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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 487 records · Page 27
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Structurally stable, thin silicon solar cells

A fabrication process for structurally stable thin solar cell wafers that produce good power output after irradiation is described. The fabrication process is as follows. A 6 mil, circular wafer is oxidized on both sides. One side is then patterned with a rectangular array of holes in the oxide that are nominally 75 mils square and separated by 2 mil spacings. Wells are then etched into the silicon with KOH to a depth of 4 mils, leaving a 2 mil, unetched thickness. Two areas on the surface are left unetched to provide pads for bonding or testing. All oxide is then removed and the rest of the processing is normal; the unetched face is used as the illuminated face. When all other processing is complete, a 2 X 2 cm cell is sawed from the starting wafer leaving a border that is approximately 10 mils wide. The effective thickness, determined by weighing an unmetallized sample, of such a cell is about 2.4 mil.

Arndt, R. A.↗
NASA NTRS1979

Scaling and the start-up phase of space industrialization

By terrestrial standards very little mass is needed to construct the space portion of a 10,000 megawatt (10 GW) power system. Use of lunar materials makes it reasonable to consider alternatives to silicon solar cells for conversion of sunlight to electricity and thereby avoid present major problems associated with solar cell production. Machinery needed on the moon to excavate lunar materials and deliver them to a transport system, to beneficiate lunar materials, to produce glasses and ceramics from lunar materials and to chemically process lunar materials into their major oxides and elements are minor mass fractions of the total mass of equipment needed in space to produce an SPS. In addition the processing equipment can throughput several hundred times their own mass each year with very little requirement for makeup mass from earth.

Criswell, D. R.↗
NASA NTRS1996

Effects of Material Degradation on the Structural Integrity of Composite Materials: Experimental Investigation and Modeling of High Temperature Degradation Mechanisms

It has previously been demonstrated that simple coupled reaction-diffusion models can approximate the aging behavior of PMR-15 resin subjected to different oxidative environments. Based on empirically observed phenomena, a model coupling chemical reactions, both thermal and oxidative, with diffusion of oxygen into the material bulk should allow simulation of the aging process. Through preliminary modeling techniques such as this it has become apparent that accurate analytical models cannot be created until the phenomena which cause the aging of these materials are quantified. An experimental program is currently underway to quantify all of the reaction/diffusion related mechanisms involved. The following contains a summary of the experimental data which has been collected through thermogravimetric analyses of neat PMR-15 resin, along with analytical predictions from models based on the empirical data. Thermogravimetric analyses were carried out in a number of different environments - nitrogen, air and oxygen. The nitrogen provides data for the purely thermal degradation mechanisms while those in air provide data for the coupled oxidative-thermal process. The intent here is to effectively subtract the nitrogen atmosphere data (assumed to represent only thermal reactions) from the air and oxygen atmosphere data to back-figure the purely oxidative reactions. Once purely oxidative (concentration dependent) reactions have been quantified it should then be possible to quantify the diffusion of oxygen into the material bulk.

Cunningham, Ronan A.↗
NASA NTRS1983

High-Performance Matrix Resins

State-of-the-art PMR polyimides provide good strength and light weight in wide variety of critical applications. However, improved processability and elevated temperature thermo-oxidative stability are desired in such polyimide systems. Resins, intended for use in advanced composites, adhesives, and neat resin articles, show improvements in both processability and elevatedtemperature stability over state-of-the-art PMR-15 polymers.

Pater, R. H.↗
NASA NTRS1988

The enzymes associated with denitrification

The enzymes involved in the reduction of nitrogenous oxides are thought to be intermediates in denitrification processes. This review examines the roles of nitrate reductase, nitrite reductases, nitric oxide reductase, mechanisms of N-N bond formation, and nitrous oxide reductases.

NASA Discipline Exobiology↗
NASA NTRSDate not supplied

The Oxidation State of Sulfur in Martian Apatite- Implications for Redox of Surficial Processes

Meteorites from Mars record fO2 values of ∆IW = -1 to +6.5 [1, 2]. This relatively large range in fO2 has been attributed to igneous processes like differentiation and assimilation, or sometimes to alteration [2, 3], modifying the range inherited from the Martian mantle, which is thought to be closer to the values recorded by lunar basalts (~∆IW -1 [e.g., 1]). Trace element compositions reveal that those Martian meteorites that are light Rare Earth Elements (LREE) enriched record higher fO2 values than those that are LREE-depleted [2]. Sulfur (S) has been used to track redox and alteration processes on Mars because it can be present in multiple redox states varying from S2- in magmatic sulfides to S6+ in sedimentary sulfate deposits and alteration products like jarosite [4, 5]. Apatite (Ca5(PO4)3(F,Cl,OH)) is found in many of the Martian meteorites as a late stage crystallizing mineral. It can incorporate both S^(2-) [6] or S^(6+) [7] or mixtures of both [7, 8] in its crystal structure, and it has been hypothesized that the relative proportions of S^(2-) and S^(6+) in apatite will depend on the prevailing fO2 in which it formed (along with P, T, and major element composition). Note: Extended abstract on document.

