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At least 487 records · Page 27

Beyond the Anderson rule: importance of interfacial dipole and hybridization in van der Waals heterostructures

Vertical stacking of two-dimensional materials with weak van der Waals (vdW) interactions has laid the ground for breakthroughs in physics as well as in technological applications. Although vdW interactions dominate interlayer binding, interlayer electronic coupling may not be negligible and can lead to properties beyond the superposition of constituent monolayers. Here, studying heterobilayers of transition-metal dichalcogenides (MQ 2 ; M = Mo, Ni, Pt; Q = S, Se) by means of density functional theory calculations, we show two mechanisms that influence the band gaps of vdW heterostructures beyond the Anderson rule: (1) interfacial hybridization (mainly involving out-of-plane states, such as chalcogen p z -states), which leads to an upshift in the valence band maxima and accordingly a decrease in the band gap. (2) Formation of an interfacial electric dipole, resulting in an effective gap increase in type-II junctions. While the former is material specific, depending on the proximity of p z -states to each other and the valence band maxima, the latter can be generally described using a model based on the charge density decay outside the monolayers and the pristine band edge positions with respect to the vacuum level, irrespective of junction type.

36 MATERIALS SCIENCE↗

Auxiliary coil controls temperature of RF induction heater

Auxiliary coil controls the temperature of an RF induction furnace that is powered by a relatively unstable RF generator. Manual or servoed adjustments of the relative position of the auxiliary coil, which is placed in close proximity to the RF coil, changes the looseness of the RF coil and hence the corresponding heating effect of its RF field.

Source record↗

The study of microstrip antenna arrays and related problems

The physical layout of the array elements and the proximity of the microstrip feed network makes the input impedance and radiation pattern values dependent upon the effects of mutual coupling, feedline discontinuities and feed point location. The extent of these dependences was assessed and a number of single patch and module structures were constructed and measured at an operating frequency of approximately 4.0 GHz. The empirical results were compared with the ones which were theoretically predicted by the cavity model of thin microstrip antennas. Each element was modelled as an independent radiating patch and each microstrip feedline as an independent, quasi-TEM transmission line. The effects of the feedline discontinuities are approximated by lumped L-C circuit models.

Lo, Y. T.↗

Support of the balloon-borne ultraviolet stellar spectrograph

A (256 x 1024)-pixel imaging ultraviolet Multi-mode Microchannel Array (MAMA) detector system for flight was fabricated, evaluated, and environmentally tested for flight on the Balloon Borne Ultraviolet Stellar Spectrograph (BUSS). The goal of the program was to replace the existing SEC Vidicon with the pulse-counting MAMA detector in order to, first, improve the overall sensitivity of the BUSS telescope and spectrograph for observations of stars down to m sub v = 7 and fainter, and, second, to improve the spectral resolution and wavelength accuracy by eliminating the image drifts in the Vidicon caused by magnetic field effects. A sealed MAMA detector tube structure employing a remotely processed photocathode mounted on a window in proximity focus with the front face of the MCP was developed to avoid contamination produced by a noisy and unstable device. The configuration of the BUSS detector system in its flight ready configuration is shown. The quantum efficiency curve for the semi-transparent Cs2Te photocathode is also shown.

Timothy, J. G.↗

Intensified-CCD focal plane detector for space applications A second generation

An intensified-CCD detector system developed for space applications from commercially available components is described. This detector uses components which are readily available and are mechanically, thermally, and optically coupled to produce the final compact system. The CCD is cooled using a Peltier-effect thermoelectric cooler to reduce thermal noise. The image is formed on the photocathode of a proximity-focused image intensifier and is transferred fiber-optically from the intensifier to the CDD. Various photocathode and window materials are used to optimize the system for use within the wavelength range extending from the far UV to the near IR. The basic design, including the image intensifier, intensifier-CCD interface, CCD array, cooling, electronics, and mounting, and the detector performance are described in detail.

