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At least 487 records · Page 27

Qualification tests and electrical measurements: Practice and problems

As part of the Flat-Plate Solar Array Project, 138 different module designs were subjected to qualification tests. Electrical measurements were subjected on well over a thousand modules representing more than 150 designs. From this experience, conclusions are drawn regarding results and problems, with discussion of the need for change or improvement. The qualification test sequence incuded application of environmental and electrical stresses to the module. With few exceptions, the tests have revealed defects necessitation of environmental and electrical stresses to the module. With few exceptions, the tests have revealed defects necessitating module design or process changes. However, the continued need for these tests may be questioned on the basis of technical and logistical factors. Technically, the current test sequence does not cover all design characteristics, does not include all field conditions and is not known to represent the desired 30-year module life. Logistically, the tests are time-consuming and costly, and there is a lack of, fully qualified independent test organizations. Alternatives to the current test program include simplification based on design specification and site environment, and/or the use of warranties or other commercial practices.

Smokler, M. I.↗

Graph Neural Networks for low-energy event classification & reconstruction in IceCube

IceCube, a cubic-kilometer array of optical sensors built to detect atmospheric and astrophysical neutrinos between 1 GeV and 1 PeV, is deployed 1.45 km to 2.45 km below the surface of the ice sheet at the South Pole. The classification and reconstruction of events from the in-ice detectors play a central role in the analysis of data from IceCube. Reconstructing and classifying events is a challenge due to the irregular detector geometry, inhomogeneous scattering and absorption of light in the ice and, below 100 GeV, the relatively low number of signal photons produced per event. To address this challenge, it is possible to represent IceCube events as point cloud graphs and use a Graph Neural Network (GNN) as the classification and reconstruction method. The GNN is capable of distinguishing neutrino events from cosmic-ray backgrounds, classifying different neutrino event types, and reconstructing the deposited energy, direction and interaction vertex. Based on simulation, we provide a comparison in the 1 GeV–100 GeV energy range to the current state-of-the-art maximum likelihood techniques used in current IceCube analyses, including the effects of known systematic uncertainties. For neutrino event classification, the GNN increases the signal efficiency by 18% at a fixed background rate, compared to current IceCube methods. Alternatively, the GNN offers a reduction of the background (i.e. false positive) rate by over a factor 8 (to below half a percent) at a fixed signal efficiency. For the reconstruction of energy, direction, and interaction vertex, the resolution improves by an average of 13%–20% compared to current maximum likelihood techniques in the energy range of 1 GeV–30 GeV. The GNN, when run on a GPU, is capable of processing IceCube events at a rate nearly double of the median IceCube trigger rate of 2.7 kHz, which opens the possibility of using low energy neutrinos in online searches for transient events.

47 OTHER INSTRUMENTATION↗

A Multi-Purpose Modular Electronics Integration Node for Exploration Extravehicular Activity

As NASA works to develop an effective integrated portable life support system design for exploration Extravehicular activity (EVA), alternatives to the current system s electrical power and control architecture are needed to support new requirements for flexibility, maintainability, reliability, and reduced mass and volume. Experience with the current Extravehicular Mobility Unit (EMU) has demonstrated that the current architecture, based in a central power supply, monitoring and control unit, with dedicated analog wiring harness connections to active components in the system has a significant impact on system packaging and seriously constrains design flexibility in adapting to component obsolescence and changing system needs over time. An alternative architecture based in the use of a digital data bus offers possible wiring harness and system power savings, but risks significant penalties in component complexity and cost. A hybrid architecture that relies on a set of electronic and power interface nodes serving functional models within the Portable Life Support System (PLSS) is proposed to minimize both packaging and component level penalties. A common interface node hardware design can further reduce penalties by reducing the nonrecurring development costs, making miniaturization more practical, maximizing opportunities for maturation and reliability growth, providing enhanced fault tolerance, and providing stable design interfaces for system components and a central control. Adaptation to varying specific module requirements can be achieved with modest changes in firmware code within the module. A preliminary design effort has developed a common set of hardware interface requirements and functional capabilities for such a node based on anticipated modules comprising an exploration PLSS, and a prototype node has been designed assembled, programmed, and tested. One instance of such a node has been adapted to support testing the swingbed carbon dioxide and humidity control element in NASA s advanced PLSS 2.0 test article. This paper will describe the common interface node design concept, results of the prototype development and test effort, and plans for use in NASA PLSS 2.0 integrated tests.

