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At least 487 records · Page 27

Phase controlled synthesis of transition metal carbide nanocrystals by ultrafast flash Joule heating

Nanoscale carbides enhance ultra-strong ceramics and show activity as high-performance catalysts. Traditional lengthy carburization methods for carbide syntheses usually result in coked surface, large particle size, and uncontrolled phase. Here, a flash Joule heating process is developed for ultrafast synthesis of carbide nanocrystals within 1 s. Various interstitial transition metal carbides (TiC, ZrC, HfC, VC, NbC, TaC, Cr 2 C 3 , MoC, and W 2 C) and covalent carbides (B 4 C and SiC) are produced using low-cost precursors. By controlling pulse voltages, phase-pure molybdenum carbides including β-Mo 2 C and metastable α-MoC 1-x and η-MoC 1-x are selectively synthesized, demonstrating the excellent phase engineering ability of the flash Joule heating by broadly tunable energy input that can exceed 3000 K coupled with kinetically controlled ultrafast cooling (>10 4 K s –1 ). Theoretical calculation reveals carbon vacancies as the driving factor for topotactic transition of carbide phases. The phase-dependent hydrogen evolution capability of molybdenum carbides is investigated with β-Mo 2 C showing the best performance.

01 COAL, LIGNITE, AND PEAT↗

Thermal Energy Storage Selection for Near Term Nuclear Integration

Thermal energy storage (TES) integration with existing and future light water reactors (LWRs) has the capability to increase the deployment options and uses for the large amounts of heat produced in nuclear reactor cores. The present method of exclusively producing electricity has become less economical with increases in renewable energy penetration leading to times of low or negative electricity prices. Some response to this new grid reality has been to begin load following nuclear reactors, an unideal choice due to the relatively small modular cost of producing nuclear energy compared to the revenue that could be received by using all of the heat produced. To support research in this area, Idaho National Laboratory (INL) has joined with Utah Associated Municipal Power Systems (UAMPS) on the Carbon Free Power Project (CFPP) to contract the Joint Use Modular Plant (JUMP). CFPP is planned to be a 12-module NuScale operating site built on INL property, with the first module dedicated to JUMP for research, development, and demonstration purposes. The JUMP module coming online around the beginning of fiscal year 2027 in the current project timeline. One primary goal of JUMP is to demonstrate TES integrated with an operating LWR in a real-world environment. TES integration will allow for the demonstration of nuclear power’s capability to participate in grid load following without reactor cycling, process heat integration, and electrical ancillary market opportunities. The goal of this research is to support both SMR deployment opportunities as well as support LWR retrofit capabilities. In a discussion limited to load following or energy arbitration, “charging” and “discharging” can be simply defined. TES charging refers to time when energy is removed from the nuclear reactor power conversion cycle and directed to be stored in the TES storage medium resulting in less available energy available for grid output. Discharging refers to the process of releasing energy stored in the TES medium and having an increase in grid. This paper quantifies energy storage technologies for use with nuclear reactors.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Microflaring in Low-Lying Core Fields and Extended Coronal Heating in the Quiet Sun

We have previously reported analyses of Yohkoh SXT data examining the relationship between the heating of extended coronal loops (both within and stemming from active regions) and microflaring in core fields lying along neutral lines near their footpoints (J. G. Porter, D. A. Falconer, and R. L. Moore 1998, in Solar Jets and Coronal Plumes, ed. T. Guyenne, ESA SP-421, and references therein). We found a surprisingly poor correlation of intensity variations in the extended loops with individual microflares in the compact heated areas at their feet, despite considerable circumstancial evidence linking the heating processes in these regions. Now, a study of Fe XII image sequences from SOHO EIT show that similar associations of core field structures with the footpoints of very extended coronal features can be found in the quiet Sun. The morphology is consistent with the finding of Wang et al. (1997, ApJ 484, L75) that polar plumes are rooted at sites of mixed polarity in the magnetic network. We find that the upstairs/downstairs intensity variations often follow the trend, identified in the active region observations, of a weak correspondence. Apparently much of the coronal heating in the extended loops is driven by a type of core field magnetic activity that is "cooler" than the events having the coronal signature of microflares, i.e., activity that results in little heating within the core fields themselves. This work was funded by the Solar Physics Branch of NASA's Office of Space Science through the SR&T Program and the SEC Guest Investigator Program.

