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At least 487 records · Page 27

Process-based balance of system cost modeling for offshore wind power plants in the United States

This paper describes the development of a process-based and open-source balance of system cost model that provides the capability to evaluate both existing and novel offshore wind technologies. Individual design and installation steps are represented with bottom-up engineering models that compute times and costs associated with the process; furthermore, operational constraints are assigned to each process so that delays caused by weather and presence of marine mammals may be accounted for in the overall project timeline. The model structure, assumptions, inputs, and results are vetted with industry partners and compared against actual projects for validation. Installation times show reasonable agreement with real data. Project cost sensitivities are investigated to compute the system-level impact of different design choices. First, individual vessel efficiencies are computed for varying numbers of installation vessels and weather time series to show the diminishing returns of more than two feeder barges. Then, array cable capital costs and installation times are determined for a representative project with different turbine sizes. These values quantify the cost-benefit tradeoffs and show a net-cost savings of decreasing numbers of turbines, increased turbine spacing, and fewer turbine terminations. These results demonstrate that the balance of system model features the accuracy, functionality, and accessibility to serve as the foundation for a wide range of analyses to identify cost reduction potentials for offshore wind energy in the United States.

17 WIND ENERGY↗

BayoTech Risk and Modeling Support of NM Gas Site

The BayoTech hydrogen generation system has been evaluated in terms of safety considerations at the NM Gas site. The consequence of a leak in different components in the system was evaluated in terms of plume dispersion and overpressure. Additionally, the likelihood of a leak scenario for different hydrogen components was identified. The worst-case plume dispersion cases, full-bore leaks, resulted in relatively large plumes. However, these cases were noted to be far less likely than the partial break cases that were evaluated. The partial break cases resulted in nearly negligible plume lengths. Similarly, the overpressure analysis of the full-bore break scenarios resulted in much larger overpressures than the partial break cases (which resulted in negligible overpressure at the lot line). There were several cases evaluated in the analysis that represented leak scenarios from both hydrogen and natural gas sources. Generally, the natural gas leak scenarios resulted in a smaller horizontal impact than that of hydrogen leaks. The worst-case consequence from a hydrogen leak resulted from the compressors, storage pods, or dispensing system. To consider the safety features that may isolate the leak, the consequence was evaluated at different times after the leak event to show the reduction of pressure. After 2 seconds, the plume dispersion from this event is contained within the perimeter of the site. The worst-case consequences show that the plume may disperse to adjacent facilities and to the street. When considering both likelihood and consequence, the risk may be considered low because the maximum frequency of a full-bore leak from any component within the hydrogen compound is 8.2 E-5/yr. This means that a full-bore leak is expected to occur less than once every 10,000 years. The risk can be further reduced by implementing mitigative countermeasures, such as CMU walls along the sides of the equipment compound. This would reduce the overall consequence of the worst-case dispersion scenarios (horizontal impact of plume). In terms of siting and safety analysis, the NFPA 2 code was used to provide a high-level evaluation of the current site plan. The most limiting equipment in terms of set-back distance are the compressors/storage units because of the high-pressure hydrogen. The site layout was evaluated for an acceptable location for the compression/storage unit based on NFPA 2 set-back distances. It is important to note that the NFPA 2 set-back distances consider both likelihood and consequence. This is important because the worst-case results evaluated herein also represent the least likely leak scenario. Other site-specific considerations were evaluated, including the parking shade structure with photovoltaic cells and refueling vehicles. These issues were dispositioned and determined to not present a safety risk.

08 HYDROGEN↗

Synthesis of data obtained at Jicamarca, Peru, during the September 11, 1969, eclipse.

Results of continuous measurements of electron temperatures, electron concentrations, and vertical plasma drift made at Jicamarca during the Sept. 11, 1969, solar eclipse and of control measurements made on Sept. 13, 1969. Synthesis of the observed electron concentrations was made, using a model that solved the time-dependent electron-ion continuity equations. Ions O(-), NO(+), O2(+), and N2(+) were treated. Physical and chemical processes pertinent to the F region were considered in a realistic way. At noon, 300 km above Jicamarca, the values q = 290 per cu cm per sec for the O(+) production rate, beta = 1.94 x 0.0001 per sec for the loss coefficient, and H = 59 km for the atomic oxygen scale height were obtained. All large-scale features observed in the F2 region were synthesized by the model. This synthesis was not sensitive to a simultaneous 30% reduction of q and beta.

