Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “chemical process”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 487 records · Page 27
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Lunar cement and lunar concrete

Results of a study to investigate methods of producing cements from lunar materials are presented. A chemical process and a differential volatilization process to enrich lime content in selected lunar materials were identified. One new cement made from lime and anorthite developed compressive strengths of 39 Mpa (5500 psi) for 1 inch paste cubes. The second, a hypothetical composition based on differential volatilization of basalt, formed a mineral glass which was activated with an alkaline additive. The 1 inch paste cubes, cured at 100C and 100 percent humidity, developed compressive strengths in excess of 49 Mpa (7100 psi). Also discussed are tests made with Apollo 16 lunar soil and an ongoing investigation of a proposed dry mix/steam injection procedure for casting concrete on the Moon.

Lin, T. D.↗
NASA NTRS1991

CFD applications in chemical propulsion engines

The present research is aimed at developing analytical procedures for predicting the performance and stability characteristics of chemical propulsion engines. Specific emphasis is being placed on understanding the physical and chemical processes in the small engines that are used for applications such as spacecraft attitude control and drag make-up. The small thrust sizes of these engines lead to low nozzle Reynolds numbers with thick boundary layers which may even meet at the nozzle centerline. For this reason, the classical high Reynolds number procedures that are commonly used in the industry are inaccurate and of questionable utility for design. A complete analysis capability for the combined viscous and inviscid regions as well as for the subsonic, transonic, and supersonic portions of the flowfield is necessary to estimate performance levels and to enable tradeoff studies during design procedures.

Merkle, Charles L.↗
NASA NTRS1990

Color and chemistry on Triton

The surface of Triton is very bright but shows subtle yellow to peach hues which probably arise from the production of colored organic compounds from CH4 + N2 and other simple species. In order to investigate possible relationships between chemical processes and the observed surface distribution of chromophores, the surface units are classified according to color/albedo properties, the rates of production of organic chromophores by the action of ultraviolet light and high-energy charged particles is estimated, and rates, spectral properties, and expected seasonal redistribution processes are compared to suggest possible origins of the colors seen on Triton's surface.

Thompson, W. Reid↗
NASA NTRS1990

Meteoritic silicon carbide - Pristine material from carbon stars

All five gases in interstellar silicon carbide grains have grossly nonsolar isotopic and elemental abundances that vary with grain size but are strikingly similar to calculated values for the helium-burning shell of low-mass carbon stars. Apparently these grains formed in carbon-star envelopes, and were impregnated with noble gas ions from a stellar wind. Meteoritic SiC provides a detailed record of nuclear and chemical processes in carbon stars.

Lewis, Roy S.↗
NASA NTRS1990

Delay compensation in integrated communication and control systems. I - Conceptual development and analysis

A procedure for compensating for the effects of distributed network-induced delays in integrated communication and control systems (ICCS) is proposed. The problem of analyzing systems with time-varying and possibly stochastic delays could be circumvented by use of a deterministic observer which is designed to perform under certain restrictive but realistic assumptions. The proposed delay-compensation algorithm is based on a deterministic state estimator and a linear state-variable-feedback control law. The deterministic observer can be replaced by a stochastic observer without any structural modifications of the delay compensation algorithm. However, if a feedforward-feedback control law is chosen instead of the state-variable feedback control law, the observer must be modified as a conventional nondelayed system would be. Under these circumstances, the delay compensation algorithm would be accordingly changed. The separation principle of the classical Luenberger observer holds true for the proposed delay compensator. The algorithm is suitable for ICCS in advanced aircraft, spacecraft, manufacturing automation, and chemical process applications.

Luck, Rogelio↗
NASA NTRS1991

Humidity and particle fields around some small cumulus clouds

Aircraft-borne measurements showed that five small cumulus clouds were surrounded by regions of high humidity out to distances of several cloud radii from their centers. Total particle concentrations in the regions of high humidity were about twice those in the air at the same level but well removed from the cloud boundaries. The regions of high humidity and particle concentrations also coincided with regions of high turbulence surrounding the clouds. In addition to affecting particle production, regions of high humidity surrounding clouds can be expected to affect chemical process and atmospheric radiation transfer.