Torr, M. R.↗

Kinematics of NGC 4826: A sleeping beauty galaxy, not an evil eye

A recent high resolution H I study of the Sab galaxy NGC 4826 (1992) reveals that the sense of rotation of the neutral gas reverses from the inner to the outer disk. The present paper reports on optical spectra at high velocity resolution in four position angles in NGC 4826, which cover the region of the gas reversal and which reveal a high degree of complexity. In the inner disk, which includes the prominent dusty lane, the stars and gas rotate in concert, and the spiral arms trail (for the adopted geometry). Arcs of ionized gas are observed partially encircling the nucleus; expansion velocities reach 400 km/s. At distances just beyond the prominent dust lane, the ionized gas exhibits a rapid, orderly velocity fall and within 500 parsecs it has reversed from 180 km/s prograde to 200 km/s retrograde; it also has a component radial toward the nucleus of over 100 km/s. The stars, however, continue their prograde rotation. Beyond this transition zone, the neutral gas continues its retrograde rotation, stellar velocities are prograde, but the sense of the almost circular arms is not established. Because of its kinematical complexity as well as its proximity, NGC 4826 is an excellent early-type galaxy in which to observe the long term effects of gas acquistion or a galaxy merger on a disk galaxy.

Rubin, Vera C.↗

Design of a Dual Waveguide Normal Incidence Tube (DWNIT) Utilizing Energy and Modal Methods

This report investigates the partition design of the proposed Dual Waveguide Normal Incidence Tube (DWNIT). Some advantages provided by the DWNIT are (1) Assessment of coupling relationships between resonators in close proximity, (2) Evaluation of "smart liners", (3) Experimental validation for parallel element models, and (4) Investigation of effects of simulated angles of incidence of acoustic waves. Energy models of the two chambers were developed to determine the Sound Pressure Level (SPL) drop across the two chambers, through the use of an intensity transmission function for the chamber's partition. The models allowed the chamber's lengthwise end samples to vary. The initial partition design (2" high, 16" long, 0.25" thick) was predicted to provide at least 160 dB SPL drop across the partition with a compressive model, and at least 240 dB SPL drop with a bending model using a damping loss factor of 0.01. The end chamber sample transmissions coefficients were set to 0.1. Since these results predicted more SPL drop than required, a plate thickness optimization algorithm was developed. The results of the algorithm routine indicated that a plate with the same height and length, but with a thickness of 0.1" and 0.05 structural damping loss, would provide an adequate SPL isolation between the chambers.

Betts, Juan F.↗

Space Environment Factors Affecting the Performance of International Space Station Materials: The First Two Years of Flight Operations

In this paper, the natural and induced space environment factors affecting materials performance on ISS are described in some detail. The emphasis will be on ISS flight experience and the more significant design and development issues of the last two years. The intent is to identify and document the set of space environment factors, affecting materials, that are producing the largest impacts on the ISS flight hardware verification and acceptance process and on ISS flight operations. Orbital inclination (S1.6 ) and altitude (nominal3S0 km to 400 km altitude) determine the set of natural environment factors affecting the functional life of materials and subsystems on ISS. ISS operates in the F2 region of Earth's ionosphere in well-defined fluxes of atomic oxygen, other ionospheric plasma species, and solar UV, VUV, and x-ray radiation, as well as galactic cosmic rays, trapped radiation, and solar cosmic rays (1,2). The high latitude orbital environment also exposes external surfaces to significantly less well-defined or predictable fluxes of higher energy trapped electrons and auroral electrons (3 ,4). The micrometeoroid and orbital debris environment is an important determinant of spacecraft design and operations in any orbital inclination. Environment factors induced by ISS flight operations include ram-wake effects, magnetic induction voltages arising from flight through Earth's magnetic field, hypergolic thruster plume impingement from proximity operations of visiting vehicles, materials outgassing, venting and dumping of fluids, ISS thruster operations, as well as specific electrical power system interactions with the ionospheric plasma (S-7). ISS must fly in a very limited number of approved flight attitudes leading to location specific environmental exposures and extreme local thermal environments (8). ISS is a large vehicle and produces a deep wake structure from which both ionospheric plasma and neutrals (atomic oxygen) are largely excluded (9-11). At high latitude, the ISS wake may produce a spacecraft charging environment similar to that experienced by the DMSP and Freja satellites (800 to 100 km altitude polar orbits), especially during geo-magnetic disturbances (12-14). ISS is also subject to magnetic induction voltages (VxB L) on conducting structure, a result of high velocity flight through Earth's magnetic field. The magnitude of the magnetic induction voltage varies with location on ISS, as well as the relative orientation of the vehicle velocity vector and planetary magnetic field vector, leading to maximum induction voltages at high latitude (15). The space environment factors, natural and induced, that have had the largest impact on pre-launch ISS flight hardware verification and flight operations during the first two years of ISS flight operations are listed below and grouped according to the physical and chemical processes driving their interaction with ISS materials.

