Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Photodissociation”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 487 records · Page 27
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Coupling Between the Thermosphere and the Stratosphere: the Role of Nitric Oxide

In order to understand the lower ionosphere and its probable control by dynamical processes, the behavior of nitric oxide below 100 km was investigated. A two dimensional model with coupled chemical and dynamical processes was constructed. Calculations based on the model reveal that the chemical conditions at the stratopause are related to the state of the thermosphere. This coupling mechanism can be partly explained by the downward transport of nitric oxide during the winter season, and consequently depends on the dynamical conditions in the mesosphere and in the lower thermosphere (mean circulation and waves). In summer, the photodissociation of nitric oxide plays an important role and the thermospheric NO abundance modulates the radiation field reaching the upper stratosphere. Perturbations in the nitric oxide concentration above the mesopause could therefore have an impact in the vicinity of the stratopause.

Brasseur, G.↗
NASA NTRS1985

Cometary atmospheres: Modeling the spatial distribution of observed neutral radicals

The dependencies on heliocentric velocity for the solar photodissociation lifetime and the solar fluorescence rate of the OH radical were incorporated into the Monte Carlo particle trajectory model for cometary radicals. For the case of CN a study was initiated on the effects of using several different adopted models on the calculation of production rates from filter photometry. Progress in these areas is discussed. A comparison of two different sets of scale length data for cometary C2 and CN is also presented.

Combi, M. R.↗
NASA NTRS1984

Luminosity and spatial distribution of the forbidden O I 6300-A emission in comets

The Tuttle, Stephan-Oterna, and Brooks 2 comets have been subjected to CCD observations of the 6300 and 6364 A forbidden oxygen lines, in order to determine the spatial profiles and absolute luminosities of the cometary forbidden O I lines. Analysis indicates the source of the observed O I photons to be direct photodissociation of water vapor. O 1D production by dissociation of OH becomes dominant at larger distances from the nucleus, and the water vapor production rates derived from O I emissions are found to be in good agreement with those determined from forbidden line OH by the IUE spacecraft, as well as ground-based photometry. It is demonstrated that analysis of cometary O 1D emission allows the determination of the spatial distribution of the parent molecule water vapor.

Fink, U.↗
NASA NTRS1984

New model of Saturn's ionosphere with an influx of water from the rings

A radically different model of Saturn's ionosphere is proposed in which water plays a major role as a minor constituent present by downward diffusion from an external source. The model ionosphere is a classical F2 type layer resulting from the photodissociative production of H(+) from H2 and rapid chemical loss by a series of charge exchange reactions with water. A planet-wide influx of about 4 x 10 to the 7th molecules/sq cm/s of water from the rings is consistent with the observed ionospheric electron densities. An enhanced influx of water occurs at latitudes (-38, +44 deg) connected magnetically at the inner edge of Saturn's B ring, where an electromagnetic erosion process takes place. The present-day influx at these latitudes may be as large as 2 x 10 to the 9th molecules/sq cm/s.

Connerney, J. E. P.↗
NASA NTRS1984

Lambda-doublet transfer and propensities in collisions of OH (X2Pi/i/, v = 2) with H2O

The present work is concerned with the changes in electronic parity (e/f states) during rotationally elastic and inelastic collisions. In the OH X2Pi(i) molecule considered in the study, the differences in the e/f state production in the photodissociation of both H2O and HONO1, in the H + O2 reaction, and in the initial-state-unselected H2-OH collisions, have been experimentally examined.

Copeland, R. A.↗
NASA NTRS1984

The CN radical in diffuse interstellar clouds

A survey of 15 lines of sight for the CN B2Sigma(+) X2Sigma(+) interstellar absorption lines shows that the CN column density in diffuse interstellar clouds follows the relation log N(CN) is proportional to m log N(H2), where m is approximately equal to 3. This result is reproduced by a reaction network in which CN is produced primarily from C2 by the neutral-neutral reaction C2 + N yields CN + C, and photodissociation is the main destruction pathway for the neutral molecules CH, C2, and CN. The CN radical is the first molecular species observed in diffuse clouds that requires a neutral-neutral reaction for its formation in the gas phase. The network also reproduces the observed ratio N(CN)/N(H2).