Hodgson, Edward↗

Development of a High-Fidelity Simulation Environment for Shadow-Mode Assessments of Air Traffic Concepts

This paper describes the Shadow-Mode Assessment Using Realistic Technologies for the National Airspace System (SMART-NAS) Test Bed. The SMART-NAS Test Bed is an air traffic simulation platform being developed by the National Aeronautics and Space Administration (NASA). The SMART-NAS Test Bed's core purpose is to conduct high-fidelity, real-time, human-in-the-loop and automation-in-the-loop simulations of current and proposed future air traffic concepts for the United States' Next Generation Air Transportation System called NextGen. The setup, configuration, coordination, and execution of realtime, human-in-the-loop air traffic management simulations are complex, tedious, time intensive, and expensive. The SMART-NAS Test Bed framework is an alternative to the current approach and will provide services throughout the simulation workflow pipeline to help alleviate these shortcomings. The principle concepts to be simulated include advanced gate-to-gate, trajectory-based operations, widespread integration of novel aircraft such as unmanned vehicles, and real-time safety assurance technologies to enable autonomous operations. To make this possible, SNTB will utilize Web-based technologies, cloud resources, and real-time, scalable, communication middleware. This paper describes the SMART-NAS Test Bed's vision, purpose, its concept of use, and the potential benefits, key capabilities, high-level requirements, architecture, software design, and usage.

human-in-the-loop↗

On the Pathways of the Return Flow of the Meridional Overturning Circulation in the Tropical Atlantic

A numerical model of the tropical Atlantic ocean is used to investigate the upper layer pathways of the Meridional Overturning Circulation (MOC) in the tropical Atlantic. The main focus of this thesis is on those parts of the tropical circulation that are thought to be important for the MOC return flow, but whose dynamics have not been understood yet. It is shown how the particular structure of the tropical gyre and the MOO act to inhibit the flow of North Atlantic water into the equatorial thermocline. As a result, the upper layers of the tropical Atlantic are mainly fed by water from the South Atlantic. The processes that carry the South Atlantic water across the tropical Atlantic into the North Atlantic as part of the MOO are described here, and three processes that were hitherto not understood are explained as follows: The North Brazil Current rings are created as the result of the reflection of Rossby waves at the South American coast. These Rossby waves are generated by the barotropically unstable North Equatorial Countercurrent. The deep structure of the rings can be explained by merger of the wave's anticyclones with the deeper intermediate eddies that are generated as the intermediate western boundary current crosses the equator. The bands of strong zonal velocity in intermediate depths along the equator have hitherto been explained as intermediate currents. Here, an alternative interpretation of the observations is offered: The Eulerian mean flow along the equator is negligible and the observations are the signature of strong seasonal Rossby waves. The previous interpretation of the observations can then be explained as aliasing of the tropical wave field. The Tsuchyia Jets are driven by the Eliassen-Palm flux of the tropical instability waves. The equatorial current system with its strong shears is unstable and generates tropical instability waves.