Koontz, Steven L.↗

Characterization of the Ignition Over-Pressure/Sound Suppression Water in the Space Launch System Mobile Launcher Using Volume of Fluid Modeling

The Space Launch System (SLS) Vehicle consists of a Core Stage with four RS-25 engines and two Solid Rocket Boosters (SRBs). This vehicle is launched from the Launchpad using a Mobile Launcher (ML) which supports the SLS vehicle until its liftoff from the ML under its own power. The combination of the four RS-25 engines and two SRBs generate a significant Ignition Over-Pressure (IOP) and Acoustic Sound environment. One of the mitigations of these environments is the Ignition Over-Pressure/Sound Suppression (IOP/SS) subsystem installed on the ML. This system consists of six water nozzles located parallel to and 24 inches downstream of each SRB nozzle exit plane as well as 16 water nozzles located parallel to and 53 inches downstream of the RS-25 nozzle exit plane. During launch of the SLS vehicle, water is ejected through each water nozzle to reduce the intensity of the transient pressure environment imposed upon the SLS vehicle. While required for the mitigation of the transient pressure environment on the SLS vehicle, the IOP/SS subsystem interacts (possibly adversely) with other systems located on the Launch Pad. One of the other systems that the IOP/SS water is anticipated to interact with is the Hydrogen Burn-Off Igniter System (HBOI). The HBOI system's purpose is to ignite the unburned hydrogen/air mixture that develops in and around the nozzle of the RS-25 engines during engine start. Due to the close proximity of the water system to the HBOI system, the presence of the IOP/SS may degrade the effectiveness of the HBOI system. Another system that the IOP/SS water may interact with adversely is the RS-25 engine nozzles and the SRB nozzles. The adverse interaction anticipated is the wetting, to a significant degree, of the RS-25 nozzles resulting in substantial weight of ice forming and water present to a significant degree upstream of the SRB nozzle exit plane inside the nozzle itself, posing significant additional blockage of the effluent that exits the nozzle upon motor start leading to detrimental effects. The purpose of the CFD simulations were to i) characterize the location of the IOP/SS water after it is ejected from the IOP/SS nozzles, ii) characterize the interaction of the IOP/SS system with the HBOI system and iii) characterize the interaction of the IOP/SS water with the RS-25 nozzles and the SRB nozzles.

West, Jeff↗

Temporary Atmospheres Produced By Human Activities on the Moon

Outgassing from materials, whether through the ascent/descent stages of lunar vehicles, airlock depressurizing, rover or astronaut suit outgassing, may cause an effect of unwanted accumulation of volatiles at the surface and exosphere. This is especially important at (or proximal) to permanently shadowed regions (PSRs) at the lunar poles. Herein, we provide estimates of expected outgassing from various human-landed objects on the Moon, including backpacks, airlocks, rovers, landers, trash and mining operations. Astronaut suits produce some level of oxygen outgassing (Helou et al., 2022), which may transport and condense in these PSRs, even in micro- cold traps (Glavin et al., 2010).We estimate the outgassing from drill mining and trash-to-gas conversion assuming a specific technology is operating. These outgassing systems can create local, temporary atmospheres in the vicinity (∼100 km radius) of the sources. The atmosphere may be particularly high within meters of the source. To obtain column densities for these temporary atmospheres, we first bracket ranges for the gas number loss as a function of time. We then derive the maximum distance traveled and the time the released molecules remain in the exosphere for a single ballistic hop, assuming the molecules are ejected from the surface of the object at its surface temperature. In some cases, such as the astronaut backpack and the rover, the temperature is that of the source. Given this information, an average and peak local exospheric density and column density can be estimated. We find that backpacks, airlock releases, and the Starship lander can create relatively high-density local atmospheres, with local near-lander outgassing water densities exceeding 107/cm3. This local water exosphere is over 106 times greater than the LADEE-derived lower limit of the natural water exosphere at ∼3/cm3. Thus, the anthropogenic temporary water exosphere will likely dominate the environment near the lander, making an assessment of the natural exospheric water environment difficult.