Sterling, D. L.↗

The surface geometry of inherited joint and fracture trace patterns resulting from active and passive deformation

Hypothetical models are considered for detecting subsurface structure from the fracture or joint pattern, which may be influenced by the structure and propagated to the surface. Various patterns of an initially orthogonal fracture grid are modeled according to active and passive deformation mechanisms. In the active periclinal structure with a vertical axis, fracture frequency increased both over the dome and basin, and remained constant with decreasing depth to the structure. For passive periclinal features such as a reef or sand body, fracture frequency is determined by the arc of curvature and showed a reduction over the reefmound and increased over the basin.

Podwysocki, M. H.↗

Electromagnetic ion beam instabilities - Comparison of oneand two-dimensional simulations

Numerical simulations of electromagnetic instabilities, driven by a cool tenuous ion beam propagating along an ambient magnetic field, have been conducted in one and two spatial dimensions. The calculations employ particle ions, fluid electrons, and a predictor corrector scheme for solving the electromagnetic field in two dimensions that is described in some detail. While the principal features of the one-dimensional calculations (which reproduce previous work) are retained, the two-dimensional simulations show some reduction of the overall level of the magnetic field fluctuations. Enhancement of the heating of the beam ions at the expense of the core ions also occurs in the case where the beam density is sufficiently large that the right-hand nonresonant instability dominates. Implications of the results for modeling of the ion foreshock and quasi-parallel shocks are discussed.

Winske, D.↗

Full-scale wind-tunnel tests of high-lift system modifications on a carrier based fighter aircraft

Modifications to the high-lift system of a full-scale F/A-I8A were tested in the 80- by 120-Foot Wind Tunnel of the National Full-Scale Aerodynamics Complex at the NASA Ames Research Center in Moffett Field, California. The objective was to measure the effect of simple modifications on the aerodynamic performance of the high-lift system. The modifications included the placement of a straight fairing in the shroud cove above the trailing-edge flap and the addition of seals to prevent air leakage through the hinge lines of the leading-edge flap, the trailing-edge shroud, and the wing fold. The test was carried out on an actual F/A-18A with it's flaps deployed in the landing approach configuration. The angle of attack ranged from 0 to 16 degrees and the wind speed was 100 knots. At an angle of attack of 8 degrees, the trimmed lift coefficient was improved by 0.09 with all wing seals in place. This corresponds to a reduction in the approach speed for the F/A-I8A of about 5 knots. The seal along the wing fold hinge, a feature present on many naval aircraft, provided one third of the total increment in trimmed lift. A comparison of the full-scale wind-tunnel results with those obtained from flight test is also presented.

Meyn, Larry A.↗

High Strength and Compatible Aluminum Alloy for Hydrogen-Peroxide Fuel Tanks

This paper describes the development of a new high strength and Hydrogen Peroxide (HP) propellant compatible aluminum alloy for NASA Hyper-X vehicle's fuel tanks and structures. The tensile strength of the new alloy is more than 3 times stronger than the conventional 5254 alloy while it still maintains HP compatibility similar to 5254 (Class 1 category). The alloy development strategy consists of selecting certain rare earth and transition metals, with unique electrochemical properties, that will not act as catalysts to decompose liquid HP at the atomic level. Such elements will added to the aluminum alloy and the mixture will be cast and rolled into thin sheet metals. Test coupons are machined from sheet metals for HP long-term exposure testing and mechanical properties testing. In addition, the ability to weld the new alloy using Friction Stir Welding has also been explored. Currently, aluminum alloy 5254 is the state-of-the-art material for HP storage, but its yield strength is very low (420 ksi) and may not be suitable for the development of light-weight fuel tanks for Hyper-X vehicles. The new high strength and HP compatible alloy could represent an enabling material technology for NASA's Hyper-X vehicles, where flight weight reduction is a critical requirement. These X-planes are currently under studied as air-breathing hypersonic research vehicles featuring a lifting body configuration with a Rocket Based Combined Cycle (RBCC) engine system.

