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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 487 records · Page 27
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Dual-Wavelength Simultaneous Patterning of Degradable Thermoset Supports for One-Pot Embedded 3D Printing

Vat photopolymerization (VP) techniques have enabled the fabrication of complex geometries while balancing high precision and fast processing times. 3D printed objects are traditionally built layer-by-layer with newly cured layers being structurally supported by previous ones. Fabricating unsupported features such as overhangs and arches risks misalignment and sagging, limiting the range of accessible designs. To overcome this issue, support structures are fabricated along with the primary object as temporary scaffolds that provide stability and conserve print fidelity. For VP specifically, patterning dissolvable sacrificial supports is attractive to avoid manual removal after printing. In this study, we demonstrate a base-degradable thermoset to pattern print supports in a one-pot formulation along with the primary structural material. Efficient printing is enabled using a dual-wavelength negative imaging (DWNI) DLP printer that patterns the degradable thermoset with visible light and the permanent network with UV light, which are simultaneously projected using a single digital micromirror device (DMD). Printed objects undergo thermal postprocessing to enhance the final conversion of the primary material, after which thermoset supports are degraded in a basic, aqueous solution. This approach provides a robust method for the dual-wavelength patterning of sacrificial thermoset supports, broadening the range of accessible 3D printable materials and geometries.

3D printing↗
DOE OSTI2017

Sub-10-nm patterning via directed self-assembly of block copolymer films with a vapour-phase deposited topcoat

Directed self-assembly (DSA) of the domain structure in block copolymer (BCP) thin films is a promising approach for sub-10-nm surface patterning. DSA requires the control of interfacial properties on both interfaces of a BCP film to induce the formation of domains that traverse the entire film with a perpendicular orientation. Here we show a methodology to control the interfacial properties of BCP films that uses a polymer topcoat deposited by initiated chemical vapour deposition (iCVD). The iCVD topcoat forms a crosslinked network that grafts to and immobilizes BCP chains to create an interface that is equally attractive to both blocks of the underlying copolymer. The topcoat, in conjunction with a chemically patterned substrate, directs the assembly of the grating structures in BCP films with a half-pitch dimension of 9.3 nm. As the iCVD topcoat can be as thin as 7 nm, it is amenable to pattern transfer without removal. As a result, the ease of vapour-phase deposition, applicability to high-resolution BCP systems and integration with pattern-transfer schemes are attractive properties of iCVD topcoats for industrial applications.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Moiré pattern of interference dislocations in condensate of indirect excitons

Interference patterns provide direct measurement of coherent propagation of matter waves in quantum systems. Superfluidity in Bose–Einstein condensates of excitons can enable long-range ballistic exciton propagation and can lead to emerging long-scale interference patterns. Indirect excitons (IXs) are formed by electrons and holes in separated layers. The theory predicts that the reduced IX recombination enables IX superfluid propagation over macroscopic distances. Here, we present dislocation-like phase singularities in interference patterns produced by condensate of IXs. We analyze how exciton vortices and skyrmions should appear in the interference experiments and show that the observed interference dislocations are not associated with these phase defects. We show that the observed interference dislocations originate from the moiré effect in combined interference patterns of propagating condensate matter waves. The interference dislocations are formed by the IX matter waves ballistically propagating over macroscopic distances. The long-range ballistic IX propagation is the evidence for IX condensate superfluidity.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Urban land patterns can moderate population exposures to climate extremes over the 21st century

Abstract Climate change and global urbanization have often been anticipated to increase future population exposure (frequency and intensity) to extreme weather over the coming decades. Here we examine how changes in urban land extent, population, and climate will respectively and collectively affect spatial patterns of future population exposures to climate extremes (including hot days, cold days, heavy rainfalls, and severe thunderstorm environments) across the continental U.S. at the end of the 21st century. Different from common impressions, we find that urban land patterns can sometimes reduce rather than increase population exposures to climate extremes, even heat extremes, and that spatial patterns instead of total quantities of urban land are more influential to population exposures. Our findings lead to preliminary suggestions for embedding long-term climate resilience in urban and regional land-use system designs, and strongly motivate searches for optimal spatial urban land patterns that can robustly moderate population exposures to climate extremes throughout the 21st century.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Vortex-induced anomalies in the superconducting quantum interference patterns of topological insulator Josephson junctions

