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At least 487 records · Page 27

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NASA NTRS1957

Identification of Foreign Objects Damaging Compressor Blades in Turbojet Engines

Damage to the compressor blades of turbojet engines due to ingestion of foreign objects is a growing problem, the solution of which has been made more difficult by the large percentage of damaging materials that have remained unknown. A rapid emission spectroscopic method was devised to identify the chemical composition of these foreign objects. Results on laboratory-prepared specimens and blades from damaged engines show that the method can be utilized to determine the nature of the ingested foreign objects.

Spakowski, A E↗

NASA NTRS1998

Extraterrestrial organic matter: a review

We review the nature of the widespread organic material present in the Milky Way Galaxy and in the Solar System. Attention is given to the links between these environments and between primitive Solar System objects and the early Earth, indicating the preservation of organic material as an interstellar cloud collapsed to form the Solar System and as the Earth accreted such material from asteroids, comets and interplanetary dust particles. In the interstellar medium of the Milky Way Galaxy more than 100 molecular species, the bulk of them organic, have been securely identified, primarily through spectroscopy at the highest radio frequencies. There is considerable evidence for significantly heavier organic molecules, particularly polycyclic aromatics, although precise identification of individual species has not yet been obtained. The so-called diffuse interstellar bands are probably important in this context. The low temperature kinetics in interstellar clouds leads to very large isotopic fractionation, particularly for hydrogen, and this signature is present in organic components preserved in carbonaceous chondritic meteorites. Outer belt asteroids are the probable parent bodies of the carbonaceous chondrites, which may contain as much as 5% organic material, including a rich variety of amino acids, purines, pyrimidines, and other species of potential prebiotic interest. Richer in volatiles and hence less thermally processed are the comets, whose organic matter is abundant and poorly characterized. Cometary volatiles, observed after sublimation into the coma, include many species also present in the interstellar medium. There is evidence that most of the Earth's volatiles may have been supplied by a 'late' bombardment of comets and carbonaceous meteorites, scattered into the inner Solar System following the formation of the giant planets. How much in the way of intact organic molecules of potential prebiotic interest survived delivery to the Earth has become an increasingly debated topic over the last several years. The principal source for such intact organics was probably accretion of interplanetary dust particles of cometary origin.

NASA Discipline Exobiology↗

NASA NTRS2010

Thermal Infrared Emission Spectroscopy of Synthetic Allophane and its Potential Formation on Mars

Allophane is a poorly-crystalline, hydrous aluminosilicate with variable Si/Al ratios approx.0.5-1 and a metastable precursor of clay minerals. On Earth, it forms rapidly by aqueous alteration of volcanic glass under neutral to slightly acidic conditions [1]. Based on in situ chemical measurements and the identification of alteration phases [2-4], the Martian surface is interpreted to have been chemically weathered on local to regional scales. Chemical models of altered surfaces detected by the Mars Exploration Rover Spirit in Gusev crater suggest the presence of an allophane-like alteration product [3]. Thermal infrared (TIR) spectroscopy and spectral deconvolution models are primary tools for determining the mineralogy of the Martian surface [5]. Spectral models of data from the Thermal Emission Spectrometer (TES) indicate a global compositional dichotomy, where high latitudes tend to be enriched in a high-silica material [6,7], interpreted as high-silica, K-rich volcanic glass [6,8]. However, later interpretations proposed that the high-silica material may be an alteration product (such as amorphous silica, clay minerals, or allophane) and that high latitude surfaces are chemically weathered [9-11]. A TIR spectral library of pure minerals is available for the public [12], but it does not contain allophane spectra. The identification of allophane on the Martian surface would indicate high water activity at the time of its formation and would help constrain the aqueous alteration environment [13,14]. The addition of allophane to the spectral library is necessary to address the global compositional dichotomy. In this study, we characterize a synthetic allophane by IR spectroscopy, X-ray diffraction (XRD), and transmission electron microscopy (TEM) to create an IR emission spectrum of pure allophane for the Mars science community to use in Martian spectral models.