Lee, Jonathan A.↗

Computational Analysis of a Chevron Nozzle Uniquely Tailored for Propulsion Airframe Aeroacoustics

A computational flow field and predicted jet noise source analysis is presented for asymmetrical fan chevrons on a modern separate flow nozzle at take off conditions. The propulsion airframe aeroacoustic asymmetric fan nozzle is designed with an azimuthally varying chevron pattern with longer chevrons close to the pylon. A baseline round nozzle without chevrons and a reference nozzle with azimuthally uniform chevrons are also studied. The intent of the asymmetric fan chevron nozzle was to improve the noise reduction potential by creating a favorable propulsion airframe aeroacoustic interaction effect between the pylon and chevron nozzle. This favorable interaction and improved noise reduction was observed in model scale tests and flight test data and has been reported in other studies. The goal of this study was to identify the fundamental flow and noise source mechanisms. The flow simulation uses the asymptotically steady, compressible Reynolds averaged Navier-Stokes equations on a structured grid. Flow computations are performed using the parallel, multi-block, structured grid code PAB3D. Local noise sources were mapped and integrated computationally using the Jet3D code based upon the Lighthill Acoustic Analogy with anisotropic Reynolds stress modeling. In this study, trends of noise reduction were correctly predicted. Jet3D was also utilized to produce noise source maps that were then correlated to local flow features. The flow studies show that asymmetry of the longer fan chevrons near the pylon work to reduce the strength of the secondary flow induced by the pylon itself, such that the asymmetric merging of the fan and core shear layers is significantly delayed. The effect is to reduce the peak turbulence kinetic energy and shift it downstream, reducing overall noise production. This combined flow and noise prediction approach has yielded considerable understanding of the physics of a fan chevron nozzle designed to include propulsion airframe aeroacoustic interaction effects.

Massey, Steven J.↗

Fast Responses on Pre-Industrial Climate from Present-Day Aerosols in A CMIP6 Multi-Model Study

In this work, we use Coupled Model Intercomparison Project Phase 6 (CMIP6) simulations from 10 Earth system models (ESMs) and general circulation models (GCMs) to study the fast climate responses on pre-industrial climate, due to present-day aerosols. All models carried out two sets of simulations: a control experiment with all forcings set to the year 1850 and a perturbation experiment with all forcings identical to the control, except for aerosols with precursor emissions set to the year 2014. In response to the pattern of all aerosols effective radiative forcing (ERF), the fast temperature responses are characterized by cooling over the continental areas, especially in the Northern Hemisphere, with the largest cooling over East Asia and India, sulfate being the dominant aerosol surface temperature driver for present-day emissions. In the Arctic there is a warming signal for winter in the ensemble mean of fast temperature responses, but the model-to-model variability is large, and it is presumably linked to aerosol-induced circulation changes. The largest fast precipitation responses are seen in the tropical belt regions, generally characterized by a reduction over continental regions and presumably a southward shift of the tropical rain belt. This is a characteristic and robust feature among most models in this study, associated with weakening of the monsoon systems around the globe (Asia, Africa and America) in response to hemispherically asymmetric cooling from a Northern Hemisphere aerosol perturbation, forcing possibly the Intertropical Convergence Zone (ITCZ) and tropical precipitation to shift away from the cooled hemisphere despite that aerosols' effects on temperature and precipitation are only partly realized in these simulations as the sea surface temperatures are kept fixed. An interesting feature in aerosol-induced circulation changes is a characteristic dipole pattern with intensification of the Icelandic Low and an anticyclonic anomaly over southeastern Europe, inducing warm air advection towards the northern polar latitudes in winter.

