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At least 487 records · Page 27

Lunar and Planetary Science XXXV: Mars: Wind, Dust Sand, and Debris

The session "Mars: Wind, Dust Sand, and Debris" included: Mars Exploration Rovers: Laboratory Simulations of Aeolian Interactions; Thermal and Spectral Analysis of an Intracrater Dune Field in Amazonis Planitia; How High is that Dune? A Comparison of Methods Used to Constrain the Morphometry of Aeolian Bedforms on Mars; Dust Devils on Mars: Scaling of Dust Flux Based on Laboratory Simulations; A Close Encounter with a Terrestrial Dust Devil; Interpretation of Wind Direction from Eolian Features: Herschel Crater, Mars Erosion Rates at the Viking 2 Landing Site; Mars Dust: Characterization of Particle Size and Electrostatic Charge Distributions; Simple Non-fluvial Models of Planetary Surface Modification, with Application to Mars; Comparison of Geomorphically Determined Winds with a General Circulation Model: Herschel Crater, Mars; Analysis of Martian Debris Aprons in Eastern Hellas Using THEMIS; Origin of Martian Northern Hemisphere Mid-Latitude Lobate Debris Aprons; Debris Aprons in the Tempe/Mareotis Region of Mars;and Constraining Flow Dynamics of Mass Movements on Earth and Mars.

Source record↗

Enhancing low-temperature sintering in the MgO-LiF system: Mechanistic insights

In the present article, we provide compelling evidence that minor (1 wt%) additions of micron and nanometre-sized LiF particles in MgO decompose leading to free Li diffusing into MgO surfaces enhancing vacancy production during direct current sintering. The addition of nanometre-sized LiF particles leads to a > 500 °C reduction in the sintering temperature and over 99 % theoretical density of final consolidated compacts. Correlating differential scanning calorimetry with in-situ x-ray diffraction, together with Schottky calculations, post sintering electron microscopy and laser induced breakdown spectroscopy, we uncover critical insights into this impressive reduction in sintering temperature. Our quantitative analysis reveals that MgO and LiF interact at low temperatures with the diffusion of Li into the surface of MgO particles due to the intrinsic structural disorder of the LiF and MgO crystallites. Nanometre-sized LiF particles were found to react the most at low temperatures due to their increased structural disorder. Our multimodal characterization points to a Li-promoted densification and sintering mechanism. This impressive reduction in sintering temperature can be harnessed to promote low-temperature fabrication of MgO-based composites for technological applications.

36 MATERIALS SCIENCE↗

PAHs in the Ices of Saturn's Satellites: Connections to the Solar Nebula and the Interstellar Medium

Aliphatic hydrocarbons and PAHs have been observed in the interstellar medium (e.g., Allamandola et al. 1985, Pendleton et al. 1994, Pendleton & Allamandola 2002, Tielens 2013, Kwok 2008, Chiar & Pendleton 2008) The inventory of organic material in the ISM was likely incorporated into the molecular cloud in which the solar nebula condensed, contributing to the feedstock for the formation of the Sun, major planets, and the smaller icy bodies in the region outside Neptune's orbit (transneptunian objects, or TNOs). Additional organic synthesis occurred in the solar nebula (Ciesla & Sandford 2012). Saturn's satellites Phoebe, Iapetus, and Hyperion open a window to the composition of one class of TNO as revealed by the near-infrared mapping spectrometer (VIMS) on the Cassini spacecraft at Saturn. Phoebe (mean diameter 213 km) is a former TNO now orbiting Saturn (Johnson & Lunine 2005). VIMS spectral maps of Phoebe's surface reveal a complex organic spectral signature consisting of prominent aromatic (CH) and aliphatic hydrocarbon (=CH2, -CH3) absorption bands (3.2-3.6 micrometers). Phoebe is the source of a huge debris ring encircling Saturn, and from which particles ((is) approximately 5-20 micrometers size) spiral inward toward Saturn (Verbiscer et al. 2009). They encounter Iapetus and Hyperion where they mix with and blanket the native H2O ice of those two bodies. Quantitative analysis of the hydrocarbon bands on Iapetus demonstrates that aromatic CH is approximately 10 times as abundant as aliphatic CH2+CH3, significantly exceeding the strength of the aromatic signature in interplanetary dust particles, comet particles, and in carbonaceous meteorites (Cruikshank et al. 2014). A similar excess of aromatics over aliphatics is seen in the qualitative analysis of Hyperion and Phoebe itself (Dalle Ore et al. 2012). The Iapetus aliphatic hydrocarbons show CH2/CH3 (is) approximately 4, which is larger than the value found in the diffuse ISM ((is) approximately 2-2.5). Insofar as Phoebe is a primitive body that formed in the outer regions of the solar nebula and has preserved some of the original nebula inventory, it can be key in understanding the content and degree of processing of that nebular material. A dynamical subset of TNOs define the Kuiper Belt, from which the short-period comets originate. Particles collected from comet 81P/Wild contain PAHs with an interstellar signature of deuterium. By inference, the PAHs contained in Phoebe and now dusted on the surfaces of two other Saturn satellites share that interstellar origin. There are other Phoebe-like TNOs that are presently beyond our ability to study in the organic spectral region, but JWST will open that possibility for a number of objects.

