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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Recent developments in monolithic phase-locked semiconductor laser arrays

Coherent combination of the power of several semiconductor lasers fabricated on the same substrate has been the subject of an intense research effort in recent years, the main motivation being to obtain higher power levels than those available from a single laser in a stable radiation pattern. Best results reported so far include 2.6 watts CW emitted power and less than 1 deg far-field angle (in the array plane) in arrays where all the lasers are electrically connected in parallel. A different type of coherent array, where each element has a separate contact, has been recently demonstrated. While requiring the more complex two-level metallization technology, applying a separate contact to each laser provides an additional degree of freedom in the design and the operation of monolithic arrays. The separate contacts can be employed to tailor the near-field and far-field distributions and to compensate for device-to-device nonuniformities. Furthermore, the control of the currents of the array elements allows the performance of a variety of other functions, such as beam scanning, spectral mode control, wavelength tuning and control of the mutual coherence between array elements.

Katz, J.↗
DOE OSTI2026

How Does Metal Spin State Affect Electronic Communication in Mixed-Valence Dimers? Insights from Ultrafast Near-Infrared and Soft X-ray Transient Absorption Spectroscopy

Recent advancements in photocatalysis, photovoltaics, and quantum information science take advantage of electron spin, and determining how spin multiplicity affects electron transfer is key to understanding these phenomena. Here, in this study, we examine how metal spin state affects electronic communication in an organometallic mixed-valence dimer, ferrocenyl cobaltocenium ([Fe II Cp 2 Co III Cp 2 ] + ). This complex can be photoexcited from its low-spin singlet Fe II ground state to form intermediate-spin triplet Fe II and high-spin quintet Fe II excited states. Using femtosecond optical transient absorption (OTA) spectroscopy with visible (vis), near-infrared (NIR), and short-wave IR (SWIR) probes, supported by time-dependent density functional theory (TD-DFT) calculations, we measure Fe II Co III →Fe III Co II intervalence charge transfer (IVCT) bands in each of the Fe II spin states. Mulliken–Hush analysis of the excited-state IVCT bands was used to compute the electronic coupling between the metal centers in all three spin states, which increased as quintet < triplet < singlet. Meanwhile, the peak energy of the bands, and thus the ΔG of the IVCT transition, increased as triplet < quintet < singlet. Then, to directly probe the electronic structure at each metal center, we employed picosecond soft X-ray transient absorption (XTA) spectroscopy at the Fe and Co L 3 edges. Our results show that the low-spin and high-spin states of [Fe II Cp 2 Co III Cp 2 ] + are valence-localized, while the intermediate-spin state is partially delocalized. The differences in charge delocalization are attributed to differences in orbital occupation and geometry that affect the free energy and superexchange coupling.

Burke, John H. [Univ. of Illinois at Urbana-Champa↗
DOE OSTI2025

A Flat Analyzer Polycapillary Spectrometer for X-ray Absorption Spectroscopy of Dilute Transition Metals at X-ray-Free Electron Lasers

X-ray absorption spectroscopy (XAS) coupled with highly intense pulses from an X-ray-free electron laser (XFEL) can be used to track ultrafast chemical dynamics. Nonetheless, measurements for dilute samples (≤1 mM) have been exceptionally challenging, as scattering background signals dominate over the sample’s X-ray fluorescence. We show that femtosecond time-resolved XAS measurements of sub-millimolar transition metal solutions are now possible at the Linac Coherent Light Source (LCLS) using a high-throughput polycapillary XAS spectrometer, designed, developed, and commissioned at LCLS and the Stanford Synchrotron Radiation Lightsource (SSRL). The instrument integrates three polycapillary optics that collect and collimate X-ray fluorescence emitted from the interaction point with a high solid angle. X-ray collimated fluorescence is then selectively diffracted by coupled graphite analyzer crystals. As a result, the contribution of scattered photons is suppressed. Experiments at the Pt L 3 -edge on 0.1 mM aqueous K 2 PtCl 6 (delivered via a 100 μm liquid jet) were successfully performed in the laser pump X-ray probe configuration at the LCLS XCS and XPP instruments. We report the transient spectra of hexachloroplatinate within the first 10 ps after a 266 nm photoexcitation. We observed a short-lived reduced intermediate (≈2 ps). The polycapillary X-ray spectrometer at LCLS now enables the efficient study of the dynamics of ultradilute transition metals in solution. This capability opens the door to investigating plasmonic systems, photocatalysts, enzymes, and other scarce and dilute samples.

