Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “condensation”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 487 records · Page 27

Adsorption and condensation of Cu on W single-crystal surfaces

The adsorption and condensation of Cu up to several monolayers in thickness on tungsten 110 and 100 single-crystal surfaces are studied by combining low-energy electron diffraction, Auger electron spectroscopy, thermal desorption spectroscopy, work-function measurements, and quartz microbalance thickness measurements in one experimental system. The results show drastic differences in the evolution of the structure, work function, and desorption behavior between 110 and 100 surfaces. These differences are understandable in terms of the atomic roughness of the surfaces.

Bauer, E.↗

Kinetic approach to the evaporation and condensation problem

In the paper, the Boltzmann equation governing the evaporation and condensation phenomena is solved by the Monte Carlo method. Based on the kinetic theory of gas the role of the non-equilibrium Knudsen layer and the growth of the hydrodynamic region outside the layer as time proceeds are simulated. Results show two possible types of transient developments in the vapor phase. The effects of the molecular absorption coefficient of the phase surface are examined. Except in the case of very strong evaporation the kinematic effects of binary collisions among vapor molecules on the mass flux rate are not serious. The limiting case of the quasi-steady evaporation and the maximal value of the evaporation rate are obtained.

Murakami, M.↗

Analysis of nitrogen condensation in an expanding nozzle flow

Condensation of nitrogen flow in an expanding nozzle flow is analyzed using one-dimensional gas dynamic equations and the equations for nucleation and droplet growth. Effects of variations in the Tolman constant and the mass accommodation factor are discussed as well as the effect of foreign nuclei. Comparisons are made with experimental data obtained from a small, contoured nozzle.

Wang, F. C.↗

The time dependent growth of H2O-H2SO4 aerosols by heteromolecular condensation

A theory for the time-dependent growth of solution droplets by heteromolecular condensation is presented. The theory is applied to the growth of H2O-H2SO4 aerosols for relative humidities less than 100 per cent. Growth curves (droplet radius as a function of time) for different values of relative humidity are evaluated.

Hamill, P.↗

The prebiotic synthesis of deoxythymidine oligonucleotides. II - Comparison of condensing agents

A reaction which oligomerizes nucleotides under possible prebiotic conditions has been characterized. Nucleoside monophosphate in the presence of cyanamide at acid pH condenses to form dithymidine pyrophosphate and phosphodiester bonded compounds. Imidazole compounds and activated precursors such as nucleoside triphosphate are not necessary for this oligomerization reaction which produces primarily cyclic oligonucleotides.

Odom, D. G.↗

Can the ordinary chondrites have condensed from a gas phase

The conditions under which ordinary chondrites containing iron in three different chemical states can form in thermodynamic equilibrium with a gas phase are calculated. Hydrogen depletion factors of 100-1000 are obtained and the formation of liquid condensates from residual gases occurs at pressures (prior to hydrogen depletion) of roughly equal to or greater than 1 atm.

Herndon, J. M.↗

'Mysterite' - A late condensate from the solar nebula

An attempt is made to clarify the nature of 'mysterite', a material that had been postulated to explain the overabundance of Tl, Bi, and Ag in certain chondrites. Four dark clasts and a vein sample from the H6 chondrite Supuhee were analyzed by radiochemical neutron activation analysis for Ag, Au, Bi, Br, Cd, Cs, Ge, In, Ir, Ni, Os, Rb, Re, Sb, Se, Te, Tl, and Zn. One of the clasts is enriched in all volatile elements, while the other four samples are enriched only in the siderophile volatiles Ag, Bi, and Tl. The enrichments range up to 100 times typical H6 chondrite abundances. The proportions of Ag, Bi, and Tl suggest the presence of at least two, Tl-rich and Tl-poor, varieties of mysterite. The former seems to dominate in Supuhee and Krymka, and the latter in Mezo-Madaras. Apparently mysterite is a late condensate from the solar nebula that collected volatiles left behind by earlier generations of chondrites. It was incorporated in Supuhee and perhaps in other chondrites (mainly of low petrologic types) during brecciation events.

Higuchi, H.↗

The adsorption and early stages of condensation of Ag and Au on W single-crystal surfaces

Silver and gold were evaporated up to several monolayers in thickness onto W single-crystal surfaces of the 110 and 100 plane types in the temperature range between 300 and 1300 K. The mode of growth and the structure of the layers were studied by Auger electron spectroscopy and low-energy electron diffraction. The results are compared with thermal desorption spectroscopy data and work-function change measurements. They show certain similarities but also some striking differences between the two systems Ag/W and Au/W as well as a strong crystallographic anisotropy of adsorption and condensation.

Bauer, E.↗

Predicting structures of cross-linked condensation polymers

Mathematical procedure is used to predict structure of cross-linked condensation polymer differentiated from an additional polymer resulting from specific reaction. Procedure will greatly reduce amount of empirical formulation and testing needed to produce desired product.

Marsh, H. E.↗

An experimental investigation of the condensation of silicate grains

Amorphous magnesium silicate smoke particles were condensed from hydrogen and argon atmospheres containing Mg and Si0. A wide range of initial compositions were observed but all particles could be recrystallized into forsterite (Mg2Si04), by heating to 1000 C in vacuum. The amount of smoke formed decreased rapidly with temperatures between 300 and 800 K at reactant partial pressures of about 1 torr.