Solar nebula↗

Investigation of desorption of hydrogen gas from polymer matrix using thermal desorption analysis and finite element modeling

Polymer materials are used widely as sealing materials and liners in hydrogen storage and transportation infrastructure. During operating conditions, polymers are exposed to high pressure hydrogen gas periodically. When in contact, the hydrogen gas diffuses through the polymer material with ease due to its smaller sized molecules compared to the polymer molecules. In the event of rapid decompression of outside hydrogen gas, the hydrogen molecules within the polymer diffuse out. This process is known as the desorption of polymer and can cause blisters or cracking causing permanent damage to the polymer. Here, we used a combined experimental and modeling approach to investigate the desorption of the hydrogen gas in the polymer. Thermal desorption analysis (TDA) experiments were performed on the polymer sample exposed to the high-pressure hydrogen gas to measure the diffusion coefficient and equilibrium hydrogen concentration. Experiments also provided the quantity of hydrogen within the polymer during the desorption process which followed Fick’s law. However, for higher pressurization values, some anomaly was observed in the quantity of hydrogen remaining in the polymer sample. A continuum mechanics based coupled diffusion–deformation-damage model was deployed to simulate the gas desorption process in the material using the finite element method to understand its effect on the material. It was found that the anomaly in TDA results were due to the blister formation on the polymer surface which resulted in longer hydrogen retention. Simulations also showed that blister formation can be affected by multiple parameters such as the addition of filler particles, and pre-existing cavity size.

36 MATERIALS SCIENCE↗

Physical properties of the particles composing the Martian dust storm of 1971-1972

Data obtained with the infrared interferometric spectrometer (IRIS) aboard Mariner 9 during the global Martian dust storm of 1971-1972 are analyzed to study the particle sizes in detail, estimate the dust particle size distribution, and determine the dust optical depth. Theoretical spectra of the emergent intensity from dust clouds with properties similar to those of the Martian cloud are generated, deficiencies of the approximation used are discussed, and the information content of the IR aerosol spectra is assessed. Analysis of IRIS spectra from a series of orbits spread through the early months of the Mariner 9 mission indicates that the dust could have been either igneous material with an SiO2 content similar to or higher than that of a typical terrestrial sediment or clay minerals similar to those on earth. In either case, the Martian dust was differentiated by geologic or weathering processes. The dust particle size distribution between 1 and 10 microns is found to have a slope similar to that of terrestrial dust size distributions far from source regions.

