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At least 487 records · Page 27

Rare Earth Garnet Selective Emitter

Thin film Ho-YAG and Er-YAG emitters with a platinum substrate exhibit high spectral emittance in the emission band (epsilon(sub lambda) approx. = 0.75, sup 4)|(sub 15/2) - (sup 4)|(sub 13/2),for Er-YAG and epsilon(sub lambda) approx. = 0.65, (sup 5)|(sub 7) - (sup 5)|(sub 8) for Ho-YAG) at 1500 K. In addition, low out-of-band spectral emittance, epsilon(sub lambda) less than 0.2, suggest these materials would be excellent candidates for high efficiency selective emitters in thermophotovoltaic (TPV) systems operating at moderate temperatures (1200-1500 K). Spectral emittance measurements of the thin films were made (1.2 less than lambda less than 3.0 microns) and compared to the theoretical emittances calculated using measured values of the spectral extinction coefficient. In this paper we present the results for a new class of rare earth ion selective emitters. These emitters are thin sections (less than 1 mm) of yttrium aluminum garnet (YAG) single crystal with a rare earth substitutional impurity. Selective emitters in the near IR are of special interest for thermophotovoltaic (TPV) energy conversion. The most promising solid selective emitters for use in a TPV system are rare earth oxides. Early spectral emittance work on rare earth oxides showed strong emission bands in the infrared (0.9 - 3 microns). However, the emittance outside the emission band was also significant and the efficiency of these emitters was low. Recent improvements in efficiency have been made with emitters fabricated from fine (5 - 10 microns) rare earth oxide fibers similar to the Welsbach mantle used in gas lanterns. However, the rare earth garnet emitters are more rugged than the mantle type emitters. A thin film selective emitter on a low emissivity substrate such as gold, platinum etc., is rugged and easily adapted to a wide variety of thermal sources. The garnet structure and its many subgroups have been successfully used as hosts for rare earth ions, introduced as substitutional impurities, in the development of solid state laser crystals. Doping, dependent on the particular ion and crystal structure, may be as high as 100 at. % (complete substitution of yttrium ion with the rare earth ion). These materials have high melting points, 1940 C for YAG (Yttrium Aluminum Garnet), and low emissivity in the near infrared making them excellent candidates for a thin film selective emitter. As previously stated, the spectral emittance of a rare earth emitter is characterized by one or more well defined emission bands. Outside the emission band the emittance(absorptance) is much lower. Therefore, it is expected that emission outside the band for a thin film selective emitter will be dominated by the emitter substrate. For an efficient emitter (power in the emission band/total emitted power) the substrate must have low emittance, epsilon(sub S). This paper presents normal spectral emittance, epsilon(sub lambda), measurements of holmium(Ho) and erbium (Er) doped YAG thin film selective emitters at (1500 K), and compares those results with the theoretical spectral emittance.

Lowe, Roland A.↗

Alterations of Cellular Immune Reactions in Crew Members Overwintering in the Antarctic Research Station Concordia

Background: Concordia Station is located inside Antarctica about 1000km from the coast at an altitude of 3200m (Dome C). Hence, individuals living in this harsh environment are exposed to two major conditions: 1.) hypobaric hypoxia and 2.) confinement and extreme isolation. Both hypoxia and confinement can affect human immunity and health, and are likely to be present during exploration class space missions. This study focused on immune alterations measured by a new global immunity test assay, similar to the phased out delayed type hypersensitivity (DTH) skin test. Methods: After informed written consent 14 healthy male subjects were included to the CHOICE-study (Consequences-of-longterm-Confinement-and-Hypobaric-HypOxia-on-Immunity-in-the Antarctic-Concordia-Environment). Data collection occurred during two winter-over periods lasting each one year. During the first campaign 6 healthy male were enrolled followed by a second campaign with 8 healthy males. Blood was drawn monthly and incubated for 48h with various bacterial, viral and fungal antigens followed by an analysis of plasma cytokine levels (TNF-alpha, IL2, IFN-gamma, IL10). As a control, blood was incubated without stimulation ("resting condition"). Goals: The scope of this study was to assess the consequences of hypoxia and confinement on cellular immunity as assessed by a new in vitro DTH-like test. Results: Initial results indicate that under resting conditions the in vitro DTH-like test showed low cytokine levels which remained almost unchanged during the entire observation period. However, cytokine responses to viral, bacterial and fungal antigens were remarkably reduced at the first month after arrival at Concordia when compared to levels measured in Europe prior to departure for Antarctica. With incrementing months of confinement this depressed DTH-like response tended to reverse, and in fact to show an "overshooting" immune reaction after stimulation. Conclusion: The reduced in vitro DTH-like test response in the early phase of Antarctic wintering over con rms distinct immune suppressive effects seen after (sub-)acute hypobaric hypoxia. The reversal and overshooting reaction of cellular immune responses upon stimulation, but not the resting state, indicate either a) priming of immune answers and/or b) an uncoupled or disregulated control of cellular immune answers by auto-, para- and endocrine pathways. Further analyses and correlations are warranted. Acknowledgement: Supported by the European Space Agency (ESA), the French (IPEV) and Italian (PNRA) polar institutes, the German National Space Program (DLR, 50WB0719/WB0919), by BELSPO/PROEDEX/ESA (C90-380/-391), NASA and by the Concordia crews who have participated with great enthusiasm.