Rosemary M Killen↗

Crucial Role of Thermal Gradients in MMS Fluxgate In-Flight Calibration

To meet the science goals of the Magnetospheric Multiscale (MMS) mission, the Fluxgate Magnetometer (FGM) must measure the ambient magnetic field with an accuracy of 0.1 nT. On a typical MMS orbit, the offsets (or zero levels) of the 3-axis FGM can vary by ~0.5 nT (exclusive of periods in Earth shadow). Previous studies have shown that these variations can be characterized as functions of sensor temperature, TS, and can thus be corrected to within 0.2 nT in the spin plane using in-flight calibration techniques (Bromund, et al., 2016, https://ntrs.nasa.gov/citations/20160014711). In that presentation, we noted two significant observations: A distinct function of TS must be used to characterize offsets during shadow: offsets at a given TScan differ by as much as 2 nT in shadow vs sunlight. Offsets change after maneuvers, without a commensurate change in TS . These changes can be as large as 2 nT. We now note a third, related observation: Offsets increase with proximity to the earth even when TS is constant, resulting in variations of ~0.2 nT at 4-5 Earth radii (RE) These effects are evidence that offsets are a multivariate function of TS and another factor, namely: thermal gradients. Due to the spacecraft spin, the Earth and the Sun each provide a relatively constant thermal input onto one instrument face while the opposite face remains in shadow, thus giving rise to thermal gradients. The thermal gradient depend on the orientation of the spin axis relative to the Earth or Sun. We observe that offsets vary by as much as 0.17 nT/degree as a function of the tilt of the spin axis towards the Sun. Thermal input from the Earth is dominated by Outgoing Longwave Radiation (OLR). Due to the proximity to Earth, the inverse proportion of the distance squared is a significant factor in the thermal gradient attributed to Earth OLR. We find that offsets can be corrected to <0.05 nT accuracy near perigee when accounting for these factors using empirically determined constants of proportionality that account for differences in emissivity of the top and bottom faces of the sensor to OLR (as well as other thermal effects). The changes in offset associated with thermal gradient are of the same order of magnitude as effects that were formerly attributed to sensor temperature alone, and thus both parameters are necessary to characterize the FGM offsets.

Kenneth R Bromund↗

Skeletal unloading induces selective resistance to the anabolic actions of growth hormone on bone

Loss of skeletal weight bearing or physical unloading of bone in the growing animal inhibits bone formation and induces a bone mineral deficit. To determine whether the inhibition of bone formation induced by skeletal unloading in the growing animal is a consequence of diminished sensitivity to growth hormone (GH) we studied the effects of skeletal unloading in young hypophysectomized rats treated with GH (0, 50, 500 micrograms/100 g body weight/day). Skeletal unloading reduced serum osteocalcin, impaired uptake of 3H-proline into bone, decreased proximal tibial mass, and diminished periosteal bone formation at the tibiofibular junction. When compared with animals receiving excipient alone, GH administration increased bone mass in all animals. The responses in serum osteocalcin, uptake of 3H-proline and 45Ca into the proximal tibia, and proximal tibial mass in non-weight bearing animals were equal to those in weight bearing animals. The responses in trabecular bone volume in the proximal tibia and bone formation at the tibiofibular junction to GH, however, were reduced significantly by skeletal unloading. Bone unloading prevented completely the increase in metaphyseal trabecular bone normally induced by GH and severely dampened the stimulatory effect (158% vs. 313%, p < 0.002) of GH on periosteal bone formation. These results suggest that while GH can stimulate the overall accumulation of bone mineral in both weight bearing and non-weight bearing animals, skeletal unloading selectively impairs the response of trabecular bone and periosteal bone formation to the anabolic actions of GH.

