governing their evolution. An inverse correlation between glucose uptake rates (GURs) and cell surface area-to-volume (SA:V) ratios across 11 yeast species was recently reported. Here, we expand the analysis to 282 species to assess the generalizability of this correlation across Saccharomycotina yeasts and the contribution of shared evolutionary history to the co-variation of these traits. Using phylogenetic regression models, we found extracellular acidification rates (ECARs, used as a proxy for GURs) were weakly, but significantly, correlated with SA:V across Saccharomycotina. ECARs were also correlated with genome sizes and growth rates. Our findings support the reported correlation between GURs and SA:V ratios, but suggest other associated traits, including genome sizes. Specifically, yeasts that consume glucose faster tend to have lower SA:V, faster growth rates, and larger genomes, suggesting a trait syndrome governing several metabolic, genomic, and morphological traits across the yeast subphylum.

biological sciences↗
NASA NTRS1992

Dynamical evolution effects on the hot stellar populations in globular clusters

Results of a study of FUV properties of Galactic globular clusters are presented. The spatially resolved spectra measured with the IUE satellite are used to find indications of color gradients in two clusters with the postcore-collapse (PCC) morphology, NGC 6752 and NGC 7099, but not in the case of NTGC 6093, a cluster with the classical King-model-type morphology. These FUV color gradients may be caused by the presence of a highly concentrated population of hot objects, such as the extreme BHB stars, blue stragglers, etc. This result extends to the FUV regime the trends seen in the ground-based data in the visible regime. PCC or highly concentrated small-core lusters are found to have bluer HB morphologies and bluer FUV colors, and the bluest FUV colors at a given metallicity. These trends indicate that dynamical evolution of clusters played some role in determining the net abundance and the spatial distribution of their hot stellar populations.

Djorgovski, S.↗
DOE OSTI2026

Causality-respecting adaptive refinement for PINNs: enabling precise interface evolution in phase field modeling

Physics-informed neural networks (PINNs) have emerged as a powerful tool for solving physical systems described by partial differential equations (PDEs). However, their accuracy in dynamical systems, particularly those involving sharp moving boundaries with complex initial morphologies, remains a challenge. Here, this study introduces an approach combining residual-based adaptive refinement (RBAR) with causality-informed training to enhance the performance of PINNs in solving spatio-temporal PDEs. Our method employs a three-step iterative process: initial causality-based training, RBAR-guided domain refinement, and subsequent causality training on the refined mesh. Applied to the Allen-Cahn equation, a widely-used model in phase field simulations, our approach demonstrates significant improvements in solution accuracy and computational efficiency over traditional PINNs. Notably, we observe an ‘overshoot and relocate’ phenomenon in dynamic cases with complex morphologies, showcasing the method’s adaptive error correction capabilities. This synergistic interaction between RBAR and causality training enables accurate capture of interface evolution, even in challenging scenarios where traditional PINNs fail. Our framework not only resolves the limitations of uniform refinement strategies but also provides a generalizable methodology for solving a broad range of spatio-temporal PDEs. The enhanced performance of the RBAR–causality combined framework demonstrates its strong potential for advancing PINN-based modeling of physical systems characterized by complex, evolving interfaces.

Allen-Cahn equations↗
DOE OSTI2023

Influence of oxygen on performance of multi-principal element alloy as braze filler for Ni-base alloys