Pre-industrial climate↗

Lightweight Thrust Chamber Assemblies using Multi-Alloy Additive Manufacturing and Composite Overwrap

Additive Manufacturing (AM) has brought significant design and fabrication opportunities for complex components with internal features such as liquid rocket engine thrust chambers not previously possible. This technology allows for significant cost savings and schedule reductions in addition to new performance optimization through weight reduction and increased margins. Specific to regeneratively-cooled combustion chambers and nozzles for liquid rocket engines, additive manufacturing offers the ability to form the complex internal coolant channels and the closeout of the channels to contain the high pressure liquid propellants with a single operation. Much of additive manufacturing development has focused on monolithic alloys using Laser Powder Bed Fusion (L-PBF), which do not allow for complete optimization of the structure. The National Aeronautics and Space Administration (NASA) completed feasibility of an AM bimetallic L-PBF GRCop-84 copper-alloy combustion chamber with an AM electron beam freeform Inconel 625 structural jacket under the Low Cost Upper Stage Propulsion (LCUSP) Project. A follow-on project called Rapid Analysis and Manufacturing Propulsion Technology (RAMPT) is under development to further expand large-scale multi-alloy thrust chambers while maturing composite overwrap technology for significant weight savings opportunities. The RAMPT project has three primary objectives: 1) Advancing blown powder Directed Energy Deposition (DED) to fabricate integral-channel large scale nozzles, 2) Develop composite overwrap technology to reduce weight and provide structural capability for thrust chamber assemblies, and 3) Develop bimetallic and multi-metallic additively manufactured radial and axial joints to optimize material performance. In addition to these primary manufacturing developments, analytical modeling efforts compliment the process development to simulate the AM processes to reduce build failures and distortions. The RAMPT project is also maturing the supply chain for various manufacturing processes described above in addition to L-PBF of GRCop-42. This paper will present an overview of the RAMPT project, the process development and hardware progress to date, material and hot-fire testing results, along with future developments.

Additive Manufacturing↗

Process-Based Balance-of-System Cost Modeling for Offshore Wind Power Plants in the United States: Preprint

This work describes the development of a process based and open source balance of system cost model which provides the capability to evaluate both existing and novel offshore wind technologies. Individual design and installation steps are represented with bottom-up engineering models that compute the times and costs associated with the process; furthermore, operational constraints are assigned to each process so that delays due to weather and presence of marine mammals may be accounted for in the overall project timeline. The model structure, assumptions, inputs, and results are vetted with industry partners and compared against actual projects for validation; installation times are shown to agree with real data with relative errors of less than 35\%. Case studies are presented to demonstrate the functionality of the model. First, individual vessel efficiencies are computed for varying numbers of installation vessels and weather time series to show the diminishing returns of more than two feeder barges. Then, array cable capital costs and installation times are determined for a representative project with different turbine sizes. This quantifies the cost benefit tradeoffs of decreasing number of turbines, increased turbine spacing, and fewer turbine terminations and shows a net cost savings. These results demonstrate that the BOS model features the accuracy, functionality, and accessibility to serve as the foundation for a wide range of analyses to identify cost reduction potentials for offshore wind energy in the United States.

17 WIND ENERGY↗

Dynamic Bubbling Balanced Proactive CO 2 Capture and Reduction on a Triple-Phase Interface Nanoporous Electrocatalyst

The formation and preservation of the active phase of the catalysts at the triple-phase interface during CO 2 capture and reduction is essential for improving the conversion efficiency of CO 2 electroreduction toward value-added chemicals and fuels under operational conditions. Designing such ideal catalysts that can mitigate parasitic hydrogen generation and prevent active phase degradation during the CO 2 reduction reaction (CO 2 RR), however, remains a significant challenge. Herein, we developed an interfacial engineering strategy to build a new SnO x catalyst by invoking multiscale approaches. This catalyst features a hierarchically nanoporous structure coated with an organic F-monolayer that modifies the triple-phase interface in aqueous electrolytes, substantially reducing competing hydrogen generation (less than 5%) and enhancing CO 2 RR selectivity (~90%). This rationally designed triple-phase interface overcomes the issue of limited CO 2 solubility in aqueous electrolytes via proactive CO 2 capture and reduction. Concurrently, we utilized pulsed square-wave potentials to dynamically recover the active phase for the CO 2 RR to regulate the production of C1 products such as formate and carbon monoxide (CO). This protocol ensures profoundly enhanced CO 2 RR selectivity (~90%) compared with constant potential (~70%) applied at -0.8 V (V vs RHE). We further achieved a mechanistic understanding of the CO 2 capture and reduction processes under pulsed square-wave potentials via in situ Raman spectroscopy, thereby observing the potential-dependent intensity of Raman vibrational modes of the active phase and CO 2 RR intermediates. Finally, this work will inspire material design strategies by leveraging triple-phase interface engineering for emerging electrochemical processes, as technology moves toward electrification and decarbonization.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Rare‐Earth Reduction in High‐Speed PM‐Assisted Synchronous Reluctance Motors Using Hybrid Magnet Strategies and Design Optimisation for 800 V EVs

