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At least 487 records · Page 27
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

Slurry-pressing consolidation of silicon nitride

A baseline slurry-pressing method for a silicon nitride material is developed. The Si3N4 composition contained 5.8 wt percent SiO2 and 6.4 wt percent Y2O3. Slurry-pressing variables included volume percent solids, application of ultrasonic energy, and pH. Twenty vol percent slurry-pressed material was approximately 11 percent stronger than both 30 vol percent slurry-pressed and dry-pressed materials. The Student's t-test showed the difference to be significant at the 99 percent confidence level. Twenty volume percent (300 h) slurry-pressed test bars exhibited strengths as high as 980 MPa. Large, columnar beta-Si3N4 grains caused failure in the highest strength specimens. The improved strength correlated with better structural uniformity as determined by radiography, optical microscopy, and image analysis.

Sanders, William A.↗
NASA NTRS1990

Reactions of SiC with H2/H2O/Ar mixtures at 1300 C

Thermochemical modeling anticipates the existence of three reaction regions for the case of a sintered alpha-SiC with 5 percent H2/H2O/Ar at 1300 C, depending on the initial water vapor or, equivalently, oxygen, content of the gas stream. While a high oxygen content leads to SiC-protecting SiO2 surface film formation and limits consumption of the SiC through passive oxidation, intermediate oxygen contents lead to SiO and CO formation and rapid SiC consumption. In this intermediate region, reaction rates appear to be controlled by H2O gas-phase transport to the sample; reacted microstructures exhibit extensive grain-boundary attack in this region. Very low oxygen content is predicted to selectively remove carbon, with free silicon formation.

Jacobson, Nathan S.↗
NASA NTRS1990

Dynamic fatigue of a lithia-alumina-silica glass-ceramic

A dynamic fatigue study was performed on a Li2O-Al2O3-SiO2 glass-ceramic in order to assess its susceptibility to delayed failure. Fracture mechanics techniques were used to analyze the results for the purpose of making lifetime predictions for optical elements made from this material. The material has reasonably good resistance (N = 20) to stress corrosion in ambient conditions. Analysis also indicated the elements should survive applied stresses incurred during grinding and polishing operations.

Tucker, Dennis S.↗
NASA NTRS1990

Space radiation shielding for a Martian habitat

Radiation shielding analyses are performed for a candidate Mars base habitat. The Langley cosmic ray transport code and the Langley nucleon transport code are used to quantify the transport and attenuation of galactic cosmic rays and solar flare protons through both the Martian atmosphere and regolith shielding. Doses at the surface and at various altitudes were calculated in a previous study using both a high-density and a low-density Mars atmosphere model. This study extends the previous low-density results to include the further transport of the ionizing radiation that reaches the surface through additional shielding provided by Martian regolith. A four-compound regolith model, which includes SiO2, Fe2O3, MgO, and CaO, was selected based on the chemistry of the Viking 1 Lander site. The spectral fluxes of heavy charged particles and the corresponding dosimetric quantities are computed for a series of thicknesses in the shield media after traversing the atmosphere. These data are then used as input to algorithms for a specific shield geometry. The results are presented as the maximum dose received in the center of the habitat versus various shield thicknesses for a base at an altitude of 0 km and 8 km.

Simonsen, Lisa C.↗
NASA NTRS1990

Crystallization behavior and properties of BaO-Al2O3-2SiO2 glass matrices

Glass of stoichiometric celsian composition, BaO-Al2O3-SiO2, has a density of 3.39 g/cu cm, a thermal expansion coefficient of 6.6 x 10 to the -6th/C, a glass-transition temperature of 910 C, and a dilatometric softening point of 925 C. On heat treatment, only hexacelsian crystallized out on the surface, but both celsian and hexacelsian were present in the bulk. Effects of cold isostatic pressing (CIP), sintering, and hot-pressing, in the presence and absence of an additive, on the formation of the celsian phase in the glass have been studied. CIP'd samples, after appropriate heat treatments, always crystallized out as celsian, whereas presence of 5-10 wt pct of an additive was necessary for formation of celsian in sintered as well as hot-pressed specimens. Green density increased with CIP'ing pressure but had no effect on sintered density. Hot-pressing resulted in fully dense samples.

