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At least 487 records · Page 27

Ultrafast transient absorption measurements of photocarrier dynamics in PdSe 2

We investigate the photocarrier dynamics in bulk PdSe 2 , a layered transition metal dichalcogenide with a novel pentagonal structure and unique electronic and optical properties. Using femtosecond transient absorption microscopy, we study the behavior of photocarriers in mechanically exfoliated bulk PdSe 2 flakes at room temperature. By employing a 400 nm ultrafast laser pulse, electron–hole pairs are generated, and their dynamics are probed using an 800 nm detection pulse. Our findings reveal that the lifetime of photocarriers in bulk PdSe 2 is approximately 210 ps. Furthermore, by spatially resolving the differential reflection signal, we determine a photocarrier diffusion coefficient of about 7.3 cm 2 s –1 . Based on these results, we estimate a diffusion length of around 400 nm and a photocarrier mobility of approximately 300 cm 2 V –1 s –1 . Furthermore, these results shed light on the ultrafast optoelectronic properties of PdSe 2 , offer valuable insights into photocarriers in this emerging material, and enable design of high-performance optoelectronic devices based on PdSe 2 .

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Element- and Time-Resolved Measurements of Spin Dynamics Using X-ray Detected Ferromagnetic Resonance

Although XFMR experiments have been carried out at a number of synchrotron radiation facilities since 2004, only a few facilities currently have XFMR setups available for user operation. Here in this review, we mainly focus on recent developments and work that has been carried out using time-resolved XFMR at beamline 4.0.2 of the Advanced Light Source and at beamline I10 of the Diamond Light Source. The experimental setup and the sample holder used at beamline I10 and beamline 4.0.2, respectively, are shown in Figure 1. We will first introduce the working principle of XFMR and then provide examples of the capabilities of this technique. Finally, we will briefly describe an outlook for the future development of and new opportunities for XFMR.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Measurement of needle and armature dynamics in a gasoline direct injector by high-speed neutron imaging

In modern spark ignition engines, precise delivery of fuel with gasoline direct injection has become increasingly important in the effort to meet ever stricter efficiency and emissions regulations. Use of multiple small close-coupled injections has become more common in attempt to precisely control fuel distribution in the cylinder, but these strategies are hindered by nonlinear injection effects due to operation in the ballistic region of the solenoid-operated valve and due to armature bounce at the end of injection. Understanding the internal dynamics of the injector is crucial to minimizing and controlling non-linearity and shot-to-shot variation, but the experimental techniques available to date are capable only of tracking the position of either the top of the needle (via laser sensors or by monitoring current and voltage in the solenoid coil) or the bottom of the needle (via transparent nozzles or high-speed x-ray imaging). Furthermore, a complete picture of the axial and radial motion of valve needle has until now remained elusive. In this work, we present high-speed ensemble neutron transmission imaging of an entire 8-hole gasoline direct injector operating at 200 bar, allowing for both visualization and quantification of the actuation dynamics including lift and wobble of the valve ball, oscillation and bending of the valve needle, lift, rocking, and bounce of the armature, compression of the springs, and radial swelling of the solenoid during energization. Because neutrons offer high penetration through the metal injector while also being sensitive to the 1 H nuclei in fuel molecules, it is also possible to simultaneously see the fluid dynamics of the injection process, including filling of the sac volume, emanation of the spray through the nozzle holes and into the downstream gas, and the formation and evolution of fuel films on the tip of the injector and the walls of the spray container.

33 ADVANCED PROPULSION SYSTEMS↗

An Integrated Approach to Precision Neutron Measurements in a Dynamic Environment [Slides]

Any quantity of special nuclear material must be accurately quantified for health, safety, and security concerns. High-Level Neutron Coincidence Counters (HLNCCs) are detectors used for assaying the mass of special nuclear material. HLNCCs record a neutron count rate over some period of time which is compared to a calibration curve to determine the quantity of special nuclear material present within the detector.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Executive summary of error sources in dynamic surface temperature measurements

