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NASA NTRS1999

The Effects of Magnetic Anomalies Discovered at Mars on the Structure of the Martian Ionosphere and the Solar Wind Interaction as Follows from Radio Occultation Experiments

The electron density distribution in the ionosphere of nonmagnetic (or weakly magnetized) planet depends not only on the solar ultraviolet intensity, but also on the nature of the SW interaction with this planet. Two scenarios previously have been developed based on the observations of the bow shock crossings and on the electron density distribution within the ionosphere. According to one of them Mars has an intrinsic magnetosphere produced by a dipole magnetic field and the Martian ionosphere is protected from the SW flow except during "overpressure conditions, when the planetary magnetic field can not balance the SW dynamic pressure. In the second scenario the Martian intrinsic magnetic dipole field is so weak that Mars has mainly an induced magnetosphere and a Venus-like SW/ionosphere interaction. Today the possible existence of a sufficiently strong global magnetic field that participates in the SW/Mars interaction can no longer be supported. The results obtained by the Mars-Global-Surveyor (MGS) space-craft show the existence of highly variable, but also very localized magnetic fields of crustal origin at Mars as high as 400-1500 nT. The absence of the large-scale global magnetic field at Mars makes it similar to Venus, except for possible effects of the magnetic anomalies associated with the remnant crustal magnetization. However the previous results on the Martian ionosphere obtained mainly by the radio occultation methods show that there appears to be a permanent existence of a global horizontal magnetic field in the Martian ionosphere. Moreover the global induced magnetic field in the Venus ionosphere is not typical at the solar zenith angles explored by the radio occultation methods. Additional information is contained in the original extended abstract.

Ness, N. F.↗
NASA NTRS2000

Troughs in Ice Sheets and Other Icy Deposits on Mars: Analysis of Their Radiative Balance

It has long been known that groove-like structures in glaciers and ice sheets can trap more incoming solar radiation than is the case for a 'normal' flat, smooth surface. In this presentation, we shall describe the radiative regimes of typical scarps and troughs on icy surfaces of Mars, and suggest how these features originate and evolve through time. The basis of our analysis is the radiation balance model presented by Pfeffer and Bretherton. Their model considers the visible band radiation regime of a V-shaped groove on a terrestrial ice surface, and shows that absorbed energy can be enhanced by up to 50 percent for grooves with small opening angles and with typical polar values of the solar zenith angle. Our work extends this model by considering: (a) departures from V-shaped geometry, (b) both englacial and surficial dust and debris, and (c) the infrared spectrum. We apply the extended model to various features on the Martian surface, including the spiral-like scarps on the Northern and Southern ice sheets, the large-scale chasms (e.g., Chasm Borealis), and groove-like lineations on valley floors thought to be filled with mixtures of dust and icy substances. In conjunction with study of valley-closure experiments, we suggest that spiral-like scarps and chasms are stable features of the Martian climate regime. We also suggest that further study of scarps and chasms may shed light on the composition (i.e., relative proportions of water ice, carbon-dioxide ice and dust) of the Martian ice sheets and valley fills.

Fountain, A.↗
NASA NTRS2000

On the Relationship of Multiple Solutions in Tropospheric Photochemistry to Observable Phenomena

Multiple steady-state solutions are a fairly robust feature of simplified models of tropospheric photochemistry and have been reported for a range of different modeling assumptions. Multiple solutions occur through a bifurcation as changes in a control parameter induce a transition from low to high NO(x) conditions. The usual control parameters are the sources of NO and of CO, CH4 or non-methane hydrocarbons. Typically, with increasing NO source, bifurcations occur at NO(x). concentrations that are higher than would be expected of even heavily polluted conditions. However, there are other ways of inducing a low NO(x) - high NO(x) transition. In this paper the primary control parameter is solar zenith angle. This is varied throughout the year by computing noontime steady states on successive days. Background NO(x), varied by assuming different NO(x) sources values, is used as a secondary control parameter. It is found that bifurcations can occur from high to low NO(x) conditions, for reasonable background NO(x) levels, as the model progresses through spring and then from low to high NO,, during the progression through fall. A time dependent version of this model has been run for the same parameter values as in the steady state runs. This shows rapid spring and fall transitions between high and low NO(x) states. H2O2, for example, rises from sub-ppb levels to about 2 ppb over a five day period in spring and declines quickly, but less precipitously, in fall. This study supports the suggestions that the rapid change in peroxide concentrations between summer and winter conditions may be understood as a manifestation of different underlying steady-state behavior.