In manufacturing of multi-principal element alloys (MPEAs), the casting process is often a primary point of oxygen introduction to the material system, which was demonstrated by the laboratory scale button arc-melting process. Oxygen introduction raises concerns for the mechanical performance of these alloys if employed as structural materials alone or in engineering applications, such as serving as filler materials to enable joining of similar or dissimilar alloy pairs that are conventionally considered difficult to join. In this work, oxide inclusions in an as-cast off-equiatomic MnFeCoNiCu MPEA and Ni-base alloy braze joints made with this MPEA were evaluated by synchrotron x-ray diffraction mapping and electron microscopy. MnO was found to be prevalent throughout the cast MPEA and was chemically reduced during brazing by trace Al from the base material, Ni-base Alloy 600. Incomplete reaction of the MnO with Al, and some alternative reaction with Cr, left a mixture of MnO, Al 2 O 3 , and Cr 2 O 3 in the as-brazed joint, with the oxides concentrated near the braze centerline due to directional solidification. Further, in the braze joints, the non-oxide constituent phases detected were an FCC matrix and particles of Cr 23 C 6 , Cr 7 C 3 , and TiN which are all native to Alloy 600. The evolution of oxides within the brazed joints at elevated service temperatures of 600-800°C was also evaluated. While MnO and Al 2 O 3 were stable during high-temperature service, Cr 2 O 3 particles grew to several hundred microns, with dissolved oxygen in the MPEA providing a significant source for oxide growth. Comparing tensile performance of the as-brazed condition with post-service conditions showed that the evolution of oxide particles contributed to an increase in strength and decrease in ductility of the brazed joints. Evaluating particle morphologies among fracture surfaces of individual specimens demonstrated that large Cr 2 O 3 particles and continuous cluster networks of Al 2 O 3 were the features most detrimental to total elongation. Hence, unmitigated evolution of oxygen-containing species during brazing and service conditions is detrimental to the ductility of the brazed joints, which highlights the importance of oxygen control in initial manufacturing of MPEAs for engineering applications.

36 MATERIALS SCIENCE↗
NASA NTRS2003

Numerical Calculation of the Morphology of a Solid/Liquid Interface Near an Insoluble Particle

A numerical mathematical model capable of accurately describing the evolution of the shape of the solid/liquid interface in the proximity of a foreign particle is presented in this paper. The model accounts for the influence of the temperature gradient and the Gibbs-Thomson and disjoining pressure effects. It shows that for the systems characterized by k(sub P) < k(sub L) the disjoining pressure causes the interface curvature to change its sign in the close-contact particle/interface region. It also shows that the increase of the temperature gradient diminishes the effect of the disjoining pressure. Calculated critical solidification velocities for the pushing/engulfment transition are compared with experimental measurements performed in microgravity conditions.

Catalina, Adrian V.↗
DOE OSTI2021

Nanoporous Iridium Nanosheets for Polymer Electrolyte Membrane Electrolysis

The growth of the hydrogen economy is predicated on advancements in electrochemical energy technologies, with water electrolysis as a key component to the technological portfolio. Much of the focus on anode catalyst development for polymer electrolyte membrane water electrolyzers (PEMWE) is centered on activity as controlled by compositional and morphological impacts on reactant/intermediate/product adsorption. However, the effectiveness of this strategy is found to be limited upon integration of these materials into PEMWE membrane electrode assemblies (MEA). Regardless of catalyst activity, the combination of electrode inhomogeneity, ionomer integration, and high density of oxide-oxide interfaces yields significant performance losses associated with poor catalytic electrode conductivity. Here many of these limitations are addressed through the development of a unique catalyst morphology composed of nanoporous Ir nanosheets (npIr(x)-NS) that exhibit high catalytic activity for the anodic oxygen evolution reaction and superior electrode electronic conductivity in comparison to a commercial IrO2 nanoparticle catalyst. The utility of the npIr(x)-NS is demonstrated through incorporation into PEMWE MEAs where their performance exceeds that of commercial catalyst coated membranes at loadings as low as 0.06 mg(Ir) cm(-2) while exhibiting a negligible loss in performance following 50 000 accelerated stress test cycles.