Jochum, Markus↗

Power System Resilience Metrics Augmentation for Critical Load Prioritization

One of the major goals of new grid operation regimes, such as transactive energy systems (TESs), is to make the power grid more resilient to withstand natural or man-made disasters and potential reliability events, and to continue to serve the maximum number of its customers. But it is a well-known fact to system operators that not all customers are the same. This implies that any discussion of TESs’ impacts on the resilience of the power system should consider the needs of its critical customers (such as the power system operation centers, fire and police stations, and hospitals) over those of other customers. When evaluating the resilience of the system, bonus points must be awarded to any system that could maintain its power supply to critical customers during a disturbance that may cause an outage. This report discusses critical infrastructure (CI) as found in the literature and then categorizes it based on the field to which the operations belong (such as human life/safety-related, operations management, necessary city operation, industrial customers, etc.). Each of these CI categories is further divided into types of critical customers (e.g., the human life/safety-related category has different types of customers like hospitals, fire and police stations, etc.). The entire demand of each of the critical customer types is not categorized as critical load (CL); instead, only a portion of the total load of these critical customers is characterized as critical load. This is done based on the categories of equipment, the function of which is crucial in the operation of the overall facility. CL categorization is performed to provide the ratio of the critical load portion to the overall load , so that it can serve as a parameter in the resilience evaluation of the grid through a metrics-based approach. Such categorization is important as it helps to augment the existing quantifiable resilience metrics with CL categorization. The metrics for a power system need to not only consider how well a system performed during a disturbance event, but also how it reduced strain and supplied power to its CLs. The first step in this process is characterize CLs in the system. After CL characterization, the next step is the inclusion of these loads in the resilience metrics. To that end, in this report weight-based augmentation of resilience metrics is proposed, where certain customers (the ones that are categorized as critical) are assigned higher weights than others. Though an overview of assigning weights to customers is discussed, there is no one-size-fits-all approach for every power system. The decisions made about assigning such weights to customers vary greatly from one operator to another, based on their unique systems and the current and predicted states of critical customers. This decision-making can include the type of disturbance event, which might only affect certain parts of the system. In general, analyzing critical customers before an event helps understand system vulnerabilities. It also helps in planning and conducting operations during the event, evaluating system performance after the event, and supporting better planning for future events. An alternative to the current practices of managing the grid for outages is an innovative TES, which has the potential to provide a platform for including distributed energy resources for managing CLs. This report also describes how TES qualities can help (1) to maintain power supply to critical customers for uninterrupted operations and (2) to restore lost power supply to the critical customers rapidly.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Free-electron laser from wave-mechanical beats of 2 electron beams

It is possible, though technically difficult, to produce beams of free electrons that exhibit beats of a quantum mechanical nature. (1) the generation of electromagnetic radiation, e.g., light, based on the fact that the beats give rise to alternating charge and current densities; and a frequency shifter, based on the fact that a beam with beats constitutes a moving grating. When such a grating is exposed to external radiation of suitable frequency and direction, the reflected rediation will be shifted in frequency, since the grating is moving. A twofold increase of the frequency is readily attainable. It is shown that it is impossible to generate radiation, because the alternating electromagnetic fields that accompany the beats cannot reform themselves into freely propagating waves. The frequency shifter is useless as a practical device, because its reflectance is extremely low for realizable beams.

Lichtenstein, R. M.↗

A new code for Galileo

Over the past six to eight years, an extensive research effort was conducted to investigate advanced coding techniques which promised to yield more coding gain than is available with current NASA standard codes. The delay in Galileo's launch due to the temporary suspension of the shuttle program provided the Galileo project with an opportunity to evaluate the possibility of including some version of the advanced codes as a mission enhancement option. A study was initiated last summer to determine if substantial coding gain was feasible for Galileo and, is so, to recommend a suitable experimental code for use as a switchable alternative to the current NASA-standard code. The Galileo experimental code study resulted in the selection of a code with constant length 15 and rate 1/4. The code parameters were chosen to optimize performance within cost and risk constraints consistent with retrofitting the new code into the existing Galileo system design and launch schedule. The particular code was recommended after a very limited search among good codes with the chosen parameters. It will theoretically yield about 1.5 dB enhancement under idealizing assumptions relative to the current NASA-standard code at Galileo's desired bit error rates. This ideal predicted gain includes enough cushion to meet the project's target of at least 1 dB enhancement under real, non-ideal conditions.