Stewart, Richard W.↗
NASA NTRS2001

Inorganic Chlorine Partitioning in the Summer Lower Stratosphere: Modeled and Measured [ClONO2/HCl] During POLARIS

We examine inorganic chlorine (Cly) partitioning in the summer lower stratosphere using in situ ER-2 aircraft observations made during the Photochemistry of Ozone Loss in the Arctic Region in Summer (POLARIS) campaign. New steady state and numerical models estimate [ClONO2]/[HCl] using currently accepted photochemistry. These models are tightly constrained by observations with OH (parameterized as a function of solar zenith angle) substituting for modeled HO2 chemistry. We find that inorganic chlorine photochemistry alone overestimates observed [ClONO2]/[HCl] by approximately 55-60% at mid and high latitudes. On the basis of POLARIS studies of the inorganic chlorine budget, [ClO]/[ClONO2], and an intercomparison with balloon observations, the most direct explanation for the model-measurement discrepancy in Cly partitioning is an error in the reactions, rate constants, and measured species concentrations linking HCl and ClO (simulated [ClO]/[HCl] too high) in combination with a possible systematic error in the ER-2 ClONO2 measurement (too low). The high precision of our simulation (+/-15% 1-sigma for [ClONO2]/[HCl], which is compared with observations) increases confidence in the observations, photolysis calculations, and laboratory rate constants. These results, along with other findings, should lead to improvements in both the accuracy and precision of stratospheric photochemical models.

Voss, P. B.↗
NASA NTRS2001

Sources, Sinks, and the Distribution of OH in the Lower Stratosphere

Extensive measurement campaigns by the NASA ER-2 research aircraft have obtained a nearly pole-to-pole database of the species that control HOx (OH + HO2) chemistry. The wide dynamic range of these in situ measurements provides an opportunity to demonstrate empirically the mechanisms that control the HOx system. Measurements in the lower stratosphere show a remarkably tight correlation of OH concentration with the solar zenith angle (SZA). This correlation is nearly invariant over latitudes ranging from 70 S to 90 N and all seasons. An analysis of the production and loss of HOx in terms of the rate determining steps of reaction sequences developed by Johnston and Podolske and Johnston and Kinnison is used to clarify the behavior of the system and to directly test our understanding of the system with observations. Calculations using in situ measurements show that the production rate of HOx is proportional to O3 and ultraviolet radiation flux. The loss rate is proportional to the concentration and the partitioning of NOy (reactive nitrogen) and the concentration of HO2. In the absence of heterogeneous reactions, the partitioning of NOy is controlled by O3 and NOx and the concentration of HO2 is controlled by NOy and O3, so that the removal rate of OH is buffered against changes in the correlation of O3 and NOy. The heterogeneous conversion of NO2 to HNO3 is not an important net source of HO, because production and removal sequences are nearly balanced. Changes in NOy partitioning resulting from heterogeneous chemistry have a large effect on the loss rates of HOx, but little or no impact on the measured abundance of OH. The enhanced loss rates at high NO2/HNO3 are offset in the data set examined here by enhanced production rates resulting from increased photolysis rates resulting from the decreased O3 column above the ER-2.