Toon, O. B.↗

Instance Segmentation for Direct Measurements of Satellites in Metal Powders and Automated Microstructural Characterization from Image Data

In this work, we propose instance segmentation as a useful tool for image analysis in materials science. Instance segmentation is an advanced technique in computer vision which generates individual segmentation masks for every object of interest that is recognized in an image. Using an out-of-the-box implementation of Mask R-CNN, instance segmentation is applied to images of metal powder particles produced through gas atomization. Leveraging transfer learning allows for the analysis to be conducted with a very small training set of labeled images. As well as providing another method for measuring the particle size distribution, we demonstrate the first direct measurements of the satellite content in powder samples. After analyzing the results for the labeled data dataset, the trained model was used to generate measurements for a much larger set of unlabeled images. The resulting particle size measurements showed reasonable agreement with laser scattering measurements. The satellite measurements were self-consistent and showed good agreement with the expected trends for different samples. Finally, we present a small case study showing how instance segmentation can be used to measure spheroidite content in the UltraHigh Carbon Steel DataBase, demonstrating the flexibility of the technique.

36 MATERIALS SCIENCE↗

Chemical imaging of individual stratospheric particles sampled over North America

The increasing size, severity, and frequency of wildfires have led to dramatic increases in particulate matter concentrations in the troposphere. Severe wildfires can generate intense convective systems capable of transporting large quantities of biomass burning organic aerosols (BBOA) to the upper troposphere and lower stratosphere (UTLS). Chemically complex organic matter and light-absorbing carbonaceous material is introduced into stratospheric regions that were historically isolated from direct surface emissions. In this study, stratospheric particles were sampled over North America during the Dynamics and Chemistry of the Summer Stratosphere (DCOTSS) campaign, an aircraft-based research project designed to characterize convective perturbation in the UTLS. Particle samples collected from six research flights during summer 2022 were analyzed using Computer-Controlled Scanning Electron Microscopy and Scanning Transmission X-ray Microscopy to investigate particle size distributions, morphology, chemical composition, and mixing state of stratospheric particles along transects across the continental United States and adjacent Pacific Ocean airspace. Analysis revealed that all sampled particles contained detectable levels of carbon, with most exhibiting organic volume fractions of 0.37 ± 0.20. Notably, about 5% of the particles also contained soot inclusions, which indicates the presence of refractory black carbon transported to stratospheric altitudes and provides direct evidence of wildfire-derived black carbon reaching the UTLS. Typical particle morphology exhibits organic shells over soot and inorganic cores and suggests secondary processing and aging of BBOA during transport to and within the UTLS. These findings provide compelling evidence that wildfire emissions play a critical role in affecting the long-term composition and radiative properties of stratospheric particles.

Sharpe, Steven [Purdue Univ., West Lafayette, IN (↗

Computational Analysis of the Impact of Boundary Conditions on a Particle-Laden Flow: A Case Study in a Pressurized Oxy-Coal Combustor

Designing an effective burner is vital for the development of coal combustion technologies. Because of high pressure, the volumetric fraction of the coal particles in the injected fuel in a pressurized oxy-combustion (POC) burner approaches or even exceeds the limitations allowed by the commercial computational fluid dynamics codes (e.g., Ansys Fluent). Consequently, for such high particle volumetric fractions, the interplay between the particles, the fluid flow, and the burner wall needs to be re-evaluated. The present computational work is a first step in a systematic analysis of the roles of various characteristics involved in the POC process, such as the method of particle release, its location, and the particle size. Specifically, pulverized coal is burned under an elevated pressure of 15 bar in an O 2 /CO 2 environment. A 100 kW, a POC combustor, is modeled with Ansys Fluent using the Reynolds-averaged Navier−Stokes approach. It is revealed that for this pilot-scale, pressurized burner, the gas phase flow velocity in the near-wall region exhibits anomalies. With the major focus on POC, this work aims to eliminate/reduce the impact of high particle loading on the gas-phase flow. To scrutinize the role of particle loading in the near-wall region and eliminate the impact of this velocity on POC downstream, the particle−gas interplay in the boundary layer is investigated by means of the computational simulations incorporating the coupling between the turbulent flow and the particles. It is found that the tuning of the particle release location makes the gas-phase flow velocity in the presence of particles consistent with the pure gas flow velocity profile. The particles size is also found to have a significant impact on the particle trajectory.

