Optics for an electron cooler for the EIC based on an electron storage ring
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43 PARTICLE ACCELERATORS↗
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Optics design for a storage ring based electron cooler for cooling at high energies
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43 PARTICLE ACCELERATORS↗
Skyrmion fluctuations at a first-order phase transition boundary
Magnetic skyrmions are topologically protected spin textures with promising prospects for applications in data storage. They can form a lattice state due to competing magnetic interactions and are commonly found in a small region of the temperature—magnetic field phase diagram. Recent work has demonstrated that these magnetic quasi-particles fluctuate at the μeV energy scale. Here, we use a coherent x-ray correlation method at an x-ray free-electron laser to investigate these fluctuations in a magnetic phase coexistence region near a first-order transition boundary where fluctuations are not expected to play a major role. Surprisingly, we find that the relaxation of the intermediate scattering function at this transition differs significantly compared to that deep in the skyrmion lattice phase. The observation of a compressed exponential behavior suggests solid-like dynamics, often associated with jamming. We assign this behavior to disorder and the phase coexistence observed in a narrow field-window near the transition, which can cause fluctuations that lead to glassy behavior.
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
Cohesive phase-field chemo-mechanical simulations of inter- and trans- granular fractures in polycrystalline NMC cathodes via image-based 3D reconstruction
The optimal design and durable utilization of lithium-ion batteries necessitates an objective modeling approach to understand fracture and failure mechanisms. This paper presents a comprehensive chemo-mechanical modeling study focused on elucidating fracture-induced damage and degradation phenomena in the polycrystalline Li $\mathcal{x}$ Ni 0.5 Mn 0.3 Co 0.2 O 2 (NMC532) cathode. An innovative approach that utilizes image-based reconstructed 3D geometry as finite element (FE) mesh input is employed to enhance the precision in capturing the convoluted architecture and morphological features. For accurately representing the intricate crack configurations within the polycrystalline system, we adopted the cohesive phase-field fracture (CPF) model. Through the integration of advanced image-based geometry reconstruction technique and the promising CPF modeling approach, lithium (de)intercalation induced crack evolution (e.g., nucleation, propagation, branching and diverse modes including inter-/trans-(intra-) granular patterns) and the resulting chemical degradation can be precisely captured, which is also compared and validated with numerical predictions using a continuum damage model. In particular, this model predicts fracture induced degradation under varying fracture properties of grain boundaries and charging rates; the conclusion that NMC particles comprised of larger grains are predicted to have less degradation than those with smaller grains can also be drawn. This comprehensive analysis provides valuable insights into the fracture and degradation within polycrystalline NMC cathodes.
25 ENERGY STORAGE↗
Large Cemented Gibbsite Agglomerates in Alkaline Nuclear Waste at the Hanford Site and the Impacts to Remediation
Recent work with the remediation of legacy alkaline nuclear waste has focused on nanometer and micrometer particle sizes, emphasizing how these small particles can impact efforts to treat the waste. Building upon this work, we present here findings that show very large particles (several centimeters in size) also exist in these waste which likewise play an important role in the remediation process. While large cemented gibbsite nodules have been periodically reported in acid soils in the literature, this study found similar large gibbsite agglomerates (7 cm in diameter) in alkaline nuclear waste, the first time that such large agglomerates have been identified in an alkaline environment. The morphology of the gibbsite in the agglomerates that were grown over more than 40 years of storage in the waste tank were similar to the much smaller agglomerates that have been reported in previous shorter term studies. Fluid dynamics calculations indicate that these cemented particles would be difficult to mobilize with standard jet slurry technologies, which is consistent with their residence in the waste heel after jet sluicing of the tank.
agglomerates, alkaline nuclear waste↗
Collimator irradiation studies in the Argonne Advanced Photon Source at energy densities expected in next-generation storage ring light sources
Not Available
43 PARTICLE ACCELERATORS↗
Nonlinear optics from hybrid dispersive orbits
Here in this paper we expand the technique of characterizing nonlinear optics from off-energy closed orbits (NOECO) to cover harmonic sextupoles in storage rings. The existing NOECO technique has been successfully used to correct the chromatic sextupole errors on the MAX-IV machine (Olsson et al., 2020), however, it does not account for harmonic sextupoles, which are still widely used on many other machines. By generating vertical dispersion with chromatic skew quadrupoles, a measurable chromatic function dependence on harmonic sextupoles can be observed on hybrid dispersive orbits. Proof of concept of this technique was accomplished by simulations and beam measurements on the National Synchrotron Light Source II (NSLS-II) storage ring.