Dolinar, S.↗

Custom Equipment Development for Processing of Surplus Plutonium

The Strategic Laboratory Assessment (SLA), a collaborative team of SRNL and ORNL personnel, has been established to advance the objectives of the Surplus Plutonium Disposition (SPD) Project, by identifying and developing technologies to accelerate disposition, reduce life cycle costs, minimize worker radiation exposure, improve worker safety, and minimize Surplus Plutonium Disposition Program risks. [1] The SLA team has identified can cutting and plutonium (Pu) oxide size reduction as two glovebox processes where technology enhancements would be valuable. The DOESTD-3013 package currently in use for Pu downblending requires cutting two nested cans before the inner convenience can that holds the Pu oxide may be accessed for further processing. A rotary tubing-style cutter is used for opening the 3013 packages within the glovebox. Collet changeouts are required between cutting of the outer and inner cans. The SLA team is currently developing and testing an adjustable-clamp can cutter design that eliminates collet changeouts and allows cutting of the outer and inner can at the same time, resulting in significant reduction of radiological dose and process time, as well as improved ergonomics. To meet the Pu oxide particle size requirement, size reduction of Pu oxide agglomerations must be performed within the process gloveboxes. The SLA team has identified jaw crushing technology as an alternative to the currently employed rotary mill. Jaw crusher advantages include reduced dust within the glovebox, increased batch sizes, and easier integration with other glovebox processes due to the flow-through nature of jaw crushing. Commercially manufactured jaw crushers are either too large and/or too heavy for implementation in the SPD gloveboxes, so the SLA team is developing and testing a custom jaw crusher to meet the needs of the SPD Project.

Krementz, Daniel [Savannah River National Laborato↗

Alternative Fuels and Their Potential Impact on Aviation

With a growing gap between the growth rate of petroleum production and demand, and with mounting environmental needs, the aircraft industry is investigating issues related to fuel availability, candidates for alternative fuels, and improved aircraft fuel efficiency. Bio-derived fuels, methanol, ethanol, liquid natural gas, liquid hydrogen, and synthetic fuels are considered in this study for their potential to replace or supplement conventional jet fuels. Most of these fuels present the airplane designers with safety, logistical, and performance challenges. Synthetic fuel made from coal, natural gas, or other hydrocarbon feedstock shows significant promise as a fuel that could be easily integrated into present and future aircraft with little or no modification to current aircraft designs. Alternatives, such as biofuel, and in the longer term hydrogen, have good potential but presently appear to be better suited for use in ground transportation. With the increased use of these fuels, a greater portion of a barrel of crude oil can be used for producing jet fuel because aircraft are not as fuel-flexible as ground vehicles.

Daggett, D.↗

Usage of Data-Encoded Web Maps with Client Side Color Rendering for Combined Data Access, Visualization and Modeling Purposes

Current approaches to satellite observation data storage and distribution implement separate visualization and data access methodologies which often leads to the need in time consuming data ordering and coding for applications requiring both visual representation as well as data handling and modeling capabilities. We describe an approach we implemented for a data-encoded web map service based on storing numerical data within server map tiles and subsequent client side data manipulation and map color rendering. The approach relies on storing data using the lossless compression Portable Network Graphics (PNG) image data format which is natively supported by web-browsers allowing on-the-fly browser rendering and modification of the map tiles. The method is easy to implement using existing software libraries and has the advantage of easy client side map color modifications, as well as spatial subsetting with physical parameter range filtering. This method is demonstrated for the ASTER-GDEM elevation model and selected MODIS data products and represents an alternative to the currently used storage and data access methods. One additional benefit includes providing multiple levels of averaging due to the need in generating map tiles at varying resolutions for various map magnification levels. We suggest that such merged data and mapping approach may be a viable alternative to existing static storage and data access methods for a wide array of combined simulation, data access and visualization purposes.