LCLS↗
DOE OSTI2021

Linear polarization–direction correlations in $\gamma $-ray scattering experiments

Scattering measurements with incident linearly polarized γ rays provide information on spins, parities, and γ-ray multipolarity mixing coefficients, and, therefore, on the nuclear matrix elements involved in the transitions. Here, we present the general formalism for analyzing the observed angular correlations. The expressions are used to compute three-dimensional radiation patterns, which are important tools for optimizing experimental setups. Frequently, γ-ray transitions can proceed via two multipolarities that mix coherently. In such cases, the relative phases of the nuclear matrix elements are important when comparing results from different measurements. We discuss different phase conventions that have been used in the literature and present their relationships. Finally, we propose a basic experimental geometry consisting of detectors located at four different spatial locations. For this geometry, we present the measured anisotropies of the emitted γ rays in graphical format as an aid in the data analysis.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2026

Superconducting qubits for particle detection and fundamental tests of quantum mechanics

Many fundamental questions at the interface of quantum mechanics, gravity, and measurement remain relatively unexplored in the laboratory. These include whether spatial superpositions experience gravitational redshift, how the quantum Zeno effect propagates through entangled systems, and whether quantum information is globally conserved or fundamentally lost during measurement-induced wavefunction collapse. In this colloquium, I will discuss how superconducting qubits—developed primarily for quantum computing—can be repurposed as ultra sensitive detectors to probe these questions and to search for low-energy particle interactions. I will describe my work at Fermilab on stabilizing these devices to the level required for next-generation qubit-based sensors. This includes mitigating decoherence from infrared radiation and cosmic rays, using machine-learning techniques to accelerate superconducting qubit design, and leveraging the quantum Zeno effect to improve coherence times and suppress qubit frequency fluctuations. Together, these advances point toward a new class of quantum sensors capable of testing fundamental physics.

Seidel, Olivia [Fermilab]↗
NASA NTRS1975

A new approach to radiative transfer theory using Jones's vectors. I Fundamentals

Radiative transfer of partially polarized radiation in an anisotropically scattering, inhomogeneous atmosphere containing an arbitrary polydispersion of particles is described using Jones's (1941) amplitude vectors and matrices. This approach exploits the close analogy between the quantum-mechanical states of spin 1/2 systems and the polarization states of electromagnetic radiation described by Jones's vector. The complete equivalence between the transport equation for Jones's vectors and the classical radiative-transfer equation for Stokes's intensity vectors is demonstrated in two independent ways after deriving the transport equations for the polarization coherency matrices and for the quaternions corresponding to the Jones's vectors. A compact-operator formulation of the theory is provided and used to derive the necessary equations for both a local and a global description of the transport of Jones's vectors. The integro-differential equations for the amplitude reflection and transmission matrices are derived and related to the usual corresponding equations.

Fymat, A. L.↗
NASA NTRS1976

Pioneer 10 ultraviolet photometer observations of Jupiter - The helium to hydrogen ratio

Pioneer 10 UV photometric observations of solar He I 584-A emissions diffusely reflected from the atmosphere of Jupiter are discussed which establish the expected presence of He in the planet. The intensity and profile of the solar He line are remeasured and found to be more intense than originally supposed, implying a lower value for the diffuse 584-A reflectivity of Jupiter and less He than previously estimated. Other measurements of the solar He line are reviewed, resonance scattering by He is analyzed, and radiative-transfer calculations for Jovian model atmospheres are improved by including the anisotropic phase function for helium resonance scattering. The assumption of coherent scattering in the formation of the Jovian airglow line is shown to be an accurate approximation, and present estimates of the atmospheric temperature and eddy diffusion coefficient are examined. An atmospheric He/H abundance ratio greater than zero but less than approximately 28% is determined by assuming an isothermal atmosphere with a temperature of 150 K and the range of eddy-diffusion values given by Pioneer 10 Ly-alpha observations. The effect of higher temperatures on the He/H abundance is briefly evaluated.

Carlson, R. W.↗
NASA NTRS2019

Radiative Feedbacks Associated with the Madden-Julian Oscillation

Radiative kernels derived from CloudSat/CALIPSO measurements are used to diagnose radiative feedbacks induced by the Madden-Julian oscillation (MJO). Over the Indo-Pacific warm pool, positive cloud and water vapor feedbacks are coincident with the convective envelope of the MJO during its active phases, whereas the lapse rate feedback shows less obvious correlation to the propagating disturbance. During phase 2/3, when the convective envelope is over the Indian Ocean, water vapor exhibits a vertically coherent response, with the largest anomalies and strongest feedback in the middle troposphere. Though spatial structures of the feedbacks vary, the most prominent difference lies in the magnitude. Cloud changes induce the largest radiative perturbations associated with the MJO. We also find that for individual MJO events, cloud feedback and precipitation are highly correlated, suggesting that the strength of individual MJO events is largely dictated by the magnitude of cloud radiative heating of the atmosphere. In addition, stronger radiative heating due to water vapor and clouds helps the MJO survive the barrier effect of the Maritime Continent, leading to further eastward propagation. These results offer process-oriented metrics that could help to improve model simulations and predictions of the MJO in the future.