Crucian, Brian↗

A Summary of the Experimental Results for a Generic Tractor-Trailer in the Ames Research Center 7- by 10-Foot and 12-Foot Wind Tunnels

Experimental measurements of a generic tractor-trailer were obtained in two wind tunnels at Ames Research Center. After a preliminary study at atmospheric conditions in the 7- by 10-Foot Wind Tunnel, additional testing was conducted at Reynolds numbers corresponding to full-scale highway speeds in the 12-Foot Pressure Wind Tunnel. To facilitate computational modeling, the 1:8-scale geometry, designated the Generic Conventional Model, included a simplified underbody and omitted many small-scale details. The measurements included overall and component forces and moments, static and dynamic surface pressures, and three-component particle image velocimetry. This summary report highlights the effects of numerous drag reduction concepts and provides details of the model installation in both wind tunnels. To provide a basis for comparison, the wind-averaged drag coefficient was tabulated for all configurations tested. Relative to the baseline configuration representative of a modern class-8 tractor-trailer, the most effective concepts were the trailer base flaps and trailer belly box providing a drag-coefficient reduction of 0.0855 and 0.0494, respectively. Trailer side skirts were less effective yielding a drag reduction of 0.0260. The database of this experimental effort is publicly available for further analysis.

Storms, Bruce L.↗

Carbon Nanotube-Based Digital Vacuum Electronics and Miniature Instrumentation for Space Exploration

JPL has developed high performance cold cathodes using arrays of carbon nanotube bundles that produce > 15 A/sq cm at applied fields of 5 to 8 V/micron without any beam focusing. They have exhibited robust operation in poor vacuums of 10(exp -6) to 10(exp -4) Torr- a typically achievable range inside hermetically sealed microcavities. Using these CNT cathodes JPL has developed miniature X-ray tubes capable of delivering sufficient photon flux at acceleration voltages of <20kV to perform definitive mineralogy on planetary surfaces; mass ionizers that offer two orders of magnitude power savings, and S/N ratio better by a factor of five over conventional ionizers. JPL has also developed a new class of programmable logic gates using CNT vacuum electronics potentially for Venus in situ missions and defense applications. These digital vacuum electronic devices are inherently high-temperature tolerant and radiation insensitive. Device design, fabrication and DC switching operation at temperatures up to 700 C are presented in this paper.

Carbon Nanotube↗

DeepSAT: A Deep Learning Approach to Tree-Cover Delineation in 1-m NAIP Imagery for the Continental United States