Rampe, E. B.↗

NASA NTRS2016

Coordinated Isotopic and Mineral Characterization of Highly Fractionated 18O-Rich Silicates in the Queen Alexandra Range 99177 CR3 Chondrite

Carbonaceous chondrites contain a mixture of solar system condensates, pre-solar grains, and primitive organic matter. Each of these materials record conditions and processes in different regions of the solar nebula, on the meteorite parent body, and beyond the solar system. Oxygen isotopic studies of meteorite components can trace interactions of distinct oxygen isotopic reservoirs in the early solar system and secondary alteration processes. The O isotopic compositions of the earliest solar system condensates fall along a carbonaceous chondrite anhydrous mineral (CCAM) line of slope approximately 1 in a plot of delta 17O against delta 18O. This trend is attributed to mixing of material from 16O-poor and 16O-rich reservoirs. Secondary processing can induce mass-dependent fractionation of the O isotopes, shifting these compositions along a line of slope approximately 0.52. Substantial mass-dependent fractionation of O isotopes has been observed in secondary minerals in CAIs, calcite, and FUN inclusions. These fractionations were caused by significant thermal or aqueous alteration. We recently reported the identification of four silicate grains with extremely fractionated O isotopic ratios (delta 18O equals 37 - 55 per mille) in the minimally altered CR3 chondrite QUE 99177. TEM analysis of one grain indicates it is a nebular condensate that did not experience substantial alteration. The history of these grains is thus distinct from those of the aforementioned fractionated materials. To constrain the origin of the silicate grains, we conducted further Mg and Fe isotopic studies and TEM analyses of two grains.

Nguyen, A. N.↗

NASA NTRS1992

Identification and evaluation of lubricants, adhesives, and seals used on LDEF

A variety of lubricants, adhesives, and seals were flown on Long Duration Exposure Facility (LDEF). They were used in the fabrication and assembly of the experiments similar to other spacecraft applications. Typically, these materials were not exposed to U.V. radiation or atomic oxygen, except possibly around the perimeter of the joints. Most of these materials were of secondary interest and were only investigated by visual examination and a 'Did they fall?' criteria. Because of this role, most applications had only a few specimens, not enough for statistical data generation. Often, no control samples were kept, and documentation of what was used was occasionally sketchy.

Keough, Bruce↗

NASA NTRS1983

Design concepts for low cost composite engine frames

Design concepts for low-cost, lightweight composite engine frames were applied to the design requirements for the frame of commercial, high-bypass turbine engines. The concepts consist of generic-type components and subcomponents that could be adapted for use in different locations in the engine and to different engine sizes. A variety of materials and manufacturing methods were assessed with a goal of having the lowest number of parts possible at the lowest possible cost. The evaluation of the design concepts resulted in the identification of a hybrid composite frame which would weigh about 70 percent of the state-of-the-art metal frame and cost would be about 60 percent.

Chamis, C. C.↗

NASA NTRS1983

Design concepts for low-cost composite engine frames

Chamis, C. C.↗

NASA NTRS1985

A review of noble gas geochemistry in relation to early Earth history

One of the most fundamental noble gas constraints on early Earth history is derived from isotopic differences in (129)Xe/(130)Xe between various terrestrial materials. The short half life (17 m.y.) of extinct (129I, parent of (129)Xe, means that these differences must have been produced within the first 100 m.y. after terrestrial accretion. The identification of large anomalies in (129)Xe/(130)Xe in mid ocean ridge basalts (MORB), with respect to atmospheric xenon, suggests that the atmosphere and upper mantle have remained separate since that time. This alone is a very strong argument for early catastrophic degassing, which would be consistent with an early fractionation resulting in core formation. However, noble gas isotopic systematics of oceanic basalts show that the mantle cannot necessarily be regarded as a homogeneous system, since there are significant variations in (3)He/(4)He, (40)Ar/(36)Ar, and (129)Xe/(130)Xe. Therefore, the early degassing cannot be considered to have acted on the whole mantle. The specific mechanisms of degassing, in particular the thickness and growth of the early crust, is an important variable in understanding present day noble gas inventories. Another constraint can be obtained from rocks that are thought to be derived from near the lithosphere asthenosphere boundary: ultramafic xenoliths.