radiative feedbacks↗
DOE OSTI2023

Dark and bright modes, and their coherent control in dipolar metasurface bilayers

Several plasmonic nanoparticles supporting dipolar resonances can couple to form normal modes. Here, we develop an analytical model to explain the formation of nonradiative “dark” and radiative “bright” modes through radiative coupling in bilayers consisting of dipolar nanoantenna arrays that are separated by a subwavelength distance. We also include near-field contributions in our model and show that the absorption and reflectance spectra obtained from our model agree reasonably well with the respective finite-difference time-domain simulation results for both perfectly aligned and misaligned bilayers. Here, the ability to vary the reflection and absorption spectra of these bilayers by changing the material and geometrical parameters has potential applications in the design of efficient spectral filters. We also show that we can selectively excite these modes by adjusting the phase between two counterpropagating normally incident fields, which has applications in all-optical modulators and switches based on purely linear interferometric effects.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS2018

Radiative Transfer in a Discrete Random Medium Adjacent to a Half-Space with a Rough Interface

For a macroscopically plane-parallel discrete random medium, the boundary conditions for the specific coherency dyadic at a rough interface are derived. The derivation is based on a modification of the Twersky approximation for a scattering system consisting of a group of particles and the rough surface, and reduces to the solution of the scattering problem for a rough surface illuminated by a plane electromagnetic wave propagating in a discrete random medium with non-scattering boundaries. In a matrix-form setting, the boundary conditions for the specific coherency dyadic imply the boundary conditions for specific intensity column vectors which in turn, yield the expressions for the reflection and transmission matrices. The derived expressions are shown to be identical to those obtained by applying a phenomenological approach based on a facet model to the solution of the scattering problem for a rough surface illuminated by a plane electromagnetic wave.

Adrian Doicu↗
DOE OSTI2026

UNLOQ: UNderstanding coherence in Light-matter interfaces for Quantum Science (Final Technical Report)

The general goal of this project is to prepare next-generation quantum systems for novel quantum information science applications. Decades of research on quantum optics have provided revolutionary systems for manipulating atomic and photonic quantum coherence in transformative ways. Our hypothesis is that the next-generation quantum systems will come from nano-molecular quantum optics. Specifically, we are interested in coupling the electronic states of molecules or nanoparticles to the quantized radiation field inside an optical cavity to create a set of new photon-matter hybrid excitations, called polaritons. As opposed to atoms, the vibrational modes of molecules and nanoparticles provide new degrees of freedom to mediate the quantum transduction between electronic and photonic states, offering new ways to tune and ultimately control the quantum coherence of the integrated system. In this project we are interested in designing, fabricating, and characterizing the polaritons that arise from coupling CdSe nanoplatelets (NPLs) to a Fabry-Pérot optical cavity. Specific attention was paid to parameters of the system (cavity mode volume, quality factor, etc.) that would maximize the collective coupling strength. Through a combined theoretical and experimental approach, we were able to make important contributions to understanding NPL exciton-polariton photophysics including how to use cavity loss as a tunable parameter in order to manipulate the populations of the upper and lower polariton states. Finally, using state-of-the-art theoretical methods, we were able to show how the collective coupling of many molecular excitons in a cavity can protect polariton coherence from vibrationally-induced decoherence. In particular, for NPL-cavity polaritonic systems, the quantum coherence can be extended by over an order of magnitude at room temperature.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Laser-Produced Coherent X-ray Sources. Final report

This is the final report for the DOE-AMO DE-FG02-05ER15663 grant. Using a high-peak-power laser system at the Extreme Light Laboratory of the University of Nebraska-Lincoln, we develop novel femtosecond radiation sources and use them to investigate ultrafast photo-induced processes. Pulses of high energy electrons and x-rays are generated when an optical pulse is focused to ultra-high intensity. The radiation is used to probe the evolution of matter under highly non-equilibrium conditions with atomic-scale temporal and spatial resolution. Moreover, the facility is small enough to fit in a university laboratory and is operated by graduate students and postdocs.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2025

Design, fabrication, and testing of diamond axicons for X-ray microscopy applications

This work presents the design, fabrication, and experimental validation of a refractive diamond axicon for X-ray beam shaping. The diamond axicon was developed to overcome the limitations of polymer-based axicons particularly for application in Transmission X-ray Microscopy (TXM) systems, offering superior mechanical strength, thermal stability, and radiation resistance, making it ideal for synchrotron applications. The axicon was fabricated using femtosecond laser ablation and tested at 11 keV under various coherence conditions. Results demonstrated that the axicon efficiently transformed the X-ray beam into a ring-shaped profile with over 80% transmission. Simulations confirmed the experimental findings and highlighted the potential for further improvements. This work paves the way for the use of diamond axicons in next-generation synchrotron facilities, with future efforts focusing on optimizing fabrication and testing the axicon in full TXM systems.