Federman, S. R.↗
NASA NTRS1985

Shielding of CO from dissociating radiation in interstellar clouds

The paper investigates the photodissociation of CO in interstellar clouds in the light of recent laboratory studies which suggest that line rather than continuum processes dominate its dissociation by ultraviolet radiation. Using a simple radiative transfer model, the shielding of representative dissociating bands is estimated, including self-shielding, mutual shielding between different isotopes, and near coincidences with strong lines of H2. Each of these processes materially affects the photodestruction rates of the various isotopic species in the transition regions of molecular clouds. These results are combined with an appropriate gas phase chemical model to determine how the abundances of the CO isotopes vary with depth into the cloud. It is found that self-shielding and mutual shielding cause significant variations in isotopic ratios. In addition, fractionation enhances species containing C-13. The relationship between the column densities of CO and H2 is found to vary for the different isotopes and to be sensitive to local conditions.

Glassgold, A. E.↗
NASA NTRS1985

Sensitivity of N2O, CFCl3, and CF2Cl2 two-dimensional distributions to O2 absorption cross sections

A good test of the transport and ultraviolet radiation treatment for any model can be based on the consideration of the three gases N2O, CFCl3 (F-11), and CF2Cl2 (F-12). Attention is given to a two-dimensional model which makes it possible to study changes in seasonal and latitudinal distributions which result from O2 cross-section changes. A latitude-dependent ozone decrease has already been predicted by two-dimensional models for chlorofluoromethane (CFM) release. For this reason, it is of interest to determine if a strong latitude-dependent change is detectable in the CFM profiles. One-dimensional models have pointed toward a trend of decreased trace gas concentrations in correlation with decreased O2 cross sections. The O2 cross sections between 180 and 230 nm are changed within a range of experimentlly allowed values. It is found that lower O2 absorption cross sections lead to larger photodissociation rates for the trace gases F-11, F-12, and N2O.

Jackman, C. H.↗
NASA NTRS1985

Self-shielding in O2 - A possible explanation for oxygen isotopic anomalies in meteorites?

The production of isotopic effects in oxygen due to self-shielding of photolysing radiation by the Schumann-Runge bands of (O-16)2 is investigated. The model studied is the simple case of incoming radiation falling on a gaseous medium of uniform composition. The enhancement of O-17 and O-18 production upon photodissociation of O2 is calculated for various column densities, and its dependence on temperature and the presence of other molecules is examined. The issue of whether the products of photolysis can be trapped and thus preserve a peculiar isotopic composition is discussed.

Navon, O.↗
NASA NTRS1985

Far-infrared spectroscopy of galaxies - The 158 micron C(+) line and the energy balance of molecular clouds

Observations of the 158 microns fine-structure line of C(+) toward the nuclei of six gas-rich galaxies are presented. The observations are compared with observations of the CO J = 1-0 and H I 21 cm lines, observations of far-IR continuum emission, and observations of forbidden C II emission with the Galaxy. The forbidden C II line comes from dense, warm gas in UV-illuminated photodissociation regions at the surfaces of molecular clouds. This line is probably optically thin in all but the brightest of galactic sources. The variation of forbidden C II brightness from source to source and its ratio to the integrated infrared continuum intensity agree well with the theoretical prediction that UV absorption by dust controls the C(+) column density. The forbidden C II line is a tracer of molecular clouds, especially those near intense sources of UV radiation.

Crawford, M. K.↗
NASA NTRS1985

Threshold kinetic processes for t-C4F9I

To determine the relative threshold of the lasant gas t-C4F9I in comparison to n-C3F7I, the pump energy to reach threshold for photodissociation iodine lasing is measured in a common aparatus. The comparison is made for the threshold energies in the iodide pressure range up to 50 Torr when 64-J electric input into a flashlamp is used for pumping. It is shown from the results that qualitative differences between the thresholds of the two gases result from the degree to which steady state is achieved by the time threshold is reached. The estimated recombination rate for t-C4F9I is found to be much larger than the value given by Ershov et al (1978).

Lee, J. H.↗
NASA NTRS1985

Temporal characteristics of the solar UV flux and He I line at 1083 nm

It is pointed out that the solar UV flux in the 170- to 210-nm range is important because it photodissociates O2 in the terrestrial atmosphere and thereby initiates the production of ozone and other odd-oxygen chemistry in the stratosphere. The 210- to 290-nm solar UV flux heats the stratosphere. There is consequently a great interest in the temporal variations of the solar UV flux and its relation to ground-based measures of solar activity which may be useful in estimating the UV flux variations. The present investigation is concerned with daily values of 205-nm solar UV flux data measured with the aid of the Nimbus 7 satellite during the period from November 1978 to November 1982, taking into account also measurements of the equivalent width of the He I solar absorption line at 1083 at the National Solar Observatory. Attention is given to an analysis of the data, episodes of activity, and long-term variations.