CFD↗

The direct effects of strain on burning rates of composite solid propellants

A mathematical model is developed to predict burn rate augmentation due to strain in a composite solid propellant. The model assumes the effect is due to the ability of the flame to penetrate the small fissures and voids that form when a propellant is strained. The number and size of these fissures is obtained by applying a flaw propagation analysis to randomly distributed flaws that form when the binder-oxidizer particle bonds break under stress. A flame height is calculated with Summerfield's burn rate equation and is used to compute the burn rate augmentation based upon the additional burn area created when the flame penetrates the fissures. Comparisons are made with data obtained from published sources. The existence of threshold pressure and strains, above which augmentation occurs, is verified although the model predicts a lower threshold pressure and higher threshold strain than expected. Further results and applications of the model are discussed.

Langhenry, M. T.↗

Airborne particulate matter in spacecraft

Acceptability limits and sampling and monitoring strategies for airborne particles in spacecraft were considered. Based on instances of eye and respiratory tract irritation reported by Shuttle flight crews, the following acceptability limits for airborne particles were recommended: for flights of 1 week or less duration (1 mg/cu m for particles less than 10 microns in aerodynamic diameter (AD) plus 1 mg/cu m for particles 10 to 100 microns in AD); and for flights greater than 1 week and up to 6 months in duration (0.2 mg/cu m for particles less than 10 microns in AD plus 0.2 mg/cu m for particles 10 to 100 microns in AD. These numerical limits were recommended to aid in spacecraft atmosphere design which should aim at particulate levels that are a low as reasonably achievable. Sampling of spacecraft atmospheres for particles should include size-fractionated samples of 0 to 10, 10 to 100, and greater than 100 micron particles for mass concentration measurement and elementary chemical analysis by nondestructive analysis techniques. Morphological and chemical analyses of single particles should also be made to aid in identifying airborne particulate sources. Air cleaning systems based on inertial collection principles and fine particle collection devices based on electrostatic precipitation and filtration should be considered for incorporation into spacecraft air circulation systems. It was also recommended that research be carried out in space in the areas of health effects and particle characterization.

Source record↗

Numerically Modeling the Erosion of Lunar Soil by Rocket Exhaust Plumes

In preparation for the Apollo program, Leonard Roberts of the NASA Langley Research Center developed a remarkable analytical theory that predicts the blowing of lunar soil and dust beneath a rocket exhaust plume. Roberts assumed that the erosion rate was determined by the excess shear stress in the gas (the amount of shear stress greater than what causes grains to roll). The acceleration of particles to their final velocity in the gas consumes a portion of the shear stress. The erosion rate continues to increase until the excess shear stress is exactly consumed, thus determining the erosion rate. Roberts calculated the largest and smallest particles that could be eroded based on forces at the particle scale, but the erosion rate equation assumed that only one particle size existed in the soil. He assumed that particle ejection angles were determined entirely by the shape of the terrain, which acts like a ballistic ramp, with the particle aerodynamics being negligible. The predicted erosion rate and the upper limit of particle size appeared to be within an order of magnitude of small-scale terrestrial experiments but could not be tested more quantitatively at the time. The lower limit of particle size and the predictions of ejection angle were not tested. We observed in the Apollo landing videos that the ejection angles of particles streaming out from individual craters were time-varying and correlated to the Lunar Module thrust, thus implying that particle aerodynamics dominate. We modified Roberts theory in two ways. First, we used ad hoc the ejection angles measured in the Apollo landing videos, in lieu of developing a more sophisticated method. Second, we integrated Roberts equations over the lunar-particle size distribution and obtained a compact expression that could be implemented in a numerical code. We also added a material damage model that predicts the number and size of divots which the impinging particles will cause in hardware surrounding the landing rocket. Then, we performed a long-range ballistics analysis for the ejected particulates.