High resolution tree cover classification maps are needed to increase the accuracy of current land ecosystem and climate model outputs. Limited studies are in place that demonstrates the state-of-the-art in deriving very high resolution (VHR) tree cover products. In addition, most methods heavily rely on commercial softwares that are difficult to scale given the region of study (e.g. continents to globe). Complexities in present approaches relate to (a) scalability of the algorithm, (b) large image data processing (compute and memory intensive), (c) computational cost, (d) massively parallel architecture, and (e) machine learning automation. In addition, VHR satellite datasets are of the order of terabytes and features extracted from these datasets are of the order of petabytes. In our present study, we have acquired the National Agriculture Imagery Program (NAIP) dataset for the Continental United States at a spatial resolution of 1-m. This data comes as image tiles (a total of quarter million image scenes with ~60 million pixels) and has a total size of ~65 terabytes for a single acquisition. Features extracted from the entire dataset would amount to ~8-10 petabytes. In our proposed approach, we have implemented a novel semi-automated machine learning algorithm rooted on the principles of "deep learning" to delineate the percentage of tree cover. Using the NASA Earth Exchange (NEX) initiative, we have developed an end-to-end architecture by integrating a segmentation module based on Statistical Region Merging, a classification algorithm using Deep Belief Network and a structured prediction algorithm using Conditional Random Fields to integrate the results from the segmentation and classification modules to create per-pixel class labels. The training process is scaled up using the power of GPUs and the prediction is scaled to quarter million NAIP tiles spanning the whole of Continental United States using the NEX HPC supercomputing cluster. An initial pilot over the state of California spanning a total of 11,095 NAIP tiles covering a total geographical area of 163,696 sq. miles has produced true positive rates of around 88 percent for fragmented forests and 74 percent for urban tree cover areas, with false positive rates lower than 2 percent for both landscapes.

Imagery↗

Utilizing NASA Earth Observations to Evaluate Urban Tree Canopy and Land Surface Temperature for Green Infrastructure Development and Urban Heat Mitigation in Huntsville, AL

Huntsville, Alabama’s population has grown by 10.8% since 2010, due in part to the city’s advancing engineering industry. Rapid urban growth negatively impacts the environment by decreasing tree canopy cover and increasing impervious surface cover, which can intensify the urban heat island effect. To examine the impacts of this urban growth on the environment, the team partnered with the City of Huntsville to utilize Landsat 5 Thematic Mapper (TM), Landsat 8 Operational Land Imager (OLI), Landsat 8 Thermal Infrared Sensor (TIRS), Terra Moderate Resolution Imaging Spectroradiometer (MODIS) and the International Space Station’s Global Ecosystems Dynamic Investigation (GEDI) and ECOsystem Spaceborne Thermal Radiometer Experiment on Space Station (ECOSTRESS). The team utilized these Earth observations in combination with ancillary datasets to create a suite of end products to assist in mitigating the effects of extreme heat due to urban expansion and tree canopy loss. Rasters of annual land surface temperature (LST) was calculated in Google Earth Engine from 2010 to 2019. The team derived land cover classes through supervised and threshold classification methods to distinguish trees, other vegetation types, impervious surfaces, and water. From 2010 to 2019, LST increased approximately 4 °F for all census tracts within the city and the total amount of tree cover increases less than 3%. The findings will aid the city in future decision-making processes by indicating areas that would benefit from increased green infrastructure.

Greta Paris↗

Noise and Fuel Burn Reduction Potential of an Innovative Subsonic Transport Configuration

A study is presented for the noise and fuel burn reduction potential of an innovative double deck concept aircraft with two three-shaft direct-drive turbofan engines. The engines are mounted from the fuselage so that the engine inlet is over the main wing. It is shown that such an aircraft can achieve a cumulative Effective Perceived Noise Level (EPNL) about 28 dB below the current aircraft noise regulations of Stage 4. The combination of high bypass ratio engines and advanced wing design with laminar flow control technologies provide fuel burn reduction and low noise levels simultaneously. For example, the fuselage mounted engine position provides more than 4 EPNLdB of noise reduction by shielding the inlet radiated noise. To identify the potential effect of noise reduction technologies on this concept, parametric studies are presented to reveal the system level benefits of various emerging noise reduction concepts, for both engine and airframe noise reduction. These concepts are discussed both individually to show their respective incremental noise reduction potential and collectively to assess their aggregate effects on the total noise. Through these concepts approximately about 8 dB of additional noise reduction is possible, bringing the cumulative noise level of this aircraft to 36 EPNLdB below Stage 4, if the entire suite of noise reduction technologies would mature to practical application. In a final step, an estimate is made for this same aircraft concept but with higher bypass ratio, geared, turbofan engines. With this geared turbofan propulsion system, the noise is estimated to reach as low as 40-42 dB below Stage 4 with a fuel burn reduction of 43-47% below the 2005 best-in-class aircraft baseline. While just short of the NASA N+2 goals of 42 dB and 50% fuel burn reduction, for a 2025 in service timeframe, this assessment shows that this innovative concept warrants refined study. Furthermore, this design appears to be a viable potential future passenger aircraft, not only in meeting the regulatory requirements, but also in competing with aircraft of different advanced designs within this N+2 timeframe and goal framework.