Drummond, Charles H., III↗
NASA NTRS1990

Space environmental effects on spacecraft thermal control coatings

A large portion of the space based applications in the near future are for low Earth orbit (LEO) including the Space Station Freedom (SSF). The lifetime needs for materials on the SSF is 30 years. Materials must be selected which can withstand the deleterious effects of LEO. Environmental effects in the LEO include atomic oxygen, UV, ionizing radiation, and hypervelocity impact. These effects can adversely affect the surface properties of materials. This is particularly critical in the case of thermal control materials where the efficiency of the thermal control is dependent on the stability of the surface properties. The current baseline thermal coating for the SSF radiators is Ag Teflon. The surface property requirements for the coatings are a solar absorptance of 0.2 and an infrared emittance of 0.8. The effects of atomic oxygen and UV radiation on the baseline coating and several other candidate thermal control materials were studied. The thermal control radiator materials included Ag and Al backed Teflon, H2SO4 anodized Al, sputter deposited SiO2 on Al, and Ag and Al backed polychloro trifluoroethylene. The simulation of several of the LEO environment constituents provided a data base to aid in the selection of the radiator thermal control material to meet the life requirements of the SSF. The effects are illustrated of the environment on thermal control coatings and the importance of this factor in the selection process for long life spacecraft materials.

Bartosik, L. G.↗
NASA NTRS1991

Processing of glass-ceramics from lunar resources

The goal is to fabricate useful ceramic materials from the by-products of lunar oxygen production processes. Specifically, the crystal nucleation and growth kinetics of ilmenite-extracted lunar regolith were studied in order to produce glass-ceramics with optimal mechanical, thermal, and abrasion resistant properties. In the initial year of the program, construction and calibration of a high temperature viscometer, used for determining the viscosity of simulated lunar glasses was finished. A series of lunar simulants were also prepared, and the viscosity of each was determined over a range of temperatures. It was found that an increase in the concentration of Fe2O3 decreases the viscosity of the glass. While this may be helpful in processing the glass, Fe2O3 concentrations greater than approximately 10 wt percent resulted in uncontrolled crystallization during viscosity measurements. Impurities (such as Na2O, MnO, and K2O) in the regolith appeared to decrease the viscosity of the parent glass. These effects, as well as those of TiO2 and SiO2 on the processability of the glass, however, remain to be quantified.

Fabes, B. D.↗
NASA NTRS1991

Vacuum deposited optical coatings experiment (AO 138-4)

The aim of this experiment was to test the optical behavior of 20 components and coatings subjected to space exposure. Most of them are commonly used for their reflective or transmittive properties in spaceborne optics. They consist in several kind of metallic and dielectric mirrors designed for the 0.12 to 10 microns spectrum, UV, and NIR bandpass filters, visible, and IR antireflecting coatings, visible/IR dichroic beam splitters, and visible beam splitter. The coatings were deposited on various substrates such as glasses, germanium, magnesium fluoride, quartz, zinc selenide, and kanigened aluminum. Several coating materials were used such as Al, Ag, Au, MgF2, LaF3, ThF3, ThF4, SiO2, TiO2, ZrO2, Al2O3, MgO, Ge, and ZnSe. Five samples of each component were manufactured. Two flight samples were mounted in such a way that one was directly exposed to space and the other looking backwards. The same arrangement was used for the spare samples stored on ground in a box identical to the flight one and they were kept under vacuum during the LDEF mission. Finally, one set of reference components was stocked in a sealed box under a dry nitrogen atmosphere. By comparing the preflight and postflight optical performances of the five samples of each component, it is possible to detect the degradations due to the space exposure.

