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At least 487 records · Page 27

Measuring Zeolite Thermal Conductivity for Carbon Dioxide Adsorption Systems

The Carbon Dioxide Removal Assembly (CDRA) currently aboard the International Space Station (ISS) is a critical component of the air revitalization system in the Environmental Control and Life Support System (ECLSS). The CDRA operates by employing a zeolite material that adsorbs carbon dioxide (CO 2 ) from the cabin air and desorbs it downstream from the cabin for further processing, ensuring CO 2 levels at 2 mmHg 1 . The low thermal conductivity of zeolite reduces the heating rate of the temperature swing cycle and increases power requirements.

multifunctional sorbent↗

Maintaining Adequate Carbon Dioxide Washout for an Advanced Extravehicular Mobility Unit

Over the past several years, NASA has realized tremendous progress in technology development that is aimed at the production of an Advanced Extravehicular Mobility Unit (AEMU). Of the many functions provided by the spacesuit and portable life support subsystem within the AEMU, delivering breathing gas to the astronaut along with removing the carbon dioxide (CO2) remains one of the most important environmental functions that the AEMU can control. Carbon dioxide washout is the capability of the ventilation flow in the spacesuit helmet to provide low concentrations of CO2 to the crew member to meet breathing requirements. CO2 washout performance is a critical parameter needed to ensure proper and sufficient designs in a spacesuit and in vehicle applications such as sleep stations and hygiene compartments. Human testing to fully evaluate and validate CO2 washout performance is necessary but also expensive due to the levied safety requirements. Moreover, correlation of math models becomes challenging because of human variability and movement. To supplement human CO2 washout testing, a breathing capability will be integrated into a suited manikin test apparatus to provide a safe, lower cost, stable, easily modeled alternative to human testing. Additionally, this configuration provides NASA Johnson Space Center (JSC) the capability to evaluate CO2 washout under off-nominal conditions that would otherwise be unsafe for human testing or difficult due to fatigue of a test subject. Testing has been under way in-house at JSC and analysis has been initiated to evaluate whether the technology provides sufficient performance in ensuring that the CO2 is removed sufficiently and the ventilation flow is adequate for maintaining CO2 washout in the AEMU spacesuit helmet of the crew member during an extravehicular activity. This paper will review recent CO2 washout testing and analysis activities, testing planned in-house with a spacesuit simulator, and the associated analytical work along with insights from the medical aspect on the testing.

Chullen, Cinda↗

CO2 Removal and Atmosphere Revitalization Systems for Next Generation Space Flight

Removal of metabolic CO2 from breathing air is a vital process for life support in all crewed space missions. A CO2 removal processor called the Low Power CO2 Removal (LPCOR) system is being developed in the Bioengineering Branch at NASA Ames Research Center. LPCOR utilizes advanced adsorption and membrane gas separation processes to achieve substantial power and mass reduction when compared to the state-of-the-art carbon dioxide removal assembly (CORA) of the US segment of the International Space Station (ISS). LPCOR is an attractive alternative for use in commercial spacecraft for short-duration missions and can easily be adapted for closed-loop life support applications. NASA envisions a next-generation closed-loop atmosphere revitalization system that integrates advanced CO2 removal, O2 recovery, and trace contaminant control processes to improve overall system efficiency. LPCOR will serve as the front end to such a system. LPCOR is a reliable air revitalization technology that can serve both the near-term and long-term human space flight needs of NASA and its commercial partners.

Luna, Bernadette↗

CDRA-4EU Testing in Support of ISS

NASA's Marshall Space Flight Center (MSFC) recently conducted tests on two desiccant beds of the four-bed molecular sieve carbon dioxide removal assembly (CDRA) returned from the International Space Station (ISS). MSFC had previously characterized the relationship between CDRA-4EU inlet conditions and the dewpoint at the desiccant bed exit and between the compressor and accumulator that make up the Carbon Dioxide Management Assembly (CDMA). MSFC installed the flight desiccant beds into the existing Exploration Test Chamber (E-chamber) using a suite of instrumentation not available on orbit to investigate the orbital performance of the desiccant beds. Test objectives, facility design and test results are presented.

Peters, Warren↗

Membranes for gas separation

Membranes, methods of making the membranes, and methods of using the membranes are described herein. The membranes can comprise a support layer, and a selective polymer layer disposed on the support layer. The selective polymer layer can comprise a selective polymer matrix and carbon nanotubes dispersed within the selective polymer matrix. The carbon nanotubes can comprise multi-walled carbon nanotubes wrapped in a hydrophilic polymer, such as polyvinylpyrrolidone or a copolymer thereof, such as poly(1-vinylpyrrolidone-co-vinyl acetate). The membranes can exhibit selective permeability to gases. As such, the membranes can be for the selective removal of carbon dioxide and/or hydrogen sulfide from hydrogen and/or nitrogen.