Kurz, M. D.↗

NASA NTRS1985

Microgravity Science and Applications Program Tasks, 1984 Revision

This report is a compilation of the active research tasks as of the end of the fiscal year 1984 of the Microgravity Science and Applications Program, NASA-Office of Space Science and Applications, involving several NASA centers and other organizations. The purpose of the document is to provide an overview of the program scope for managers and scientists in industry, university, and government communities. The report is structured to include an introductory description of the program, strategy and overall goal; identification of the organizational structures and people involved; and a description of each research task, together with a list of recent publications. The tasks are grouped into six categories: (1) electronic materials; (2) solidification of metals, alloys, and composites; (3) fluid dynamics and transports; (4) biotechnology; (5) glasses and ceramics; and (6) combustion.

Elizabeth Pentecost↗

NASA NTRS1988

Microgravity Science and Applications Program tasks, 1987 revision

A compilation is presented of the active research tasks as of the end of the FY87 of the Microgravity Science and Applications Program, NASA-Office of Space Science and Applications, involving several NASA centers and other organizations. An overview is provided of the program scope for managers and scientists in industry, university, and government communities. An introductory description is provided of the program along with the strategy and overall goal, identification of the organizational structures and people involved, and a description of each task. A list of recent publications is also provided. The tasks are grouped into six major categories: Electronic Materials; Solidification of Metals, Alloys, and Composites; Fluid Dynamics and Transport Phenomena; Biotechnology; Glasses and Ceramics; and Combustion. Other categories include Experimental Technology, General Studies and Surveys; Foreign Government Affiliations; Industrial Affiliations; and Physics and Chemistry Experiments (PACE). The tasks are divided into ground based and flight experiments.

Source record↗

NASA NTRS1991

Iddingsite in the Nakhla meteorite: TEM study of mineralogy and texture of pre-terrestrial (Martian?) alterations

Rusty-colored veinlets and patches in the Nakhla meteorite, identified as iddingsite, are pre-terrestrial. The rusty material is iddingsite (smectites + hematite + ferrihydrite); like terrestrial iddingsites, it probably formed during low-temperature interaction of olivine and water. Fragments of rusty material with host olivine were removed from thin sections of Nakhla with a tungsten needle. Fragments were embedded in epoxy, microtomed to 100 nanometers thickness, and mounted on Cu grids. Phase identifications were by Analytical Electron Microscopy/Energy Dispersive X-ray Analysis (EM/EDX) standardless chemical analyses (for silicates), electron diffraction (hematite and ferrihydrite), and lattice fringe imaging. This iddingsite in Nakhla is nearly identical to some formed on Earth, suggesting similar conditions of formation on the Shergottites-Nakhlites-Chassigny (SNC) meteorite parent planet. A more detailed account of the results is presented.

Treiman, Allan H.↗

NASA NTRS1992

Space Station Furnace Facility. Volume 3: Program cost estimate

The approach used to estimate costs for the Space Station Furnace Facility (SSFF) is based on a computer program developed internally at Teledyne Brown Engineering (TBE). The program produces time-phased estimates of cost elements for each hardware component, based on experience with similar components. Engineering estimates of the degree of similarity or difference between the current project and the historical data is then used to adjust the computer-produced cost estimate and to fit it to the current project Work Breakdown Structure (WBS). The SSFF Concept as presented at the Requirements Definition Review (RDR) was used as the base configuration for the cost estimate. This program incorporates data on costs of previous projects and the allocation of those costs to the components of one of three, time-phased, generic WBS's. Input consists of a list of similar components for which cost data exist, number of interfaces with their type and complexity, identification of the extent to which previous designs are applicable, and programmatic data concerning schedules and miscellaneous data (travel, off-site assignments). Output is program cost in labor hours and material dollars, for each component, broken down by generic WBS task and program schedule phase.