72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
Nanoscale hydration in layered manganese oxides
Birnessite is a layered MnO2 mineral with a nanoscale interlayer region that accommodates layers of intercalated water. Variable distributions of Mn sites with oxidation states of II, III and IV are responsible for the high catalytic reactivity of birnessite in nature and as a valuable candidate for energy storage solutions. We here report water loading capabilities and the vibrational spectral signatures of two forms of birnessite of strongly contrasting particle size. Using X-ray diffraction we find that potassium-birnessite accommodates no more than one monolayer (1W) of water in its interlayer region. Molecular simulations show that this is an energetically favorable hydration state where interlayer potassium-water and direct water-birnessite interactions are greater than at other hydration levels. Simulations also suggest a stable 2W state but that is not achieved experimentally by contact with water vapor. Finally, this work provides a means to predict the distribution of adsorbed and interlayer water molecules using a recently developed composite model.
Cheng, Wei↗
Photoinitiated thermoset polymerization through controlled release of metathesis catalysts encapsulated in poly(phthalaldehyde)
Photoinitiated polymerization enables spatiotemporal control of reaction conditions and can thereby generate materials with high complexity while consuming minimal energy. Where ring opening metathesis polymerization (ROMP) is concerned, photo-activated processes are typically enabled by chemical inhibition of ruthenium carbenes via the careful design of complexed ligands such that photoactivation can proceed through an isomerization or ligand dissociation event. In this contribution, we have explored a new approach to photoinitiation of ROMP based on physical inhibition through microencapsulation and controlled release of metathesis catalysts. Micron-sized particles of poly(phthalaldehyde) (PPA), catalyst, and photoacid generator were fabricated by spray drying. The particles were dispersed in dicyclopentadiene monomer, after which polymerization was initiated through temperature or UV exposure, both inducing depolymerization of the PPA particles and in situ catalyst release. The monomer/particle dispersions were found to be stable and reproducibly polymerizable with 3 weeks of storage at room temperature. Furthermore, the dispersions can be used for both photo- and thermal-initiated frontal ROMP, yielding a polymerized thermoset of equivalent properties to conventional bulk- and frontally-polymerized analogues. In conclusion, this work will ultimately enable new manufacturing techniques for ROMP-based materials, due to the modular, easily tunable nature of the underlying initiating system and its unparalleled stability.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Beam Dynamics Simulations of Transient Beam Loading Effects in the 10GeV EIC Electron Storage Ring
We report on beam dynamics studies of transient beam loading effects in the 10 GeV EIC electron storage ring [1]. The studies are carried out with time-dependent Vlasov-Fokker-Planck simulations performed with the parallel, particle tracking code SPACE [2], which allows to follow self-consistently the dynamics of h bunches, where h in the number of RF buckets, in arbitrary multi-bunch configurations. The specific goal of the numerical simulations is to determine stable RF cavity settings under heavy beam loading. We also study the option to operate with a passive, third-harmonic cavity (3HC) system for bunch lengthening, addressing both stability and the performance limitation due to a gap in the uniform filling pattern for ion clearing.
43 PARTICLE ACCELERATORS↗
Ultracold Storage Ring
The modern ring upgrades aim at reaching beam low emittance while paying little attention to the beam energy spread. The purpose of this note is to conjecture on a possibility of designing a storage ring with ultimately small energy spread. This might be of interest with respect to the following two applications: increasing brightness and coherence of radiation at higher harmonics of undulator radiation and a potential of building a soft X-ray FEL on a storage ring. Throughout the tech note we are taking a 3 GeV storage ring of the NSLS-II size as an example.
43 PARTICLE ACCELERATORS↗
Compact Counter Flow Fluidized Bed Heat Exchanger (Final Report)
Generation 3 concentrating solar power systems which utilize solid granular media as the heat transfer and storage media hold promise in reducing the levelized cost of electricity relative to generation 2 systems which utilize molten salt. The particles can be heated to temperatures exceeding 800 °C which enables the use of high efficiency supercritical CO 2 Brayton power cycles. A key challenge associate with the use of solid media is its low bulk thermal conductivity which limits the ability to transfer heat from the particles to a working fluid, such as supercritical CO 2 . Tradition shell and tube and shell and plate heat exchangers feature gravity driven particle flow which limits the maximum particle side heat transfer coefficient in these systems to approximately 400 W/m 2 K. A fluidized bed heat exchanger does not rely solely on gravity for particle flow. Instead, enhanced mixing and horizontal conveyance is achieved through fluidization induced through air injection at the bottom of a bed of particles. A tube bundle within the bed conveys the supercritical CO 2 which is heated via the turbulent particle motion at the tube wall.