Hanisco, T. F.↗
NASA NTRS2001

Establishing the Dependence of [HO2]/[OH] on Temperature, Halogen Loading, O3, and NO(x) Based on in Situ Measurements from the NASA ER-2

In situ observations of OH and HO2 from the Airborne Southern Hemisphere Ozone Experiment/Measurements for Assessing the Effects of Stratospheric Aircraft (ASHOE/MAESA), Stratospheric TRacers of Atmospheric Transport (STRAT), and Polar Ozone Loss in the Arctic Region in Summer (POLARIS) NASA ER-2 field campaigns are used to examine the partitioning of HO(x) in the lower stratosphere (tropopause to approx.21 km) and upper troposphere (approx.10 km to tropopause). These measurements span a latitude range from 70degS to 90degN and a variety of atmospheric conditions as a result of seasonal changes and altitude. The response of the observed [HO2]/[OH] to changes in temperature, [03], [CO], [NO], [CIO], and [BrO] is investigated. The measured ratio is accurately described (approx.+/-10%) by a steady-state model constrained by the measured mixing ratios of O3, CO, NO, CIO, and BrO, where the model is valid for conditions of HO(x) cycling much faster than HO(x) production and loss. The concentration of HO2 depends on [OH], which, to first order, has been observed to be a simple function of the solar zenith angle in the lower stratosphere. The partitioning between OH and HO2 is controlled by the local chemistry between the HO, radicals and O3, CO, NO, CIO, and BrO. The response of [HO(x)] to changes in [NO(x)] and [O3] is demonstrated. Further observations are necessary to illustrate the response of HO(x) to changes in halogen concentrations. A quantitative understanding of [HO2]/[OH] is important, since many of the reactions that control this ratio are directly involved in catalytic removal of O3 in the lower stratosphere and production of O3 in the upper troposphere.

Lanzendorf, E. J.↗
NASA NTRS1999

The Coupling of ClONO2, ClO, and NO2 in the Lower Stratosphere From in Situ Observations Using the NASA ER-2 Aircraft

The first in situ measurements of ClONO2 in the lower stratosphere, acquired using the NASA ER-2 aircraft during the Polar Ozone Loss in the Arctic Region in Summer (POLARIS) mission, are combined with simultaneous measurements of ClO, NO2, temperature, pressure, and the calculated photolysis rate coefficient (J(sub ClONO2)) to examine the balance between production and loss of ClONO2. The observations demonstrate the ClONO2 photochemical steady state measurement, [ClONO2](sup PSS) = k[ClO][No2]/J(sub ClONO2), is in good agreement with the direct measurement, [ClONO2](sup MEAS). For the bulk of the data (80%), where T > 220 K and latitudes > 45 N, [ClONO2](sup PPS) = 1.15 +/- 0.36(1-sigma)[ClONO2](sup MEAS), while for T< 220 K and latitudes < 45 N, the result is somewhat less at 1.01 +/- 0.30. The cause of the temperature and/or latitude trend is unidentified. These results are independent of solar zenith angle and air density, thus there is no evidence in support of a pressure-dependent quantum yield for photodissociation of ClONO2 at wavelengths > 300 nm. These measurements confirm the mechanism by which active nitrogen (NOx = NO + NO2) controls the abundance of active chlorine (Clx = ClO + Cl) in the stratosphere.

Stimpfle, R. E.↗
NASA NTRS2001

Joint Characterization of Vegetation by Satellite Observations from Visible to Microwave Wavelengths - A Sensitivity Analysis

This study presents an evaluation and comparison of visible, near-infrared, passive, and active microwave observations for vegetation characterization on a global basis for a year, with spatial resolution compatible with climatological studies. Visible and near-infrared observations along with the Normalized Difference Vegetation Index come from the Advanced Very High Resolution Radiometer. An atlas of monthly mean microwave land surface emissivities from 19 to 85 GHz has been calculated from the Special Sensor Microwave/Imager for a year, suppressing the atmospheric problems encountered with the use of simple channel combinations. The active microwave measurements are provided by the ERS-1 scatterometer at 5.25 GHz. The capacity to discriminate between vegetation types and to detect the vegetation phenology is assessed in the context of a vegetation classification obtained from in situ observations. A clustering technique derived from the Kohonen topological maps is used to merge the three data sets and interpret their relative variations. NDVI varies with vegetation density but is not very sensitive in semiarid environments and in forested areas. Spurious seasonal cycles and large spatial variability in several areas suggest that atmospheric contamination and/or solar zenith angle drift still affect the NDVI.