Ho, W. S. Winston↗

Impact of UV-induced ozone and low-energy Ar + -ion cleaning on the chemical structure of Cu(In,Ga)(S,Se) 2 absorber surfaces

Dry buffer layer deposition techniques for chalcopyrite (CIGSSe)-based thin-film solar cells lack the surface-cleaning characteristics of the commonly used CdS or Zn(O,S) wet-chemical bath deposition. Here, a UV-induced ozone and/or a low-energy Ar + -ion treatment could provide dry CIGSSe surface cleaning steps. To study the impact of these treatments, the chemical surface structure of a CIGSSe absorber is investigated. For this purpose, a set of surface-sensitive spectroscopic methods, i.e., laboratory-based x-ray photoelectron spectroscopy and x-ray-excited Auger electron spectroscopy, is combined with synchrotron-based soft x-ray emission spectroscopy. After treatment times as short as 15 s, the UV-induced ozone treatment decreases the amount of carbon adsorbates at the CIGSSe surface significantly, while the oxygen content increases. This is accompanied by the oxidation of all absorber surface elements, i.e., indium, selenium, sulfur, and copper. Short (60 s) low-energy Ar + -ion treatments, in contrast, primarily remove oxygen from the surface. Longer treatment times also lead to a removal of carbon, while extremely long treatment times can also lead to additional (likely metallic) Cu phases at the absorber surface as well.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Automated Reflectance Measurement System Designed and Fabricated to Determine the Limits of Atomic Oxygen Treatment of Art Through Contrast Optimization

Atomic oxygen generated in ground-based research facilities has been used to not only test erosion of candidate spacecraft materials but as a noncontact technique for removing organic deposits from the surfaces of artwork. NASA has patented the use of atomic oxygen to remove carbon-based soot contamination from fire-damaged artwork. The process of cleaning soot-damaged paintings with atomic oxygen requires exposures for variable lengths of time, dependent on the condition of a painting. Care must be exercised while cleaning to prevent the removal of pigment. The cleaning process must be stopped as soon as visual inspection or surface reflectance measurements indicate that cleaning is complete. Both techniques rely on optical comparisons of known bright locations against known dark locations on the artwork being cleaned. Difficulties arise with these techniques when either a known bright or dark location cannot be determined readily. Furthermore, dark locations will lighten with excessive exposure to atomic oxygen. Therefore, an automated test instrument to quantitatively characterize cleaning progression was designed and developed at the NASA Glenn Research Center at Lewis Field to determine when atomic oxygen cleaning is complete.

Sechkar, Edward A.↗

Connecting mechanical properties to hydrogen defects in PAN-based carbon fibers

Atomic-level defects dictate the mechanical properties of carbon fibers and strong correlations have been established between the crystallite sizes and mechanical properties. We recently demonstrated similar correlations with hydrogen content, but reliably quantifying the hydrogen content is not possible using only inelastic neutron scattering experiments. Here, we present prompt-gamma activation analysis (PGAA) experiments collected on 20 commercially available carbon fibers to quantify the hydrogen content of carbon fibers and find correlations between fiber modulus and hydrogen content. We then evaluate the role of hydrogen defect type and connect the PGAA results to both newly acquired and recently reported inelastic neutron scattering experiments. In conclusion, we find that intercalated hydrogen defects are preferentially removed at carbonization temperatures required for high-modulus fibers, potentially giving rise to voids within the carbon fibers that undermine their tensile strength.

36 MATERIALS SCIENCE↗

Sabatier Engineering Development Unit

To facilitate life support system loop closure on board the International Space Station (ISS), the Node 3 Oxygen Generation System (OGS) rack contains a functional scar to accommodate a carbon dioxide reduction assembly (CRA). As part of the effort to better understand and define the functional scar, significant risk mitigation activities have been performed. To address integration risks, a CRA Engineering Development Unit (EDU) has been developed that is functionally equivalent to a flight CRA and is suitable for integrating with ground based carbon dioxide removal and oxygen generation systems. The CRA EDU has been designed to be functionally equivalent to the Sabatier Reactor Subsystem (SRS) portion of the CRA. The design of the CRA EDU and testing results in a stand alone configuration with simulated OGA and CDRA interfaces are reported. Carbon dioxide flow control is a major area requiring development since the size of the CO2 accumulator may result in periods of CRA starvation. The capability of the CO2 flow control algorithm to effectively manage integrated CRA operations is discussed.