Source record↗

Instrument Would Detect and Collect Biological Aerosols

A proposed compact, portable instrument would sample micron-sized airborne particles, would discriminate between biological ones (e.g., bacteria) and nonbiological ones (e.g., dust particles), and would collect the detected biological particles for further analysis. The instrument is intended to satisfy a growing need for means of rapid, inexpensive collection of bioaerosols in a variety of indoor and outdoor settings. Purposes that could be served by such collection include detecting airborne pathogens inside buildings and their ventilation systems, measuring concentrations of airborne biological contaminants around municipal waste-processing facilities, monitoring airborne effluents from suspected biowarfare facilities, and warning of the presence of airborne biowarfare agents

Savoy, Steve↗

Laser anemometer signals - Visibility characteristics and application to particle sizing

Investigations have been conducted concerning the characteristics of the visibility function as determined by the parameters of the laser anemometer system and the electromagnetic scattering properties of the particles. Experiments have been performed to evaluate the backscatter visibility of signals from a symmetric, s polarization laser anemometer as a function of the particle diameter and a parameter ratio. The results have been compared with the predictions of an analysis based on Mie's scattering theory. The analysis has also been used to evaluate the effects of the collecting aperture's size and location.

Adrian, R. J.↗

Computationally Guided Development of Components for High Energy Density Solid-State Lithium-Sulfur Batteries

All electric vertical take-off and landing vehicles (eVTOL) for urban air mobility (UAM) concepts face numerous challenging technical barriers before their introduction into the consumer marketplace. The most challenging of these technical barriers to overcome is developing an energy storage system capable of meeting the rigorous aerospace safety and performance criteria1. The performance metrics for eVTOL craft, such as specific energy, specific power, and safety, exceed those of electric automobiles by a factor of two to four. Current state-of-the-art (SOA) lithium-ion batteries are incapable of meeting the key performance criteria of energy and safety for eVTOL. Therefore, next generation advanced chemistries and designs must be developed to meet required performance metrics for electric aviation2. Beyond lithium-ion chemistries, such as lithium-sulfur, show promise in their high energy, while limitations exist in their power and cyclability due to low electrical conductivity and high intermediate solubility in organic liquid electrolytes. Several strategies to overcome the low electrical conductivity involve the use of selenium as a dopant in the active sulfur material, along with the incorporation of 2-dimensional electron-conducting holey-graphene to improve the composite cathodes electronic conductivity. Furthermore, combining this chemistry with a solid-electrolyte avoids the components’ dissolution issues3. However, the development of composite solid-state cathodes is non-trivial as several components must be intimately mixed so that the active component has sufficient access to both electrons and lithium ions to undergo full electrochemical conversion. Mathematical modeling of battery components can assist experimental design through a robust and rigorous combination of computational modeling techniques covering multiple length scales. The objective is to leverage modern computational materials methods combined with battery multiphysics tools to develop radically advanced compatible cathode and electrolyte materials, build and test solid state lithium-sulfur cells and packs. A NASA-based cross-organizational team of high-powered experts combined integrated computational predictive modeling, fundamental chemistry analysis, advanced material science, and battery cell development to tackle this very challenging, multidisciplinary problem. This presentation will show a multiscale computational modeling approach that has produced a novel particle dynamics method called Solid Electrolyte Sphere Approximation Model (SESAM). SESAM modeling targets the 1-10 µm scale structures and provides electromechanical and grain interactions for predictive design guidelines for the manufacturing of solid-state components. Parameters such as particle size and volume fraction of the constituent materials were modeled and experimentally fabricated to optimize electrochemical performance through improved microstructure design. Experimental feedback was provided through ionic and electronic conductivity assessment and structural analysis of developed materials and cell components.

battery↗

Investigations of Clouds and Aerosols on Mars, Venus and Titan

This final report was included as part of a new proposal. This new proposal was selected for funding on 9 Nov. 1999. For Titan our interest during the past few years was to explain the observed asymmetry in the albedo. We suggested earlier, from one-dimensional modeling studies, that vertical transport rates were comparable to particle fall speeds. Since heating of the upper atmosphere, which drives dynamical motions, is largely due to the aerosols, a nonlinear interaction between dynamics, radiative heating and particle microphysics is possible. We pursued this interaction in a two-dimensional model. We showed that the observed variations in the albedo between the two hemispheres and over an orbital cycle, could be due to dynamical motions suspending particles so that particle sizes and optical depths vary across the planet. In the Cassini time frame, future studies of this interaction between dynamics, radiation and microphysics may be worthwhile using, the strong modeling base that others, and we have developed. In our recently approved proposal, however, we plan to extend our modeling to hydrocarbon clouds that lie at lower levels. We know very little about such clouds, and numerical models for their properties are non-existent. These clouds may be observed by the Huygen's Probe, and by the Cassini orbiter, so predictions of their properties should help in the analysis of Cassini data. We have also developed a sophisticated model for the lower, condensational, clouds on Venus. In this model we explored the water vapor budget on Venus, and the properties of the clouds such as particle size distribution. During the past few years we have applied our model of the water ice clouds on Mars to new data sets from Pathfinder, and Mars Global Surveyor. We have compared our predictions of cloud properties with those seen by Pathfinder, and found reasonable agreement.