NORMALIZED DIFFERENCE VEGETATIVE INDEX↗
NASA NTRS2001

Three Dimensional Atmospheric Radiative Transfer-Applications and Methods Comparison

We review applications of 3D radiative transfer in the atmosphere, emphasizing the wide spectrum of scales important to remote sensing and modeling of cloud fields, and the characteristic scales introduced into observed radiances and fluxes by the distribution of photon pathlengths at conservative and absorbing wavelengths. We define the "plane-parallel bias", which is a measure of the importance of 3D cloud structure in large-scale models, and the "independent pixel errors" that quantify the significance of 3D effects in remote sensing, and emphasize their relative magnitude and scale dependence. A variety of approaches in current use in 3D radiative transfer, and issues of speed, accuracy, and flexibility are summarized. We also describe a recently initiated "International Intercomparison of 3-Dimensional Radiation Codes", or I3RC. I3RC is a 3-phase effort that has as its goals to: (1) understand the errors and limits of 3D methods; (2) provide "baseline" cases for future 3D code development; (3) promote sharing of 3D tools; (4) derive guidelines for 3D tool selection; and (5) improve atmospheric science education in 3D radiative transfer. Selected results from Phases 1 and 2 of I3RC are discussed. These are taken from five cloud fields: a 1D field of bar clouds, a 2D radar-derived field, a 3D Landsat-derived field, a stratiform cloud from the model of C. Moeng, and a convective cloud from the model of B. Stevens. Computations have been carried out for three monochromatic wavelengths (one conservative, one absorptive, and one thermal) and two solar zenith angles (0, 60 degrees).

Cahalan, Robert F.↗
NASA NTRS2001

Sensitivity Studies for Space-Based Global Measurements of Atmospheric Carbon Dioxide

Carbon dioxide (CO2) is well known as the primary forcing agent of global warming. Although the climate forcing due to CO2 is well known, the sources and sinks of CO2 are not well understood. Currently the lack of global atmospheric CO2 observations limits our ability to diagnose the global carbon budget (e.g., finding the so-called "missing sink") and thus limits our ability to understand past climate change and predict future climate response. Space-based techniques are being developed to make high-resolution and high-precision global column CO2 measurements. One of the proposed techniques utilizes the passive remote sensing of Earth's reflected solar radiation at the weaker vibration-rotation band of CO2 in the near infrared (approx. 1.57 micron). We use a line-by-line radiative transfer model to explore the potential of this method. Results of sensitivity studies for CO2 concentration variation and geophysical conditions (i.e., atmospheric temperature, surface reflectivity, solar zenith angle, aerosol, and cirrus cloud) will be presented. We will also present sensitivity results for an O2 A-band (approx. 0.76 micron) sensor that will be needed along with CO2 to make surface pressure and cloud height measurements.

Mao, Jian-Ping↗
NASA NTRS2001

Results of the Second SeaWiFS Data Analysis Round Robin, March 2000 (DARR-00)

The accurate determination of upper ocean apparent optical properties (AOPs) is essential for the vicarious calibration of the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) instrument and the validation of the derived data products. To evaluate the importance of data analysis methods upon derived AOP values, the Second Data Analysis Round Robin (DARR-00) activity was planned during the latter half of 1999 and executed during March 2000. The focus of the study was the intercomparison of several standard AOP parameters: (1) the upwelled radiance immediately below the sea surface, L(sub u)(0(-),lambda); (2) the downward irradiance immediately below the sea surface, E(sub d)(0(-),lambda); (3) the diffuse attenuation coefficients from the upwelling radiance and the downward irradiance profiles, L(sub L)(lambda) and K(sub d)(lambda), respectively; (4) the incident solar irradiance immediately above the sea surface, E(sub d)(0(+),lambda); (5) the remote sensing reflectance, R(sub rs)(lambda); (6) the normalized water-leaving radiance, [L(sub W)(lambda)](sub N); (7) the upward irradiance immediately below the sea surface, E(sub u)(0(-)), which is used with the upwelled radiance to derive the nadir Q-factor immediately below the sea surface, Q(sub n)(0(-),lambda); and (8) ancillary parameters like the solar zenith angle, theta, and the total chlorophyll concentration, C(sub Ta), derived from the optical data through statistical algorithms. In the results reported here, different methodologies from three research groups were applied to an identical set of 40 multispectral casts in order to evaluate the degree to which differences in data analysis methods influence AOP estimation, and whether any general improvements can be made. The overall results of DARR-00 are presented in Chapter 1 and the individual methods used by the three groups and their data processors are presented in Chapters 2-4.