P. Chowdhury↗
NASA NTRSDate not supplied

Advanced Diagnostics for Megahertz Imaging of Mixing, Fuel Spray, and Combustion Processes for Rotating Detonation Combustors

Recent advancements in megahertz rate, high-power, burst-mode laser technology are leveraged to perform and explore imaging measurements that spatially and temporally resolve the mixing, combustion, and detonation flow field in two laboratory-scale rotating detonation combustors (RDCs). In a non-premixed annular RDC, multiple imaging diagnostics are explored to investigate gaseous and liquid injector behavior, the detonation wave structure, and the propellant refill. In one instance, OH planar laser-induced fluorescence (OH-PLIF) imaging is performed up to a 2 MHz repetition rate to track the combustion products and reaction zone locations. In the same annular RDC, a single liquid fuel jet is injected, and laser-based 355-nm imaging of the fuel spray is performed up to a 1 MHz repetition rate. For this configuration, the annular RDC is used as a detonation driver to impose periodic detonation waves to interact with the fuel spray. Moreover, in this annular RDC, a range of tracer-based laser imaging measurements are explored to time-resolve the unsteady oxidizer air recovery and refill process. In a non-premixed linear RDC, planar imaging measurements of the fuel mixing are performed up to a 200 kHz repetition rate using PLIF of a tracer in the fuel supply. The fuel mixing imaging helps explain the origin of the observed pre and post wave burning, detonation structure, and enables quantifying injector recovery timescales. This paper will provide a high-level broad survey of diagnostics applied in these RDCs, lessons learned, and interesting observations.

Combustion↗
NASA NTRSDate not supplied

Advanced Diagnostics For Megahertz Imaging Of Mixing, Fuel Spray, And Combustion Processes For Rotating Detonation Combustors

Recent advancements in megahertz rate, high-power, burst-mode laser technology are leveraged to perform and explore imaging measurements that spatially and temporally resolve the mixing, combustion, and detonation flow field in two laboratory-scale rotating detonation combustors (RDCs). In a non-premixed annular RDC, multiple imaging diagnostics are explored to investigate gaseous and liquid injector behavior, the detonation wave structure, and the propellant refill. In one instance, OH planar laser-induced fluorescence (OH-PLIF) imaging is performed up to a 2 MHz repetition rate to track the combustion products and reaction zone locations. In the same annular RDC, a single liquid fuel jet is injected, and laser-based 355-nm imaging of the fuel spray is performed up to a 1 MHz repetition rate. For this configuration, the annular RDC is used as a detonation driver to impose periodic detonation waves to interact with the fuel spray. Moreover, in this annular RDC, a range of tracer-based laser imaging measurements are explored to time-resolve the unsteady oxidizer air recovery and refill process. In a non-premixed linear RDC, planar imaging measurements of the fuel mixing are performed up to a 200 kHz repetition rate using PLIF of a tracer in the fuel supply. The fuel mixing imaging helps explain the origin of the observed pre and post wave burning, detonation structure, and enables quantifying injector recovery timescales. This paper will provide a high-level broad survey of diagnostics applied in these RDCs, lessons learned, and interesting observations.

Combustion↗
NASA NTRS1991

The influences of fluorine and process variations on polysilicon film stress and MOSFET hot carrier effects

The use of fluorinated gate oxides may provide an improvement in nMOSFET reliability by enhancing hot carrier resistance. In order to clarify the mechanisms by which polysilicon processing and fluorination influence the oxide behavior, a matrix of nMOSFET structures was prepared using various processing, doping, and implantation strategies. These structures were evaluated for crystalline morphology and chemical element distribution. Mechanical stress measurements were taken on the polysilicon films from room temperature to cryogenic temperature. These examinations showed that fluorination of a structure with randomly oriented polysilicon can reduce residual mechanical stress and improve hot carrier resistance at room temperature.

Lowry, Lynn E.↗
NASA NTRS1993

Containerless measurements on liquids at high temperatures

The application of containerless techniques for measurements of the thermophysical properties of high temperature liquids is reviewed. Recent results obtained in the materials research laboratories at Intersonics are also presented. Work to measure high temperature liquid properties is motivated by both the need for reliable property data for modeling of industrial processes involving molten materials and generation of data form basic modeling of materials behavior. The motivation for this work and examples of variations in thermophysical property values from the literature are presented. The variations may be attributed to changes in the specimen properties caused by chemical changes in the specimen and/or to measurement errors. The two methods used to achieve containerless conditions were aeroacoustic levitation and electromagnetic levitation. Their qualities are presented. The accompanying slides show the layout of levitation equipment and present examples of levitated metallic and ceramic specimens. Containerless techniques provide a high degree of control over specimen chemistry, nucleation and allow precise control of liquid composition to be achieved. Effects of minor additions can thus be measured in a systematic way. Operation in reduced gravity enables enhanced control of liquid motion which can allow measurement of liquid transport properties. Examples of nucleation control, the thermodynamics of oxide contamination removal, and control of the chromium content of liquid aluminum oxide by high temperature containerless processes are presented. The feasibility of measuring temperature, emissivity, liquidus temperature, enthalpy, surface tension, density, viscosity, and thermal diffusivity are discussed in the final section of the paper.

