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Status Update - Installation and Operation of GeoMelt{sup R} ICV{sup TM} Process in the NNL's Central Laboratory on the Sellafield Site - 16410

Thermal treatment of nuclear waste in the UK has seen much renewed interest recently, owing to the advantages that can be gained in terms of reduced waste volumes, compatibility with reactive metals and organics and its ability to treat mixed generic wastes. Vitrification is a treatment option which destroys organics and some hazardous inorganics such as asbestos, reduces wasteform volume, and produces a robust leach resistant wasteform. Kurion's GeoMelt{sup R} In-Container Vitrification (ICV){sup TM} is a vitrification process where the treatment vessel can serve as an interim-storage, transport, and final long-term storage vessel - thus negating the need to pour glass into a separate container, effectively leading to a much simpler system than traditional waste melters. The UK's National Nuclear Laboratory (NNL) and Kurion have entered into a joint project to deploy an active waste ICV{sup TM} plant based on Kurion's GeoMelt{sup R} technology, at NNL's flagship Central Laboratory on the Sellafield site. NNL is the UK's national laboratory for civil nuclear science and technology, providing advice to government, protecting key skills, supporting industry and delivering national nuclear programs. NNL is bringing the Kurion GeoMelt{sup R} process alongside its existing capabilities in thermal waste treatment. Kurion provides technology solutions to minimize and stabilize nuclear and hazardous waste through its families of technologies: access, separation and stabilization processes. The GeoMelt{sup R} plant being installed at the NNL's Central Laboratory creates a platform to evaluate the vitrification technology for the variety of wastes from the NDA estate and creates a treatment path for problematic waste streams that currently have no disposition pathway. With the diverse facilities under NNL management coupled with the NNL's ability to import wastes from within the UK and Europe, this arrangement with Kurion provides waste owners with treatment disposition pathways for problematic wastes. The Kurion / NNL team completed non-radioactive commissioning of a GeoMelt{sup R} ICV{sup TM} treatment system in 2015. Commissioning consisted of performing two tests at NNL's Workington Laboratory. Commissioning Test 1 involved vitrification of 367 kg of glass frit over the course of approximately 18 hours. Commissioning Test 2 consisted of processing 470 kg of soil and additives in approximately 27 hours. The soil processed in the second test was non-radioactive soil from Sellafield and was used as an analog for radioactive soil to be processed during radioactive commissioning at the Central Laboratory at Sellafield. All commissioning test goals were easily achieved and all subsystems operated as designed. Radioactive commissioning will be carried out in early 2016. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Dielectron production in central Pb-Pb collisions at $\sqrt{s_{NN}}$ = 5.02TeV

The first measurement of the 𝑒 + ⁢𝑒 − pair production at midrapidity and low invariant mass in central Pb-Pb collisions at $\sqrt{s_{NN}}$ = 5.02 TeV at the Large Hadron Collider is presented. The yield of 𝑒 + ⁢𝑒 − pairs is compared with a cocktail of expected hadronic decay contributions in the invariant mass (𝑚𝑒⁢𝑒) and pair transverse momentum (𝑝 T,𝑒⁢𝑒 ) ranges 𝑚 𝑒⁢𝑒 < 3.5 GeV/𝑐 2 and 𝑝 T,𝑒⁢𝑒 < 8 GeV/𝑐. For 0.18 < 𝑚 𝑒⁢𝑒 < 0.5 GeV/𝑐 2 the ratio of data to the cocktail of hadronic contributions amounts to 1.40 ± 0.11⁢(stat.) ± 0.23 ⁢(syst.) ± 0.16⁢ (cocktail) and 1.42 ± 0.11⁢ (stat.) ± 0.23 (syst.)$^{+0.24}_{−0.29}$ ⁢(cocktail), including or not including medium effects in the estimation of the heavy-flavor background, respectively. It is consistent with predictions from two different models for an additional contribution of thermal 𝑒+⁢𝑒− pairs from the hadronic and partonic phases. In the intermediate-mass range (1.2 < 𝑚 𝑒⁢𝑒 < 2.6 GeV/𝑐 2 ), the pair transverse impact parameter of the 𝑒 + ⁢𝑒 − pairs (DCA𝑒⁢𝑒, where “DCA” denotes “distance of closest approach”) is used for the first time in Pb-Pb collisions to separate displaced dielectrons from heavy-flavor hadron decays from a possible (thermal) contribution produced at the interaction point. The data are consistent with a suppression of 𝑒 + ⁢𝑒 − pairs from $𝑐\bar{𝑐}$ and an additional prompt component. Finally, the first direct-photon measurement in the 10% most central Pb-Pb collisions at $\sqrt{s_{NN}}$ = 5.02 TeV is reported via the study of virtual direct photons in the transverse momentum range 1 < 𝑝 T < 5 GeV/𝑐. A model including prompt photons, as well as photons from the preequilibrium and fluid-dynamic phases, can reproduce the result, while being at the upper edge of the data uncertainties.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Impact of Aerosols on Atmospheric Attenuation Loss in Central Receiver Systems: Preprint