Non-NASA Center↗

Phase-Slip Lines and Anomalous Josephson Effects in Tungsten Nanoscale Cluster-Based Topological Insulator Nanobridges: Implications for Topologically Protected Qubits and Quantum Sensors

Superconducting topological systems formed by a strong 3D topological insulator (TI) in proximity to a conventional s-wave superconductor (SC) have been intensely studied, as they may host Majorana zero modes. However, there are limited experimental realizations of TI-SC systems in which robust superconducting pairing is induced on the surface states of the TI and a topological superconducting state is established. Here, we fabricate a TI-SC system by depositing, via a focused ion beam, tungsten (W) nanoscale clusters on the surface of TI Bi 0.91 Sb 0.09 . We find that the resulting heterostructure supports phase-slip lines (PSLs) that act as effective Josephson junctions (JJs). Here, we probe the response of the system to microwave radiation. We find that for some ac frequencies, and powers, the resulting Shapiro steps’ structure of the voltage–current characteristic exhibits a missing first step and an unexpectedly wide second Shapiro step. The theoretical analysis of the measurements shows that the unusual Shapiro response arises from the interplay between a static JJ and a dynamic one and allows us to identify the conditions under which the missing first step can be attributed to the topological nature of the JJs formed by the PSLs. Our results suggest an approach to induce superconductivity in a TI, a route to realizing highly transparent topological JJs, and show how the response of superconducting systems to microwave radiation can be used to infer the dynamics of PSLs. Highly transparent topological junctions are promising candidates to realize vector field sensors with very high sensitivity. In addition, due to the nontrivial Berry phase of the TI’s surface states such junctions can be in a topological state which is ideal to create topologically protected qubits.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Nitric oxide delivery and heme-assisted S-nitrosation by the bedbug nitrophorin

Here, nitrophorins are heme proteins used by blood feeding insects to deliver nitric oxide (NO) to a victim, leading to vasodilation and antiplatelet activity. Cimex lectularius (bedbug) nitrophorin (cNP) accomplishes this with a cysteine ligated ferric (Fe(III)) heme. In the acidic environment of the insect's salivary glands, NO binds tightly to cNP. During a blood meal, cNP-NO is delivered to the feeding site where dilution and increased pH lead to NO release. In a previous study, cNP was shown to not only bind heme, but to also nitrosate the proximal cysteine, leading to Cys-NO (SNO) formation. SNO formation requires oxidation of the proximal cysteine, which was proposed to be metal-assisted through accompanying reduction of ferric heme and formation of Fe(II)-NO. Here, we report the 1.6 Å crystal structure of cNP first chemically reduced and then exposed to NO, and show that Fe(II)-NO is formed but SNO is not, supporting a metal-assisted SNO formation mechanism. Crystallographic and spectroscopic studies of mutated cNP show that steric crowding of the proximal site inhibits SNO formation while a sterically relaxed proximal site enhances SNO formation, providing insight into specificity for this poorly understood modification. Experiments examining the pH dependence for NO implicate direct protonation of the proximal cysteine as the underlying mechanism. At lower pH, thiol heme ligation predominates, leading to a smaller trans effect and 60-fold enhanced NO affinity (K d = 70 nM). Unexpectedly, we find that thiol formation interferes with SNO formation, suggesting cNP-SNO is unlikely to form in the insect salivary glands.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The response of accident tolerant fuel cladding to LOCA burst testing: A comparative study of leading concepts