Radke, Lawrence F.↗
NASA NTRS1991

Field-aligned dynamics of chemically induced perturbations to the ionosphere

Ionospheric modification using photochemically reactive vapors is studied with a one-dimensional, multiion, fluid model of plasma flow along magnetic field lines. The magnitudes of ion and electron density changes are determined by considering both chemical processes (i.e., photoionization, ion-molecule reactions, dissociative recombination, electron attachment) and transport processes (i.e., multispecies diffusion, electric currents, ambipolar electric fields). The numerical treatment in the model is not specific to any type of release or any interaction chemistry. It has been used to simulate releases of Ba, CO2, and CF3Br in the ionosphere, but generalization to other species may be easily accomplished. The results of the calculations are found to be in good agreement with experimental observations. The feasibility of modifying the parallel current paths in the auroral F region is examined.

Bernhardt, P. A.↗
NASA NTRS1991

Soil emissions of nitric oxide in a seasonally dry tropical forest of Mexico

Soil emissions of NO were measured at the Chamela Biological Station, Mexico, using soil covers and a field apparatus of NO detection based on CrO3 conversion of NO to NO2 and detection of NO2 by chemiluminescence with Luminol. Mean NO fluxes from forest soils ranged from 0.14 to 0.52 ng NO-N/sq cm/hr during the dry season and from 0.73 to 1.27 ng NO-N/sq cm/hr during the wet season. A fertilized floodplain pasture exhibited higher fluxes, but an unfertilized upland pasture, which represents the fastest growing land use in the region, had flux rates similar to the forest sites. Wetting experiments at the end of the dry season caused large pulses of NO flux, equaling 10 percent to 20 percent of the estimated annual NO emissions of 0.5-1.0 kg N/ha from the forest sites. Absence of a forest canopy during the dry season and the first wet season rain probably results in substantial NO(x) export from the forest system that may be important to regional atmospheric chemical processes. Wetting experiments during the wet season and a natural rain event had little or no stimulatory effect on NO flux rates.

Davidson, Eric A.↗
NASA NTRS1992

Electrochemical System Would Supply O2, H2O, N2, And H2

Electrochemical system includes fuel cells that convert high-energy-density chemical propellants to atmospheric gases. System provides cooling, water, and electrical energy. Applicable to terrestrial enclosed environments, laboratories, chemical processing plants, or portable medical facilities.

Walter, Richard T.↗
NASA NTRS1992

Automated Simulation For Analysis And Design

Design Assistant Workstation (DAWN) software being developed to facilitate simulation of qualitative and quantitative aspects of behavior of life-support system in spacecraft, chemical-processing plant, heating and cooling system of large building, or any of variety of systems including interacting process streams and processes. Used to analyze alternative design scenarios or specific designs of such systems. Expert system will automate part of design analysis: reason independently by simulating design scenarios and return to designer with overall evaluations and recommendations.

Cantwell, E.↗
NASA NTRS1992

Expert-System Consultant To Operating Personnel

Artificial intelligence aids engineers and technicians in controlling and monitoring complicated systems. Operations Analyst for Distributed Systems (OPERA) software is developmental suite of expert-system computer programs helping engineers and technicians operating from number of computer workstations to control and monitor spacecraft during prelaunch and launch phases of operation. OPERA designed to serve as consultant to operating engineers and technicians. It preprocesses incoming data, using expertise collected from conglomerate of specialists in design and operation of various parts of system. Driven by menus and mouse-activated commands. Modified versions of OPERA used in chemical-processing plants, factories, banks, and other enterprises in which there are distributed-computer systems including computers that monitor or control other computers.

Heard, Astrid E.↗
NASA NTRS1992

Human Factors Of Flight-Deck Checklists

Report analyzes functions, formats, designs, lengths, and usage of normal cockpit checklists, as well as limitations of aircraft personnel who must interact with them. Checklist problems discussed in report also found in other high-risk industries such as: marine, nuclear, and chemical-process industries, as well as, civilian and military air transportation.

Degani, Asaf↗
NASA NTRS1991

Studies of volatiles and organic materials in early terrestrial and present-day outer solar system environments

A review and partial summary of projects within several areas of research generally involving the origin, distribution, chemistry, and spectral/dielectric properties of volatiles and organic materials in the outer solar system and early terrestrial environments are presented. The major topics covered include: (1) impact delivery of volatiles and organic compounds to the early terrestrial planets; (2) optical constants measurements; (3) spectral classification, chemical processes, and distribution of materials; and (4) radar properties of ice, hydrocarbons, and organic heteropolymers.

