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At least 487 records · Page 27

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NASA NTRS1974

Cold cathodes for sealed-off CO2 lasers

Cold cathodes for CO2 lasers should possess a very low sputtering rate, have a minimum of negative ions in the sputtering products, and consume no oxygen. These conditions can be satisfied by selecting cathode materials from those elements of group I in the periodic table which form semiconducting oxide layers and then exposing these elements to a reducing gas mixture. Experimental results show that silver, internally oxidized silver-copper alloys, and pure copper satisfy most of these requirements in He-CO2-CO-Xe gas mixtures. Infrared CO and CO2 gas analysis performed on simple gas discharge tubes using such cathodes indicate that laser lives of 10,000 hr can be expected.

Hochuli, U. E.↗

NASA NTRS1975

Nonthermal rotational distribution of CO/A 1Pi/ fragments produced by dissociative excitation of CO2 by electron impact

Measurements were made of the rotational profiles of specific bands of the CO fourth-positive group (4PG). The CO 4PG bands were excited by electron impact dissociative excitation of CO2. The results are applicable to analysis of the Mariner observations of the CO 4PG in the dayglow of Mars. The results indicate that dissociative excitation of CO2 by electron impact leads to CO(A 1Pi) fragments with a rotational distribution that is highly nonthermal. The parent CO2 temperature was about 300 K in the experiment, while the fragment CO(A 1Pi) showed emission band profiles consistent with a rotational temperature greater than about 1500 K. Laboratory measurement of the reduced transmission of the hot bands by thermal CO appears to be the most direct way of determining the column density responsible for the CO(v',0) absorption of Mars.

Mumma, M. J.↗

NASA NTRS1975

CO2 laser doppler systems for the measurement of atmospheric winds and turbulence

Two CO2 laser doppler systems developed by NASA and some results obtained with them are discussed. A continuous wave, monostatic system for short-range wind measurement is described, and direct comparisons between the data obtained with it and with a cup-anemometer/wind vane system and a hot-wire anemometer show excellent agreement between the systems. Improvements being made in three CW, CO2 laser doppler systems, including a filter bank for optimized signal processing and a versatile scanning system, are noted. A pulsed CO2 system for measuring clear air turbulence is described, and results of test performance on board a Convair 990 are presented. It is noted that while the system was able to measure air speed and turbulence, the range of its transmitter-atmosphere-receiver was lower than predicted, and a difference of about 20 to 30 dB existed between the actual and theoretical turbulence measurements. Factors that may account for this loss are listed.

Huffaker, R. M.↗

NASA NTRS1975

A photoionization study of the formation of CO2/+/ by reaction of excited O2/+/ ions with CO

The production of CO2(+) by the ion-molecule reaction O2(+) + CO yields CO2(+) + O has been investigated using a photoionization mass spectrometer. The photoionization efficiency for production of CO2(+) by this reaction was measured from threshold at 924 A (13.42 eV) to 650 A (19.07 eV). The appearance potential corresponds to reaction of ground vibronic O2(+) ions formed in the nu-prime = 6 level. The high-vibrational-level ions of the ground ionic state are most likely produced by autoionization of O2. At wavelengths shorter than 760 A, there is a large increase in the reaction cross section associated with formation of ions in the metastable state. The peak reaction cross section occurs at 720 A.

Ajello, J. M.↗

NASA NTRS1975

Atmospheric transmission of CO2 laser radiation with application to laser Doppler systems

The molecular absorption coefficients of carbon dioxide, water vapor, and nitrous oxide are calculated at the P16, P18, P20, P22, and P24 lines of the CO2 laser for temperatures from 200 to 300 K and for pressures from 100 to 1100 mb. The temperature variation of the continuum absorption coefficient of water vapor is taken into account semi-empirically from Burch's data. The total absorption coefficient from the present calculations falls within + or - 20 percent of the results of McClatchey and Selby. The transmission loss which the CO2 pulsed laser Doppler system experiences was calculated for flight test conditions for the five P-lines. The total transmission loss is approximately 7 percent higher at the P16 line and 10 percent lower at the P24 line compared to the P20 line. Comparison of the CO2 laser with HF and DF laser transmission reveals the P2(8) line at 3.8 micrometers of the DF laser is much better from the transmission point of view for altitudes below 10 km.

Murty, S. S. R.↗

NASA NTRS1975

Non-thermal 10 micrometers CO2 emission lines in the atmospheres of Mars and Venus

Mechanisms for the excitation of strong 10 micrometer CO2 emission lines seen on Mars and Venus are examined. Line absorption of near IR solar flux directly by CO2 or by H2O with collisional transfer of energy to CO2 are proposed as likely excitation mechanisms. Altitudes for peak 10 micrometer emission are estimated to be near 80 km for Mars and 120 km for Venus.