Atmospheric attenuation loss between the heliostat field and receiver has been recognized as a significant source of loss in Central Receiver Systems. In clear sky situations, extinction of Direct Normal Irradiance (DNI) is primarily by aerosols in the atmosphere. When aerosol loading is high close to the surface the attenuation loss between heliostat and receivers is significantly influenced bythe amount of aerosols present on a particular day. This study relates measured DNI to aerosol optical depths close to the surface of the earth. The model developed in the paper uses only measured DNI to estimate the attenuation between heliostat and receiver in a central receiver system. The requirement that only a DNI measurement is available potentially makes the model a candidate forwidespread use.

14 SOLAR ENERGY↗

Fisheries Management of Mexican and Central American Estuaries

The contributed papers in this book provide research undertaken in estuarine systems of Mexico and Central America that aim to provide a scientific basis for proper estuarine management. The book is divided in three parts that cover topics associated with fisheries management and regulations: physicochemical studies, ecological studies and socioeconomic studies. This introduction outlines the contents of this book in relation to the management of coastal ecosystems, which have a high socioeconomic importance for a large proportion of the population in this area of the world. Rather than be a definitive suite of papers for the regulation of these habitats, the goal of this book is to outline the urgent need to continue research of threatened coastal ecosystems of Mexico and Central America.

Central America↗

Increasing risk of cascading hazards in the central Himalayas

Cascading hazards are becoming more prevalent in the central Himalayas. Primary hazards (e.g., earthquakes, avalanches, and landslides) often trigger secondary hazards (e.g., landslide dam, debris flow, and flooding), compounding the risks to human settlements, infrastructures, and ecosystems. Risk management strategies are commonly tailored to a single hazard, leaving human and natural systems vulnerable to cascading hazards. In this commentary, we characterize diverse natural hazards in the central Himalayas, including their cascading mechanisms and potential impacts. A scientifically sound understanding of the cascading hazards, underlying mechanisms, and appropriate tools to account for the compounding risks are crucial to informing the design of risk management strategies. Here, we also discuss the need for an integrated modeling framework, reliable prediction and early warning system, and sustainable disaster mitigation and adaptation strategies.

54 ENVIRONMENTAL SCIENCES↗

Dynamics of zero-energy nonspreading non-Gaussian wave packets for a class of central potentials

Zero-energy wave packets, coherent states, are constructed in such a way that they retain their shape during the time evolution for a large class of central potentials. The packets are not of the Gaussian type with −r{sup 2} dependence but, instead, their shape is determined by −r{sup 1/(μ+1/2)} with −1/2<μ<1/2. A very close quantum–classical correspondence is also shown, i.e., the well localized states travel along suitable classical trajectories. -- Highlights: •Central potentials are considered. •Nonspreading, non-Gaussian wave packets are constructed. •Time evolution of the zero-energy packets is studied. •Quantum–classical correspondence is discussed.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Relative Fisher information in some central potentials

Highlights: • Relative Fisher information in both r and p spaces is calculated analytically. • In case of central potentials, circular state of a given l, is selected as reference. • In hydrogenic system IR provides better result than that of I. • In case of oscillator potentials IR comments about change of bond strength with n{sub r}. - Abstract: Relative Fisher information (IR) was pursued for 1D quantum harmonic oscillator (QHO), 3D isotropic QHO, hydrogen atom and pseudoharmonic potential (PHP) in both r and p spaces. In 1D case, the n=0 state is chosen as reference, whereas for a central potential, the respective circular (corresponding to lowest radial quantum number n{sub r}) state of a given l quantum number, is selected. Starting from their exact wave functions, expressions of IR in both r and p spaces are obtained in closed analytical forms in all these systems. For the 1D QHO, IR in r,p spaces increases linearly with n. For 3D QHO and PHP, it varies with single power of n{sub r} in both spaces. But, in H atom they depend on both principal (n) and azimuthal (l) quantum numbers. However, at a fixed l, IR initially advances with rise of n and then falls off; also for a given n, it always decreases with l.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Polluting of Winter Convective Clouds upon Transition from Ocean Inland Over Central California: Contrasting Case Studies