14 SOLAR ENERGY↗
Auroral Boundaries: Comparison Between UV Images, In Situ Precipitation, and Groundbased Optical Observations
The location of poleward and equatorward boundaries are used as diagnostics of substorm phase and energy storage in the magnetosphere. Boundaries are estimated from groundbased observations (all sky imagers, meridian scanning photometers, and magnetometers), from in situ particle observations, and from spacebased global auroral observations. Each observational technique has relative advantages. Based on recent studies, different observing techniques can give differing boundary locations. Understanding any differences in the boundaries from each observing technique is important when using the data as a diagnostic for the magnetosphere. In this study, FUV auroral images from the POLAR Ultraviolet Imager are used to estimate auroral boundaries. These boundaries are then compared with similar boundaries derived from DMSP in situ particle precipitation observations and from groundbased meridian scanning photometers. The goal is to see how well the boundaries from these three dissimilar observations correlate, to estimate dependences on instrumental capabilities, i.e. imager resolution, and to serve as a potential first step to derive an algorithm for finding oval boundaries from groundbased optical data.
Germany, G. A.↗
Auroral Boundaries: Comparison Between UV Images, In Situ Precipitation, and Groundbased Optical Observations
The location of poleward and equatorward boundaries are used as diagnostics of substorm phase and energy storage in the magnetosphere. Boundaries are estimated from groundbased observations (all sky imagers, meridian scanning photometers, and magnetometers), from in situ particle observations, and from spacebased global auroral observations. Each observational technique has relative advantages. However, recent studies suggest caution when comparing boundaries derived from different methods. in the study, FUV auroral images from the POLAR Ultraviolet Imager are used to estimate auroral boundaries. These boundaries are then compared with similar boundaries derived from DMSP in situ particle precipitation observations and from groundbased meridian scanning photometers. The goal is to see how well the boundaries from these three dissimilar observations correlate, to estimate dependencies on instrumental capabilities, i.e. imager resolution, and to serve as a potential first step to derive an algorithm for finding oval boundaries from groundbased optical data.
Germany, G. A.↗
Continued Development of a Highly Reflective Solar Coating for Cryogenic Liquid Storage in Space
State-of-the-art solar reflectors absorb 6-8 % of the sun's irradiant power, which is adequate for spacecraft thermal control; but not for storage of cryogens in tanks exposed to the Sun. A solar reflector must absorb less than 0.4% of the Sun's power, while radiating effectively in the far IR, to allow LOX storage. Hibbard realized this in 1960's, at about the same time that nearly perfect optical reflectors were developed based on particle scattering. In 2015, under funding from the NASA Innovative Advanced Concepts Program (NIAC), these breakthroughs were rediscovered. Theoretical analysis showed that a tank coated with a thick (1 cm) layer of 150 nm particles, composed of a broadband material, could allow the tank to chill to cryogenic temperatures, even in the presence of 1 AU solar irradiance. Subsequent work lead to the demonstration and testing of BaF2 based rigid coupons. Placing one of these in a cryocooler-based simulated deep space environment and irradiating with simulated sunlight has shown about 1% absorption. This is better than the state-of-the-art but not yet sufficient for LOX storage.This paper will review the background material presented above but will concentrate on work performed over the last year, including the design and build-up of the testing apparatus. Since our last publication, we have changed materials from BaF2 to Y2O3. Y2O3 has slightly higher solar absorptance, but is hydrophobic and higher index.
Swanger, Adam↗
Light scattering by size-shape distributions of randomly oriented axially symmetric particles of a size comparable to a wavelength
Rigorously light scattering by size-shape distributions of randomly oriented axially symmetric particles are calculated by the T-matrix method, as extended to randomly oriented scatterers. The computational scheme is described along with a newly developed convergence procedure that makes it possible to substantially reduce computer time and storage requirements. The elements of the Stokes scattering matrix for a power-law size distribution of randomly oriented moderately aspherical spheroids are shown to be much smoother than and differ substantially from those of equivalent monodisperse spheroids; averaging over orientations does not eliminate the necessity of averaging over particle sizes. The angular-scattering behavior of the ensembles of nonspherical particles is found to be significantly different from that of the equivalent polydisperse spheres.