Obtaining bulk T requires measuring apparent sample interface T surface , knowledge of any window conditions T window , and knowledge of thermal transport from the sample to the window. To obtain bulk T with uncertainties below 5% requires relatively small uncertainties in each of these areas, and large uncertainties in one area require smaller uncertainties in others to maintain the error budget. For example, if T window is known to 10%, a 5% total uncertainty can be obtained if T surface is known to 1% and combined transport uncertainties are known to 20%. If T surface can only be measured to 2%, combined transport uncertainties must be 17% to reach the same overall uncertainty. As the form of transport is unknown at high pressure, and window temperatures are difficult to measure by their very nature, reducing surface T uncertainties is the practical first step. Here we will discuss various error sources in the measurement of apparent T surface , and which ones must be correctly obtained prior to the experiment.

36 MATERIALS SCIENCE↗

Merger Response of Halo Anisotropy Properties

Anisotropy properties—halo spin, shape, position offset, velocity offset, and orientation—are an important family of dark matter halo properties that indicate the level of directional variation of the internal structures of halos. These properties reflect the dynamical state of halos, which in turn depends on the mass assembly history. In this work, we study the evolution of anisotropy properties in response to merger activity using the IllustrisTNG simulations. We find that the response trajectories of the anisotropy properties significantly deviate from secular evolution. These trajectories have the same qualitative features and timescales across a wide range of merger and host properties. We propose explanations for the behavior of these properties and connect their evolution to the relevant stages of merger dynamics. We measure the relevant dynamical timescales. We also explore the dependence of the strength of the response on time of merger, merger ratio, and mass of the main halo. These results provide insight into the physics of halo mergers and their effects on the statistical behavior of halo properties. This study paves the way toward a physical understanding of scaling relations, particularly to how systematics in their scatter are connected to the mass assembly histories of halos.

79 ASTRONOMY AND ASTROPHYSICS↗

Dynamic technique for measuring adsorption in a gas chromatograph

Gas-chromatographic procedure, together with mathematical analysis of adsorption isotherm, allows relative surface areas and adsorptive powers for trace concentrations to be determined in a few minutes. Technique may be used to evaluate relative surface areas of different adsorbates, expressed as volume of adsorbent/gram of adsorbate, and to evaluate their relative adsorptive power.

Deuel, C. L.↗

An experiment for Shuttle aerodynamic force coefficient determination from inflight dynamical and atmospheric measurements

A two-phase experiment is proposed which utilizes the Shuttle Orbiter and its unique series of repeated entries into the earth's atmosphere as an airborne in situ aerodynamic testing laboratory. The objective of the experiment is to determine static aerodynamic force coefficients, first of the orbiter, and later of various entry configurations throughout the high speed flight regime, including the transition from free molecule to continuum fluid flow. The objective will be accomplished through analysis of inflight measurements from both shuttle-borne and shuttle-launched instrumented packages. Results are presented to demonstrate the feasibility of such an experiment.

Compton, H. R.↗

Simultaneous measurements of magnetotail dynamics by IMP spacecraft

Changes in tail energy density during substorms in the magnetotail are given. In addition to plasma sheet thinnings seen prior to substorm onsets, a gradual decrease in plasma beta was detected in the deep tail which precedes onset and the more prominent plasma disappearance that typically accompanies it. The frequency of thinnings and the regions over which they occurred indicate that drastic changes in plasma sheet thickness are common features of substorms which occur at all locations across the tail.

Fairfield, D. H.↗

Simultaneous measurements of magnetotail dynamics by IMP spacecraft

Pressure in the magnetotail is investigated using observations obtained by IMP spacecraft. Using combined field and plasma data, the approximate balance of pressure between the high beta plasma sheet and the low beta tail lobes is demonstrated. The changes in this pressure during substorms and the characteristics of the plasma and field that produce it are discussed. A distance of about 15 earth radii separates an inner region where the plasma sheet thins during the hour before substorm onset from an outer region where the plasma sheet thins within 5 or 10 min of the time of onset. Substorm onset and plasma sheet expansion in the inner region are simultaneous if the spacecraft is near the equatorial plane. This expansion may be delayed as much as a few tens of minutes if the spacecraft is at high latitudes.

Fairfield, D. H.↗