The trend towards electrifying transportation systems has stimulated research endeavours aimed at developing electric machines that are not only high speed and efficient but also low‐cost and compact. To support this transition, the US Department of Energy (DOE) has established ambitious targets of $7/kW cost and 12 kW/L power density for the electric drivetrains. This paper attempts to meet these targets by proposing high‐speed permanent magnet assisted synchronous reluctance machine (PMASynRM) topologies enabled by hybrid magnet strategies, combining rare‐earth (RE) magnets with low‐cost, RE‐free alternatives. Modified 2‐layer and 3‐layer U‐shaped rotor configurations, featuring structural reinforcements to withstand high mechanical stress at elevated speeds, are developed. A multi‐objective design optimisation framework is employed to optimise the rotor design, targeting reductions in RE magnet volume, magnet demagnetisation risk and torque ripple while achieving the desired electromagnetic performance. A comprehensive analysis of the optimised rotor designs, compared against a 16,000 rpm, 800 V baseline IPM motor, shows over 70% RE reduction, demagnetisation risk below 3.5% and torque ripple under 10%. Detailed analyses of performance trends across various magnet combinations and rotor configurations highlight the viability of hybrid magnet PMASynRM designs as cost‐effective, robust and energy‐efficient solutions for next‐generation EVs.

33 ADVANCED PROPULSION SYSTEMS↗

Inhibition of Alkali Metal Reduction of 1-Adamantanol by London Dispersion Effects

Here, a series of alkali metal 1-adamantoxide (OAd 1 ) complexes of formula [M(OAd 1 )(HOAd 1 ) 2 ], where M=Li, Na or K, were synthesised by reduction of 1-adamantanol with excess of the alkali metal. The syntheses indicated that only one out of every three HOAd 1 molecules was reduced. An X-ray diffraction study of the sodium derivative shows that the complex features two unreduced HOAd 1 donors as well as the reduced alkoxide (OAd 1 ), with the Ad 1 fragments clustered together on the same side of the NaO 3 plane, contrary to steric considerations. This is the first example of an alkali metal reduction of an alcohol that is inhibited from completion due to the formation of the [M(OAd 1 )(HOAd 1 ) 2 ] complexes, stabilized by London dispersion effects. NMR spectroscopic studies revealed similar structures for the lithium and potassium derivatives. Computational analyses indicate that decisive London dispersion effects in the molecular structure are a consequence of the many C–H•••H–C interactions between the OAd 1 groups.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

HAZARD ANALYSIS OF DIGITAL ENGINEERED SAFETY FEATURES ACTUATION SYSTEM IN ADVANCED NUCLEAR POWER PLANTS USING A REDUNDANCY-GUIDED APPROACH