Guo, Yueping↗

Iona Ecological Conservation: Utilizing Earth Observations to Understand Landscape Patterns and Assist in Wildlife Management in Iona National Park, Angola

Following the end of the Angolan civil war in 2002, human and livestock populations have increased exponentially within Iona National Park. An ongoing drought since 2017 has brought these people and livestock into increasing competition with local wildlife for resources – highlighting a conservation challenge that will become more entrenched as the effects of anthropogenic climate change increase. In 2019, African Parks began co-managing Iona National Park in Angola with the Angolan government, hoping to enact scientifically grounded management strategies to meet this challenge. To accomplish this, African Parks needed contemporary and historic information on the spatial distribution of landcover types within Iona and adjacent areas. We constructed and applied a Random Forest classifier in Google Earth Engine to multispectral imagery gathered from Landsat 5, 7, 8 and Sentinel-1 and 2 to meet this need. Using the classifier, we generated a time-series of land cover maps between 1990–2023, from which landscape metrics and change detection analysis were calculated to show how certain habitats and formations had changed over time. The resulting maps have producer and user’s accuracies above 87% and show four broad landcover regions within the study area. Notably, we observed a decrease in the park’s diversity as per the Shannon Diversity Index – an index that considers the richness of classes, as well the evenness of their distribution. A lack of arid specific land cover indices and ground-truthed training data from earlier years limited the accuracy and resolution of our landcover maps. However, this project still demonstrates that Earth observations can be used to form the basis of conservation policy in arid environments, where ground-truth data may be difficult to obtain or non-existent.

remote sensing↗

Reference data, predictors, and probability grids for forest degradation classes in three sites in the Brazilian Amazon

Forest degradation by fires and selective logging is widespread in the Amazon region. We implemented a gradient boosted classification modeling framework to classify intact, logged, and burned forests at three Amazonian sites: Feliz Natal Municipality and Xingu Indigenous Territory in Mato Grosso State, and Saracá-Taquera National Forest in Pará State. We used forest degradation history from Landsat time-series as reference data and textural metrics derived from PlanetScope images as predictors. Textural metrics were computed using the Gray-Level Co-Occurrence Matrix (GLCM) textural technique. Included in the attached zip file are ten files: - a shapefile containing the reference data (fire and selective logging polygons and year of event) for each site; - a multiband tif file containing the 8 GLCM metrics used as predictors (Mean, Variance, Homogeneity, Contrast, Dissimilarity, Entropy, Angular Second Moment, Correlation) at the original PlanetScope resolution (3.125m) for each site; - a multiband tif file containing the 72 aggregated GLCM metrics used as predictors (Mean, Variance, Homogeneity, Contrast, Dissimilarity, Entropy, Angular Second Moment, and Correlation aggregated using the mean, first quartile, third quartile, maximum, median, minimum, root mean square, standard deviation, and skewness statistics) at 562m resolution for each site; - a multiband tif file containing the 3 probability grids for either intact, logged, or burned forests at the aggregation resolution (562m) for each site.

54 ENVIRONMENTAL SCIENCES↗

New physics particles mixing with mesons: Production in the fragmentation chain

A class of extensions to the Standard Model adds hypothetical long-lived particles (LLPs) that have mass- or kinetic-mixing with neutral mesons, such as pions or rho mesons. The mixing can contribute significantly to the production of LLPs at proton accelerator experiments, and no consistent description of these production modes exists in the literature. In this paper, we develop a framework for studying different LLPs—dark photons, vector mediators coupled to the baryon current, and axionlike particles with different coupling patterns. In particular, we implement the production mechanisms in PYTHIA 8, study how the overall flux and kinematic distributions depend on the LLP’s mass, and compare various subprocesses where the mixing contributes—proton bremsstrahlung, meson decay, and production in the fragmentation chain. We find that our new description of LLP production predicts an integrated flux that differs from current approaches by one to two orders of magnitude, and highlight the unavoidable theoretical uncertainties coming from poor knowledge of the properties of heavy mesons.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Mass-dependent channel electron multiplier operation

The absolute counting efficiency and pulse height distributions of a continuous-channel electron multiplier used in the detection of hydrogen, argon and xenon ions are assessed. The assessment technique, which involves the post-acceleration of 8-eV ion beams to energies from 100 to 4000 eV, provides information on counting efficiency versus post-acceleration voltage characteristics over a wide range of ion mass. The charge pulse height distributions for H2 (+), A (+) and Xe (+) were measured by operating the experimental apparatus in a marginally gain-saturated mode. It was found that gain saturation occurs at lower channel multiplier operating voltages for light ions such as H2 (+) than for the heavier ions A (+) and Xe (+), suggesting that the technique may be used to discriminate between these two classes of ions in electrostatic analyzers.

