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Ta2NbTc crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Ta2NbTc ribbons oriented in the (1, 0, 0) direction. Ta is bonded in a linear geometry to one Nb and one Tc atom. The Ta–Nb bond length is 2.39 Å. The Ta–Tc bond length is 2.25 Å. Nb is bonded in a linear geometry to two equivalent Ta atoms. Tc is bonded in a linear geometry to two equivalent Ta atoms.
TcIr crystallizes in the hexagonal P-6m2 space group. The structure is three-dimensional. Tc3- is bonded to six equivalent Tc3- and six equivalent Ir3+ atoms to form a mixture of distorted edge, face, and corner-sharing TcTc6Ir6 cuboctahedra. All Tc–Tc bond lengths are 2.76 Å. All Tc–Ir bond lengths are 2.71 Å. Ir3+ is bonded in a 6-coordinate geometry to six equivalent Tc3- atoms.
Lu2TcCd is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Lu is bonded in a body-centered cubic geometry to four equivalent Tc and four equivalent Cd atoms. All Lu–Tc bond lengths are 3.03 Å. All Lu–Cd bond lengths are 3.03 Å. Tc is bonded in a body-centered cubic geometry to eight equivalent Lu atoms. Cd is bonded in a body-centered cubic geometry to eight equivalent Lu atoms.
Nb2TcFe crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Nb2TcFe ribbons oriented in the (1, 0, 0) direction. Nb is bonded in a linear geometry to one Tc and one Fe atom. The Nb–Tc bond length is 2.20 Å. The Nb–Fe bond length is 2.10 Å. Tc is bonded in a linear geometry to two equivalent Nb atoms. Fe is bonded in a linear geometry to two equivalent Nb atoms.
Nb2TcRh crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Nb2TcRh ribbons oriented in the (1, 0, 0) direction. Nb is bonded in a linear geometry to one Tc and one Rh atom. The Nb–Tc bond length is 2.20 Å. The Nb–Rh bond length is 2.30 Å. Tc is bonded in a linear geometry to two equivalent Nb atoms. Rh is bonded in a linear geometry to two equivalent Nb atoms.
Zr2TcGa crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Zr2TcGa ribbons oriented in the (1, 0, 0) direction. Zr is bonded in a linear geometry to one Tc and one Ga atom. The Zr–Tc bond length is 2.23 Å. The Zr–Ga bond length is 2.78 Å. Tc is bonded in a linear geometry to two equivalent Zr atoms. Ga is bonded in a linear geometry to two equivalent Zr atoms.
Zr2TcIr crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Zr2TcIr ribbons oriented in the (1, 0, 0) direction. Zr is bonded in a linear geometry to one Tc and one Ir atom. The Zr–Tc bond length is 2.22 Å. The Zr–Ir bond length is 2.37 Å. Tc is bonded in a linear geometry to two equivalent Zr atoms. Ir is bonded in a linear geometry to two equivalent Zr atoms.
Zr2TcCd crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Zr2TcCd ribbons oriented in the (1, 0, 0) direction. Zr is bonded in a linear geometry to one Tc and one Cd atom. The Zr–Tc bond length is 2.25 Å. The Zr–Cd bond length is 3.14 Å. Tc is bonded in a linear geometry to two equivalent Zr atoms. Cd is bonded in a linear geometry to two equivalent Zr atoms.
Zr2TcCu crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Zr2TcCu ribbons oriented in the (1, 0, 0) direction. Zr is bonded in a linear geometry to one Tc and one Cu atom. The Zr–Tc bond length is 2.28 Å. The Zr–Cu bond length is 2.69 Å. Tc is bonded in a linear geometry to two equivalent Zr atoms. Cu is bonded in a linear geometry to two equivalent Zr atoms.
NbW2Tc crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two NbW2Tc ribbons oriented in the (1, 0, 0) direction. Nb is bonded in a linear geometry to two equivalent W atoms. Both Nb–W bond lengths are 2.32 Å. W is bonded in a linear geometry to one Nb and one Tc atom. The W–Tc bond length is 2.24 Å. Tc is bonded in a linear geometry to two equivalent W atoms.
Ti2MoTc crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Ti2MoTc ribbons oriented in the (1, 0, 0) direction. Ti is bonded in a linear geometry to one Mo and one Tc atom. The Ti–Mo bond length is 2.27 Å. The Ti–Tc bond length is 2.12 Å. Mo is bonded in a linear geometry to two equivalent Ti atoms. Tc is bonded in a linear geometry to two equivalent Ti atoms.
BeZr2Tc crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two BeZr2Tc ribbons oriented in the (1, 0, 0) direction. Be is bonded in a linear geometry to two equivalent Zr atoms. Both Be–Zr bond lengths are 2.72 Å. Zr is bonded in a linear geometry to one Be and one Tc atom. The Zr–Tc bond length is 2.25 Å. Tc is bonded in a linear geometry to two equivalent Zr atoms.
Nb2TcNi crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Nb2TcNi ribbons oriented in the (1, 0, 0) direction. Nb is bonded in a linear geometry to one Tc and one Ni atom. The Nb–Tc bond length is 2.29 Å. The Nb–Ni bond length is 2.38 Å. Tc is bonded in a linear geometry to two equivalent Nb atoms. Ni is bonded in a linear geometry to two equivalent Nb atoms.
Zr2TcIr is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Zr is bonded in a body-centered cubic geometry to four equivalent Tc and four equivalent Ir atoms. All Zr–Tc bond lengths are 2.86 Å. All Zr–Ir bond lengths are 2.86 Å. Tc is bonded in a body-centered cubic geometry to eight equivalent Zr atoms. Ir is bonded in a body-centered cubic geometry to eight equivalent Zr atoms.
Zr2TcRu crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Zr2TcRu ribbons oriented in the (1, 0, 0) direction. Zr is bonded in a linear geometry to one Tc and one Ru atom. The Zr–Tc bond length is 2.31 Å. The Zr–Ru bond length is 2.29 Å. Tc is bonded in a linear geometry to two equivalent Zr atoms. Ru is bonded in a linear geometry to two equivalent Zr atoms.
TcNi crystallizes in the hexagonal P-6m2 space group. The structure is three-dimensional. Tc3- is bonded to six equivalent Tc3- and six equivalent Ni3+ atoms to form a mixture of edge, face, and corner-sharing TcTc6Ni6 cuboctahedra. All Tc–Tc bond lengths are 2.65 Å. All Tc–Ni bond lengths are 2.60 Å. Ni3+ is bonded in a 6-coordinate geometry to six equivalent Tc3- atoms.
Hf2TcNi is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Hf is bonded in a body-centered cubic geometry to four equivalent Tc and four equivalent Ni atoms. All Hf–Tc bond lengths are 2.80 Å. All Hf–Ni bond lengths are 2.80 Å. Tc is bonded in a body-centered cubic geometry to eight equivalent Hf atoms. Ni is bonded in a body-centered cubic geometry to eight equivalent Hf atoms.
Hf2TcCu crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Hf2TcCu ribbons oriented in the (1, 0, 0) direction. Hf is bonded in a linear geometry to one Tc and one Cu atom. The Hf–Tc bond length is 2.25 Å. The Hf–Cu bond length is 2.75 Å. Tc is bonded in a linear geometry to two equivalent Hf atoms. Cu is bonded in a linear geometry to two equivalent Hf atoms.