Sagan, Carl↗
NASA NTRS1991

Catalysis and biocatalysis program

The annual report presents the fiscal year (FY) 1990 research activities and accomplishments for the Catalysis and Biocatalysis Program of the Advanced Industrial Concepts Division (AICD), Office of Industrial Technologies of the Department of Energy (DOE). The mission of the AICD is to create a balanced program of high risk, long term, directed interdisciplinary research and development that will improve energy efficiency and enhance fuel flexibility in the industrial sector. The Catalysis and Biocatalysis Program's technical activities were organized into five work elements: the Molecular Modeling and Catalysis by Design element; the Applied Microbiology and Genetics element; the Bioprocess Engineering element; the Separations and Novel Chemical Processes element; and the Process Design and Analysis element.

Source record↗
NASA NTRS1991

Spectroscopy of comets

Observations of NH2, OI, CH, CO(+), CO2(+), H2O(+), and N2(+) in optical spectra of comets represent ionization and dissociation product abundances of N2, NH3, H2O, CH4, CO2, and CO. The primary objectives are to determine: (1) accurate production rates for the observed species, and (2) accurate relative abundances of condensates in a sample of comet nuclei. The ultimate goal is to constrain models of comet formation and chemical processing in the outer primordial solar nebula.

Wyckoff, Susan↗
NASA NTRS1990

Aircraft deployment, and airborne arctic stratospheric expedition

The Airborne Arctic Stratospheric Expedition had two primary objectives: to study the production and loss mechanisms of ozone in the north polar stratosphere and to study the effect on ozone distribution of the Arctic Polar Vortex and of the cold temperatures associated with the formation of Polar Stratospheric Clouds. Two specially instrumented NASA aircraft were flown over the Arctic region. Each aircraft flew to acquire data on the meteorological, chemical and cloud physical phenomena that occur in the polar stratosphere during winter. The chemical processes which occur in the polar stratosphere during winter were also observed and studied. The data acquired are being analyzed.

Condon, Estelle↗
NASA NTRS1990

Relative effects on stratospheric ozone of halogenated methanes and ethanes of social and industrial interest

Four atmospheric modeling groups have calculated relative effects of several halocarbons (chlorofluorocarbons (CFC's)-11, 12, 113, 114, and 115; hydrochlorofluorocarbons (HCFC's) 22, 123, 124, 141b, and 142b; hydrofluorocarbons (HFC's) 125, 134a, 143a, and 152a, carbon tetrachloride; and methyl chloroform) on stratospheric ozone. Effects on stratospheric ozone were calculated for each compound and normalized relative to the effect of CFC-11. These models include the representations for homogeneous physical and chemical processes in the middle atmosphere but do no account for either heterogeneous chemistry or polar dynamics which are important in the spring time loss of ozone over Antarctica. Relative calculated effects using a range of models compare reasonably well. Within the limits of the uncertainties of these model results, compounds now under consideration as functional replacements for fully halogenated compounds have modeled stratospheric ozone reductions of 10 percent or less of that of CFC-11. Sensitivity analyses examined the sensitivity of relative calculated effects to levels of other trace gases, assumed transport in the models, and latitudinal and seasonal local dependencies. Relative effects on polar ozone are discussed in the context of evolving information on the special processes affecting ozone, especially during polar winter-springtime. Lastly, the time dependency of relative effects were calculated.

Fisher, Donald A.↗
NASA NTRS1991

Laminar flames in premixed gases

Numerical simulation of laminar flames in premixed gases is addressed. Various efforts to solve the laminar flame problem are briefly described, and basic equations to be modeled in a comprehensive description of laminar flames are discussed along with the physical and chemical processes represented by these equations and the numerical requirements to model them. Two flame methods are discussed in some detail: a numerical model for studying transient phenomena and its 2D counterpart method. The various input parameters needed for the models are addressed, and the use of the models is illustrated in several studies of laminar flames in premixed gases. Flammability limits and multidimensional flame propagation are also examined.

Kailasanath, K.↗