Fields, S. A.↗

Magnetospheric Substorms and Tail Dynamics

This grant funded several studies of magnetospheric substorms and their effect on the dynamics of the earth's geomagnetic tail. We completed an extensive study of plasmoids, plasma/magnetic field structures that travel rapidly down the tail, using data from the ISEE 3 and IMP 8 spacecraft. This study formed the PhD thesis of Mark Moldwin. We found that magnetically plasmoids are better described as flux-ropes (twisted magnetic flux tubes) rather than plasma bubbles, as had been generally regarded up to that point (Moldwin and Hughes, 1990; 1991). We published several examples of plasmoids observed first in the near tail by IMP 8 and later in the distant tail by ISEE 3, confirming their velocities down tail. We showed how the passage of plasmoids distorts the plasma sheet. We completed the first extensive statistical survey of plasmoids that showed how plasmoids evolve as they move down tail from their formation around 30 RE to ISEE 3 apogee at 240 RE. We established a one-to-one correspondence between the observation of plasmoids in the distant tail and substorm onsets at earth or in the near tail. And we showed that there is a class of plasmoid-like structures that move slowly earthward, especially following weak substorms during northward IMF. Collectively this work constituted the most extensive study of plasmoids prior to the work that has now been done with the GEOTAIL spacecraft. Following our work on plasmoids, we turned our attention to signatures of substorm onset observed in the inner magnetosphere near geosynchronous orbit, especially signatures observed by the CRRES satellite. Using data from the magnetometer, electric field probe, plasma wave instrument, and low energy plasma instrument on CRRES we were able to better document substorm onsets in the inner magnetosphere than had been possible previously. Detailed calculation of the Poynting flux showed energy exchange between the magnetosphere and ionosphere, and a short burst of tailward convective flow just prior to onset, suggesting the active role of the ionosphere in the onset process, and adding credibility to the ballooning instability theory of substorm onset. This grant also supported a number of other substorm studies and reviews. These are represented by the list of publications and meeting presentations resulting out of this grant.

Hughes, W. Jeffrey↗

Fuel Efficient Strategies for Reducing Contrail Formations in United States Air Space

This paper describes a class of strategies for reducing persistent contrail formation in the United States airspace. The primary objective is to minimize potential contrail formation regions by altering the aircraft's cruising altitude in a fuel-efficient way. The results show that the contrail formations can be reduced significantly without extra fuel consumption and without adversely affecting congestion in the airspace. The contrail formations can be further reduced by using extra fuel. For the day tested, the maximal reduction strategy has a 53% contrail reduction rate. The most fuel-efficient strategy has an 8% reduction rate with 2.86% less fuel-burnt compared to the maximal reduction strategy. Using a cost function which penalizes extra fuel consumed while maximizing the amount of contrail reduction provides a flexible way to trade off between contrail reduction and fuel consumption. It can achieve a 35% contrail reduction rate with only 0.23% extra fuel consumption. The proposed fuel-efficient contrail reduction strategy provides a solution to reduce aviation-induced environmental impact on a daily basis.

Sridhar, Banavar↗

A Mystery in Chamaeleon: Serendipitous Discovery of a Galactic Symbiotic Nova

We present the serendipitous discovery of a low optical-luminosity nova occurring in a D-type symbiotic binary star system in the Milky Way. We lay out the extensive archival data alongside new follow-up observations related to the stellar object CN Cha in the constellation of Chamaeleon. The object had long period (250 days), high amplitude (3 mag) optical variability in its recent past, preceding an increase in optical brightness by 8 magnitudes and a persistence at this brightness for about 3 yr, followed by a period of 1.4 mag yr{sup −1} dimming. The object’s current optical luminosity seems to be dominated by Hα emission, which also exhibits blueshifted absorption (a P-Cygni-like profile). After consideration of a number of theories to explain these myriad observations, we determine that CN Cha is most likely a symbiotic (an evolved-star–white-dwarf binary) system that has undergone a long-duration, low optical brightness, nova, placing it squarely in the class of so-called “slow novae,” of which there are only a few known examples. The duration of the optical plateau in CN Cha would make it the shortest timescale plateau of any known slow symbiotic novae.