Polymer Electrolyte Membrane Electrolysis↗
NASA NTRS1995

Morphology of galaxy mergers at intermediate redshift

Using a combination of numerical simulation and synthesized Hubble Space Telescope Wide Field Camera 2 (HST WFC2) images, we follow the detectability of morphological signatures of disk galaxy mergers at intermediate redshifts z = 0.4 and z = 1.0. Rapid evolution in the surface brightness of tidal tails makes their use as an interaction signature limited; long tidal tails will only be detectable relatively early in the encounter, before the galaxies actually merge. Violent relaxation rapidly smooths isophotal irregularities after the galaxies merge, leaving the very low surface brightness tidal debris surrounding the remnant as the only sign of peculiarity after a few hundred Myr. This debris becomes indistinguishable from the main body of the remnant after less than or approximately equal to 0.2 (z = 1.0) to 1 (z = 0.4) Gyr, leaving a morphologically normal elliptical galaxy behind. Using WFC1, all signatures become undetectable almost immediately once the galaxies merge, due to the aberrated Point Speed Function (PSF). We interpret these results in light of recent HST programs investigating the nature of starburst and E + A galaxies in moderate redshift clusters.

Mihos, J. Christopher↗
DOE OSTI2026

Shapeshifting Nanocatalyst for CO2 Conversion

The conversion of CO2 into high-value chemicals through a photoreduction reaction in water is a promising route to reduce the dependence on fossil fuels. Enhancing selectivity toward hydrocarbons or alcohols can be achieved by Ag-Cu alloys. However, the stabilized surface state created by Ag-Cu interactions is still poorly understood. In this work, multi-modal in situ X-ray experiments reveals underlying mechanisms and the evolution of Ag-Cu nanoparticles under CO2 reduction reaction (CO2RR) conditions. Both morphological and chemical changes of Ag and Cu species induced by diffusion mechanics are tracked during nanocatalyst operation. The initial spheroid Ag-Cu nanoparticles are composed of a Cu-rich shell and Ag-rich core. The reduction treatment promotes Ag migration toward the surface. During photocatalytic CO2 reduction reaction, Cu atoms migrate back to the surface, forming Ag-Cu-O species. The study observes the surface oxidation of Cu(0) to Cu+ and the presence of Ag at the sub-surface region. Furthermore, nanoparticles change their shape, decreasing their specific surface area, driven by Cu diffusion during the CO2 photoreduction reaction. The results provide invaluable insights into the dynamic restructuring of the catalyst under reaction conditions and into the active species responsible for CO2 conversion.

CO2 reduction reaction↗
DOE OSTI2024

Identifying critical features of iron phosphate particle for lithium preference

One-dimensional (1D) olivine iron phosphate (FePO 4 ) is widely proposed for electrochemical lithium (Li) extraction from dilute water sources, however, significant variations in Li selectivity were observed for particles with different physical attributes. Understanding how particle features influence Li and sodium (Na) co-intercalation is crucial for system design and enhancing Li selectivity. Here, we investigate a series of FePO 4 particles with various features and revealed the importance of harnessing kinetic and chemo-mechanical barrier difference between lithiation and sodiation to promote selectivity. The thermodynamic preference of FePO 4 provides baseline of selectivity while the particle features are critical to induce different kinetic pathways and barriers, resulting in different Li to Na selectivity from 6.2 × 10 2 to 2.3 × 10 4 . Importantly, we categorize the FePO 4 particles into two groups based on their distinctly paired phase evolutions upon lithiation and sodiation, and generate quantitative correlation maps among Li preference, morphological features, and electrochemical properties. By selecting FePO 4 particles with specific features, we demonstrate fast (636 mA/g) Li extraction from a high Li source (1: 100 Li to Na) with (96.6 ± 0.2)% purity, and high selectivity (2.3 × 10 4 ) from a low Li source (1: 1000 Li to Na) with (95.8 ± 0.3)% purity in a single step.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Li2O-Based Cathode Additives Enabling Prelithiation of Si Anodes

Low first-cycle Coulombic efficiency is especially poor for silicon (Si)-based anodes due to the high surface area of the Si-active material and extensive electrolyte decomposition during the initial cycles forming the solid electrolyte interphase (SEI). Therefore, developing successful prelithiation methods will greatly benefit the development of lithium-ion batteries (LiBs) utilizing Si anodes. In pursuit of this goal, in this study, lithium oxide (Li2O) was added to a LiNi0.6Mn0.2Co0.2O2 (NMC622) cathode using a scalable ball-milling approach to compensate for the initial Li loss at the anode. Different milling conditions were tested to evaluate the impact of particle morphology on the additive performance. In addition, Co3O4, a well-known oxygen evolution reaction catalyst, was introduced to facilitate the activation of Li2O. The Li2O + Co3O4 additives successfully delivered an additional capacity of 1116 mAh/gLi2O when charged up to 4.3 V in half cells and 1035 mAh/gLi2O when charged up to 4.1 V in full cells using Si anodes.