Hooker, Stanford B.↗
NASA NTRS2003

Reflectance-Based Sensor Validation Over Ice Surfaces

During this period work was performed in the following areas. These areas are defined in the Work Schedule presented in the original proposal: BRDF development, Data acquisition and processing, THR Table generation and Presentations and Publications. BRDF development involves creating and/or modifying a reflectance model of the Antarctic surface. This model must, for a temporal and spatial average, be representative of the East Antarctic plateau and be expressed in terms of the three standard surface angles: solar zenith angle (SolZA), view zenith angle (SatZA), and relative azimuth angle (RelAZ). We successfully acquired a limited amount of NOAA-9 AVHRR data for radiance validation. The data were obtained from the Laboratory for Terrestrial Physics at Goddard Space Flight Center. We developed our own reading and unpacking software, which we used to select Channel 1 data (visible). We then applied geographic subsetting criteria (same as used for TOMS), and wrote only the relevant data to packed binary files. We proceeded with analysis of these data, which is not yet complete.

Jaross, Glen↗
NASA NTRS2003

Satellite and Surface Data Synergy for Developing a 3D Cloud Structure and Properties Characterization Over the ARM SGP. Stage 1: Cloud Amounts, Optical Depths, and Cloud Heights Reconciliation

One of the primary Atmospheric Radiation Measurement (ARM) Program objectives is to obtain measurements applicable to the development of models for better understanding of radiative processes in the atmosphere. We address this goal by building a three-dimensional (3D) characterization of the cloud structure and properties over the ARM Southern Great Plains (SGP). We take the approach of juxtaposing the cloud properties as retrieved from independent satellite and ground-based retrievals, and looking at the statistics of the cloud field properties. Once these retrievals are well understood, they will be used to populate the 3D characterization database. As a first step we determine the relationship between surface fractional sky cover and satellite viewing angle dependent cloud fraction (CF). We elaborate on the agreement intercomparing optical depth (OD) datasets from satellite and ground using available retrieval algorithms with relation to the CF, cloud height, multi-layer cloud presence, and solar zenith angle (SZA). For the SGP Central Facility, where output from the active remote sensing cloud layer (ARSCL) valueadded product (VAP) is available, we study the uncertainty of satellite estimated cloud heights and evaluate the impact of this uncertainty for radiative studies.

Genkova, I.↗
NASA NTRS2003

The O+ Density Trough at 5000 km Altitude in the Polar Cap

At altitudes near 5000 km over the Southern polar cap region of the terrestrial magnetospherehonosphere, the Thermal Ion Dynamics Experiment (TIDE) onboard the Polar satellite has observed O+ ion density trough regions, in which the O+ densities were at least one order of magnitude lower than the surrounding O+ densities. In the O+ demify trough regions, the estimated O+ densities were generally lower than 0.01 per cc. The boundaries between normal density level regions and the trough density regions were usually abrupt transitions. From December 1, 1997 to November 30, 1998, polar cap O+ troughs in Polar/TIDE observations occurred at a frequency of about 48%. Statistical examination of the Polar perigee observations from December 1 , 1997 to November 30, 1998 shows that the Polar perigee passes evenly covered the southern polar cap region, while the O+ density trough was always located on the nightside portion of the polar cap magnetospherehonosphere, and that invariant latitude spans of such troughs could be as large as 230 in extent. The trough occurrence displayed strong seasonal dependence; in the winter season (e.g. for July in the southern hemisphere) the O+ ion density trough occurrence frequency ranged up to 92%, while in the summer season (e.g. for January in the southern hemisphere) it decreased to as infrequent as 15%. The O+ ion density trough occurrence appeared relatively independent of the geomagnetic Kp index, and IMF Bz, By conditions. However, as suggested by the seasonal dependence, the O+ ion density trough occurrence was strongly related to the solar zenith angle (SZA). In the SZA range 500 to 1250, the trough occurrence increased monotonically with SZA. Also, case-by-case examinations of near-simultaneous O+ densities and vertical velocities observed by the DMSP satellite group orbiting at 840 km altitude indicate that the O+ density troughs observed at 5000 km altitude exhibit moderate correlation or anti-correlation with topside ionosphere density or velocity features at 840 km altitude for approximately half of the near-conjunction cases examined.