Perry, Jay↗

Application of Vacuum Swing Adsorption for Carbon Dioxide and Water Vapor Removal from Manned Spacecraft Atmospheres

In NASA's Vision for Space Exploration (Bush, 2004), (Griffin, 2007), humans will once again travel beyond the confines of earth's gravity, this time to remain there for extended periods. These forays will place unprecedented demands on launch systems. They must not only blast out of earth's gravity well as during the Apollo moon missions, but also liftoff the supplies needed to sustain a larger crew over much longer periods. Thus all spacecraft systems, including those for the separation of metabolic carbon dioxide and water from a crewed vehicle, must be minimized with respect to mass, power, and volume. Emphasis is also placed on system robustness both to minimize replacement parts and ensure crew safety when a quick return to earth is not possible. For short-term phases of manned space exploration, such as transit from the earth to the moon, venting of metabolic carbon dioxide and water to space is more efficient than the inclusion of large recycling systems on the spacecraft. The baseline system for the Orion spacecraft is an amine-based vacuum swing system (Smith, Perry et aI., 2006). As part of the development of an alternative approach, a sorbent-based CO2 and H2O removal system (Knox, Adams et aI., 2006), subscale testing was conducted to evaluate potential performance improvements obtainable by recuperating the heat of adsorption to aid in vacuum desorption. This bed design is shown in Figure 1, is depicted here with a lattice structure instead of reticulated foam for heat transfer. The slot widths are approximately 1.2 mm wide and 8.5 mm long. Bed depth is approximately 4.7 mm. Headers (not shown) were produced by the stereo lithography apparatus at MSFC.

Knox, J.↗

AmeriFlux US-GL1 Stannard Rock

This is the AmeriFlux version of the carbon flux data for the site US-GL1 Stannard Rock. Site Description - Stannard Rock is located 39 km from the nearest shore (Keweenaw Peninsula) in Lake Superior, 44 miles NNE of Marquette, Michigan, and 24 miles ESE of Manitou Island. The site is located on the historic Stannard Rock Lighthouse, which was completed in 1882. Eddy covariance instrumentation was installed in 2008 by a network of scientists from both US and Canada, eventually to be called the Great Lakes Evaporation Network (GLEN). The intent of GLEN has been to provide observations of over-lake meteorology and evaporation, improve forecasting of Great Lakes water levels, and support a wide variety of stakeholders, including the National Weather Service (NWS), Environment and Climate Change Canada, National Oceanic and Atmospheric Administration, U.S. Coast Guard, recreational boaters and commercial shipping, emergency management officials, and the Great Lakes research community. The eddy covariance station along with other ancillary meteorological instrumentation is located at an approximate elevation of 39.2 meters above mean lake water level. Meteorological data from the lighthouse are sent to the National Data Buoy Center, where they can be viewed in real-time at http://www.ndbc.noaa.gov/station_page.php?station=stdm4 Uncorrected half-hour fluxes were computed directly on the logger using a 30-minute block averaging period as high-frequency data were not available. The half hour flux measurements downloaded from the datalogger were post-processed with the following filters and corrections. Latent and sensible heat and carbon dioxide fluxes were corrected with 2-D coordinate rotation. Although the primary objective of data collection at Stannard Rock was to quantify the evaporative flux, additional preliminary measurements of the carbon dioxide concentration and flux from the LI-7500 are also included in this dataset but it is advised to use the carbon data with caution. Carbon data reported in this dataset includes turbulent fluxes of CO2 with no storage correction (FC, µmol m-2 s-1) and CO2 density in mole fraction of wet air (CO2), which was originally output on the datalogger as average CO2 density (mg m-2 s-1) and converted into µmol mol-1 using air temperature and pressure in post-processing. Webb, Pearman, and Leuning terms were applied to account for density fluctuations for water vapor and CO2. Sonic path length, high-frequency attenuation and sensor separation were accounted for according to Horst and Massman, and the oxygen absorption correction for the KH2O hygrometer was also applied. Latent and sensible heat fluxes were assumed to be unrealistic above an absolute value of 1000 W m-2 and were removed. Both carbon flux (FC) and carbon dioxide mole fraction in wet air (CO2) and were assumed to be unrealistic above 1000 µmol m-2 s-1 and 1000 µmol mol-1 respectively. Spikes in latent and sensible heat and carbon fluxes and densities (often due to periods of precipitation) were identified by computing the mean and standard deviation over a moving, overlapping window of 336 half-hours (7 days), similar to Shao et al., and were removed when the flux was more than 1.5 standard deviations from the moving window’s mean. While Vickers and Mahrt use a threshold of 3.5 standard deviations from the mean, a conservative value of 1.5 was chosen due to the noisy nature of over-lake data at this particular site. This process was repeated twice for latent and sensible heat, and carbon dioxide fluxes and densities and therefore it is possible that some real, realistic data was filtered out in this process. No detrending was performed. As per AmeriFlux standards, no friction velocity (USTAR, m s-1) filtering was performed.

