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At least 487 records · Page 27

Deciphering the Dynamic Balance Between Solvation Strength and Polysulfides Reaction Heterogeneity in Practical Lithium‐Sulfur Batteries

Achieving stable interfacial chemistry in lithium–sulfur batteries under practical conditions remains a key barrier to commercialization. Here, we demonstrate that interfacial dynamics can be effectively regulated by coupling solvation-power control with intrinsic heterogeneity of sulfur redox chemistry through the introduction of a weakly solvating fluorinated cosolvent, LIB 1200ET (1200ET). Compared with conventional fluorinated ethers, 1200ET efficiently shifts Li + solvation environment toward a more non-coordinated configuration at low volume fractions, enabling substantial solvation modulation without significantly impairing sulfur redox kinetics. This solvation transition weakens Li + –solvent interactions while strengthening Li + –anion and Li + –lithium polysulfide (LPS) coordination, suppressing LPS solubility and promoting reconstruction of solid–electrolyte interphase (SEI). Regulated LPS chemistry, together with 1200ET, leads to formation of a S 4+ -rich, LiF-reinforced SEI with enhanced ionic conductivity and mechanical robustness. Spatially resolved sulfur K-edge X-ray absorption spectroscopy on pouch cells reveals pronounced current-density-dependent chemical heterogeneity, distinguishing kinetically dominated and solvation-controlled regions. Under practical conditions (3.7 mg cm −2 sulfur loading, E/S = 6 µL mg −1 ), a single-layer pouch cell delivers 527 mAh g −1 over 200 cycles at C/3, while an Ah-level multilayer pouch cell achieves an energy density of 358 Wh kg −1 . These results establish non-coordinating cosolvent-driven solvation engineering as a scalable strategy for practical Li–S batteries.

36 MATERIALS SCIENCE↗

A review of collaborative studies between the NSTX/-U and MAST/-U spherical tokamaks

The National Spherical Torus Experiment (NSTX) at the Princeton Plasma Physics Laboratory in the United States, and the mega ampere spherical tokamak (MAST) at the United Kingdom Atomic Energy Authority in the United Kingdom, and their respective upgrades (NSTX-U and MAST-U) are two MAST fusion devices that have operated roughly over the past two decades. Both devices have made significant contributions to understanding spherical tokamak (ST) plasma physics, and fusion plasmas in general, and both have contributed data to multi-machine database studies. Several diagnostics have been physically moved from one machine to the other by diagnostic teams working on both devices. Collaboration has benefited both research teams in the areas of operational expertise, scenario development, and equilibrium reconstruction techniques. More focused comparative studies between the two devices have been pursued over the years in many areas as well, including stability calculations, disruption characterization, pedestal and edge localized mode stability, confinement and transport, energetic particles, and heating and current drive modelling. Together NSTX/-U and MAST/-U set the stage for the future of STs, which is entering the phase of design of demonstration power plant devices.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Electric field control of magnetism

Electric field control of magnetism is an extremely exciting area of research, from both a fundamental science and an applications perspective and has the potential to revolutionize the world of computing. To realize this will require numerous further innovations, both in the fundamental science arena as well as translating these scientific discoveries into real applications. Thus, this article will attempt to bridge the gap between condensed matter physics and the actual manifestations of the physical concepts into applications. We have attempted to paint a broad-stroke picture of the field, from the macroscale all the way down to the fundamentals of spin–orbit coupling that is a key enabler of the physics discussed. Here, we hope it will help spur more translational research within the broad materials physics community. Needless to say, this article is written on behalf of a large number of colleagues, collaborators and researchers in the field of complex oxides as well as current and former students and postdocs who continue to pursue cutting-edge research in this field.