Charlier, Jean↗
NASA NTRS1991

Sliding wear of self-mated Al2O3-SiC whisker reinforced composites at 23-1200 C

Microstructural changes occurring during sliding wear of self-mated Al2O3-SiC whisker reinforced composites were studied using optical, scanning electron microscopy, and transmission electron microscopy. Pin-on-disk specimens were slid in air at 2.7 m/sec sliding velocity under a 26.5 N load for 1 hr. Wear tests were conducted at 23, 600, 800, and 1200 C. Mild wear with a wear factor of 2.4 times 10(exp -7) to 1.5 times 10(exp -6) cu mm/Nm was experienced at all test temperatures. The composite shows evidence of wear by fatigue mechanisms at 800 C and below. Tribochemical reaction (SiC oxidation and reaction of SiO2 and Al2O3) leads to intergranular failure at 1200 C. Distinct microstructural differences existing at each test temperature are reported.

Farmer, Serene C.↗
NASA NTRS1990

Effect of high temperature hydrogen exposure on the strength and microstructure of mullite

The corrosion of near stoichiometric mullite (3Al2O3-2SiO2) by pure dry hydrogen gas was studied at 1050 and 1250 C for times up to 500 hr. The hydrogen preferentially attacked the grain boundaries of the mullite where an aluminosilicate glass was present. Corrosion of the mullite grains was observed after 125 hr at 1250 C. The hydrogen reaction removed SiO2 from the glassy grain boundaries and the mullite grains resulting in a porous alumina rich surface. At 1250 C the strength increased after short exposure times (at least up to 125 hr) and decreased by 53 percent after 500 hr. At 1050 C, all exposure times (25 to 500 hr) decreased the strength. At 500 hr room temperature strength of mullite exposed to 1050 C was reduced by 22 percent. The strength reduction after short exposure times at 1050 C is attributed to crystallization of the grain boundary glass phase.

Herbell, Thomas P.↗
NASA NTRS1990

Comparison of the effects of ionizing radiation at twelve dose rates from 0.0015 to 100 rad(Si)/s

Evidence is presented that two competing failure mechanisms exist in the Si-SiO2 system, with one mechanism dominating at low dose rates and the other at high. Much lower dose failures than expected were discovered at low dose rates (less than 0.1 rad(Si)/s) and very low dose rates (about 0.001 rad(Si)/s) in commercial SGS 4007 CMOS devices. These failure doses plotted versus dose rate have a bell-shaped curve, rather than the expected straight line (decreasing with increasing dose rate), indicating that a different failure mechanism is dominant at low dose rates than at high.

Goben, C. A.↗
NASA NTRS1991

Crystallization kinetics of a lithia-silica glass - Effect of sample characteristics and thermal analysis measurement techniques

DTA and both isothermal and nonisothermal DSC techniques are presently used to investigate the crystallization kinetics of a 40 (mol) percent Li2O-60 percent SiO2 glass as a function of glass powder particle size, the use of either alumina or Pt as the crucible material, the use of N, O, or Ar atmospheres, and surface pretreatments of the glass powder with deionized water, HCl, or HF. Neither the furnace atmosphere nor the crucible material had a significant effect on activation energy, frequency factor, or Avrami exponent. Washings of the glass with the three different fluids decreased the crystallization temperature by 25 to 30 C.

Ray, Chandra S.↗
NASA NTRS1991

Chassigny petrogenesis - Melt compositions, intensive parameters, and water contents of Martian (?) magmas

This paper considers petrogenesis of SNC meteorites by examining partially crystallized melt inclusions in cumulus olivine grains in Chassigny meteorite. First, all phases in the Chassigny inclusions were analyzed by electron microprobe, followed by an experimental investigation of the kaersutite/melt equilibria. Results yield the intensive parameters which stabilize igneous kaersutite and the melt compositions that coexist with kaersutite. The results are used to model Chassigny petrogenesis. It is argued that the existence in the Chassigny of hydrous melts and the conditions appropriate for amphibole crystallization suggest the existence on the Chassigny parent body (Mars) of SiO2-rich lavas.