In-situ aircraft measurements of aerosol chemical and cloud microphysical properties were conducted during the CalWater campaign in February and March 2011 over the Sierra Nevada Mountains and the coastal waters of central California. The main objective was to elucidate the impacts of aerosol properties on clouds and precipitation forming processes. In order to accomplish this, we compared contrasting cases of clouds that ingested aerosols from different sources. The results showed that clouds containing pristine oceanic air had low cloud drop concentrations and started to develop rain 500 m above their base. This occurred both over the ocean and over the Sierra Nevada, mainly in the early morning when the radiatively cooled stable continental boundary layer was decoupled from the cloud base. Supercooled rain dominated the precipitation that formed in growing convective clouds in the pristine air, up to the -21°C isotherm level. A contrasting situation was documented in the afternoon over the foothills of the Sierra Nevada, when the clouds ingested high pollution aerosol concentrations produced in the Central Valley. This led to slow growth of the cloud drop effective radius with height and suppressed and even prevented the initiation of warm rain while contributing to the development of ice hydrometeors in the form of graupel. Our results show that cloud condensation and ice nuclei were the limiting factors that controlled warm rain and ice processes, respectively, while the unpolluted clouds in the same air mass produced precipitation quite efficiently. These findings provide the motivation for deeper investigations into the nature of the aerosols seeding clouds.

central California↗

On the application of betweenness centrality in chemical network analysis: Computational diagnostics and model reduction

Here, the concept of shortest path and betweenness centrality (BC) is introduced in combustion systems, with its application demonstrated in chemical network analysis and skeletal mechanism generation. After establishing the graphical representation of a chemical network for given pressure, temperature, and species concentrations, a metric BC is defined to rank the shortest paths passed by other nodes between the pair of source and target node, and as such captures the dominant indirect kinetic pathways between any pair of nodes in the network for computational diagnostics. As a result, the controlling pathways are retained by collecting the species with larger BC values. Such a notion then indicates that the index of importance of species could then be assigned based on their BC values to further guide skeletal mechanism generation. Unlike existing methods, the betweenness centrality approach takes into account of both the fluxes between species and their relative positioning within the chemical network. To demonstrate its potential utility to combustion studies, the approach was applied to the GRI-3.0, LLNL and USC-Mech II mechanisms to identify the important pathways in the chemical network at each local reaction state, and develop skeletal mechanisms from all reaction state samples in auto-ignition and perfectly stirred reactor (PSR) simulations. The performance of the BC ranking is compared to the methods of directed relation graph (DRG), DRG with error propagations (DRGEP) and sensitivity analysis (SA), and is shown to possess sufficient utility in producing skeletal mechanisms with good accuracy and flexibility for the cases studied.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Sources and Composition of Organic Aerosols in the Central Arctic during Spring and Summer

Organic aerosols (OA) are a major component of Arctic aerosol mass and influence the region’s radiation budget, yet their sources and physicochemical properties remain largely unknown. We investigate OA sources and climate-relevant characteristics over the central Arctic Ocean in spring and summer, by applying positive matrix factorization to aerosol mass spectrometry data from two ship-based expeditions (2018 and 2020), complemented by total and interstitial aerosol measurements during fog periods. Six distinct OA factors were identified: haze-related OA, Arctic oxygenated OA, two mixed-OA types resembling biomass burning and primary marine OA linked to warm-air intrusions, marine OA, and hydrocarbon-related OA. Seasonal transitions strongly shaped OA composition. Following polar sunrise, highly oxygenated OA, likely formed secondarily from photo-oxidized volatile organic compounds, became dominant. After the polar vortex collapsed in May, episodic spikes in marine OA from the marginal ice zone appeared, alongside a reduced influence from Eurasian anthropogenic sources. These transitions influenced OA oxidation state and related properties including volatility, acidity, and hygroscopicity, highlighting the role of the Arctic spring atmosphere as an active photochemical reactor. Overall, OA was highly oxidized, with particles activated in fog during summer showing even greater oxidation, suggesting that central Arctic OA can be highly cloud active.