Spence, Chris↗

AmeriFlux FLUXNET-1F US-GL1 Stannard Rock

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-GL1 Stannard Rock. This is the FLUXNET version of the carbon flux data for the site US-GL1 Stannard Rock produced by applying the standard ONEFlux (1F) software. Site Description - Stannard Rock is located 39 km from the nearest shore (Keweenaw Peninsula) in Lake Superior, 44 miles NNE of Marquette, Michigan, and 24 miles ESE of Manitou Island. The site is located on the historic Stannard Rock Lighthouse, which was completed in 1882. Eddy covariance instrumentation was installed in 2008 by a network of scientists from both US and Canada, eventually to be called the Great Lakes Evaporation Network (GLEN). The intent of GLEN has been to provide observations of over-lake meteorology and evaporation, improve forecasting of Great Lakes water levels, and support a wide variety of stakeholders, including the National Weather Service (NWS), Environment and Climate Change Canada, National Oceanic and Atmospheric Administration, U.S. Coast Guard, recreational boaters and commercial shipping, emergency management officials, and the Great Lakes research community. The eddy covariance station along with other ancillary meteorological instrumentation is located at an approximate elevation of 39.2 meters above mean lake water level. Meteorological data from the lighthouse are sent to the National Data Buoy Center, where they can be viewed in real-time at http://www.ndbc.noaa.gov/station_page.php?station=stdm4 Uncorrected half-hour fluxes were computed directly on the logger using a 30-minute block averaging period as high-frequency data were not available. The half hour flux measurements downloaded from the datalogger were post-processed with the following filters and corrections. Latent and sensible heat and carbon dioxide fluxes were corrected with 2-D coordinate rotation. Although the primary objective of data collection at Stannard Rock was to quantify the evaporative flux, additional preliminary measurements of the carbon dioxide concentration and flux from the LI-7500 are also included in this dataset but it is advised to use the carbon data with caution. Carbon data reported in this dataset includes turbulent fluxes of CO2 with no storage correction (FC, µmol m-2 s-1) and CO2 density in mole fraction of wet air (CO2), which was originally output on the datalogger as average CO2 density (mg m-2 s-1) and converted into µmol mol-1 using air temperature and pressure in post-processing. Webb, Pearman, and Leuning terms were applied to account for density fluctuations for water vapor and CO2. Sonic path length, high-frequency attenuation and sensor separation were accounted for according to Horst and Massman, and the oxygen absorption correction for the KH2O hygrometer was also applied. Latent and sensible heat fluxes were assumed to be unrealistic above an absolute value of 1000 W m-2 and were removed. Both carbon flux (FC) and carbon dioxide mole fraction in wet air (CO2) and were assumed to be unrealistic above 1000 µmol m-2 s-1 and 1000 µmol mol-1 respectively. Spikes in latent and sensible heat and carbon fluxes and densities (often due to periods of precipitation) were identified by computing the mean and standard deviation over a moving, overlapping window of 336 half-hours (7 days), similar to Shao et al., and were removed when the flux was more than 1.5 standard deviations from the moving window’s mean. While Vickers and Mahrt use a threshold of 3.5 standard deviations from the mean, a conservative value of 1.5 was chosen due to the noisy nature of over-lake data at this particular site. This process was repeated twice for latent and sensible heat, and carbon dioxide fluxes and densities and therefore it is possible that some real, realistic data was filtered out in this process. No detrending was performed. As per AmeriFlux standards, no friction velocity (USTAR, m s-1) filtering was performed.