79 ASTRONOMY AND ASTROPHYSICS↗

Ultraviolet observations of M1-2 (= VV 8)

First IUE spectrograms of the peculiar emission-line object M1-2 (= VV 8) are presented. In the wavelength region 1150-3200 A this object is characterized by emission lines superposed on a moderately strong continuum. Some ultraviolet and optical properties of M1-2 are discussed in the context of symbiotic stars and protoplanetary and planetary nebulae. An E(B-V) extinction of 0.37 mag is obtained from the ratio of the He II flux at 1640 and 4686 A and is compared with values derived from other parameters. The ultraviolet observations suggest that M1-2 is a young, high-density planetary nebula of excitation class 5 or 6 with characteristics similar to IC 4997.

Feibelman, W. A.↗

NASA's Radio Frequency Bolt Monitor: A Lifetime of Spinoffs

This story begins in the 1970s, when Dr. Joseph Heyman, a young scientist at NASA s Langley Research Center, was asked to support the investigation of a wind tunnel accident at a sister center. Although the work was outside of his physics background, it sparked a research focus that guided his lengthy NASA career and would earn him a slew of accolades, including NASA s highest award medals for Exceptional Leadership, Exceptional Achievement, and Exceptional Service; the coveted Silver Snoopy Astronaut Award for Space Shuttle Return to Flight; and the Arthur Fleming Award for being one of the Top Ten Federal Scientists in Government Service. He won 30 additional NASA awards, including the Agency s Invention of the Year and the Agency s highest award for technology transfer, and was the only person to ever win 4 R&D 100 Awards. Back in 1973, though, Heyman was a young civil servant with a background in physics who was asked to sit on an accident review panel. The panel met at Ames Research Center, in Moffet Field, California, and after considerable investigation, concluded that a high-pressure pebble heater used for heating gas had failed, due to improperly tightened bolts in a 1,000-pound gate valve control section. The accident showered the facility with incendiary ceramic spheres and nearly a ton of metal, but, luckily, caused no injuries. Heyman returned to Langley and began work on a solution. He developed an ultrasonic device that would measure bolt elongation, as opposed to torque, the factor typically measured in testing bolt preload or tension. Torque measurement can lead to load errors, with miscalculations as high as 80 percent that can be passed over during installation. Bolt stretch, however, is nearly always accurate to 1 percent or better. Within 1 month, he had an acoustic resonance solution that accurately determined bolt elongation. He assumed his work on this project had ended, but it was actually the start of nearly 15 years of work perfecting, improving, inventing, and modifying the "bolt monitor", all the while, filing numerous patents, presenting papers, and holding demonstrations as the technology matured. Industry engineers challenged Heyman s inventiveness, and reminded the physicist that most bolts are not perfect resonators, and that early devices required that the bolt have reasonably flat and parallel faces. The U.S. Geological Survey asked NASA for help in determining the load in mine roof bolts, which are 8- to 10-feet-long and rough cut. To solve that problem, Heyman modified the original device to operate at a lower frequency and to generate propagation modes that could be used to "lock" the instrument on a particular mode. Further work in this vein led to the development of the Pulsed Phase Locked Loop (P2L2) that worked on the mine bolts. The next set of problems involved high-strength bolts with head markings. For this solution, Heyman invented a modified P2L2 that tracked a specific phase point in the measurement wave. This class of instrumentation, well suited to measuring small changes in acoustic velocity, won the NASA "Invention of the Year" award in 1982. Other scientists and engineers have continued the evolution of this technology both inside NASA and outside of the Agency. Within NASA, the technology has been improved for medical applications, with a particular focus on intercranial pressure (ICP) monitoring.