Source record↗

NASA NTRS2001

ISS-Crystal Growth of Photorefractive Materials (BSO): Critical Design Issues for Optimized Data Extraction from Space Experiments

Realization of the full potential of photorefractive materials in device technology is seriously impeded by our inability to achieve controlled formation of critical defects during single crystal growth and by difficulties in meeting the required degree of compositional uniformity on a micro-scale over macroscopic dimensions. The exact nature and origin of the critical defects which control photorefractivity could not as yet be identified because of gravitational interference. There exists, however, strong evidence that the density of defect formation and their spatial distribution are adversely affected by gravitational interference which precludes the establishment of quantifiable and controllable heat and mass transfer conditions during crystal growth. The current, NASA sponsored research at MIT is directed at establishing a basis for the development of a comprehensive approach to the optimization of property control during melt growth of photorefractive materials, making use of the m-g environment, provided in the International Space Station. The objectives to be pursued in m-g research on photorefractive BSO (Bi12SiO20) are: (a) identification of the x-level(s) responsible for photorefractivity in undoped BSO; (b) development of approaches leading to the control of x-level formation at uniform spatial distribution; (c) development of doping and processing procedures for optimization of the critical, application specific parameters, spectral response, sensitivity, response time and matrix stability. The presentation will focus on: the rationale for the justification of the space experiment, ground-based development efforts, design considerations for the space experiments, strategic plan of the space experiments, and approaches to the quantitative analysis of the space experiments.

Hyers, Robert W.↗

NASA NTRS2018

Discreditation of Bobdownsite and the Establishment of Criteria for the Identification of Minerals with Essential Monofluorophosphate (PO3F2-)

Bobdownsite, IMA number 2008-037, was approved as a new mineral by the Commission on New Minerals, Nomenclature and Classification (CNMNC) as the fluorine endmember of the mineral whitlockite. The type locality of bobdownsite is in Big Fish River, Yukon Canada, and bobdownsite was reported to be the first naturally occurring mineral with essential monofluorophosphate (PO3F2-). The type specimen of bobdownsite has been reinvestigated by electron probe microanalysis (EPMA), and our data indicate that fluorine abundances are below detection in the mineral. In addition, we conducted detailed analysis of bobdownsite from the type locality by gas chromatography isotope ratio mass spectrometry, Raman spectroscopy, EPMA, and NMR spectroscopy. These data were compared with previously published data on synthetic monofluorophosphate salts. Collectively, these data indicate that bobdownsite is indistinguishable from whitlockite with a composition along the whitlockite-merrillite solid solution. Bobdownsite is therefore discredited as a valid mineral species. An additional mineral, krásnoite, has been purported to have monofluorophosphate components in its structure, but reexamination of those data indicate that F- in krásnoite forms bonds with Al, similar to OH- bonded to Al in perhamite. Consequently, krásnoite also lacks monofluorophosphate groups, and there are currently no valid mineral species with monofluorophosphate in their structure. We recommend that any future reports of new minerals that contain essential monofluorophosphate anions be vetted by abundance measurements of fluorine, vibrational spectroscopy (both Raman and FTIR), and where paramagnetic components are permissibly low, NMR spectroscopy. Furthermore, we emphasize the importance of using synthetic compounds containing monofluorophosphate anions as a point of comparison in the identification of minerals with essential monofluorophosphate. Structural data that yield satisfactory P-F bond lengths determined by X-ray crystallography, coupled with direct chemical analyses of fluorine in a material do not constitute sufficient evidence alone to identify a new mineral with essential monofluorophosphate anions.

McCubbin, Francis M.↗

NASA NTRS1985

Lambda Point Equipment

A compilation of the active research tasks as of the end of the fiscal year 1984 of the Microgravity Science and Applications Program, NASA-Office of Space Science and Applications, involving several NASA centers and other organizations is presented. The purpose is to provide an overview of the program scope for managers and scientists in industry, university, and government communities. An introductory description of the program, strategy and overall goal; identification of the organizational structures and people involved; and a description of each research task, together with a list of recent publications is presented. The tasks are grouped into six categories: Electronic Materials; Solidification of Metals, Alloys, and Composites; Fluid Dynamics and Transports; Biotechnology; Glasses and Ceramics; and Combustion.