Porter, Jason G.↗

Nonadiabatic processes in the Earth's magnetotail

The challenge of the assumption of an adiabatic equation of state for the plasma sheet made in several studies of quiet time convection and expansive phase activity is addressed. The observed plasma pressures at distances of approximately 10 RE are less than that predicted by adiabatic convection by over an order of magnitude. Studies of the local plasma properties for individual events as well as an ensemble of all quiet time plasma sheet samples during two years of ISEE coverage show that the polytropic index is below 5/3, and on occasion may be less than unity. During substorm activity the main effect of the plasma sheet is an increase in plasma temperature. This is seen both in statistical and case studies of individual substorms. The nature of the heating process is nonadiabatic, as evidenced by the anticorrelation between changes in plasma density and temperature. These recent observations of nonadiabatic behavior emphasize thermodynamic processes in the magnetosphere, an area which has been largely ignored.

Huang, C. Y.↗

Laserfax

The photo shows an Associated Press technician receiving a photograph prepared by means of a high speed, high resolution facsimile system known as Laserfax, so called because it employs a laser beam to scan the photo being sent. Laser scanning data is converted to electrical signals and transmitted to news bureaus within the Associated Press network via microwave radio or telephone lines. At the other end, another laser sweeps reconverted imagery onto a special, light-sensitive, dry silver paper. The paper is then heat processed to reproduce the photograph. Manufactured by Harris Electronics Systems Inc., Melbourne, Florida, Laserfax incorporates NASA thermal control coating technology developed by Jet Propulsion Laboratory for use on spacecraft antennas; the coatings block absorption of solar radiation which would interfere with the antenna's proper operation. Harris Electronics Systems, originally Radiation, Inc., reused the NASA technology in development of Laserfax. A NASA technical support package provided information about the thermal properties that could be expected of various coatings for the facsimile system's paper rollers; this information served as a design base for the infrared heat source used in developing the photo. Although relatively new, Laserfax is in extensive service. It is manufactured in several models. One of them is the type used by the Associated Press, its news bureaus and affiliated newspapers, radio and television stations. Other models have been sold in large numbers to law enforcement agencies for transmitting high quality fingerprints and identification photos. Laserfax is also in service with the National Weather Service, which converts satellite imagery to weather photographs and relays them to local weather stations, television stations, newspapers and airlines.

Source record↗

Ion pseudoheating by low-frequency Alfven waves revisited

Pseudoheating of ions in the presence of Alfven waves is studied. We show that this process can be explained by E Multiplication-Sign B drift, indicating that the pseudoheating is a consequence of equilibrium MHD system. The analytic solution obtained in this paper is quantitatively in accordance with previous results. Our simulation results show that the Maxwellian distribution is broadened during the pseudoheating; however, the shape of the broadening distribution function depends on the number of wave modes (i.e., a wave spectrum or a monochromatic dispersionless wave) and the initial thermal speed of ions (v{sub p}). It is of particular interests to find that the Maxwellian shape is more likely to maintain during the pseudoheating under a wave spectrum compared with a monochromatic wave. It significantly improves our understanding of heating processes in interplanetary space where Alfvenic turbulences exist pervasively. Compared with a monochromatic Alfven wave, E Multiplication-Sign B drift produces more energetic particles in a broad spectrum of Alfven waves, especially when the Alfvenic turbulence with phase coherent wave modes is given. Such particles may escape from the region of interaction with the Alfven waves and can contribute to fast particle population in astrophysical and space plasmas.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

THE SUPERLUMINOUS SN DES13S2cmm AS A SIGNATURE OF A QUARK-NOVA IN A HE-HMXB SYSTEM

We show that by appealing to a Quark-Nova (QN) (the explosive transition of a neutron star (NS) to a quark star (QS)) occurring in a helium-high-mass X-ray binary (He-HMXB) system we can account for the lightcurve of the first superluminous SN, DES13S2cmm, discovered by the Dark-energy Survey. The NS’s explosive conversion is triggered as a result of accretion during the He-HMXB’s second common envelope (CE) phase. The dense, relativistic, QN ejecta in turn energizes the extended He-rich CE in an inside-out shock heating process. We find an excellent fit (reduced χ{sup 2} of 1.09) to the bolometric light curve of SN DES13S2cmm including the late time emission, which we attribute to black hole accretion following the conversion of the QS to a black hole.

