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At least 487 records · Page 27

Rocket ultraviolet spectroscopy of comet Halley and abundance of carbon monoxide and carbon

Two far ultraviolet observations of comet Halley made on 26 February, 1986 and 13 March, 1986 with a sounding rocket experiment are reported. The observed CO spatial profiles can be modelled by a radial outflow model for a parent molecule and suggest that the CO is produced directly from the nucleus of the comet. Using the observed O I emission profile to deduce the H2O production rate, the abundance of CO relative to H2O is found to be 20 percent + or - 5 percent for the first flight and 17 percent + or - 4 percent for the second flight, making CO the second most abundant parent molecule in the coma. The derived production rate of atomic carbon is consistent with that expected from the photodissociation of carbon monoxide.

Woods, T. N.↗

Optical region elemental abundance analyses of B and A stars. VI - The normal stars HR 6559 (A7 IV) and Eta Leporis (F0 IV)

Abundance analyses using optical region data and fully line-blanketed model atmospheres have been performed for the sharp-lined superficially normal stars HR 6559 (A7 IV) and Eta Leporis (F0 IV), consistent with previous studies of middle B through early A type stars. HR 6559 and Eta Lep are slightly metal-weak in general. Their analyses and that of Theta Leo (A2 V) support the suggestion of Smith (1974) that sharp-lined normal A stars do not necessarily have photospheric abundances identical with those of normal middle to late B stars.

Adelman, S. J.↗

Quantitative abundance estimates from bidirectional reflectance measurements

A simplified approach for estimating mineral abundances in mineral mixtures from bidirectional reflectance measurements is presented. Fundamental to this approach is a priori information concerning reflectance spectra of the individual minerals and an estimate of the particle sizes of the components. Simplified equations for bidirectional reflectance are used to linearize the systematics of spectral mixing. The method was used to determine the relative proportions of olivine, magnetite, enstatite, and anorthite in a mixture; the mass fractions of mixture components were calculated on the basis of known particle diameters. The results indicate that for materials without strongly adsorbing components, the accuracy of abundance determinations is better than 5 percent.

Mustard, John F.↗

Al-26, Pu-244, Ti-50, REE, and trace element abundances in hibonite grains from CM and CV meteorites

Hibonites from the CM meteorites Murchison, Murray, and Cold Bokkeveld, and hibonites and Ti-rich pyroxene from the CV chondrite Allende are studied. Electron microprobe measurements of major element concentrations and track and ion probe measurements of Mg and Ti isotopic ratios, rare earth elements (REEs), and trace element abundances are analyzed. Correlations between isotopic anomalies in Ti, Al-26, Pu-244, and Mg-26(asterisk) are examined. Ti isotopic anomalies are compared with REE and trace element abundance patterns. Reasons for the lack of Al-26 in the hibonites are investigated and discussed. It is observed that there is no correlation between the Ti isotopic compositions, and the presence of Mg-26(asterisk), Pu-244, and REE and trace element patterns in individual hibonite samples. The data reveal that hibonites are not interstellar dust grains but formed on a short time scale and in localized regions of the early solar system.

Fahey, A. J.↗

Optical region elemental abundance analyses of B and A stars. VII - The metallic-lined star 32 Aquarii

An abundance analysis using photographic region spectrograms and fully line-blanketed model atmospheres has been performed for the metallic-lined (Am) star 32 Aquarii consistent with previous papers of this series. Its pattern of abundance anomalies is not identical with those of the hot Am stars although there are definite similarities. Changes of up to order 1 dex are foundly by comparison with the previous analysis by Smith. Slightly better agreement is found with the recent analyses of singly-ionized rare earth lines by Magazzu and Cowley. Results are also presented for a model selected on the basis of photometric indices according to the formula of Moon and Dworetsky.

Kocer, D.↗

Element abundances in the interstellar atomic material

In the interstellar medium, a significant fraction of the free atoms for elements heavier than helium must have condensed into solids, in the form of small, interstellar dust grains. Observations of optical and ultraviolet absorption lines in the spectra of hot stars indicate that the depletions below the cosmic abundances of various elements range from almost none at all to a factor of 0.0001 and seem to be enhanced along lines of sight with higher mean density. Other methods of measuring abundances confirm the absorption line results. The available evidence supports the notion that the grains form in both the atmospheres of cool stars and in dense interstellar clouds, and they are destroyed by shocks which frequently pass through the low density gas.

Jenkins, Edward B.↗

Chemical abundances in molecular clouds

At present approximately 70 interstellar molecules are known. The paper discusses methods for determining chemical abundances in interstellar clouds and presents results for the best studied regions, which include the 'spiral arm' clouds seen towards distant continuum sources, quiescent dark and giant clouds, and the gas in regions of active star formation. For many simple molecules, abundances are rather uniform over a range of densities and temperatures in quiescent clouds, in accord with gas phase, ion-molecule chemical models. Some striking chemical differences do exist both within and among clouds, however, particularly in star-forming regions.