Lipa, J. A.↗

NASA NTRS2013

Testing the Origins of Basalt Fragments fro Apollo 16

Several 2-4 mm regolith fragments of basalt from the Apollo 16 site were recently described by [1]. These included a high-Ti vitrophyric basalts (60603,10-16) and one very-low-titanium (VLT) crystalline basalt (65703,9-13). As Apollo 16 was the only highlands sample return mission distant from the maria, identification of basaltic samples at the site indicates input from remote sites via impact processes [1]. However, distinguishing between impact melt and pristine basalt can be notoriously difficult and requires significant sample material [2-6]. The crystal stratigraphy method utilizes essentially non-destructive methods to make these distinctions [7,8]. Crystal stratigraphy combines quantitative petrography in the form of crystal size distributions (CSDs) coupled with mineral geochemistry to reveal the petrogenetic history of samples. The classic CSD plot of crystal size versus population density can reveal insights on growth/cooling rates, residence times, and magma history which in turn can be used to evaluate basaltic vs impact melt origin [7-9]. Electron microprobe (EMP) and laser ablation (LA)-ICP-MS analyses of mineral phases complement textural investigations. Trace element variations document subtle changes occurring during the formation of the samples, and are key in the interpretation and preservation of this rare lunar sample collection.

Donohue, P. H.↗

NASA NTRS2013

OSIRIS-REx Will Return a Sample of Asteroid 1999 RQ36 for Astrochemistry

Origins, Spectral Interpretation, Resource Identification, Security, Regolith Explorer (OSIRIS-REx) is the third mission in NASA's New Frontiers program. OSIRIS-REx launches in 2016 and will return the first pristine samples of carbonaceous material from the surface of a primitive asteroid in 2023. The target, (101955) 1999 RQ36, is 1/2 km diameter roughly spherical Apollo near-Earth asteroid. It is expected to be carbonaceous, similar to CI or CM carbonaceous chondrites. This organic-rich remnant from the early Solar System is also among the most potentially hazardous asteroids known with a 1 in 2500 chance of impacting the Earth in the late 22nd century. OSIRIS-REx will measure the Yarkovsky effect to better constrain future orbit and impact potential of this and other asteroids. OSIRIS-REx will image, map, and spectrally characterize RQ36 from 0.4-50 icron. The returned sample of regolith will be >60g (and up to 2kg) and thus the largest extraterrestrial sample returned from space since Apollo 17. Unlike meteorites, the sample will come from a known, well-characterized source and will be collected and transported to Earth pristine from terrestrial contamination. It will be available for study by the global astrochemistry community to address fundamental questions about the origin and evolution of the solar system and the life it harbors.

organic-rich↗

NASA NTRSDate not supplied

Electrical Endurance to Extrinsic Aging of Polyphenylsulfone-Boron Nitride Composite Insulation for Aeronautical Power Systems

Various insulating materials which can be potentially used in energy application, especially in electrified transportation, are investigated in this paper. They are based on Polyphenylsulfone matrix filled by macro and nano hexagonal Boron-nitride particles. Our study focuses on electrical properties, particularly endurance to partial discharges. Upon developing an original testing procedure and adequate partial discharge inception modeling, it is shown that that the h-BN micron and nano fillers can significantly improve the dielectric strength and resistance of PPSU to extrinsic aging, even in comparison with the insulating material typically used for electrified transportation, i.e., corona resistant polyimide. Also, a new diagnostic marker, extracted from partial discharge monitoring and analytics obtained by an innovative software, i.e., the likelihood surface discharge identification, seems to be very promising for dynamic residual life prediction for an insulation system subjected to surface discharges.

Polyphenylsulfone (PPSU)↗