79 ASTRONOMY AND ASTROPHYSICS↗

Emission factors of industrial boilers burning biomass-derived fuels

Boilers are combustion devices that provide process heat and are integral to many industrial facilities. Historically, outside of the pulp and paper industry, most boilers burned fossil fuels, although interest in decarbonization has been leading to an increased use of renewable fuels in boilers. These boilers, including those in the biorefineries, are often large sources of air pollutant emissions, and the characterization of these emissions is critical to obtaining air permits and ensuring protection of the surrounding air quality. Several industrial boilers and new biorefineries allow utilization of biomass-derived fuels (e.g. wastewater sludge, lignin, etc.) produced during their operation as a fuel for the boiler to meet process energy needs. However, there is limited empirical data on emission factors for the burning of unconventional fuels, such as solid-gas mixtures containing biomass residues. To fill this gap, we carry out a comprehensive data survey, collecting information on emission factors for boilers burning either a single or a mixture of solid and gaseous biomass-derived fuels. We review multiple hard-to-obtain and unconventional data sources, such as air permit applications, stack test data, and industry-sponsored data collection efforts, to compile emission factors for biomass-derived fuels. We then compare this data with wood residue emission factors from the U.S. Environmental Protection Agency’s AP-42 emission factor database. Our results indicate that the emission factors for boilers burning unconventional fuels vary widely depending on the fuel composition, boiler type, and fuel characteristics. Overall, we find that median emission factors of selected biomass-derived fuels are typically lower than those of wood residue boilers in AP-42. The information collected herein could be useful to permitting agencies and industries utilizing boilers who may want to reduce the carbon impact of their facilities by combusting biomass-derived wastes for process energy needs, for more accurate emission estimation for permitting.

09 BIOMASS FUELS↗

MAPPING CO GAS IN THE GG TAURI A TRIPLE SYSTEM WITH 50 au SPATIAL RESOLUTION

We aim to unveil the observational imprint of physical mechanisms that govern planetary formation in the young, multiple system GG Tau A. We present ALMA observations of {sup 12}CO and {sup 13}CO 3–2 and 0.9 mm continuum emission with 0.″35 resolution. The {sup 12}CO 3–2 emission, found within the cavity of the circumternary dust ring (at radius <180 au) where no {sup 13}CO emission is detected, confirms the presence of CO gas near the circumstellar disk of GG Tau Aa. The outer disk and the recently detected hot spot lying at the outer edge of the dust ring are mapped both in {sup 12}CO and {sup 13}CO. The gas emission in the outer disk can be radially decomposed as a series of slightly overlapping Gaussian rings, suggesting the presence of unresolved gaps or dips. The dip closest to the disk center lies at a radius very close to the hot spot location at ∼250–260 au. The CO excitation conditions indicate that the outer disk remains in the shadow of the ring. The hot spot probably results from local heating processes. The two latter points reinforce the hypothesis that the hot spot is created by an embedded proto-planet shepherding the outer disk.

79 ASTRONOMY AND ASTROPHYSICS↗

Electron Bulk Acceleration and Thermalization at Earth's Quasiperpendicular Bow Shock

Electron heating at Earth's quasiperpendicular bow shock has been surmised to be due to the combined effects of a quasistatic electric potential and scattering through wave-particle interaction. Here we report the observation of electron distribution functions indicating a new electron heating process occurring at the leading edge of the shock front. Incident solar wind electrons are accelerated parallel to the magnetic field toward downstream, reaching an electron-ion relative drift speed exceeding the electron thermal speed. The bulk acceleration is associated with an electric field pulse embedded in a whistler-mode wave. The high electron-ion relative drift is relaxed primarily through a nonlinear current-driven instability. The relaxed distributions contain a beam traveling toward the shock as a remnant of the accelerated electrons. Similar distribution functions prevail throughout the shock transition layer, suggesting that the observedacceleration and thermalization is essential to the cross-shock electron heating.

Chen, L.-J.↗

Electron Bulk Acceleration and Thermalization at Earth’s Quasiperpendicular Bow Shock [Electron Acceleration and Thermalization at Earth's Quasi-Perpendicular Bow Shock]

Electron heating at Earth’s quasiperpendicular bow shock has been surmised to be due to the combined effects of a quasistatic electric potential and scattering through wave-particle interaction. Here we report the observation of electron distribution functions indicating a new electron heating process occurring at the leading edge of the shock front. Incident solar wind electrons are accelerated parallel to the magnetic field toward downstream, reaching an electron-ion relative drift speed exceeding the electron thermal speed. The bulk acceleration is associated with an electric field pulse embedded in a whistler-mode wave. The high electron-ion relative drift is relaxed primarily through a nonlinear current-driven instability. Here, the relaxed distributions contain a beam traveling toward the shock as a remnant of the accelerated electrons. Similar distribution functions prevail throughout the shock transition layer, suggesting that the observed acceleration and thermalization is essential to the cross-shock electron heating.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Carbon Nanotube Supported Amorphous MoS 2 via Microwave Heating Synthesis for Enhanced Performance of Hydrogen Evolution Reaction