36 MATERIALS SCIENCE↗

Turbulence characteristics and flow dynamics impacts on the H-mode transition in favourable magnetic geometry with lower power threshold

We report the L-H transition power threshold (P LH ) in favourable magnetic geometry (ion ∇B drift pointing towards X-point) is much lower than in the unfavourable magnetic geometry (ion ∇B drift pointing away from X-point) on multiple tokamaks. In a systematic experiment on DIII-D, the ion ∇B drift direction was changed continuously from the unfavourable to favourable configuration during plasma discharges. During such process, the input neutral beam power was kept constant at a value that was above P LH for favourable configuration, but lower than P LH for unfavourable configuration. Toroidal field and plasma current were also kept constant and there was little change in the edge electron density ne and electron temperature T e profiles. The density fluctuation amplitude was reduced approaching the transition, while a large increase of turbulence Reynolds stress and flow shear were simultaneously observed. The turbulence decorrelation rate was found to increase as the ion ∇B drift direction was moving towards the favourable configuration, but the flow shear also increased and exceeded the turbulence decorrelation rate. These measurements demonstrate an important correlation between turbulence and turbulence-driven flow and a lowering of PLH, provide insights into the underlying physics behind the hidden parameters and inform a more complete physics-based model of the L-H transition power threshold.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Bent Crystal Channeling for Optimized Beam Shadowing and Proton Extraction at Mu2e

The Mu2e experiment is designed to investigate the CLFV through the observation of a neutrinoless muon-to-electron conversion in the field of an Al nucleus. The observation of such a process would be clear evidence of physics beyond the standard model. Due to the rarity of this process, a cutting-edge, intense muon beam is required to achieve an improvement of the current single-event sensitivity by 4 orders of magnitude. To achieve this goal, a primary proton beam with 8 GeV is extracted from the Fermilab Delivery Ring using the slow resonant extraction technique. Mu2e requires ~3.6x10$^{20}$ protons-on-target to meet its goal; hence, it is crucial to minimize the extraction losses. An important source of such losses are the particles impacting on the electrostatic septum blade. A very promising solution to the problem lies in the beam shadowing scheme tested at CERN SPS. In this approach, a bent crystal is strategically placed upstream of the septum, deflecting particles from the blade at a precise angle via the phenomenon of channeling. As a result, a zone with reduced particle flux is created downstream of the crystal, safeguarding the septum anode by minimizing interactions with the beam. This work explores the optimization of beam shadowing design and the process in the manufacturing and characterization of the bent crystal sample. It emphasizes the promising role of channeling in bent crystals, and it underscores the significant potential of channeling in bent crystals to assist the Mu2e experiment.

Fedeli, Pierluigi [Ferrara U.; INFN, Ferrara] (ORC↗

On an apparent discrepancy between pulsation and evolution masses for Cepheids.

Results of new theoretical pulsation calculations in the linear nonadiabatic approximation are presented. Emphasis is placed on the location of blue edges (the borderline between stability and instability against pulsation) for pulsation in the fundamental mode. The results of evolutionary calculations for the helium-burning phase are introduced, and a theoretical period-luminosity relationship is obtained for Cepheids that lie on the blue edge of the instability strip. The theoretical results are then compared with current estimates of the intrinsic bulk properties of 13 Cepheids, and it is shown how theoretical and observational properties may be reconciled without assuming significant mass loss or the necessity of major adjustments in the theory. Finally, it is argued that the required revision in Cepheid luminosities lies within the observational uncertainties.

Iben, I., Jr.↗

Insulator edge voltage gradient effects in spacecraft charging phenomena

Insulating surfaces on geosynchronous satellites were charged by geomagnetic substorms to a point where discharges occur. The electromagnetic pulses from these discharges couple into satellite electronic systems disrupting operations are examined. Laboratory tests conducted on insulator charging have indicated that discharges appear to be initiated at insulator edges where voltage gradients can exist. An experimental investigation was conducted to measure edge voltage gradients on silvered Teflon samples as they are charged by monoenergetic electron beams. It was found that the surface voltage at insulator edges can be approximated by an exponential expression based on an electron current density balance.