Arctic haze↗

Summertime Near-Surface Temperature Biases Over the Central United States in Convection-Permitting Simulations

Convection-Permitting Model (CPM) simulations of the Central United States climate for the summer of 2011 are studied to understand the causes of warm biases in 2-m air temperature (T 2m ) and related underestimates of precipitation including that from mesoscale convective systems (MCSs). Based on 10 CPM simulations and 9 coarser-resolution model simulations, we quantify contributions from evaporative fraction (EF) and radiation to the T 2m bias with both types of models overestimating T 2m largely because they underestimate EF. The performance of CPMs in capturing MCS characteristics (frequency, rainfall, propagation) varies. The pre-summer precipitation bias has large correlation with mean summertime T 2m bias but the relationship between summertime MCS mean rainfall bias and T 2m bias is non-monotonic. Analysis of lifting condensation level deficit and convective available potential energy suggests that models with T 2m warm biases and low EF have too dry and stable boundary layers, inhibiting the formation of clouds, precipitation and MCSs. Among the CPMs with differing model formulations (e.g., transpiration, infiltration, cloud macrophysics and microphysics), evidence suggests that altering the land-surface model is more effective than altering the atmospheric model in reducing T 2m biases. In conclusion, these results demonstrate that land-atmosphere interactions play a very important role in determining the summertime climate of the Central United States.

2-m air temperature↗

A 200kW central receiver CPV system

Raygen Resources has recently completed a Central Receiver CPV (CSPV) pilot plant in Central Victoria, Australia. The system is under final commissioning and initial operation is expected in late April 2015. The pilot demonstrates a full scale CSPV repeatable unit in a form that is representative of a commercial product and provides a test bed to prove out performance and reliability of the CSPV technology. Extensive testing of the system key components: dense array module, wireless solar powered heliostat and control system has been performed in the laboratory and on sun. Results from this key component testing are presented herein.

14 SOLAR ENERGY↗

Early warm-season mesoscale convective systems dominate soil moisture–precipitation feedback for summer rainfall in central United States

Land–atmosphere interactions play an important role in summer rainfall in the central United States, where mesoscale convective systems (MCSs) contribute to 30 to 70% of warm-season precipitation. Previous studies of soil moisture–precipitation feedbacks focused on the total precipitation, confounding the distinct roles of rainfall from different convective storm types. Here, we investigate the soil moisture–precipitation feedbacks associated with MCS and non-MCS rainfall and their surface hydrological footprints using a unique combination of these rainfall events in observations and land surface simulations with numerical tracers to quantify soil moisture sourced from MCS and non-MCS rainfall. Furthermore, we find that early warm-season (April to June) MCS rainfall, which is characterized by higher intensity and larger area per storm, produces coherent mesoscale spatial heterogeneity in soil moisture that is important for initiating summer (July) afternoon rainfall dominated by non-MCS events. On the other hand, soil moisture sourced from both early warm-season MCS and non-MCS rainfall contributes to lower-level atmospheric moistening favorable for upscale growth of MCSs at night. However, soil moisture sourced from MCS rainfall contributes to July MCS rainfall with a longer lead time because with higher intensity, MCS rainfall percolates into deeper soil that has a longer memory. Therefore, early warm-season MCS rainfall dominates soil moisture–precipitation feedback. This motivates future studies to examine the contribution of early warm-season MCS rainfall and associated soil moisture anomalies to predictability of summer rainfall in the major agricultural region of the central United States and other continental regions frequented by MCSs.

54 ENVIRONMENTAL SCIENCES↗

Non-universality of dark-matter halos: Cusps, cores, and the central potential

Dark-matter halos grown in cosmological simulations appear to have central Navarro–Frenk–White-like density cusps with mean values of dlogρ/dlogr≈−1, and some dispersion, which is generally parametrized by the varying index α in the Einasto density profile fitting function. Non-universality in profile shapes is also seen in observed galaxy clusters and possibly dwarf galaxies. Here we show that non-universality, at any given mass scale, is an intrinsic property of DARKexp, a theoretically derived model for collisionless self-gravitating systems. We demonstrate that DARKexp—which has only one shape parameter, ϕ{sub 0}—fits the dispersion in profile shapes of massive simulated halos as well as observed clusters very well. DARKexp also allows for cored dark-matter profiles, such as those found for dwarf spheroidal galaxies. We provide approximate analytical relations between DARKexp ϕ{sub 0}, Einasto α, or the central logarithmic slope in the Dehnen–Tremaine analytical γ-models. The range in halo parameters reflects a substantial variation in the binding energies per unit mass of dark-matter halos.