Replacing the existing aging analog instrumentation and control (I&C) systems with modern safety control and protection digital technology offers one of the foremost means of performance improvements and cost reductions for the existing nuclear power plants (NPPs). However, the qualification of digital I&C systems remains a challenge, especially considering the issue of software common-cause failures (CCFs), which are difficult to address. With the application and upgrades of advanced digital I&C systems, software CCFs have become a potential threat to plant safety because most redundant designs use similar digital platforms or software in the operating and application systems. With complex designs of multilayer redundancy to meet the single-failure criterion, digital I&C safety systems (e.g., engineered safety-features actuation system [ESFAS]) are of a particular concern in the U.S. Nuclear Regulatory Commission (NRC) licensing procedures. This paper applies a modularized approach to conduct redundancy-guided systems-theoretic hazard analysis for an advanced digital ESFAS with multilevel redundancy designs. Systematic methods and risk-informed tools are incorporated to address both hardware and software CCFs, which provide guidance to eliminate the triggers of potential single points of failure in the design of digital safety systems in advanced plant designs.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Hybrid CMS methods with model reduction for assembly of structures

Future on-orbit structures will be designed and built in several stages, each with specific control requirements. Therefore there must be a methodology which can predict the dynamic characteristics of the assembled structure, based on the dynamic characteristics of the subassemblies and their interfaces. The methodology developed by CSC to address this issue is Hybrid Component Mode Synthesis (HCMS). HCMS distinguishes itself from standard component mode synthesis algorithms in the following features: (1) it does not require the subcomponents to have displacement compatible models, which makes it ideal for analyzing the deployment of heterogeneous flexible multibody systems, (2) it incorporates a second-level model reduction scheme at the interface, which makes it much faster than other algorithms and therefore suitable for control purposes, and (3) it does answer specific questions such as 'how does the global fundamental frequency vary if I change the physical parameters of substructure k by a specified amount?'. Because it is based on an energy principle rather than displacement compatibility, this methodology can also help the designer to define an assembly process. Current and future efforts are devoted to applying the HCMS method to design and analyze docking and berthing procedures in orbital construction.

Farhat, Charbel↗

Pd‐Ru Alloy Nanocages with a Face‐Centered Cubic Structure and Their Enhanced Activity toward the Oxidation of Ethylene Glycol and Glycerol

Abstract This article reports a facile method for the synthesis of Pd‐Ru nanocages by activating the galvanic replacement reaction between Pd nanocrystals and a Ru(III) precursor with I ‐ ions. The as‐synthesized nanocages feature a hollow interior, ultrathin wall of ≈2.5 nm in thickness, and a cubic shape. Our quantitative study suggests that the reduction rate of the Ru(III) precursor can be substantially accelerated upon the introduction of I ‐ ions and then retarded as the ratio of I ‐ /Ru 3+ is increased. The Pd‐Ru nanocages take an alloy structure, with the Ru atoms in the nanocages crystallized in a face‐centered cubic structure instead of the hexagonal close‐packed phase taken by bulk Ru. Using Pd nanocubes with different edge lengths, the dimensions of the nanocages in the range of 6−18 nm can readily be tuned. When tested as catalysts toward the electro‐oxidation of ethylene glycol and glycerol, respectively, the Pd‐Ru cubic nanocages prepared from 18 nm Pd cubes exhibit 5.1‐ and 6.2‐fold enhancements in terms of mass activity relative to the commercial Pd/C. After 1000 cycles of accelerated durability test, the mass activities of the nanocages are still 3.3 and 3.7 times as high as that of the pristine commercial Pd/C catalyst, respectively.

Zhao, Ming↗

Sequential oxidation-depolymerization strategies for lignin conversion to low molecular weight aromatic chemicals

Lignin is the largest source of bio-derived aromatic chemicals, and oxidative conversion of this polymeric material can generate valuable oxygenated aromatic compounds. Oxidative depolymerization of lignosulfonate feedstocks under alkaline conditions is used commercially for vanillin production. Recent studies have led to other oxidation methods that access different aromatic products from lignin in good yields. A particularly effective strategy that accesses some of the highest yields of aromatic monomers to date features a two-step process in which the oxidation of specific alcohol groups in lignin is followed by an oxidative, reductive, or redoxneutral step that cleaves the polymer into aromatic monomers and oligomers. Studies of model compounds have provided crucial mechanistic insights and contributed to the development of effective lignin depolymerization methods. Furthermore, this review provides a general overview of lignin depolymerization methods, followed by a survey of oxidation-depolymerization methods that access oxygenated aromatic monomers in good yields.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