Johnson, M. A.↗

NASA NTRS1976

Nonthermal 10 micron CO2 emission lines in the atmospheres of Mars and Venus

Mechanisms are examined for excitation of strong 10-micron CO2 emission lines seen on Mars and Venus. Line absorption of near-infrared solar flux directly by CO2 or H2O with collisional transfer of energy to CO2 are proposed as likely excitation mechanisms. Altitudes for peak 10-micron emission are estimated to be near 80 km for Mars and 120 km for Venus.

Johnson, M. A.↗

NASA NTRS1976

Breadboard CO2 and humidity control system

A regenerable CO2 and humidity control system is being developed for potential use on shuttle as an alternate to the baseline lithium hydroxide (LiOH)/condensing heat exchanger system. The system utilizes a sorbent material, designated HS-C, to adsorb CO2 and water vapor from the cabin atmosphere. The material is regenerated by exposing it to space vacuum. A half-size breadboard system, utilizing a flight representative HS-C canister, was designed, built, and performance tested to shuttle requirements for total CO2 and total humidity removal. The use of a new chemical matrix material allowed significant optimization of the system design by packing the HS-C chemical into the core of a heat exchanger which is manifolded to form two separate and distinct beds. Breadboard system performance was proven by parametric testing and simulated mission testing over the full range of shuttle crew sizes and metabolic loadings. Vacuum desorption testing demonstrated considerable savings in previously projected shuttle vacuum duct sizing.

Boehm, A. M.↗

NASA NTRS1976

CO2 and humidity removal system for extended Shuttle missions - Equilibrium testing and performance analysis

In Shuttle orbiter cabins, lithium hydroxide (LiOH) canisters are currently planned to be used for CO2 adsorption and condensing heat exchangers for humidity control. In this paper a more effective CO2 and humidity removal method is proposed by replacing the LiOH component with HS-C adsorbent (a polyethylenimine coated acrylic ester), thus eliminating the low temperature constraints on the active thermal control system. Since the adsorption of CO2 and H2O are reversible, a double bed configuration operating cyclicly is planned to provide continuous atmospheric control. Apparatus and the experimental procedure to test the adsorption equilibrium are described and some of the indicative results, tabulated by computers, are presented with the help of exponential expressions and differential equations. By using a computer model of the Shuttle HS-C system, performance predictions are made.

Davis, S. H.↗

NASA NTRS1976

A regenerable CO2 and humidity control system for Shuttle

A regenerable CO2 and humidity control system is presently being developed for potential use on Shuttle as an alternate to the baseline Lithium Hydroxide (LiOH) system. The system utilizes a sorbent material (designated 'HS-C') to adsorb CO2 and water vapor from the cabin atmosphere and desorb the CO2 and water vapor overboard when exposed to a space vacuum. Past development programs concentrated on material development and breadboard system fabrication and testing. The present program calls for the design of a flight prototype system capable of integration into the Shuttle vehicle and the development of major components. This paper will show that a regenerable system utilizing HS-C material trades even with the shuttle LiOH system for the baseline four-man, seven-day mission and offers increased savings up to 448 kg for a seven-man, 30-day mission.

Boehm, A. M.↗

NASA NTRS1977

Observations of the phase variation of Venus CO2 equivalent widths

Equivalent widths determined from photoelectric scans of Venus CO2 absorption lines measured at phase angles of 5.1 to 170 deg are presented. The data-reduction procedure is described in detail, and phase curves are plotted for three model atmospheres in which CO2 is homogeneously mixed with Mie-scattering particles or inhomogeneously mixed with Henyey-Greenstein particles. All three data sets are found to indicate that the equivalent-width maximum occurs at a phase angle much lower than 100 deg. It is concluded that two scattering layers are not required on Venus to explain the shape of the observed phase curve and that the mixing ratio of scattering particles to CO2 increases with depth at high altitudes.

Barker, E. S.↗

NASA NTRS1977

The development and testing of a regenerable CO2 and humidity control system for Shuttle

A regenerable CO2 and humidity control system is presently being developed for potential use on Shuttle as an alternate to the baseline lithium hydroxide (LiOH) system. The system utilizes a sorbent material (designated 'HS-C') to adsorb CO2 and water vapor from the cabin atmosphere and desorb the CO2 and water vapor overboard when exposed to a space vacuum. Continuous operation is achieved by utilizing two beds which are alternately cycled between adsorption and desorption. This paper presents the significant hardware development and test accomplishments of the past year. A half-size breadboard system utilizing a flight configuration canister was successfully performance tested in simulated Shuttle missions. A vacuum desorption test provided considerable insight into the desorption phenomena and allowed a significant reduction of the Shuttle vacuum duct size. The fabrication and testing of a flight prototype canister and flight prototype vacuum valves have proven the feasibility of these full-size, flight-weight components.