Stevens, N. J.↗

Driven magnetic reconnection in three dimensions - Energy conversion and field-aligned current generation

The energy conversion processes occurring in three-dimensional driven reconnection is analyzed. In particular, the energy conversion processes during localized reconnection in a taillike magnetic configuration are studied. It is found that three-dimensional driven reconnection is a powerful energy converter which transforms magnetic energy into plasma bulk flow and thermal energy. Three-dimensional driven reconnection is an even more powerful energy converter than two-dimensional reconnection, because in the three-dimensional case, plasmas were drawn into the reconnection region from the sides as well as from the top and bottom. Field-aligned currents are generated by three-dimensional driven reconnection. The physical mechanism responsible for these currents which flow from the tail toward the ionosphere on the dawnside of the reconnection region and from the ionosphere toward the tail on the duskside is identified. The field-aligned currents form as the neutral sheet current is diverted through the slow shocks which form on the outer edge of the reconnected field lines (outer edge of the plasma sheet).

Sato, T.↗

Part A: Nonprincipal-plane scattering from flat plates: Second-order and corner diffractions

Two models of a flat plate for nonprincipal-plane scattering are explored. The first is a revised version of the Physical Optics/Physical Theory of Diffraction (PO/PTD) model with second-order PTD equivalent currents included to account for second-order interactions among the plate edges. The second model uses a heurisitcally derived corner diffraction coefficient to account for the corner scattering mechanism. The patterns obtained using the newer models were compared to the data of previously reported models, the Moment Method (MM), and experimental results. Near normal incidence, all the models agreed; however, near grazing incidence a need for higher-order and corner diffraction mechanisms was noted. In many instances the second-order and corner-scattered fields which were formulated improved the results.

Balanis, Constantine A.↗

Longitudinal vortex control - Techniques and applications (The 32nd Lanchester Lecture)

A summary is presented of vortex control applications and current techniques for the control of longitudinal vortices produced by bodies, leading edges, tips and intersections. Vortex control has up till now been performed by many approaches in an empirical fashion, assisted by the essentially inviscid nature of much of longitudinal vortex behavior. Attention is given to Reynolds number sensitivities, vortex breakdown and interactions, vortex control on highly swept wings, and vortex control in juncture flows.

Bushnell, D. M.↗

Axial Surface Mapping of Wrinkle Ridges on Solis Planum, Mars from MOLA Topography: Constraints on Subsurface Blind Thrust Geometry

We undertook axial surface mapping of selected wrinkle ridges on Solis Planum, Mars in order to assess the subsurface geometry of blind thrusts proposed to exist beneath them. This work builds on previous work that defined structural families of wrinkle ridges based on their surface morphology in this region. Although a growing consensus exists for models of wrinkle ridge kinematics and mechanics, a number of current problems remain. These include the origin of topographic offset across the edges of wrinkle ridges, the relationship between broad arches and superposed ridges, the origin of smaller wrinkles, and perhaps most importantly, the trajectory of blind thrusts that underlie wrinkle ridges and accommodate shortening at deeper crustal levels. We are particularly interested in defining the depths at which blind thrusts flatten under wrinkle ridges in order to provide constraints on the brittle-ductile transition during Early Hesperian time. We also seek to test whether wrinkle ridges on Solis Planum develop above reactivated faults or newly formed ones.

Vidal, A.↗

On Multi-Dimensional Unstructured Mesh Adaption

Anisotropic unstructured mesh adaption is developed for a truly multi-dimensional upwind fluctuation splitting scheme, as applied to scalar advection-diffusion. The adaption is performed locally using edge swapping, point insertion/deletion, and nodal displacements. Comparisons are made versus the current state of the art for aggressive anisotropic unstructured adaption, which is based on a posteriori error estimates. Demonstration of both schemes to model problems, with features representative of compressible gas dynamics, show the present method to be superior to the a posteriori adaption for linear advection. The performance of the two methods is more similar when applied to nonlinear advection, with a difference in the treatment of shocks. The a posteriori adaption can excessively cluster points to a shock, while the present multi-dimensional scheme tends to merely align with a shock, using fewer nodes. As a consequence of this alignment tendency, an implementation of eigenvalue limiting for the suppression of expansion shocks is developed for the multi-dimensional distribution scheme. The differences in the treatment of shocks by the adaption schemes, along with the inherently low levels of artificial dissipation in the fluctuation splitting solver, suggest the present method is a strong candidate for applications to compressible gas dynamics.