The superconducting quantum interference (SQI) patterns of Josephson junctions fabricated from hybrid structures that interface an s-wave superconductor with a topological insulator can be used to detect signatures of novel quasiparticle states. Here, we compare calculated and experimental SQI patterns obtained from hybrid junctions fabricated on cadmium arsenide, a two-dimensional topological insulator. The calculations account for the effects of Abrikosov (anti-) vortices in the superconducting contacts. They describe the experimentally observed deviations of the SQI from an ideal Fraunhofer pattern, including anomalous phase shifts, node lifting, even/odd modulations of the lobes, irregular lobe spacing, and an asymmetry in the positive/negative magnetic field. We also show that under a current bias, these vortices enter the electrodes even if there is no intentionally applied external magnetic field. The results show that Abrikosov vortices in the electrodes of the junctions can explain many of the observed anomalies in the SQI patterns of topological insulator Josephson junctions.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Greater committed warming after accounting for the pattern effect

Our planet’s energy balance is sensitive to spatial inhomogeneities in sea surface temperature and sea ice changes, but this is typically ignored in climate projections. Here, we show the energy budget during recent decades can be closed by combining changes in effective radiative forcing, linear radiative damping and this pattern effect. The pattern effect is of comparable magnitude but opposite sign to Earth’s net energy imbalance in the 2000s, indicating its importance when predicting the future climate on the basis of observations. Additionally, after the pattern effect is accounted for, the best-estimate value of committed global warming at present-day forcing rises from 1.31 K (0.99–2.33 K, 5th–95th percentile) to over 2 K, and committed warming in 2100 with constant long-lived forcing increases from 1.32 K (0.94–2.03 K) to over 1.5 K, although the magnitude is sensitive to sea surface temperature dataset. Further constraints on the pattern effect are needed to reduce climate projection uncertainty.

58 GEOSCIENCES↗
DOE OSTI2017

Information Connections among Multiple Investors: Evolutionary Local Patterns Revealed by Motifs

The concept of motifs provides a fresh perspective for studying local patterns, which is useful for understanding the essence of a network structure. However, few previous studies have focused on the evolutionary characteristics of weighted motifs while further considering participants’ differences. We study how information connections differ among multiple investors. The evolutionary 10-year trend of weighted 3-motifs in China’s energy stock markets is explored for the networks of co-holding behaviors among shareholders, who are classified as companies, funds and individuals. Our works allow us to detect the preferential local patterns distributed among different agents as their fluctuate involvement in networks. We find that the diversity of shareholders contributes to the statistical significance of local patterns, while homophily always exist among individuals. Modules of information connections are stable among reserved investors, which is especially apparent among companies. Individuals prefer to keep their connections with companies and funds. Unsteady modules happen owing to strengthen links among funds during the time that they are main participants in stock markets. More details about multiple investors informationally connected in evolutionary local patterns can be detected by our work.

99 GENERAL AND MISCELLANEOUS↗
DOE OSTI2018

Ferroelectric Domain Studies of Patterned (001) BiFeO 3 by Angle-Resolved Piezoresponse Force Microscopy

We have studied the ferroelectric domains in (001) BiFeO 3 (BFO) films patterned into mesas with various aspect ratios, using angle-resolved piezoresponse force microscope (AR-PFM), which can image the in-plane polarization component with an angular resolution of 30 degrees. We observed not only stable polarization variants, but also meta-stable polarization variants, which can reduce the charge accumulated at domain boundaries. We considered the number of neighboring domains that are in contact, in order to analyze the complexity of the ferroelectric domain structure. Comparison of the ferroelectric domains from the patterned and unpatterned regions showed that the elastic relaxation induced by removal of the film surrounding the mesas led to a reduction of the average number of neighboring domains, indicative of a decrease in domain complexity. Finally, we also found that the rectangular BFO patterns with high aspect ratio had a simpler domain configuration and enhanced piezoelectric characteristics than square-shaped mesas. Manipulation of the ferroelectric domains by controlling the aspect ratio of the patterned BFO thin film mesas can be useful for nanoelectronic applications.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Measuring Liquid Drop Properties on Nanoscale 1D Patterned Photoresist Structures

This communication reports liquid wetting properties of DI-water on one-dimensional nano-patterned photoresist lines atop a silicon substrate as the pattern period is varied from 0.3- to 1.0-µm. Both constant photoresist height and constant width/height ratios are investigated. The line/period ratio was fixed at 0.3 (0.4) for different measurement sequences. The surface of the photoresist was treated with a short CHF 3 reactive ion etch to ensure consistent hydrophobic photoresist: water surface energies. Average parallel contact angle (θ || ), average perpendicular contact angle (θ ⊥ ), drop width (W), and drop length (L) at constant volume were measured on nano-patterned surfaces fabricated with interferometric lithography. Both θ || and θ ⊥ contact angles increase as the period (0.3- to 1-μm) increases; the θ || spreading rate is faster than θ ⊥ due to pinning on the grooves resulting in an elongated drop shape. The traditional Wenzel and Cassie-Baxter models of drop contact angles were developed for isotropic random 2D roughness and do not account for the anisotropy induced by the 1D line patterns. The observed angular variations with period are not consistent with either model. Understanding liquid wetting properties and hydrophobicity on 1D silicon surfaces has many applications in lab-on-a-chip, micro/nano-fluidic devices, roll-to-roll nano-imprint fabrication, self-cleaning surfaces, and micro-reactors.