Samadi, Nazanin↗
NASA NTRS1979

The vertical structure and thickness of Saturn's rings

The steady state thickness and vertical structure of Saturn's rings are discussed with regard to whether a collapse to a monolayer due to particle collisions may be prevented by various mechanisms. The differences between thick rings and wavy monolayers are outlined and used to show that such coherent perturbations to the rings as satellite and solar gravitational effects would produce a wavy monolayer while such dispersive mechanisms as meteoroid impact, radiation pressure, Kepler shear and radial spreading, which would produce the random particle motions necessary to maintain a thick layer, are probably insignificant. Given a typical power law distribution of particle sizes, it is found that gravitational scattering of small particles by large ones would maintain a ring thickness of several times the radius of the largest particles. A steady state ring thickness of 20 to 50 meters, derived from energy considerations, would imply a maximum particle size of a few meters.

Cuzzi, J. N.↗
NASA NTRS1984

Method and apparatus for self-calibration and phasing of array antenna

A technique for self-calibrating and phasing a lens-feed array antenna, while normal operation is stopped, utilizes reflected energy of a continuous and coherent wave broadcast by a transmitter through a central feed while a phase controller advances the phase angles of reciprocal phase shifters in radiation electronics of the array elements at different rates to provide a distinct frequency modulation of electromagnetic wave energy returned by reflection in one mode and leakage in another mode from the radiation electronics of each array element. The composite return signal received by a synchronous receiver goes through a Fourier transform processing system and produces a response function for each antenna element. Compensation of the phase angles for the antenna elements required to conform the antenna response to a precomputed array pattern is derived from the reciprocal square root of the response functions for the antenna elements which, for a rectangular array of NXM elements, is a response function T(n,m). A third mode of calibration uses an external pilot tone from a separate antenna element. Respective responses are thus obtained from the three modes of calibration.

Wu, C.↗
NASA NTRS1988

Conceptual test of frequency diversity lidar

The present consideration of the estimation accuracy of lidar-backscattered signals in atmospheric remote sensing proposes a method that can furnish additional uncorrelated data within the atmospheric decorrelation time, with enhanced energy efficiency. This frequency-diversity method recognizes that additional uncorrelated data from a given illuminated region is obtainable by changing the frequency of the incoming radiation. The mathematical analysis of the frequency-diversity concept by Wallace (1953) confirms the physical scenario employed. A simple version of a coherent lidar system incorporating the frequency-diversity concept is included to illustrate the design principles involved.

Schotland, Richard M.↗
DOE OSTI2026

Measuring quasiparticle dynamics for particle impact reconstruction in a superconducting qubit chip

Quasiparticle poisoning following particle impacts poses a significant challenge to the development of fault-tolerant superconducting quantum computers, as a sudden excess of quasiparticles can simultaneously degrade the coherence of multiple qubits across large device arrays. In this work, we present a statistical analysis that models the time evolution of radiation-induced qubit energy relaxation through quasiparticle density dynamics. This study provides insight into quasiparticle loss processes by distinguishing between recombination and trapping decay channels and assessing their respective impact on qubit performance. We precisely measure quasiparticle recombination in multiple transmon qubits and uncover an unexpected dependence of qubit relaxation dynamics on deposited energy. By linking correlated relaxation events across qubits to ballistic phonon propagation, we introduce a statistical localization approach to extract the energy deposited in the substrate, which is in good agreement with Monte Carlo simulation. This work establishes the quantitative framework for using an arbitrary subset of superconducting transmon qubits in a QPU as energy-resolving witness particle detectors.

Celi, E. [Northwestern U.]↗
DOE OSTI2025

X-ray Absorption Spectroscopy of Dilute Metalloenzymes at X-ray Free-Electron Lasers in a Shot-by-Shot Mode

X-ray absorption spectroscopy (XAS) of 3d transition metals provides important electronic structure information for many fields. However, X-ray-induced radiation damage under physiological temperature has prevented using this method to study dilute aqueous systems, such as metalloenzymes, as the catalytic reaction proceeds. Here we present a new approach to enable operando XAS of dilute biological samples and demonstrate its feasibility with K-edge XAS spectra from the Mn cluster in photosystem II and the Fe–S centers in photosystem I. This approach combines highly efficient sample delivery strategies and a robust signal normalization method with high-transmission Bragg diffraction-based spectrometers at X-ray free-electron lasers (XFELs) in a damage-free, shot-by-shot mode. These photon-out spectrometers have been optimized for discriminating the metal Mn/Fe Kα fluorescence signals from the overwhelming scattering background present on currently available detectors for XFELs that lack suitable energy discrimination. We quantify the enhanced performance metrics of the spectrometer and discuss its potential applications for acquiring time-resolved XAS spectra of biological samples during their reactions at XFELs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