Day, K. L.↗

Onset of condensation effects with a NACA 0012-64 airfoil tested in the Langley 0.3-meter cryogenic tunnel

A 0.137m airfoil was tested in a 0.3m transonic cryogenic tunnel at free stream Mach numbers of 0.75, 0.85, and 0.95 over a total pressure range from 1.2 to 5.0 atmospheres. The onset of condensation effects were found to correlate more with the amount of supercooling in the free stream than it did with the supercooling in the region of maximum local Mach number over the airfoil. Effects in the pressure distribution over the airfoil were generally seen to appear over its entire length at nearly the same total temperature. Both observations suggest the possibility of heterogeneous nucleation occurring in the free stream. The potential operational benefits of the supercooling realized are presented in terms of increased Reynolds number capability at a given tunnel total pressure, reduced drive fan power if Reynolds number is held constant, and reduced liquid nitrogen consumption if Reynolds number is again constant. Depending on total pressure and free stream Mach number, these three benefits are found to respectively vary from 7 to 19%, 11 to 25%, and 9 to 20%.

Hall, R. M.↗

Guide to a condensed form of NASTRAN

A limited capability form of NASTRAN level 16 is presented to meet the needs of universities and small consulting firms. The input cards, the programming language of the direct matrix abstraction program, the plotting, the problem definition, and the modules' diagnostic messages are described. Sample problems relating to the analysis of linear static, vibration, and buckling are included. This guide can serve as a handbook for instructional courses in the use of NASTRAN or for users who need only the capability provided by the condensed form.

Rogers, J. L., Jr.↗

Chondrules as condensation products

The formation of meteoritic chondrules via condensation from the primordial solar nebula is discussed. Chondrule formation in regions where the gas/dust ratio was enhanced, and where transient high energy events heated the gas and temporarily vaporized the dust, is advocated. The observed diversity of chondrule types can be understood as resulting from local variations in the initial gas/dust proportions and other parameters.

Wood, J. A.↗

Low-temperature condensates in comets

Recent observational data on the volatile fraction of comets are confronted with a model based on the fractional condensation, in the 80-100 K range, of a higher-temperature equilibrium obtained from a solar mixture, more or less depleted in oxygen and in hydrogen. It is possible to almost duplicate the observational data, only by assuming that the solar ratio of C/O is at least as large as 0.66 and that the hydrogen was drastically depleted by an unknown process in the primitive solar nebula. Although none of these two assumptions is at variance with present knowledge, the latter is sufficiently exotic to propose a simpler explanation, namely that comets could be made of interstellar grains relatively unprocessed by heat.

Delsemme, A. H.↗

The isothermal dust condensation of Nova Vulpeculae 1976

Nova Vulpeculae 1976 has been followed with broad-band photometry at wavelengths of 0.5 to 12.5 microns from day 3 to day 235. Three definite phases are identified. They are expanding pseudophotosphere, free-free expansion, and dust condensation. A very long (day 80 to day 220) period of isothermal infrared emission (temperature approximately 900 K) is accompanied by an exponential decrease in infrared luminosity and is interpreted in terms of continuous mass ejection in the nova wind.

Ney, E. P.↗

Interaction of NaCl/g/ and HCl/g/ with condensed Na2SO4

Na2SO4(l)-NaCl(g) interactions were studied at a total pressure of one atmosphere of air or oxygen for various temperatures of Na2SO4(l) and for various partial pressures of NaCl(g) and H2O(g). Mass spectrometric sampling techniques were used to identify and monitor gas phase species. Continuous recording thermomicrogravimetric measurements were conducted to determine condensed phase weight change rates. Experimental measurements were supplemented with thermodynamic calculations. Numerous experiments were performed at sample temperatures of 900 and 1000 C with 300 ppm NaCl(g). In these experiments, the reproducibility of the Na2SO4 vaporization weight loss rate and initial weight gain upon addition of NaCl(g) were found to be satisfactory. It was found that the addition of NaCl(g) to air flowing over Na2SO4(l) at 900 and 1000 C enhances the rate of weight loss of the Na2SO4(l). This enhancement increases when H2O(g) is also added to the air flow.

Stearns, C. A.↗

Onset of condensation effects with an NACA 0012-64 airfoil tested in the Langley 0.3-meter transonic cryogenic tunnel

The onset of condensation effects as determined by varying the stagnation temperature was found to correlate better with the amount of supercooling in the free stream than it did with the supercooling in the region of maximum local Mach number over the air foil. Effects in the pressure distribution over the air foil were seen to appear over its entire length at nearly the same total temperature. Both observations suggest that heterogeneous nucleation does occur in the free stream. The benefits realized from supercooling are presented in terms of increased Reynolds number capability at a given tunnel total pressure and reduced drive-fan power and liquid nitrogen consumption if Reynolds number is held constant. Depending on total pressure and free-stream Mach number, these three benefits are found to vary respectively from 8 to 19 percent, 12 to 24 percent, and 9 to 19 percent. The data analysis and error estimates are given.

Hall, R. M.↗

Re-evaporation of condensed matter during the formation of the solar system

From the properties of matter the conclusion is derived that the mineral assemblage characteristic of most chondritic meteorites is not at all what is expected to form directly from solar matter. Rather, the major minerals of the ordinary chondrites have chemical compositions indicative of formation from a medium greatly depleted in hydrogen and somewhat deficient in oxygen relative to solar elemental abundance ratios. The re-evaporation of condensed material, after separation from a large fraction of the gaseous components of solar matter, will lead to a medium of the appropriate composition. Such re-evaporation must have occurred at a time prior to the formation of many primitive meteorites.

Herndon, J. M.↗