Irvine, W. M.↗

Elemental abundance analyses with coadded Dominion Astrophysical Observatory spectrograms. II - The mercury-manganese stars 53 Tauri, Mu Leporis and Kappa Cancri

Elemental abundance analyses based on the coaddition of at least 10 2.4 A/mm Ila-O Dominion Astrophysical Observatory spectrograms have been performed for three mercury-manganese stars, 53 Tauri, Mu Leporis, and Kappa Cancri. These fine analyses show a greater degree of internal consistency than previous studies based on lower signal-to-noise data. Lines as weak as of order 3 mA are employed in these studies, and lines of atomic species not previously identified have been discovered. The status of 53 Tau as an anomalous member of this class is confirmed in that it lacks a Hg II 3984 A line even at the 2 mA level. Further, its surface gravity indicates it is less evolved than Mu Lep and Chi Cnc. Violations of the odd-even effect in the photospheric abundances of all three stars suggest that nonnuclear processes have operated in their atmospheres. Some of the values are substantially changed from their presumably initial solar values.

Adelman, Saul J.↗

Cosmic-ray elemental abundances from 1 to 10 GeV per amu for boron through nickel

The relative abundances of cosmic-ray nuclei in the charge range boron through nickel over the energy range 1-10 GeV per amu were measured with a balloon-borne detector. The instrument consists of a scintillation and Cerenkov counter telescope with a multiwire proportional chamber hodoscope and has been flown in four high-altitude balloon flights. Good charge resolution (sigma = 0.2 charge units at iron) and high statistical accuracy have been achieved. These data are used to derive the energy dependence of the leakage path length using the leaky box model of propagation and confinement in the galaxy. This energy dependence is found to be best fit by lambda = E(tot) exp -n, where n = 0.49 + or - 0.06 over 1-10 GeV per amu. Relative abundances at the source are consistent with an energy-independent composition.

Dwyer, Robert↗

Chemical constraints on the water and total oxygen abundances in the deep atmosphere of Jupiter

The mechanisms responsible for the observed H2O/H2 mixing ratio (HMR) in the Jovian troposphere are analyzed, with a focus on the relationship between HMR and O2 abundance and the abundance of the nonequilibrium trace gases CO and SiH4. The results of computations using a Jupiter atmosphere model consistent with recent observations (Bjoraker et al., 1986) are presented graphically and discussed in detail. It is found that the observed mixing ratios of CO (about 10 to the -9th) and SiH4 (upper limit 2-4 x 10 to the -9th) preclude O2 depletion and the presence of significant global H2O. The low observed HMRs (0.00003 at 6 bar) are tentatively attributed to local condensation in cloud-forming regions.

Fegley, Bruce, Jr.↗

The helium abundance of Uranus from Voyager measurements

Voyager radio-occultation and IR spectroscopy measurements are combined to infer an He mole fraction in the upper troposphere of Uranus of 0.152 + or - 0.033; the corresponding mass fraction is Y = 0.262 + or - 0.048. This value is in agreement with recent estimates of the solar He abundance, suggesting that He differentiation has not occurred on Uranus. Comparisons with values previously obtained for Jupiter and Saturn imply that migration of He toward the core began long ago on Saturn and may also have recently begun on Jupiter. The protosolar He abundance inferred from the Uranus measurements and from recent solar evolutionary models is used along with an assumed primordial He mass fraction of 0.23-0.24 to estimate a 3-4-percent enrichment of He in the interstellar medium between the big bang and the origin of the solar system. The result is in agreement with galactic chemical evolution models which include a substantial decrease in D during the evolutionary process.

Conrath, B.↗

Insensitivity of solar p-mode frequencies to changes in the helium abundance

P-mode oscillation spectra (l = 0-4; n = 12-30) were calculated for three solar models with helium mass fractions Y = 0.230, 0.235, and 0.240. The solar models were tuned to have the Sun's radius and luminosity by adjusting both the age and the ratio of the mixing length to pressure scale height parameter. The models were identically constrained in all other respects. A 4 percent change in the mass fraction of helium produces less than a 0.1 percent change in the frequencies of the low degree p-modes. This result implies that it will be very difficult to determine the helium abundance of the sun directly from the p-mode oscillation spectrum since the frequencies of the modes are relatively insensitive to changes in the helium abundance.

Guenther, D. B.↗

Abundances in Comet Halley at the time of the spacecraft encounters

Spectrophotometric observations of Comet Halley obtained in March 1986 at the time of the spacecraft encounters with the comet are described, and the column densities derived from the integrated emission band fluxes are presented. The scale lengths are determined from the spatial profiles of the observed species. Production rates are derived and the parent identities and abundance ratios of the studied species are discussed. The data indicate that the abundance of the primordial condensate NH3 comprises about 0.2 percent of the total volatile fraction of the comet nucleus. The ratio of production rates Q(NH2)/Q(H2O) = 0.003 indicates that Q(NH3)/Q(H2O) is roughly 0.3 percent, which is nearly 10 times lower than the value determined from Giotto ion mass spectrometer data. The production rate Q(CH)/Q(H2O) of 0.007 and the CH spatial profile indicate that CH cannot derive entirely from direct photodissociation of CH4.