Pliutau, Denis↗

A Formally Verified Floating-Point Implementation of the Compact Position Reporting Algorithm

The Automatic Dependent Surveillance-Broadcast (ADS-B) system allows aircraft to communicate their current state, including position and velocity information, to other aircraft in their vicinity and to ground stations. The Compact Position Reporting (CPR) algorithm is the ADS-B module responsible for the encoding and decoding of aircraft positions. CPR is highly sensitive to computer arithmetic since it heavily relies on functions that are intrinsically unstable such as floor and modulo. In this paper, a formally-verified double-precision floating-point implementation of the CPR algorithm is presented. The verification proceeds in three steps. First, an alternative version of CPR, which reduces the floating-point rounding error is proposed. Then, the Prototype Verification System (PVS) is used to formally prove that the ideal real-number counterpart of the improved algorithm is mathematically equivalent to the standard CPR definition. Finally, the static analyzer Frama-C is used to verify that the double-precision implementation of the improved algorithm is correct with respect to its operational requirement. The alternative algorithm is currently being considered for inclusion in the revised version of the ADS-B standards document as the reference implementation of the CPR algorithm.

Laura Titolo↗

Improvements to the Ionizing Radiation Risk Assessment Program for NASA Astronauts

To perform dosimetry and risk assessment, NASA collects astronaut ionizing radiation exposure data from space flight, medical imaging and therapy, aviation training activities and prior occupational exposure histories. Career risk of exposure induced death (REID) from radiation is limited to 3 percent at a 95 percent confidence level. The Radiation Health Office at Johnson Space Center (JSC) is implementing a program to integrate the gathering, storage, analysis and reporting of astronaut ionizing radiation dose and risk data and records. This work has several motivations, including more efficient analyses and greater flexibility in testing and adopting new methods for evaluating risks. The foundation for these improvements is a set of software tools called the Astronaut Radiation Exposure Analysis System (AREAS). AREAS is a series of MATLAB(Registered TradeMark)-based dose and risk analysis modules that interface with an enterprise level SQL Server database by means of a secure web service. It communicates with other JSC medical and space weather databases to maintain data integrity and consistency across systems. AREAS is part of a larger NASA Space Medicine effort, the Mission Medical Integration Strategy, with the goal of collecting accurate, high-quality and detailed astronaut health data, and then securely, timely and reliably presenting it to medical support personnel. The modular approach to the AREAS design accommodates past, current, and future sources of data from active and passive detectors, space radiation transport algorithms, computational phantoms and cancer risk models. Revisions of the cancer risk model, new radiation detection equipment and improved anthropomorphic computational phantoms can be incorporated. Notable hardware updates include the Radiation Environment Monitor (which uses Medipix technology to report real-time, on-board dosimetry measurements), an updated Tissue-Equivalent Proportional Counter, and the Southwest Research Institute Radiation Assessment Detector. Also, the University of Florida hybrid phantoms, which are flexible in morphometry and positioning, are being explored as alternatives to the current NASA computational phantoms.

Semones, E. J.↗

From ash to oxides: Recovery of rare-earth elements as a step towards valorization of coal fly ash waste

Coal fly ash (CFA) is both a valuable waste material and a potential source of environmental contamination. The inclusion of metals such as rare-earth elements offer a possible incentive towards waste valorization if the metals can be extracted and recovered in an economical manner. Rare-earth elements (REEs) have many technological applications and are critically important in the manufacture of electric vehicles, communication devices, and industrial magnets. However, the global supply of rare-earth elements has faced shortages and price shocks. Current methods for separating and isolating individual rare-earth elements use large amounts of energy and organic solvents, raising concerns over environmental impacts. These factors have led to the investigation of nontraditional sources and separation techniques for these elements. Here, we describe a column-based system that uses a newly developed ligand-associated organosilica sorbent to concentrate and separate rare-earth elements from fly ash leachate. The fly ash used in this study originally contained 0.024 wt% rare-earth elements and the final oxide powder after enrichment contained > 10 wt% rare-earth elements, which is a enrichment of > 400 times. This process requires no additional organic solvents after the sorbent media has been synthesized, offering an alternative to the current standard using solvent extraction for rare-earth element recovery.