Toon, Owen B.↗

Investigations of Clouds and Aerosols on Mars, Venus and Titan

For Titan our interest during the past few years was to explain the observed asymmetry in the albedo. We suggested earlier, from one-dimensional modeling studies, that vertical transport rates were comparable to particle fall speeds. Since heating of the upper atmosphere, which drives dynamical motions, is largely due to the aerosols, a non- linear interaction between dynamics, radiative heating and particle microphysics is possible. We pursued this interaction in a two-dimensional model. We showed that the observed variations in the albedo between the two hemispheres and over an orbital cycle, could be due to dynamical motions suspending particles so that particle sizes and optical depths vary across the planet. In the Cassini time frame, future studies of this interaction between dynamics, radiation and microphysics may be worthwhile using the strong modeling base that others, and we have developed. In our recently approved proposal, however, we plan to extend our modeling to hydrocarbon clouds that lie at lower levels. We know very little about such clouds, and numerical models for their properties are non-existent. These clouds may be observed by the Huygen's Probe, and by the Cassini orbiter, so predictions of their properties should help in the analysis of Cassini data. We have also developed a sophisticated model for the lower, condensational, clouds on Venus. In this model we explored the water vapor budget on Venus, and the properties of the clouds such as particle size distribution. Most researchers have investigated the upper clouds on Venus, which are essentially a photochemical aerosol with a long lifetime. The lower clouds, however, are similar to stratus clouds on Earth. These clouds have short lifetimes, and are tightly coupled to the dynamics at the base of the Venus cloud deck. We believe that the holes in these clouds seen at near infrared wavelengths by Galileo are related to some interaction between dynamics and cloud physics. One goal of our recently approved proposed work is to better understand this interaction, and to better understand how these clouds may vary if the climate of Venus were to vary. During the past few years we have applied our model of the water ice clouds on Mars to new data sets from Pathfinder, and Mars Global Surveyor. We have compared our predictions of cloud properties with those seen by Pathfinder, and found reasonable agreement. More recently we have improved our model by including a radiative transfer algorithm and a boundary layer transport scheme . The goal of this work is to understand the thermal inversions seen in Mars Global Surveyor data. We find that the inversions are created by clouds radiatively cooling the atmospheric layers in which the clouds form. We have also initiated laboratory work on the physics of carbon dioxide particle formation. In our recently approved work we propose to use these laboratory data, and to extend our modeling to carbon dioxide clouds in the Martian atmosphere.

Toon, Owen B.↗

Physical characteristics of cometary dust from dynamical studies - A review

Progress made in the determination of the physical characteristics of cometary dust particles from studies of dust tail dynamics is reviewed. Applications of the combined dynamical photometric approach of Finson and Probstein (1968) to studies of cometary tails exhibiting continuous light intensity variations are discussed, with attention given to determinations of the particle-size-related distribution function of the solar radiation pressure exerted on the particles, the contribution of comets to the interplanetary dust, calculations of dust ejection rates and a Monte Carlo approach to the analysis of dust tails. Investigations of dust streamers and striae, which are believed to be related to comet outbursts entailing brief but sharp enhancements of dust production, are then reviewed, with particular attention given to observations of Comet West 1976 VI. Finally, the question of cometary particle type is addressed, and it is pointed out that the presence of submicron absorbing particles in the striae of Comet West is not incompatible with the presence of micron-size dielectric particles in the inner coma.

Sekanina, Z.↗