Source record↗

Investigating Commercial Off-The-Shelf (COTS) Glovebox and Support Components Compared to Custom Curatorial Laboratories

There is a need envisioned to investigate the application of commercial off-the-shelf (COTS) systems as tools that could be used within commercial preliminary curation as the expected space economy is supported and begins to take flight. NASA is involved with supporting and developing the space economy [1] and therefore it’s feasible that at some point, a commercial space company would bring back materials and either store initially, or permanently, within COTS equipment as a stand-in for custom curation laboratories. While utilizing opportunities to explore this capability at NASA-Johnson Space Center (JSC) during the establishment of other laboratories [2] it was realized that cleanliness and/or other properties could be evaluated for these COTS systems during their installation in advanced research facilities that are not ISO-class rated clean rooms. Several aspects of a COTS-Curation system were explored including various gloves for curation manipulation within a negative pressure glovebox (Fig.1), Balazs organic and inorganic contaminant levels testing prior to glovebox ever being used, mode swapping comparison of recirculation vs. single pass, constant monitoring of oxygen (O2) and moisture (H2O) levels in various conditions, etc. To acquire inorganic and organic compound loads inside the glovebox, Balazs wafer testing and gas sampling were implemented. These are standardized analytical tests provided by Balazs™ NanoAnalysis, a division of Air Liquide USA. Deployment of 8-inch silicon wafer witness plates for 24-hours in an undisturbed environment capture the organic compound load and inorganic trace metal contents which can be obtained by Vapor Phase Decomposition Inductively Coupled Plasma Mass Spectrometry (VPD ICP-MS). Balazs gas sample analysis was also performed for better measurements of volatile organic compounds (VOC) in glovebox air analyzed by Thermal Desorption Gas Chromatography Mass Spectrometry (TD GC-MS). These analytical testings were carried out in a controlled ultra high pure (UHP) gaseous nitrogen (N2)-purged environment where oxygen and moisture contents were continuously monitored at certain temperature and pressure. The preliminary outcomes of these testings are promising. The COTS systems appear to maintain the steady-state controlled environment for days, if not weeks, with uninterrupted gaseous N2-supply which was operated from a standard medium pressure LN2 250L 230L dewar, exchanged as needed. The outgassing load can be maintained by selecting the glove materials that have the least outgassing and particle shedding performances. Further experiments will be considered to validate the preliminary findings. While this project is exploratory, it is not intended as an endorsement by NASA Curation for approved materials or usage for advanced curatorial activities. NASA does not endorse nor promote any one particular product or company. References: [1] McCubbin F. M. et al. (2019) Space Science Reviews 215:A48. [2] Lewis, E.K. et. al (2024) LPSC LV, Abstract #2457.

Curation↗

Quaternary borocarbides: New class of intermetallic superconductors

Our recent discovery of superconductivity (SC) in the four-element multiphase Y-Ni-B-C system at an elevated temperature (TC approximately 12 K) has opened up great possibilities of identifying new superconducting materials and generating new physics. Superconductivity with Tc (greater than 20 K) higher than that known so far in bulk intermetallics has been observed in multiphase Y-Pd-B-C and Th-Pd-B-C systems and a family of single phase materials RENi2B2C (RE= Y, rare earth) have been found. Our investigations show YNi2B2C to be a strong coupling hard type-II SC. HC2(T) exhibits an unconventional temperature dependence. Specific heat and magnetization studies reveal coexistence of SC and magnetism in RNi2B2C (R = Ho, Er, Tm) with magnetic ordering temperatures (Tc approximately 8 K, 10.5 K, 11 K and Tm approximately 5 K, approximately 7K, approximately 4 K respectively) that are remarkably higher than those in known magnetic superconductors . Mu-SR studies suggest the possibility of Ni atoms carrying a moment in TmNi2B2C. Resistivity results suggests a double re-entrant transition (SC-normal-SC) in HoNi2B2C. RENi2B2C (RE = Ce, Nd, Gd) do not show SC down to 4.2 K. The Nd- and Gd-compounds order magnetically at approximately 4.5 K and approximately 19.5 K, respectively. Two SC transitions are observed in Y-Pd-B-C (Tc approximately 22 K, approximately 10 K) and in Th-Pd-B-C (Tc approximately 20 K, approximately 14 K) systems, which indicate that there are at least two structures which support SC in these borocarbides. In our multiphase ThNi2B2C we observe SC at approximately 6 K. No SC was seen in multiphase UNi2B2C, UPd2B2C, UOs2Ge2C and UPd5B3C(0.35) down to 4.2 K. Tc in YNi2B2C is depressed by substitutions (Gd, Th and U at Y-sites and Fe, Co at Ni-sites).

Nagarajan, R.↗