Wood, William A.↗

The Invariant Twist of Magnetic Fields in the Relativistic Jets of Active Galactic Nuclei

The origin of cosmic magnetic (B) fields remains an open question. It is generally believed that very weak primordial B fields are amplified by dynamo processes, but it appears unlikely that the amplification proceeds fast enough to account for the fields presently observed in galaxies and galaxy clusters. In an alternative scenario, cosmic B fields are generated near the inner edges of accretion disks in Active Galactic Nuclei (AGNs) by azimuthal electric currents due to the difference between the plasma electron and ion velocities that arises when the electrons are retarded by interactions with photons. While dynamo processes show no preference for the polarity of the (presumably random) seed field that they amplify, this alternative mechanism uniquely relates the polarity of the poloidal B field to the angular velocity of the accretion disk, resulting in a unique direction for the toroidal B field induced by disk rotation. Observations of the toroidal fields of 29 AGN jets revealed by parsec-scale Faraday rotation measurements show a clear asymmetry that is consistent with this model, with the probability that this asymmetry came about by chance being less than 1 %. This lends support to the hypothesis that the Universe is seeded by B fields that are generated in AGN via this mechanism

Contopoulos, Ioannis↗

Effects of collisional ion orbit loss on tokamak radial electric field and toroidal rotation in an L-mode plasma

Abstract Ion orbit loss has been used to model the formation of a strong negative radial electric field E r in the tokamak edge, as well as edge momentum transport and toroidal rotation. To quantitatively measure ion orbit loss, an orbit-flux formulation has been developed and numerically applied to the gyrokinetic particle-in-cell code XGC. We study collisional ion orbit loss in an axisymmetric DIII-D L-mode plasma using gyrokinetic ions and drift-kinetic electrons. Numerical simulations, where the plasma density and temperature profiles are maintained through neutral ionization and heating, show the formation of a quasisteady negative E r in the edge. We have measured a radially outgoing ion gyrocenter flux due to collisional scattering of ions into the loss orbits, which is balanced by the radially incoming ion gyrocenter flux from confined orbits on the collisional time scale. This suggests that collisional ion orbit loss can shift E r in the negative direction compared to that in plasmas without orbit loss. It is also found that collisional ion orbit loss can contribute to a radially outgoing (counter-current) toroidal-angular-momentum flux, which is not balanced by the toroidal-angular-momentum flux carried by ions on the confined orbits. Therefore, the edge toroidal rotation shifts in the co-current direction on the collisional time scale.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Test Report - Fault Current Through Graphite Filament Reinforced Plastic

Tests were performed to determine the damage to samples of composite material when a current carrying wire is shorted to the surface of the composite material, and to determine whether enough current can flow through the material to blow a fuse before damage can occur. Fault current tests were performed on samples of graphite epoxy materials. Samples consisted of six layers of IM7 graphite fiber mat in Hercules 8552 epoxy resin. A variable power supply provided up to 35 amps of current. The high voltage side of the power supply was attached to a wire at the end of a hinged arm, and the low side was attached to the edge of the sample. To test joints, the return was connected to the edge of one sample, and the high side was shorted to the top of the other sample. Tests show that when current exceeds approximately 5 amps, the graphite glows, and the epoxy melts out at the shorted contact. At higher current levels the epoxy burns. At voltages above 15 volts the epoxy outer coat is easily broken, and fire, flame, and a rise in current occur suddenly. When joints are introduced, resistance is increased, and the maximum current resulting from a short circuit to the graphite epoxy is reduced. This condition can easily result in fault current lower than the circuit breaker limit and higher than the 5 amp ignition level. The shorting contact and the joint become hot spots with melting epoxy, smoke, and fire.