42 ENGINEERING↗

Representative-cell-based Modeling of HTTF in SAM

Although the current nuclear power market is primarily occupied by the light water reactors (LWRs), the TRISO-fueled helium-cooled graphite-moderated high temperature gas reactors (HTGRs) are drawing growing attention as the nuclear power industry marches towards more advanced systems. Compared to that of conventional LWRs, the thermal hydraulics of HTGR cores show extra complexity from their multi-scale heat transfer mechanisms with varying importance during different operation modes or transient stages. The modeling of HTGR cores for the system analysis purpose therefore faces the challenge of reaching reasonable fidelity and accuracy while maintaining sufficient simplicity. Previous development and validation efforts have demonstrated that a “2-D ring model” with reasonable performance can be implemented in the System Analysis Module (SAM) for prismatic HTGR cores. In the current project, an alternative modeling methodology based on “representative cells” is proposed for the typical prismatic core of HTGRs. Different from the previous ring model approach, the proposed methodology first separately models and then combines the small- and large-scale thermal conductions, by connecting representative local heat transfer units (cells) with effective core- wise thermal resistance. A modeling practice for an integral high-temperature test facility (HTTF) elaborates the modeling details. Steady-state validation of the resultant candidate model is performed against a higher-resolution benchmark from a 3D-1D coupled simulation, which shows satisfactory prediction with reasonably captured global parameters and well-represented temperature fields. A postulated pressurized conduction cooldown (PCC) is also simulated and analyzed, demonstrating the model’s capability of transient prediction with physically captured phenomena resolved in both small and large temporal and spatial scales. In general, the current work achieves a preliminary success in proposing a methodology using representative cells to model prismatic HTGR cores in SAM. Future efforts are envisioned with more validation activities and with potential modeling improvements to eventually achieve the high confidence on a high-fidelity robust modeling methodology with reasonable accuracy.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Evaluation of Various Radar Data Quality Control Algorithms Based on Accumulated Radar Rainfall Statistics

The primary function of the TRMM Ground Validation (GV) Program is to create GV rainfall products that provide basic validation of satellite-derived precipitation measurements for select primary sites. A fundamental and extremely important step in creating high-quality GV products is radar data quality control. Quality control (QC) processing of TRMM GV radar data is based on some automated procedures, but the current QC algorithm is not fully operational and requires significant human interaction to assure satisfactory results. Moreover, the TRMM GV QC algorithm, even with continuous manual tuning, still can not completely remove all types of spurious echoes. In an attempt to improve the current operational radar data QC procedures of the TRMM GV effort, an intercomparison of several QC algorithms has been conducted. This presentation will demonstrate how various radar data QC algorithms affect accumulated radar rainfall products. In all, six different QC algorithms will be applied to two months of WSR-88D radar data from Melbourne, Florida. Daily, five-day, and monthly accumulated radar rainfall maps will be produced for each quality-controlled data set. The QC algorithms will be evaluated and compared based on their ability to remove spurious echoes without removing significant precipitation. Strengths and weaknesses of each algorithm will be assessed based on, their abilit to mitigate both erroneous additions and reductions in rainfall accumulation from spurious echo contamination and true precipitation removal, respectively. Contamination from individual spurious echo categories will be quantified to further diagnose the abilities of each radar QC algorithm. Finally, a cost-benefit analysis will be conducted to determine if a more automated QC algorithm is a viable alternative to the current, labor-intensive QC algorithm employed by TRMM GV.