79 ASTRONOMY AND ASTROPHYSICS↗

Topology-Aware Reinforcement Learning for Voltage Control: Centralized and Decentralized Strategies

Volt-VAR control (VVC) methods based on deep reinforcement learning (DRL) can effectively control distribution grid voltage and minimize power loss by implementing corrective and preventive control measures on the reactive power output of inverter-based distributed energy resources (DERs). However, model-free DRL-based VVC approaches usually cannot capture the important topological feature of the power system since they use a fully-connected network (FCN) to deliver the action. Therefore, this paper proposes a graph convolutional network (GCN)-based DRL approach that can employ the topological information of the network to take better control action for regulating the voltage. Our implementation allows for both centralized and decentralized configurations, utilizing a single agent and multiple agents respectively. Although the centralized GCN-based DRL approach has its advantages of minimizing voltage fluctuation and power loss, it is not suitable for large scale power systems due to its challenges in terms of scalability, computation speed and potential single points of failure. Therefore, these problems can be resolved using the decentralized GCN-based DRL approach. Moreover, to ensure the safe operation of the model, our proposed approach incorporates an exponential barrier function while formulating the reward function for each agent. To validate performance of the proposed approaches, the proposed model is tested on modified IEEE test systems and the performances are measured in terms on voltage fluctuation reduction, minimization of power loss and computational speed. Finally, the results show that the proposed topology-aware approach outperforms the FCN-based DRL approach in terms of reducing voltage fluctuation and minimizing power loss of the network. Moreover, it is shown that the decentralized GCN-based DRL has faster computational speed than other approaches.

42 ENGINEERING↗

Fast scanning in x-ray microscopy: the effects of offset in the central stop position

Scanning of lightweight circular diffractive optics, separate from central stops and apertures, is emerging as an approach to exploit advances in synchrotron x-ray sources. We consider the effects in a scanning microscope of offsets between the optic and its central stop and find that scan ranges of up to about half the diameter of the optic are possible with only about a 10% increase in the focal spot width. Finally, for large scanning ranges, we present criteria for the working distance between the last aperture and the specimen to be imaged.

47 OTHER INSTRUMENTATION↗

Seismicity Monitoring in North-Central New Mexico by the Los Alamos Seismic Network

The initial seismic stations of the Los Alamos Seismic Network (LASN) were installed in 1973, as a part of research on monitoring of nuclear testing. The extent of the network rapidly expanded by the late 1970s. By the middle 1980s, spatial coverage of the network was drastically reduced, due to a loss of funding. Since then, however, it has been possible to expand the coverage of the network with additional stations and to slowly upgrade network equipment to match contemporary instrument standards. These improvements will make it possible to keep recording the network’s data and to initiate real-time exchange of data with other institutions to improve earthquake monitoring throughout New Mexico and neighboring states. During more than 40 yr of operation, the network has provided a slow but steady increase in the volume of earthquake seismograms available to study seismicity and tectonics in north-central New Mexico. The current network covers an area from the Valles Caldera on the west, to within the Rio Grande rift on the east. LASN has yielded locations for about 900 earthquakes in north-central New Mexico between 1973 and 2013 (the most recent locations available). Epicenters of these have a complex pattern, with some that can be attributed to the deformation of the rift, though most are spread in areas west of the rift. A lack of seismicity in and near the Valles Caldera reinforces an earlier observation, based on far fewer earthquakes, which first called attention to this paucity of seismicity and attributed it to ductile deformation resulting from elevated crustal temperatures.

58 GEOSCIENCES↗

Central and Eastern United States (CEUS) Seismic Source Characterization (SSC) for Nuclear Facilities Project

This report describes a new seismic source characterization (SSC) model for the Central and Eastern United States (CEUS). It will replace the Seismic Hazard Methodology for the Central and Eastern United States, EPRI Report NP-4726 (July 1986) and the Seismic Hazard Characterization of 69 Nuclear Plant Sites East of the Rocky Mountains, Lawrence Livermore National Laboratory Model, (Bernreuter et al., 1989). The objective of the CEUS SSC Project is to develop a new seismic source model for the CEUS using a Senior Seismic Hazard Analysis Committee (SSHAC) Level 3 assessment process. The goal of the SSHAC process is to represent the center, body, and range of technically defensible interpretations of the available data, models, and methods. Input to a probabilistic seismic hazard analysis (PSHA) consists of both seismic source characterization and ground motion characterization. These two components are used to calculate probabilistic hazard results (or seismic hazard curves) at a particular site. This report provides a new seismic source model.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