42 ENGINEERING↗
DOE OSTI2019

Bifurcation and Pattern Symmetry Selection in Reaction-Diffusion Systems with Kinetic Anisotropy

Abstract Ordering and self-organization are critical in determining the dynamics of reaction-diffusion systems. Here we show a unique pattern formation mechanism, dictated by the coupling of thermodynamic instability and kinetic anisotropy. Intrinsically different from the physical origin of Turing instability and patterning, the ordered patterns we obtained are caused by the interplay of the instability from uphill diffusion, the symmetry breaking from anisotropic diffusion, and the reactions. To understand the formation of the void/gas bubble superlattices in crystals under irradiation, we establish a general theoretical framework to predict the symmetry selection of superlattice structures associated with anisotropic diffusion. Through analytical study and phase field simulations, we found that the symmetry of a superlattice is determined by the coupling of diffusion anisotropy and the reaction rate, which indicates a new type of bifurcation phenomenon. Our discovery suggests a means for designing target experiments to tailor different microstructural patterns.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Transient pattern formation in an active matter contact poisoning model

Abstract One of the most notable features in repulsive particle based active matter systems is motility-induced-phase separation (MIPS) where a dense, often crystalline phase and low density fluid coexist. Most active matter studies involve time-dependent activity; however, there are many active systems where individual particles transition from living or moving to dead or nonmotile due to lack of fuel, infection, or poisoning. Here we consider an active matter particle system at densities where MIPS does not occur. When we add a small number of infected particles that can poison other particles, rendering them nonmotile, we find a rich variety of time dependent pattern formation, including MIPS, a wetting phase, and a fragmented state formed when mobile particles plow through a nonmotile packing. We map the patterns as a function of time scaled by epidemic duration, and show that the pattern formation is robust for a wide range of poisoning rates and activity levels. We also show that pattern formation does not occur in a random death model, but requires the promotion of nucleation by contact poisoning. Our results should be relevant to biological and active matter systems where there is some form of poisoning, death, or transition to nonmotility.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2016

Self-patterning Gd nano-fibers in Mg-Gd alloys

Manipulating the shape and distribution of strengthening units, e.g. particles, fibers, and precipitates, in a bulk metal, has been a widely applied strategy of tailoring their mechanical properties. Here, we report self-assembled patterns of Gd nano-fibers in Mg-Gd alloys for the purpose of improving their strength and deformability. 1-nm Gd nano-fibers, with a $\langle$c$\rangle$ -rod shape, are formed and hexagonally patterned in association with Gd segregations along dislocations that nucleated during hot extrusion. Such Gd-fiber patterns are able to regulate the relative activities of slips and twinning, as a result, overcome the inherent limitations in strength and ductility of Mg alloys. Finally, this nano-fiber patterning approach could be an effective method to engineer hexagonal metals.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Fronts and patterns in a spatially forced CDIMA reaction

Here we use the CDIMA chemical reaction and the Lengyel–Epstein model of this reaction to study resonant responses of a pattern-forming system to time-independent spatial periodic forcing. We focus on the 2 : 1 resonance, where the wavenumber of a one-dimensional periodic forcing is about twice the wavenumber of the natural stripe pattern that the unforced system tends to form. Within this resonance, we study transverse fronts that shift the phase of resonant stripe patterns by π. We identify phase fronts that shift the phase discontinuously, and pairs of phase fronts that shift the phase continuously, clockwise and anti-clockwise. We further identify a front bifurcation that destabilizes the discontinuous front and leads to a pair of continuous fronts. This bifurcation is the spatial counterpart of the nonequilibrium Ising–Bloch (NIB) bifurcation in temporally forced oscillatory systems. The spatial NIB bifurcation that we find occurs as the forcing strength is increased, unlike earlier studies of the NIB bifurcation. Furthermore, the bifurcation is subcritical, implying a range of forcing strength where both discontinuous Ising fronts and continuous Bloch fronts are stable. Finally, we find that both Ising fronts and Bloch fronts can form discrete families of bound pairs, and we relate arrays of these front pairs to extended rectangular and oblique patterns.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Programming entropy production hotspots via interaction patterning

Dissipation in soft matter and living systems is highly heterogeneous, giving rise to complex local entropy production patterns. Recent work has identified the connection between local entropy production and locally extractable amount of work. This suggests that locally produced entropy can be recovered to power nanorobots and biological machines, prompting the need for efficient strategies to modulate and fine-tune local entropy production. In this work, we propose to program entropy production hotspots by leveraging local interaction patterns and test this approach in simulations of a fluid driven through a nanopore or past an obstacle. Here, the results show that patterning the surface of the pore with a repulsive patch gives rise to an entropy production hotspot around the patch, while an attractive patch leads to an entropy production cold spot. Varying the strength of the interaction and width of the patch enables modulating the hotness and extent of the hot spot. In flows past interaction patterned-obstacles, we show that the combined effects of steric hindrance and attraction allows to program a specific entropy production map, thereby opening the door to the precise powering of nanomachines.