Robinson, Michael↗

Screen-Printed Complex Ag Inks for Si HJT Metallization

Metallization using reactive metal inks has recently attracted significant research interest due to its advantages in cost of materials and manufacturing, while still achieving performance comparable to traditional fire-through particle pastes. Here, we present for the first time the use of reactive silver (Ag) inks via industrial screen-printing and inkjet printing methods for the metallization of different Si surfaces used in tunneling oxide passivating contacts (TOPCon) and Silicon heterojunction (SHJ) solar cells. Printed Ag lines exhibit a conductivity of ~5 Mu O·cm, which is approximately 3 times that of bulk Ag (1.59 µO·cm). The printed metal has a thickness of ~0.5-1.5 Mu m, an order of magnitude smaller than the current fire-through metal finger thickness (~15 Mu m). Contact resistivity measurements of the screen-printed and inkjet-printed samples on a transparent conducting oxide (TCO) surface show a very low value of ~0.2-12 mO·cm 2. Photoluminescence images of the metallized samples demonstrate minimal surface passivation degradation compared to the non-metallized areas (?iVoc <3.5 mV). Scanning electron microscopy images (SEM) reveal the structure of the printed metals on the Si surfaces as porous but much denser than fire-through Ag by nanoparticle paste. In the final presentation, we will showcase our results of printing these reactive Ag inks on high-efficiency heterojunction and TOPCon solar cells with full-area M6 wafers. Additionally, the adhesion of these reactive Ag inks on different Si surfaces according to ASTM D3359-17, as well as the performance of solar cells after standard IEC 61215 freeze/thaw and damp heat tests, will be presented. These new metal inks show promising potential as an alternative to the currently dominant particle-based pastes, offering lower Ag consumption and lower processing temperatures without compromising performance.

heterojunction solar cells↗

Development of Next Generation Hierarchical Hybrid Cu-Si anode Batteries via Direct-Ink Writing Application: End of (6th) Month Report - November 2025

Sustainable renewable energy continues to be in dire need to effectively combat global warming. Emerging technology for electric vehicles/ devices remains in high demand that is not only lower in cost, more efficient, but safer in comparison to commercial materials on the market. Although first-generation lithium-ion batteries have exhibited extensive commercial application, conventional graphite no longer meets this increasing demand as an efficient anode material. Due to the fact that graphite has a subpar theoretical specific capacity (372 mAh g -1 ), thus significant limitations in rate capability (for potential faster charging at higher C-rates currently commercially available.). Alternatively, silicon has gained significant attention as a superior candidate to potentially surpass graphite. Due to silicon’s exceedingly high theoretical capacity (4,200 mAh g -1 ) in comparison to standard graphite, its abundance thus in turn it’s low-cost, in addition to exhibiting a significantly low working potential (< 0.4 V vs Li/Li + ). However, one of the main (and most detrimental) challenges is silicon’s tendency to expand in volume (> 300%) upon discharge as it begins the lithiation process. As a direct result, it causes not only for the particles to both crack and pulverize under mechanical stress as the volume continues to expand and contract during cycling. Upon assembling the cell, it needs to undergo ‘charging’ for initially discharging/ ‘activating’ the cell, otherwise commonly known as the ‘formation’ step. As a result a solid electrolyte interface (SEI) layer begins to form at the anode surface because some of the electrolyte begins to react during the formation process. However, this (SEI) layer is deemed as a ‘protective’ interlayer because in theory it prevents further reaction as the cell continues to cycle. However, due to the volume change it causes significant degradation at the interface. As cracking starts to occur at the anode surface, it results in a ‘new’ altered surface with each cycle that causes further reaction with the electrolyte as a byproduct quickly consuming active Li/ and more electrolyte. Thus, fracturing this ‘protective layer,’ causing significantly higher impedance as a result, and in turn a decline in capacity due to active Li-loss. In addition to the active material exfoliating off from the current collector, further contributing to the steady decline in capacity and overall performance. Current state of the art Si-anode batteries on the market range between a maximum content of 5-10 Si wt%. It has been previously reported Tesla has utilized SiO x -C anodes containing 5 wt% Si within their ‘Model 3/ Model X’ electric vehicles. However, more recent ‘Model 3’ vehicles have started to incorporate 10 Si wt%, in which they were able to increase their energy density upwards by approximately 30%. Recent effort has been focused on continuing to increase the wt% of Si being utilized, eventually to 100 wt% of Si, to maximize the energy density even further.

36 MATERIALS SCIENCE↗