Boehm, A. M.↗

NASA NTRS1978

Photodissociation of CO2 and quenching of metastables

Investigations in four different areas were carried out to further our understanding of the chemistry of the atmospheres of Mars and Venus. CO2 photodissociation quantum yields were determined in the 1300-1500 A spectral region by measuring both CO and oxygen atoms. The O(1S) quantum yield was determined for CO2 photodissociation in the 1060-1175 A spectral region. The measurement resolves the differences between two earlier experiments, and demonstrates that the O(1S) yield is unity throughout most of the measured region. The pathways for the quenching of O(1S) by N2O, CO2, H2O and NO were investigated and the source of the Venus nightglow, detected by Venera 9 and 10, was investigated. What appears to be a new O2 band system, was detected although the identity of the transition is not yet evident.

Slanger, T. G.↗

NASA NTRS1978

Technology advancement of the electrochemical CO2 concentrating process

The overall objectives of the present program are to: (1) improve the performance of the electrochemical CO2 removal technique by increasing CO2 removal efficiencies at pCO2 levels below 400 Pa, increasing cell power output and broadening the tolerance of electrochemical cells for operation over wide ranges of cabin relative humidity; (2) design, fabricate, and assemble development hardware to continue the evolution of the electrochemical concentrating technique from the existing level to an advanced level able to efficiently meet the CO2 removal needs of a spacecraft air revitalization system (ARS); (3) develop and incorporate into the EDC the components and concepts that allow for the efficient integration of the electrochemical technique with other subsystems to form a spacecraft ARS; (4) combine ARS functions to enable the elimination of subsystem components and interfaces; and (5) demonstrate the integration concepts through actual operation of a functionally integrated ARS.

Schubert, F. H.↗

NASA NTRS1979

Development of tunable high pressure CO2 laser for lidar measurements of pollutants and wind velocities, January 1976 to December 1977

A tunable multiatmospheric pulsed CO2 laser with emphasis on experimental features and supporting theoretical analyses important to differential absorption lidar and Doppler lidar measurement of pollutants and wind velocities is reported. The energy deposition and the means to produce the uniform high density plasma in the multiatmospheric medium, through UV preionization of an organic seed gas is discussed. Design features of the pulsed CO2 laser are presented. The radiative processes which are operative and prevent the laser from breaking into oscillations in a large number of modes over its broad amplification bandwidth are described. The mode competition for the transient pulsed laser oscillation in a standing wave and traveling wave ring laser configuration is discussed and contrasted with the approach to steady state oscillations. The latter findings are important to transient injection locking for production of a highly stable pulsed CO2 laser output.

Javan, A.↗

NASA NTRS1978

Atomic carbon emission from photodissociation of CO2

Atomic carbon fluorescence, C I 1561, 1657, and 1931 A, has been observed from photodissociation of CO2, and the production cross sections have been measured. A line emission source provided the primary photons at wavelengths from threshold to 420 A. The present results suggest that the excited carbon atoms are produced by total dissociation of CO2 into three atoms. The cross sections for producing the O I 1304-A fluorescence through photodissociation of CO2 are found to be less than 0.01 Mb in the wavelength region from 420 to 835 A. The present data have implications with respect to photochemical processes in the atmospheres of Mars and Venus.

Wu, C. Y. R.↗

NASA NTRS1978

The dependence of the CO2 removal efficiency of LiOH on humidity and mesh size

The effect of humidity on the CO2 removal efficiency of small beds of anhydrous LiOH has been studied. Experimental data taken in this small bed system clearly show that there is an optimum humidity for beds loaded with LiOH from a single lot. The CO2 efficiency falls rapidly under dry conditions, but this behavior is approximately the same in all samples. The behavior of the bed under wet conditions is quite dependent on material size distribution. The presence of large particles in a sample can lead to rapid fall off in the CO2 efficiency as the humidity increases.

Davis, S. H.↗

NASA NTRS1979

CO2 and CO electron vibrational cooling rates

Electron cooling rates for electron vibrational excitation of CO2 and CO and rotational excitation of CO are calculated. Results of the calculation are expressed as closed form analytic relations that are both convenient for numerical calculations and valid over a wide range of electron and neutral temperatures. It is found that the cooling rates and their temperature dependences differ significantly from other calculations. For CO2, these differences are related mainly to the assumptions about the approach to equilibrium and not to the actual cross-section choices. For electron temperatures below 1000 K and gas temperatures near 300 K (representative of conditions in the Venus atmosphere, where collisional cooling of the electrons dominates), the CO2 cooling rate is as much as an order of magnitude larger than previously considered in ionospheric models.

Porter, H. S.↗