Amorphous molybdenum disulfide (MoS 2 ) is a promising electrochemical catalyst for hydrogen evolution reaction (HER) due to more active sites exposed on the surface compared to its crystalline counterpart. In this study, a novel fast three-minute one-pot method is proposed to prepare the single-wall carbon nanotube- (SWCNT-) supported amorphous MoS 2 via a microwave heating process. Compared to traditional hydro- or solvent thermal methods to prepare MoS 2 which usually consume more than 10 hours, it is more promising for fast production. An overpotential at 10 mA/cm 2 of amorphous MoS 2 @SWCNT is 178 mV, which is 99 mV and 22 mV lower than crystalline MoS 2 @SWCNT and pure amorphous MoS 2 , respectively. After running 1000 cycles of polarization, ~2% increase in overpotential is observed, indicating its good stability. The enhanced performance results from the beneficial combination of the SWCNT substrate and the amorphous microstructures. The introduction of SWCNT increases catalyst conductivity and prevents MoS 2 aggregation. The amorphous microstructures of MoS 2 prepared by a microwave heating method lead to more Mo edges or active sites exposed.

Tang, Wei↗

Limitations of electron cyclotron resonance ion source performances set by kinetic plasma instabilities

Electron cyclotron resonance ion source (ECRIS) plasmas are prone to kinetic instabilities due to anisotropy of the electron energy distribution function stemming from the resonant nature of the electron heating process. Electron cyclotron plasma instabilities are related to non-linear interaction between plasma waves and energetic electrons resulting to strong microwave emission and a burst of energetic electrons escaping the plasma, and explain the periodic oscillations of the extracted beam currents observed in several laboratories. It is demonstrated with a minimum-B 14 GHz ECRIS operating on helium, oxygen, and argon plasmas that kinetic instabilities restrict the parameter space available for the optimization of high charge state ion currents. The most critical parameter in terms of plasma stability is the strength of the solenoid magnetic field. It is demonstrated that due to the instabilities the optimum B{sub min}-field in single frequency heating mode is often ≤0.8B{sub ECR}, which is the value suggested by the semiempirical scaling laws guiding the design of modern ECRISs. It is argued that the effect can be attributed not only to the absolute magnitude of the magnetic field but also to the variation of the average magnetic field gradient on the resonance surface.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

System Modeling of a Lunar Molten Regolith Electrolysis Plant

Introduction: In-Situ Resource Utilization (ISRU) is the process of extracting local resources to produce commodities for propulsion, life support systems, and off-planet construction rather than transporting consumables from Earth. Molten Regolith Electrolysis (MRE) is a novel ISRU method of extracting oxygen gas and metal alloy from lunar regolith. The MRE process involves placing lunar regolith between two electrodes, through which current is passed, to melt the regolith and reduce the metal oxide constituents by direct electrolysis (e.g. FeO, SiO2, MgO, Al2O3) into oxygen gas and metal alloys. The oxygen is liquefied and used as propellant for landers, while the metals (e.g. Ferro-alloys) are further processed and used in structural building materials and parts manufacturing. A system model was developed that accounted for the major processes of an MRE plant (from excavation of raw materials to storage of products) to assess the feasibility of a lunar MRE plant. The System Engineering and Integration (SE&I) ISRU Modeling and Analysis (SIMA) team utilized its previously documented system sizing model, the Mission Analysis and Integration Tool (MAIT) [1] as framework of the system model. MAIT uses MATLAB/Simulink to integrate subsystem models into a complete system model of the MRE plant. Total mass, volume, and power requirements were computed for numerous iterations of a MRE plant. System Model: Figure 1: MRE Plant Block Diagram The regolith excavation model determines the mass and power needed to excavate sufficient regolith. The preheating auger initiates the regolith heating process before regolith enters the MRE re-actor to reduce the energy required to turn the solid into a molten liquid. The MRE reactor is modeled in COMSOL Multiphysics and based on the research by Dominguez, Sibille, and Schreiner [2, 3, 4]. This preliminary reactor model provides an accurate calculation of thermal equilibrium during electrochemical operation of the reactor system to assess the optimal mass and power required to process the inlet flow of regolith. The model also computes the outlet flowrates of oxygen and molten products. For this analysis, the primary components of the metal alloy considered were iron and silicon. The oxygen is then purified using an Yttrium Stabilized Zirconia (YSZ) electrode, followed by liquefaction using a 90K cryocooler to be stored as liquid oxygen in insulated cylindrical tanks. In future iterations of the system model, the molten metal tapped from the MRE reactor will undergo additional processing or refinement. However, downstream handling of metals is currently a technology gap that is missing a high TRL subsystem model. Therefore, for this analysis, the accumulated metal alloy stream terminates after leaving the MRE reactor. Study Goals: This analysis investigates multiple input variables to the system to determine the sensitivity of a (near) complete plant at full-scale. This preliminary investigation ran parametric sweeps on the MRE reactor geometry, electrical current supply, layers of multi-layer insulation (MLI) on the reactor, size of the electrodes in the oxygen purification model, and regolith composition (based on landing site location). Three production targets of oxygen (1,000, 10,000, and 50,000 kg/yr) were investigated for this analysis. The parametric sweeps conducted in this analysis provide valuable insight into the expected impact of the various model inputs on plant size. This information can be used to identify the most critical components of the plant and guide future decisions on allocating funding for research and development, providing subsystem developers with appropriate interfaces with downstream and upstream processes, and assessing the overall feasibility of MRE when compared to other ISRU plants. References: [1] Carlson, A. et al. (2024) ICES, ICES-2024-53. [2] Dominguez, D.A., and Sibille, L. (2011) AIAA, AIAA-2011-700. [3] Schreiner, S.S. (2015) MIT, Dissertation. [4] Schreiner, S.S. et al. (2016) ASR, 57(7), pp.1585-1603.