Johnson, Marie C.↗
NASA NTRS1991

Earth's core-mantle boundary - Results of experiments at high pressures and temperatures

Laboratory experiments document that liquid iron reacts chemically with silicates at high pressures (above 2.4 x 10 to the 10th Pa) and temperatures. In particular, (Mg,Fe)SiO3 perovskite, the most abundant mineral of earth's lower mantle, is expected to react with liquid iron to produce metallic alloys (FeO and FeSi) and nonmetallic silicates (SiO2 stishovite and MgSiO3 perovskite) at the pressures of the core-mantle boundary, 14 x 10 to the 10th Pa. The experimental observations, in conjunction with seismological data, suggest that the lowermost 200 to 300 km of earth's mantle, the D-double-prime layer, may be an extremely heterogeneous region as a result of chemical reactions between the silicate mantle and the liquid iron alloy of earth's core. The combined thermal-chemical-electrical boundary layer resulting from such reactions offers a plausible explanation for the complex behavior of seismic waves near the core-mantle boundary and could influence earth's magnetic field observed at the surface.

Knittle, Elise↗
NASA NTRS1991

Silicon dioxide with a silicon interfacial layer as an insulating gate for highly stable indium phosphide metal-insulator-semiconductor field effect transistors

A novel gate insulator consisting of silicon dioxide (SiO2) with a thin silicon (Si) interfacial layer has been investigated for high-power microwave indium phosphide (InP) metal-insulator-semiconductor field effect transistors (MISFETs). The role of the silicon interfacial layer on the chemical nature of the SiO2/Si/InP interface was studied by high-resolution X-ray photoelectron spectroscopy. The results indicated that the silicon interfacial layer reacted with the native oxide at the InP surface, thus producing silicon dioxide, while reducing the native oxide which has been shown to be responsible for the instabilities in InP MISFETs. While a 1.2-V hysteresis was present in the capacitance-voltage (C-V) curve of the MIS capacitors with silicon dioxide, less than 0.1 V hysteresis was observed in the C-V curve of the capacitors with the silicon interfacial layer incorporated in the insulator. InP MISFETs fabricated with the silicon dioxide in combination with the silicon interfacial layer exhibited excellent stability with drain current drift of less than 3 percent in 10,000 sec, as compared to 15-18 percent drift in 10,000 sec for devices without the silicon interfacial layer. High-power microwave InP MISFETs with Si/SiO2 gate insulators resulted in an output power density of 1.75 W/mm gate width at 9.7 GHz, with an associated power gain of 2.5 dB and 24 percent power added efficiency.

Kapoor, V. J.↗
NASA NTRS1991

Instantaneous planar visualization of reacting supersonic flows using silane seeding

A new visualization technique for reacting flows has been developed. This technique, which is suitable for supersonic combustion flows, has been demonstrated on a scramjet combustor model. In this application, gaseous silane (SiH4) was added to the primary hydrogen fuel. When the fuel reacted, so did the (SiH4), producing silica (SiO2) particles in situ. The particles were illuminated with a laser sheet formed from a frequency-doubled Nd:YAG laser (532 nm) beam and the Mie scattering signal was imaged. These planar images of the silica Mie scattering provided instantaneous 'maps' of combustion progress within the turbulent reacting flowfield.

Smith, Michael W.↗
NASA NTRS1991

Highly mobile oxygen hole-type charge carriers in fused silica

Some peculiar positive charge carriers are thermally generated in fused silica above 500 C. These charge carriers appear to be positive holes, chemically O-states, probably arising from dissociation of peroxy defects. The charge carriers give rise to a pronounced positive surface charge which disappears upon cooling but can be quenched by rapid quenching from about 800 C. Reheating to 200 C remobilizes these charge carriers and causes them to anneal below 400 C. The generation of positive holes charge carriers may be important to understand failure mechanisms of SiO2 insulators.

Freund, Friedemann↗