25 ENERGY STORAGE↗
NASA NTRS1989

A Monte Carlo-finite element model for strain energy controlled microstructural evolution - 'Rafting' in superalloys

This paper presents a specialized microstructural lattice model, MCFET (Monte Carlo finite element technique), which simulates microstructural evolution in materials in which strain energy has an important role in determining morphology. The model is capable of accounting for externally applied stress, surface tension, misfit, elastic inhomogeneity, elastic anisotropy, and arbitrary temperatures. The MCFET analysis was found to compare well with the results of analytical calculations of the equilibrium morphologies of isolated particles in an infinite matrix.

Gayda, J.↗
NASA NTRS1993

Clustering of very luminous infrared galaxies and their environment

The IRAS survey reveals a class of ultraluminous infrared (IR) galaxies (ULIRG's) with IR luminosities comparable to the bolometric luminosities of quasars. The nature, origin, and evolution of ULIRG's are attracting more and more attention recently. Since galaxy morphology is certainly a function of environment, morphological observations show that ULIRG's are interacting/merging galaxies, and some ULIRG's might be the dust-enshrouded quasars (S88) or giant ellipticals, the study of ULIRG's environment and large scale clustering effects should be worthwhile. ULIRG's and very luminous IR galaxies have been selected from the 2Jy IRAS redshift survey. Meanwhile, a catalog of IRAS groups of galaxies has been constructed using a percolation-like algorithm. Therefore, whether ULIRG's and/or VLIRG's have a group environment can be checked immediately. Other aspects of the survey are discussed.

Gao, YU↗
NASA NTRS1993

Geomorphic evolution of the Martian highlands through ancient fluvial processes

The evolution of crater degradation in the Martian highlands based on variations in crater morphology is traced. The timing of this process related to geology, elevation, and latitude is examined, the nature of fluvial resurfacing is studied, and the approximate rate of denudation is determined. The obtained data make it possible to understand the early geologic history of Mars, the interaction between the atmosphere and surface processes through time, and the nature of highland surface materials. Degradation was found to begin with sheet-flooding and the formation of runoff channels in both the interior and exterior of the craters. Progressive stripping of the ejecta material led to craters with incised rims. Erosion and infilling led to flat doors. With time, continued erosion removed ejecta and rim materials completely. Timing of degradation based on cumulative size-frequency distribution curves of highland crater population indicates that the process ceased completely in the late Hesperian. Global average denudation rates were found to be between 0.0001 and 0.005 mm/yr.

Craddock, Robert A.↗
NASA NTRS2003

Physical Characteristics, Geologic Setting, and Possible Formation Processes of Spring Deposits on Mars Based on Terrestrial Analogs

Spring formation is a predicted consequence of the interaction of former Martian aquifers with structures common to Mars, including basin margins, Tharsis structures, and other structural deformation characteristics. The arid environment and high abundance of water soluble compounds in the crust will have likewise encouraged spring deposit formation at spring sites. Such spring deposits may be recognized from morphological criteria if the characteristics of formation and preservation are understood. An important first step in the current Mars exploration strategy [10] is the detection of sites where there is evidence for past or present near-surface water on Mars. This study evaluates the large-scale morphology of spring deposits and the physical processes of their formation, growth, and evolution in terms that relate to (1) their identification in image data, (2) their formation, evolution, and preservation in the environment of Mars, and (3) their potential as sites of long-term or late stage shallow groundwater emergence at the surface of Mars.

L S Crumpler↗