Evans, R. W.↗

Spatial distribution of plasma wave activity in the nightside ionosphere of Venus

In this study we use 14 years of Pioneer Venus Orbiter Electric Field Detector (OEFD) data to define the characteristics of (VLF) burst activity in the nightside ionosphere of Venus. Our statistical results show that there are essentially four types of VLF signals. The first type of signal is only observed in the 100 Hz channel and not in any of the higher frequency channels (730 Hz, 5.4 kHz or 30 kHz). Occurrence of these waves is controlled by the magnetic field with a weaker dependence on electron density. The occurrence of these waves is controlled by the magnetic field with a weaker dependence on electron density. The occurrence rate decreases with increasing altitude to a height of 600 km. For higher altitudes beyond 600 km the occurrence rate remains roughly constant. The statistics of these signals are what one would expect for whistler mode waves from a subionospheric source. The second type of signal is broadline wave activity appearing below 300 km in the low altitude ionosphere. These signals often occur in all four channels of the OEFD. These signals are also thought to come from a subionospheric source. The third type of signal appearing near the edge of the planetary optical shadow. They are probably ion acoustic waves generated by a current driven instability associated with plasma clouds in the wake. The fourth type of signal is a narrow band wave. It occurs in either of the two high frequency channels in the high altitude tail region, and is attributed to locally generated Langmuir waves. In addition, we also observe spacecraft interference noise in both the 100 and 730 Hz channels. These signals mainly occur near the edge of the planetary optical shadow and have an inbound and outbound asymmetry in activity.

Ho, C.-M.↗

Experimental Verification of Dispersed Fringe Sensing as a Segment Phasing Technique using the Keck Telescope

Dispersed fringe sensing (DFS) is an efficient and robust method for coarse phasing of segmented primary mirrors (from one quarter of a wavelength to as much as the depth of focus of a single segment, typically several tens of microns). Unlike phasing techniques currently used for ground-based segmented telescopes, DFS does not require the use of edge sensors in order to sense changes in the relative heights of adjacent segments; this makes it particularly well suited for phasing of space-borne segmented telescopes, such as the James Webb Space Telescope. We validate DFS by using it to measure the piston errors of the segments of one of the Keck telescopes. The results agree with those of the Shack-Hartmann-based phasing scheme currently in use at Keck to within 2% over a range of initial piston errors of +/-16 (mu)m.

algorithm↗

The full-scale process and design changes for elimination of insulation edge separations and voids in tang flap area

Qualification of the full-scale process and design changes for elimination of redesigned solid rocket motor tang nitrile butadiene rubber insulation edge separations and voids was performed from 24 March to 3 December 1990. The objectives of this test were: to qualify design and process changes on flight hardware using a tie ply between the redesigned solid rocket motor steel case and the nitrile butadiene rubber insulation over the tang capture features; to qualify the use of methyl ethyl ketone in the tang flap region to reduce voids; and to determine if holes in the separator film reduce voids in the tang flap region. The tie ply is intended to aid insulation flow during the insulation cure process, and thus reduce or eliminate edge unbonds. Methyl ethyl ketone is intended to reduce voids in the tang flap area by providing better tacking characteristics. The perforated film was intended to provide possible vertical breathe paths to reduce voids in the tang area. Tang tie ply testing consisted of 270 deg of the tang circumference using a new layup method and 90 deg of the tang circumference using the current layup methods. Tie ply process success was defined as a reduction of insulation unbonds. Lack of any insulation edge unbonds on the tang area where the new process was used, and the presence of 17 unbonds with the current process, proves the test to be a success. Successful completion of this test has qualified the new processes.

Danforth, Richard A.↗