Zeng, W.↗
NASA NTRS2003

TRMM Fire Algorithm, Product and Applications

Land fires are frequent menaces to human lives and property. They also change the state of the vegetation and contribute to the climate forcing by releasing large amount of aerosols and greenhouse gases into the atmosphere. This paper summarizes methodologies of detecting global land fires from the Tropical Rainfall Measuring Mission (TRMM) Visible Infrared Scanner FIRS) measurements. The TRMM Science Data and Information System (TSDIS) fire products include global images of daily hot spots and monthly fire counts at 0.5 deg. x 0.5 deg. resolution, as well as text fiies that details necessary information of all fire pixels. The information includes date, orbit number, pixel number, local time, solar zenith angle, latitude, longitude, reflectance of visible/near infrared channels, brightness temperatures of infrared channels, as well as background brightness temperatures of infrared channels. These products have been archived since January 1998. The TSDIS fire products are compared with the coincidental European Commission (EC) Joint Research Center (JRC) 1 km AVHRR fire products. Analyses of the TSDIS monthly fire products during the period from 1998 to 2003 manifested seasonal cycles of biomass fires over Southeast Asia, Africa, North America and South America. The data also showed interannual variations associated with the 98/99 ENS0 cycle in Central America and the Indonesian region. In order to understand the variability of global land fires and their effects on the distribution of atmospheric aerosols, statistical methods were applied to the TSDIS fire products as well as to the Total Ozone Mapping Spectrometer (TOMS) aerosol index products for a period of five years from January 1998 to December 2002. The variability of global atmospheric aerosol is consistent with the fire variations over these regions during this period. The correlation between fire count and TOMS aerosol index is about 0.55 for fire pixels in Southeast Asia, Indonesia, and Africa. Parallel statistical analyses such as Empirical Orthogonal Function (EOF) analysis and Singular Spectrum Analysis (SSA) methods were applied to pentad TRMM fire data and TOMS aerosol data. The EOF analyses showed contrast between North and South hemispheres and also inter- continental transitions in Africa and America. EOF and SSA analyses also identified 25-60 day intra-seasonal oscillations that were superimposed on the annual cycles of both fire and aerosol data. The intra-seasonal variability of fires showed similarity of tropical rainfall oscillation modes. The TRMM fire products were also compared to the coincident TRMh4 rainfall and other rainfall products to investigate the interaction between rainfall and fire. The results indicate that the annual, interannual and intraseasonal variability of fire are dominated by global rainfall variations. However, the feedback of fire to the rainfall occurrence at regional scale for certain regions is also evident.