ISRU↗

srlife : A software tool for estimating the life of high temperature concentrating solar receivers. Part II – Ceramic receivers

As Concentrating Solar Power (CSP) technologies aim for higher operating temperatures to enhance efficiency and meet industrial process heat demands, high-temperature metallic materials, including nickel-based superalloys, face challenges in maintaining structural integrity. Advanced ceramics offer a promising alternative due to their superior high-temperature strength. However, accurately assessing the performance of ceramic components requires a fundamentally different approach from that used for metallic components. This Part II of a two-part paper describes the integration of ceramic statistical failure models within srlife – an open-source tool for predicting the life of high-temperature CSP receivers. These models account for the inherent variability in ceramic strength, as well as the effects of subcritical crack growth (SCG) under high temperature cyclic loads. Here, the paper includes an example problem that demonstrate the process of evaluating ceramic receivers using srlife. Part I details the life estimation process for metallic receivers (i.e. creep-fatigue life) along with input and output data structure, thermohydraulic analysis, and structural analysis. The complete tool is available as open-source software at https://github.com/srlife-project/srlife and can be installed via the PyPi package manager (https://pypi.org). By supporting both ceramic and metallic receiver analyses, srlife facilitates fair comparisons between competing metallic and ceramic designs, enabling accurate evaluations of plant efficiency and the economic benefits of ceramic solar receivers and other components.

High temperature ceramic receivers↗

Application of the general thermal field model to simulate the behaviour of nanoscale Cu field emitters

Strong field electron emission from a nanoscale tip can cause a temperature rise at the tip apex due to Joule heating. This becomes particularly important when the current value grows rapidly, as in the pre-breakdown (the electrostatic discharge) condition, which may occur near metal surfaces operating under high electric fields. The high temperatures introduce uncertainties in calculations of the current values when using the Fowler–Nordheim equation, since the thermionic component in such conditions cannot be neglected. In this paper, we analyze the field electron emission currents as the function of the applied electric field, given by both the conventional Fowler–Nordheim field emission and the recently developed generalized thermal field emission formalisms. We also compare the results in two limits: discrete (atomistic simulations) and continuum (finite element calculations). The discrepancies of both implementations and their effect on final results are discussed. In both approaches, the electric field, electron emission currents, and Joule heating processes are simulated concurrently and self-consistently. We show that the conventional Fowler–Nordheim equation results in significant underestimation of electron emission currents. We also show that Fowler–Nordheim plots used to estimate the field enhancement factor may lead to significant overestimation of this parameter especially in the range of relatively low electric fields.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Discovering SPP Thermomechanical Pathways

Final report for SPPSi project in Thrust One Friction extrusion is a thermomechanical process that combines conventional extrusion with the action of a rotating die. The plastic deformation of the material being sheared and extruded is the primary source of process heat and it produces strain distributions unlike those resulting from conventional extrusion. This paper proposes an improved strain analysis that evaluates three main strain components in a series of rate-controlled friction extrusions in which the steady state was achieved. Cylindrical AA1100 extrusion billets with two embedded markers were extruded to wire with a 10:1 diametral reduction. The shape change of the embedded markers was determined via serial, transverse sectioning and quantitative metallography of the extruded wires. Three mutually orthogonal strain components (longitudinal, circumferential, and radial) were calculated at different positions along each extruded wire from the marker's shape change. The development of strain from the initial transient to the steady state is discussed. The variation of the steady-state strain with different process parameters is correlated with the die advance per revolution.

42 ENGINEERING↗