Wyckoff, Susan↗

Effect of solar proton events in 1978 and 1979 on the odd nitrogen abundance in the middle atmosphere

Daily average solar proton flux data for 1978 and 1979 are used in a proton energy degradation scheme to derive ion pair production rates and atomic nitrogen production rates. The latter are computed in a form suitable for inclusion in an atmopheric, two-dimensional, time-dependent photochemical model. Odd nitrogen distributions are computed from the model, including atomic nitrogen production from solar protons, and are compared with baseline distributions. The comparisons show that the average effect of the solar protons in 1978 and 1979 was to cause changes in odd nitrogen only above 10 mbar and at latitudes only above about 50 deg in both hemispheres. The influence of the solar proton-produced odd nitrogen on the local abundance of odd nitrogen depends primarily on the background odd nitrogen abundance as well as the altitude and season.

Jackman, Charles H.↗

Galactic interstellar abundance surveys with IUE. III - Silicon, manganese, iron, sulfur, and zinc

This paper continues a survey of intestellar densities, abundances, and cloud structure in the Galaxy using the IUE satellite. A statistical data set of 223 O3-B2.5 stars is constructed, including 53 stars in the Galactic halo. It is found that S II lines in B stars, of luminosity classes IV and V, have possible contamination from stellar S II, particular for stars with v sin i less than 200 km/s. The mean logarithmic depletions are -1.00, -1.19. -0.63, and -0.23 (Si, Mn,Fe,S, Zn). Depletions of Si, Mn, and Fe correlate with the mean hydrogen density n-bar along the line of sight, with a turnover for n-bar greater than 1/cm. Sulfur depletions correlate with n-bar along the line of sight. The slight Zn depletion correlation also appears to be statistically insignificant. No correlation of depletion is found with the physical density derived from H2 rotational states in 21 lines of sight. Depletion variations in the disk are consistent with a Galactic abundance gradient or with enhanced mean depletions in the anticenter region.

Van Steenberg, Michael E.↗

The abundances of carbon and nitrogen in I Zw 18

The first measurements of the semiforbidden C III 1909 A and forbidden N II 6583 A emission lines in I Zw 18 are reported. These data are combined with previously published spectrophotometry in order to derive the carbon and nitrogen abundances in I Zw 18 with the aid of a nebular model. The CNO abundances in I Zw 18 are found to exceed those found in the Magellanic Clouds and other well-observed oxygen-poor irregular galaxies and are more similar to those in the sun and nearby Galactic H II regions. It is argued that I Zw 18 may be older and more chemically evolved than previously believed, and that its extremely low O/H results from escape of O-rich supernova ejecta from the Galaxy or from dilution by accretion of primordial gas. Alternatively, I Zw 18 may have formed from a preenriched intergalactic medium. Spectroscopic diagnostics for composite photoionization models to fit the spectrum of I Zw 18 are discussed.

Dufour, Reginald J.↗

Chemical abundance of comets

Observations of NH2, (OI) and molecular ion spectra in comets represent virtually all of the volatile fraction of a comet nucleus. Their study leads to the N2, NH3, H2O, CO2, CO content of the nucleus, and thus to important constraints on models of comet formation and chemical processing in the primitive solar nebula. The observations of Comet Halley provide the opportunity for the first comprehensive determination of the abundances in a comet nucleus. The carbon isotope abundance ratio 12 C/13 C = 65 plus or minus 8 has been determined for Comet Halley from resolved rotational line structure in the CN B-X (0,0) band. The ratio is approximately 30 pct lower than the solar system value, 89, indicating either an enhancement of 13CN or a depletion of 12CN in the comet. Scenarios consistent with the observed carbon isotope ratio are: (1) formation of the comet at the periphery of the solar nebula in a fractionation-enriched 13CN region, or hidden from 12CN enrichment sources, and (2) capture of an interestellar comet. Long-slit charge coupled device (CCD) spectra obtained at the time of the spacecraft encounter of Comet Halley have also been analyzed. Scale lengths, production rates and column densities of CH, CN, C2 and NH2 were determined.

Wyckoff, Susan↗

ISM chemical abundances in two intermediate-velocity clouds in the line of sight to SN 1987A

The earliest IUE high-resolution spectra of SN 1987A have been studied and reveal the presence of several clouds in the line of sight to the LMC. In particular, there are two clouds with radial velocities of about 130 km/s and about 180 km/s. These clouds' velocities are between those of Galactic clouds at 0-80 km/s and those of LMC gas at about 270 km/s. Chemical-abundance determinations may help to determine the origin and location of these clouds. Curve-of-growth analysis and 21-cm observations show that they may be underabundant in heavy elements by about a factor of 2 as compared to solar abundances. No depletion indicative of grain formation can be seen.

Morgan, Siobahn↗