Spence, Chris [Environment and Climate Change Cana↗

Environmental control/life support

It is pointed out that the life support systems technology used on projects Mercury, Gemini, Apollo, and Space Shuttle required an employment of expendables. Skylab was the only manned space project which made use of regenerable life support technology, taking into account the employment of a silica gel/molecular sieve for carbon dioxide removal. A number of investigations indicate that significant launch weight and volume as well as recurring cost savings can be realized by using regenerative life support processes for a Space Station. A number of developed regenerative processes are believed to be applicable to a Space Station. Aspects of air revitalization are discussed, taking into account carbon dioxide reduction, oxygen generation, trace contaminant control, temperature and humidity control, instrumentation, and nitrogen supply. Attention is also given to water reclamation, solid waste treatment, and future development and testing programs.

Quattrone, P. D.↗

CDRA-4EU Testing to Assess Increased Number of ISS Crew

The International Space Station (ISS) program is investigating methods to increase carbon dioxide (CO2) removal on ISS in order to support an increased number of astronauts at a future date. The Carbon Dioxide Removal Assembly - Engineering Unit (CDRA-4EU) system at NASA Marshall Space Flight Center (MSFC) was tested at maximum fan settings to evaluate CO2 removal rate and power consumption at those settings.

Peters, Warren T.↗

CRADA Number NFE-22-09333 with Holocene Climate Corporation (CRADA Final Report:)

Holocene Climate Corporation has developed and scaled up a novel technology for Direct Air Capture (DAC) that is based on cutting-edge research initiated at Oak Ridge National Laboratory (ORNL). According to the IPCC, carbon dioxide capture from the air and its sequestration are necessary to keep global temperature rise below 1.5°C by 2050. DAC is a viable and practical way to reach this goal. DAC can happen anywhere in the world, takes up a fraction of the land of forests, and along with the sequestration of CO 2 , provides permanent and verifiable removal of carbon from the atmosphere. The proposed project aimed to facilitate knowledge transfer from ORNL to Holocene focusing on (i) the synthesis of the ORNL patented material which builds the cornerstone of the DAC technology, and (ii) required analytical methods needed to conduct crystallization bench-scale experimentation and technology development. Furthermore, ORNL conducted research centered around CO 2 absorption using an air-liquid contacting structure with an aqueous amino acid solution. The achievements under this project comprise successful knowledge transfer from ORNL to the entire Holocene team to jump-start their internal R&D and technological development activities.

54 ENVIRONMENTAL SCIENCES↗

Computer Simulation and Modeling of CO2 Removal Systems for Exploration 2013-2014

The Atmosphere Revitalization Recovery and Environmental Monitoring (ARREM) project was initiated in September of 2011 as part of the Advanced Exploration Systems (AES) program. Under the ARREM project and the follow-on Life Support Systems (LSS) project, testing of sub-scale and full-scale systems has been combined with multiphysics computer simulations for evaluation and optimization of subsystem approaches. In particular, this paper will describes the testing and 1-D modeling of the combined water desiccant and carbon dioxide sorbent subsystems of the carbon dioxide removal assembly (CDRA). The goal is a full system predictive model of CDRA to guide system optimization and development.

Coker, R.↗

Reliability Growth in Space Life Support Systems

A hardware system's failure rate often increases over time due to wear and aging, but not always. Some systems instead show reliability growth, a decreasing failure rate with time, due to effective failure analysis and remedial hardware upgrades. Reliability grows when failure causes are removed by improved design. A mathematical reliability growth model allows the reliability growth rate to be computed from the failure data. The space shuttle was extensively maintained, refurbished, and upgraded after each flight and it experienced significant reliability growth during its operational life. In contrast, the International Space Station (ISS) is much more difficult to maintain and upgrade and its failure rate has been constant over time. The ISS Carbon Dioxide Removal Assembly (CDRA) reliability has slightly decreased. Failures on ISS and with the ISS CDRA continue to be a challenge.

life support↗

Carbon-14 activities in recently fallen meteorites and Antarctic meteorites

This paper reports C-14 measurements in meteorites using an extraction method which employs RF melting of samples as small as 0.1 g. A study of extraction of cosmic-ray-produced C-14 in samples of Bruderheim gave C-14 levels between 38 and 60 dpm/kg for samples which had been preheated in air between 250 and 700 C, with a mean value of 46.8 + or - 1.4 dpm/kg. A range of values between 35 and 59 dpm/kg was found for other falls of saturated meteorites preheated to 500 C. The preheating step is shown to be effective in removing terrestrial carbon contamination. A series of samples previously dated by Kr-81 as having ages of 120-310 kyr gave C-14 levels of between less than 0.16 and 0.37 + or - 0.10 dpm/kg. These levels are consistent with levels of in situ production by cosmic rays at the earth's surface.

Jull, A. J. T.↗