Donnelly, R. F.↗
NASA NTRS1985

The N II 2143-A dayglow from Spacelab 1

During the Spacelab 1 Shuttle mission (November 28 to December 7, 1983) spectral measurements were made in the ultraviolet which resolve the N(+)(S-5) doublet at 2143 A from the NO(1-0) gamma band at 2148 A in the upper thermosphere. The measured slant-path surface-brightness profile of the N(+) feature is well explained by photodissociative ionization of N2 with a yield of 0.2. The intensity of the N(+) feature relative to the NO(1-0) gamma band is dependent on the conditions prevailing at the time and location of the measurement. For the near-twilight mid-latitude measurements made in the upper thermosphere the N(+)(S-5) feature would contribute 20 to 75 percent of a low spectral resolution NO measurement.

Torr, M. R.↗
NASA NTRS1985

Extinction coefficient of H2CC(3B2) at 137 nm

In spite of the conduction of numerous studies regarding the vinylidene free radical, its role and importance as a reactive intermediate is not well characterized. Laufer (1980, 1983) has reported the absorption spectrum of metastable H2CC(3B2), the lowest excited state, in the vacuum ultraviolet and has measured several aspects of its quenching properties. The present study provides a measurement of the extinction coefficient of H2CC(3B2). Knowledge of the vinylidene concentration is required to convert readily available absorption data into an extinction coefficient or cross section. In the current work, the H2CC(3B2) concentration was determined in an investigation of the photodissociation of vinyl chloride.

Fahr, A.↗
NASA NTRS1985

Solar pressure and molecular decay in cometary atmospheres

The effects of solar pressure and molecular decay on number density in cometary atmospheres are rigorously separated and scale lengths for each are determined from an analysis of observed brightness profiles in the solar and antisolar directions. It is found that the pressure scale length of CN is approximately 160,000 km and that of C2 is approximately 110,000 km. The scale length for molecular decay, heretofore incorrectly inferred from the observational data, is approximately 3 times as long as the pressure scale lengths. It is difficult to determine adequately from observations that extend no more than about 100,000 km from the comet nucleus. The scale length for molecular decay by photodissociation or whatever cause is found to be about 350,000 km for C2 and 500,000 km for CN.

Beard, D. B.↗
NASA NTRS1985

Direct solar-pumped iodine laser amplifier

This semiannual progress report covers the period from April 1, 1985 to Sept. 30, 1985 under NASA grant NAS1-441 entitled direct solar pumped iodine laser amplifier. During this period the parametric studies of the iodine laser oscillator pumped by a Vortek simulator was carried out before the amplifier studies. The amplifier studies are postponed to the extended period following completion of the parametric studies. In addition, the kinetic modeling of a solar pumped iodine laser amplifier, and the experimental work for a solar pumped dye laser amplifier are in progress. This report contains three parts: (1) the radiation characteristics of solar simulator and the parametric characteristics of photodissociation iodine laser continuously pumped by a Vortek solar simulator; (2) kinetic modeling of a solar pumped iodine laser amplifier; and (3) the study of the dye laser amplifier pumped by a Tamarack solar simulator.

Han, K. S.↗
NASA NTRS1985

Extended atmospheres of outer planet satellites and comets

The new cometary hydrogen particle-trajectory model, completed last year, has been used successfully to analyze observations of Comet P/Giacobini-Zinner. The Pioneer Venus Orbiter Ultraviolet Spectrometer observed the comet at 1216 A (hydrogen Lyman-a) on 11 September 1985 when the comet was 1.03 AU from the Sun and 1.09 AU from Venus. The analysis implies a production rate at 1.03 AU 2.3 x 10 to the 28th power/sec of the water molecules which photodissociate to produce the observed hydrogen. An upper limit for the H2O production rate of Comet P/Halley of 5 x 10 to the 28th power/sec at 2.60 AU was also obtained from the Pioneer Venus instrument.

Smyth, W. H.↗
NASA NTRS1986

Measurements of HO2 chemical kinetics with a new detection method

Research for the period from December 1, 1985 to May 31, 1986 is discussed, i.e., the reaction rate constant of HO2+O3 has been measured with a discharge-flow-tube apparatus. The HO2 radical was detected by the OH(A-X) photofragment emission produced from photodissociative excitation of HO2 at 147 nm. In the meantime, the optical emissions produced by the vacuum ultraviolet excitation of chemical species in the flow tube were investigated and used to examine the possibility for their interference with the HO2 detection. The research results are summarized below.

Lee, L. C.↗