Accident tolerant fuel claddings seek to improve safety margins during loss-of-coolant accident (LOCA) scenarios by reducing cladding steam oxidation rates, hydrogen production, delaying or mitigating cladding burst, and reducing cladding deformation. After rapid and extensive progress in recent years, Cr coated Zr-based alloys, ferritic FeCrAl, and SiC/SiC ceramic matrix composites (CMCs) have emerged as the most promising cladding concepts, but there are few studies comparing the accident tolerance of all three concepts simultaneously. Here, in this study, LOCA burst testing has been conducted on Cr high impulse power magnetron sputtered Zry-4 (Cr/Zry-4), C26M (FeCrAl), and SiC/SiC SiGA (CMC). Experimental observations indicate Cr/Zry-4 burst at higher temperatures than Zry-4 however the effectiveness of the coating on mitigating ZrO 2 formation via Cr 2 O 3 formation depended on physical proximity to the burst opening. No dramatic improvement in diametrical strain nor opening geometry was observed. C26M burst at higher temperatures than Zry-4 at lower pressures, exhibiting small amounts of strain and smaller openings, and formed slow-growing Al 2 O 3 regardless of location. The CMCs did not burst or show any macroscopic signs of deformation, all the way up to an internal cladding pressure of 15.2 MPa. High temperature expanding Nb plug testing indicated that CMC room temperature strength may persist up to 1650°C, with an approximately 40% loss of strength at 1900°C. CMC steam oxidation was also compared to reference chemically vapor deposited SiC up to 1700°C, and CMCs were found to oxidize at slightly accelerated rates that were still orders of magnitude lower than bare Zry-4. Projected H 2 generation during LOCA burst testing showed that when accounting for cladding burst exposing inner diameters to steam, Cr coated Zry-4 reduced H 2 generation by a factor of two compared with bare Zry-4, while both C26M and SiC/SiC reduced H 2 generation by orders of magnitude relative to bare Zry-4.

36 MATERIALS SCIENCE↗

Electrical Detection of Spin-Hall-Induced Auto-oscillations in Lithium Aluminate Ferrite Thin Films

Ferrimagnetic insulators with ultralow damping are of great interest for their potential applications in energy-efficient computing devices. Here, we report the direct electrical detection of magnetic auto-oscillations in unpatterned ultralow damping ferrimagnetic insulator epitaxial Li 0.5 Al 0.5 Fe 2 O 4 thin films, driven by a current in a proximal Pt nanowire. Auto-oscillations occur for only one current polarity, consistent with the spin-Hall effect inducing the oscillation state. Micromagnetic modeling shows good agreement with the experimental frequency and field dispersions, showing only one dominant oscillation mode, in contrast to the multiple modes typically observed in transition-metal nanowire-type spin-Hall nanooscillators. This study illustrates a new material system for neuromorphic computing and magnonics, a simple material platform with the direct-current generation of high-frequency (~10 GHz) signals and their electrical detection.

36 MATERIALS SCIENCE↗

Shuttle booster separation aerodynamics

A wind tunnel test program of some complexity was used to define the aerodynamic forces exerted on the space shuttle solid rocket boosters and orbiter/external tank during staging. In these tests, problems associated with the use of up to three models in close proximity and with the need to simulate high pressure separation motor plumes were handled in a unique and effective manner. A new method was developed for efficiently organizing data which is a function of a large number of independent variables. Data derived from the test program drastically reduced previous estimates of aerodynamic uncertainties and allowed certification of the separation system at the design maximum staging dynamic pressure. Reduction of flight data has implicitly verified the staging aerodynamics data base and its associated uncertainties.

Mark K. Craig↗

Deimos: A reddish, D-type asteroid spectrum

We have obtained high quality CCD spectra of Deimos from 0.5 to 1.0 microns at a spectral resolution of 15 A. The spectra are remarkably red, similar to the spectra of D type asteroids rather than those of carbonaceous chondrites or C type asteroids. During the 1988 opposition of Mars, we obtained new CCD spectra of its outer satellite, Deimos. The data were obtained over a 2 1/2 hour period on the night of 9 Oct., using the 1.54 meter Catalina telescope and the LPL long-slit CCD spectrometer. From 0.5 to 1.1 microns, the spectrum is dispersed across an 800 x 800 Texas Instruments CCD chip at a scale of 7.21 A per pixel for an effective lambda/delta(lambda) approximately equals 500. The primary observational difficulty in ground based spectroscopy of Deimos was its proximity to Mars. To minimize scattered light from Mars, Deimos was observed near greatest elongation. The spectrograph slit was narrowed to 2.5 arcseconds, slightly larger than the seeing disk. An apodizing mask at the re-imaged telescope primary, to remove the diffraction cross of Mars light caused by the telescope's secondary mirror mount. Residual scattered light was modeled and removed in data reduction. Solar analog stars BS560, BS2007, and BS8931 were observed to allow removal of telluric absorptions. The resulting spectrum is plotted with other data.

Grundy, William M.↗