Weber, Richard↗
NASA NTRS1980

Chemical kinetic models for combustion of hydrocarbons and formation of nitric oxide

The formation of nitrogen oxides NOx during combustion of methane, propane, and a jet fuel, JP-4, was investigated in a jet stirred combustor. The results of the experiments were interpreted using reaction models in which the nitric oxide (NO) forming reactions were coupled to the appropriate hydrocarbon combustion reaction mechanisms. Comparison between the experimental data and the model predictions reveals that the CH + N2 reaction process has a significant effect on NO formation especially in stoichiometric and fuel rich mixtures. Reaction models were assembled that predicted nitric oxide levels that were in reasonable agreement with the jet stirred combustor data and with data obtained from a high pressure (5.9 atm (0.6 MPa)), prevaporized, premixed, flame tube type combustor. The results also suggested that the behavior of hydrocarbon mixtures, like JP-4, may not be significantly different from that of pure hydrocarbons. Application of the propane combustion and nitric oxide formation model to the analysis of NOx emission data reported for various aircraft gas turbines showed the contribution of the various nitric oxide forming processes to the total NOx formed.

Jachimowski, C. J.↗
NASA NTRS1991

Tough, High-Performance, Thermoplastic Addition Polymers

Series of addition-type thermoplastics (ATT's) exhibit useful properties. Because of their addition curing and linear structure, ATT polymers have toughness, like thermoplastics, and easily processed, like thermosets. Work undertaken to develop chemical reaction forming stable aromatic rings in backbone of ATT polymer, combining high-temperature performance and thermo-oxidative stability with toughness and easy processibility, and minimizing or eliminating necessity for tradeoffs among properties often observed in conventional polymer syntheses.

Pater, Ruth H.↗
NASA NTRS1984

Terrestrial nitrous oxide cycles and atmospheric effects

The basic processes that cause N2O emission from soils are briefly discussed, and the rate of the processes is shown to vary widely in space and time, depending on soil, climate, and agrotechnical conditions. Although significant amounts of N2O are indeed emitted from the land, the complexity of the soil processes involved and the wide variation of measured rates still prevents the quantitative evaluation, global budgeting, and reliable prediction of atmospheric N2O. Increased atmospheric N2O abundance increases the levels of odd-nitrogen in the stratosphere, which, in turn, decreases the stratospheric ozone density via a catalytic cycle. Using appropriate atmospheric models and current chemical kinetic data, it has been found that the dependence of ozone reduction on N2O increase is nearly linear; a simulated doubling of N2O leads to a predicted decrease of about 14 percent in total ozone column density. A 10 percent increase in N2O yields a predicted increase in nonmelanoma skin cancer of several percent, and a possible raising of surface temperature of 0.03 K.

Whitten, R. C.↗
NASA NTRS2009

Two-Step Plasma Process for Cleaning Indium Bonding Bumps

A two-step plasma process has been developed as a means of removing surface oxide layers from indium bumps used in flip-chip hybridization (bump bonding) of integrated circuits. The two-step plasma process makes it possible to remove surface indium oxide, without incurring the adverse effects of the acid etching process.

Greer, Harold F.↗
NASA NTRS1990

Indium phosphide solar cells - Recent developments and estimated performance in space

The current status of indium phosphide solar cell research is reviewed. In the NASA research program, efficiencies of 18.8 percent were achieved for standard n/p homojunction InP cells while 17 percent was achieved for ITO/InP cells processed by sputtering n-type indium tin oxide onto p-type indium phosphide. The latter represents a cheaper, simpler processing alternative. Computer modeling calculations indicate that efficiencies of over 21 percent are feasible. Relatively large area cells are produced in Japan with a maximum efficiency of 16.6 percent.

Weinberg, Irving↗
NASA NTRS2008

Solar Concentrator Demonstrator for Lunar Regolith Processing

NASA at the Marshall Space Flight Center (MSFC) is building a portable inflatable solar concentrator ground demonstrator for use in testing in-situ resource utilization (ISRU) lunar regolith processing methods. Of primary interest is the production of oxygen as a propellant oxidizer and for life support. There are various processes being proposed for the in-situ reduction of the lunar regolith, the leading processes are hydrogen reduction, carbothermal reduction and vapor phase pyrolysis. The concentrator system being built at MSFC could support demonstrations of all of these processes. The system consists of a light inflatable concentrator that will capture sunlight and focus it onto a receiver inside a vacuum chamber. Inflatable concentrators are good for space based applications due to their low weight and dense packaging at launch. The hexapod design allows the spot size to be increased to reduce the power density if needed for the process being demonstrated. In addition to the hardware development, a comprehensive simulation model is being developed and will be verified and validated using the system hardware. The model will allow for the evaluation of different lunar locations and operational scenarios for the lunar regolith processing with a high confidence in the predicted results.

Fikes, John C.↗