Desgranges, Caroline [University of Massachusetts,↗
DOE OSTI2014

Writing magnetic patterns with surface acoustic waves

A novel patterning technique that creates magnetization patterns in a continuous magnetostrictive film with surface acoustic waves is demonstrated. Patterns of 10 μm wide stripes of alternating magnetization and a 3 μm dot of reversed magnetization are written using standing and focusing acoustic waves, respectively. The magnetization pattern is size-tunable, erasable, and rewritable by changing the magnetic field and acoustic power. This versatility, along with its solid-state implementation (no moving parts) and electronic control, renders it as a promising technique for application in magnetic recording, magnonic signal processing, magnetic particle manipulation, and spatial magneto-optical modulation.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2014

The improvement of GaN-based light-emitting diodes using nanopatterned sapphire substrate with small pattern spacing

Self-assembly SiO{sub 2} nanosphere monolayer template is utilized to fabricate nanopatterned sapphire substrates (NPSSs) with 0-nm, 50-nm, and 120-nm spacing, receptively. The GaN growth on top of NPSS with 0-nm spacing has the best crystal quality because of laterally epitaxial overgrowth. However, GaN growth from pattern top is more difficult to get smooth surface than from pattern bottom. The rougher surface may result in a higher work voltage. The stimulation results of finite-difference time-domain (FDTD) display that too large or too small spacing lead to the reduced light extracted efficiency (LEE) of LEDs. Under a driving current 350 mA, the external quantum efficiencies (EQE) of GaN-based LEDs grown on NPSSs with 0-nm, 50-nm, and 120-nm spacing increase by 43.3%, 50.6%, and 39.1%, respectively, compared to that on flat sapphire substrate (FSS). The optimized pattern spacing is 50 nm for the NPSS with 600-nm pattern period.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Square Turing patterns in reaction-diffusion systems with coupled layers

Square Turing patterns are usually unstable in reaction-diffusion systems and are rarely observed in corresponding experiments and simulations. We report here an example of spontaneous formation of square Turing patterns with the Lengyel-Epstein model of two coupled layers. The squares are found to be a result of the resonance between two supercritical Turing modes with an appropriate ratio. Besides, the spatiotemporal resonance of Turing modes resembles to the mode-locking phenomenon. Analysis of the general amplitude equations for square patterns reveals that the fixed point corresponding to square Turing patterns is stationary when the parameters adopt appropriate values.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2014

Investigation on synchronization of the offset printing process for fine patterning and precision overlay

Offset printing processes are promising candidates for producing printed electronics due to their capacity for fine patterning and suitability for mass production. To print high-resolution patterns with good overlay using offset printing, the velocities of two contact surfaces, which ink is transferred between, should be synchronized perfectly. However, an exact velocity of the contact surfaces is unknown due to several imperfections, including tolerances, blanket swelling, and velocity ripple, which prevents the system from being operated in the synchronized condition. In this paper, a novel method of measurement based on the sticking model of friction force was proposed to determine the best synchronized condition, i.e., the condition in which the rate of synchronization error is minimized. It was verified by experiment that the friction force can accurately represent the rate of synchronization error. Based on the measurement results of the synchronization error, the allowable margin of synchronization error when printing high-resolution patterns was investigated experimentally using reverse offset printing. There is a region where the patterning performance is unchanged even though the synchronization error is varied, and this may be viewed as indirect evidence that printability performance is secured when there is no slip at the contact interface. To understand what happens at the contact surfaces during ink transfer, the deformation model of the blanket's surface was developed. The model estimates how much deformation on the blanket's surface can be borne by the synchronization error when there is no slip at the contact interface. In addition, the model shows that the synchronization error results in scale variation in the machine direction (MD), which means that the printing registration in the MD can be adjusted actively by controlling the synchronization if there is a sufficient margin of synchronization error to guarantee printability. The effect of synchronization on the printing registration was verified experimentally using gravure offset printing. The variations in synchronization result in the differences in the MD scale, and the measured MD scale matches exactly with the modeled MD scale.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