Mishchenko, Michael I.↗
Cryogenic Selective Surfaces
There are many challenges involved in deep-space exploration, but several of these can be mitigated, or even solved, by the development of a coating that reflects most of the Sun’s energy, yet still provides far-infrared heat emission. Such a coating would allow non-heat-generating objects in space to reach cryogenic temperatures without using an active cooling system. This would benefit deep-space sensors that require low temperatures, such as the James Webb Telescope focal plane array. It would also allow the use of superconductors in deep space, which could lead to magnetic energy storage rings, lossless power delivery, or perhaps a large-volume magnetic shield against galactic cosmic radiation. However, perhaps the most significant enablement achieved from such a coating would be the long-term, deep space storage of cryogenic liquids, such as liquid oxygen (LOX). In our Phase I NIAC study, we realized that a combination of scattering particles and a silver backing could yield a highly effective, very broadband, reflector that could potentially reflect more than 99.9% of the Sun’s irradiant power. We developed a sophisticated model of this reflector and theoretically showed that cryogenic temperatures could be achieved in deep space at one astronomical unit (1 AU) from the Sun. We showed how this new reflector could minimize heat conduction into the cryogenic tanks by coating the tank support struts. We then modelled a strawman architecture for a mission to Mars, using a coated LOX tank, coated struts, and infrared shields, to show that with our new coating it would be possible to maintain liquid oxygen passively. As a result of this work a patent application was generated and a paper published in Optics Letters. Our Phase II NIAC study had two primary goals, to develop a rigid version of the cryogenic selective surface proposed in Phase I and to test its performance in a simulated deep space environment. During the first year of the project the work concentrated on developing rigid tiles of BaF2, leading to tiles as large as 4 inches in diameter that transmitted very little visible light. In addition, during the first year a simulated deep space environment was created using a vacuum chamber and cryocooler. Using this facility, we showed that our BaF2 tiles absorbed less than ¼% of 375 nm radiation, a significant milestone for the work. During the second year of the project, we continued to develop the BaF2 tiles and we put significant effort into the construction of a deep space environment where we could project simulated solar radiation onto a sample. In the spring of 2018, we conducted our first solar simulator test with BaF2 and saw about 3.6% absorption. This is better than the state-of-the-art, but disappointing since predictions were for much lower absorption. We, erroneously, attributed this absorption to water retention by the BaF2, and decided to change materials. We considered several oxides and settled on yttrium oxide (Y2O3) for further development, because it is broadband, lightweight, has high index, and is hydrophobic. In July 2018 we conducted our first test of a rigid tile of Y2O3 in the simulated deep space environment and saw significant absorption again. We then realized that the issue was not water, but mid-wave radiation passing through the tile and being absorbed by the temperature sensor and the varnish used to hold it in place. We wrapped the sensor in silver foil, re-ran the test, and saw much lower absorption; only 1.1%. We then re-ran the BaF2 tile and saw 1.4% absorption. These values are almost adequate to maintain LOX in deep space, but we suspect that there are still issues in our test apparatus; we suspect thermocouple wires may be absorbing radiation. Further, post-NIAC, testing will better determine the performance of our new solar reflector. In order to restrict the size of this report, we will only briefly describe topics that we have previously published, allowing us to devote more time to new material. So minimal material will be devoted to modeling the material and deep space cryogenic storage, while longer sections will cover our material development, simulated deep space testing, and new applications. The Launch Service Program (LSP) requested that we explore ways to use this new coating to maintain LOX in low Earth Orbit and that work is described. In addition, the Nuclear Thermal Propulsion (NTP) Program asked us to explore ways to reduce the heat load for liquid hydrogen, resulting in the development of a spray-on version of the coating that should significantly improve in-space multi-layer insulation performance.
Robert C. Youngquist,↗
Mechanisms and heterogeneity of in situ mineral processing by the marine nitrogen fixer Trichodesmium revealed by single-colony metaproteomics
The keystone marine nitrogen fixer Trichodesmium thrives in high-dust environments. While laboratory investigations have observed that Trichodesmium colonies can access the essential nutrient iron from dust particles, less clear are the biochemical strategies underlying particle–colony interactions in nature. Here we demonstrate that Trichodesmium colonies engage with mineral particles in the wild with distinct molecular responses. We encountered particle-laden Trichodesmium colonies at a sampling location in the Southern Caribbean Sea; microscopy and synchrotron-based imaging then demonstrated heterogeneous associations with iron oxide and iron-silicate minerals. Metaproteomic analysis of individual colonies by a new low-biomass approach revealed responses in biogeochemically relevant proteins including photosynthesis proteins and metalloproteins containing iron, nickel, copper, and zinc. The iron-storage protein ferritin was particularly enriched implying accumulation of mineral-derived iron, and multiple iron acquisition pathways including Fe(II), Fe(III), and Fe-siderophore transporters were engaged. While the particles provided key trace metals such as iron and nickel, there was also evidence that Trichodesmium was altering its strategy to confront increased superoxide production and metal exposure. Chemotaxis regulators also responded to mineral presence suggesting involvement in particle entrainment. These molecular responses are fundamental to Trichodesmium’s ecological success and global biogeochemical impact, and may contribute to the leaching of particulate trace metals with implications for global iron and carbon cycling.
Held, Noelle A.↗