Ji, Yi-Min↗
NASA NTRS2004

The O(+) Density Trough at 5000 km Altitude in the Polar Cap

At altitudes near 5000 km over the southern polar cap region of the terrestrial magnetosphere/ionosphere, the Thermal Ion Dynamics Experiment (TIDE) on board the Polar satellite has observed O(+) ion density trough regions, in which the densities were at least one order of magnitude lower than the surrounding O(+) densities. In the 0" density trough regions, the estimated O+ densities were generally lower than 0.01 per cc. The boundaries between normal density level regions and the trough density regions were usually abrupt transitions. From 1 December 1997 to 30 November 1998, polar cap O(+) troughs in Polar/TIDE observations occurred at a frequency of about 48%. Statistical examination of the Polar perigee observations from 1 December 1997 to 30 November 1998 shows that the Polar perigee passes evenly covered the southern polar cap region, while the O(+) density trough was always located on the nightside portion of the polar cap magnetosphere/ionosphere, and that invariant latitude spans of such troughs could be as large as 23 deg. in extent. The trough occurrence displayed a strong seasonal dependence; in the winter season (e.g., for July in the Southern Hemisphere) the O(+) ion density trough occurrence frequency ranged up to 92%, while in the summer season (e.g., for January in the Southern Hemisphere) it decreased to as low as 15%. Our statistical results show that the trough occurrence was generally anticorrelated with solar wind dynamic pressure in the solar wind dynamic pressure range 0.8 - 2.6 nanopascal. The O(+) ion density trough occurrence appeared relatively independent of the geomagnetic Kp index, IMF Bz, and By conditions. However, as suggested by the seasonal dependence, the O(+) ion density trough occurrence was strongly related to the solar zenith angle (SZA). In the SZA range 50 deg. to 125 deg., the trough occurrence increased monotonically with SZA. In addition, we sought to determine consistent density and velocity signatures at lower altitudes associated the O(+) ion density trough at 5000 km by examining the near-simultaneous O(+) densities and vertical velocities observed by the DMSP satellite group orbiting at 840 km altitude. However, consistent correlations between the dual altitudes were not reliably established from the present examinations.

Zeng, W.↗
NASA NTRS2004

A Comparison of TOMS Version 8 Total Column Ozone Data with Data from Groundstations

The Nimbus-7 and Earth Probe Total Ozone Mapping Spectrometer (TOMS) data have been reprocessed with a new retrieval algorithm, (Version 8) and an updated calibration procedure. These data have been systematically compared to total ozone data from Brewer and Dobson spectrophotometers for 73 individual ground stations. The comparisons were made as a function of latitude, solar zenith angle, reflectivity and total ozone. Results show that the accuracy of the TOMS retrieval'is much improved when aerosols are present in the atmosphere, when snow/ice and sea glint are present, and when ozone in the northern hemisphere is extremely low. TOMS overpass data are derived from the single TOMS best match measurement, almost always located within one degree of the ground station and usually made within an hour of local noon. The version 8 Earth Probe TOMS ozone values have decreased by an average of about 1% due to a much better understanding of the calibration of the instrument. The remaining differences between TOMS and ground stations suggest that there are still small errors in the TOMS retrievals. But if TOMS is used as a transfer standard to compare ground stations, the large station-to-station differences suggest the possibility of significant instrument errors at some ground stations.

Labow, G. J.↗
NASA NTRS2004

Comparison of TOMS, SBW & SBUV/2 Version 8 Total Column Ozone Data with Data from Groundstations

The Nimbus-7 and Earth Probe Total Ozone Mapping Spectrometer (TOMS) data as well as SBUV and SBUV/2 data have been reprocessed with a new retrieval algorithm (Version 8) and an updated calibration procedure. An overview will be presented systematically comparing ozone values to an ensemble of Brewer and Dobson spectrophotometers. The comparisons were made as a function of latitude, solar zenith angle, reflectivity and total ozone. Results show that the accuracy of the TOMS retrieval has been improved when aerosols are present in the atmosphere, when snow/ice and sea glint are present, and when ozone in the northern hemisphere is extremely low. TOMS overpass data are derived from the single TOMS best match measurement, almost always located within one degree of the ground station and usually made within an hour of local noon. The Version 8 Earth Probe TOMS ozone values have decreased by an average of about 1% due to a much better understanding of the calibration of the instrument. N-7 SBUV as well as the series of NOAA SBUV/2 column ozone values have also been processed with the Version 8 algorithm and have been compared to values from an ensemble of groundstations. Results show that the SBW column ozone values agree well with the groundstations and the datasets are useful for trend studies.

Labow, G. J.↗