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At least 487 records · Page 27
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Origin of the difference of the coverage-dependent vibrational shift for S on Ni(100) and O on Ni(100)

The p(2 x 2) and c(2 x 2) coverages of S on Ni(100) are studied with a cluster model. Consistent with a recent lattice-dynamics study, the chemical contribution (rigid Ni lattice) to the coverage-dependent shift of the S vibrational energy is of opposite sign to that for O. Analysis of the cluster wave functions suggests that S becomes less negatively charged with coverage, while O becomes more ionic; however, this effect is small.

Bauschlicher, C. W., Jr.↗
NASA NTRS1984

Similar photospheres, different mantles - A study of four O stars

The present investigation is concerned with a comparison of the spectra of four O stars (10 Lac, S Mon, HD 46223, and Zeta Pup) which have similar effective temperatures, taking into account an attempt to find the reason for differences regarding the spectral type of the stars. The photospheres of the stars are examined, taking into account the effective temperatures, radii, speed of rotation, and masses. Information is presented about the equivalent widths and profiles of strong lines in the visible and ultraviolet spectra of each star. It is found that the four stars have similar photospheres but different mantles. The stars are assigned different spectral types because the empirically selected lines used for determining spectral type in class O are sensitive primarily to conditions in the mantle of the star and not to conditions in the photosphere. Questions concerning the reasons for the differences regarding the mantles are also explored.

Underhill, A. B.↗
NASA NTRS1985

O VIII resonant absorption in PKS 2155 - 304 - A hot wind

The broad X-ray absorption feature in PKS 2155 - 304 could be due to O VIII Ly-alpha resonant absorption in a wind with outflow speeds up to about 30,000 km/s. The properties of such a wind are calculated. A homogeneous, spherically symmetric wind would involve a mass flux of about a 1000 solar masses/year, but this estimate could be greatly reduced if the outflow were beamed, and/or the absorbing gas were clumped into small clouds. In the latter case, the O VIII absorption offers clues to the physical state of thermal material closer to the central energy source than the clouds which produce optical emission lines in quasars.

Krolik, J. H.↗
NASA NTRS1985

p(2 x 2) and c(2 x 2) coverages of Cl and F on Ni(100), a comparison with O and S on Ni(100)

The rigid lattice adsorbate vibrational frequency normal to the surface, omega(e,r) and height above the surface, R(transverse), are computed for p(2 x 2) (0.25 ML) and c(2 x 2) (0.5 ML) coverages of Cl and F. These calculations show a small change in omega(e,r) and a small increase in R(transverse) with increased coverage. The bonding of Cl and F is compared to that found for O and S, both of which show a decrease in R(transverse) and O which shows a larger shift in omega(e,r).

Bauschlicher, C. W., Jr.↗
NASA NTRS1985

International Ultraviolet Explorer Atlas of O-typespectra from 1200 to 1900 Angstrom

The IUE archives provide an unprecedented sample of uniform, high-quality ultraviolet stellar spectra. In particular, they contain high-resolution SWP data for nearly 200 different O stars. We have undertaken a survey of the 1200-1900 A region in about 120 of them having homogeneous optical spectral classifications to investigate systematically the behavior of the ultraviolet features, incuding the prominent stellar wind profiles and the degree to which they correlate with the optical types. The standard extracted spectrograms have been rebinned to a constant wavelength resolution of 0.25A and uniformly normalized (not dereddened) at the GSFC RDAF. They are then plotted at 10A/cm, with reseau, photometric quality and echelle order junction flags available. This atlas contains such plots for about 100 stars, arranged in spectral-type, luminosity and peculiar object sequences. The results show a high degree of correlation between the ultraviolet features, both photospheric and stellar-wind, and the optical classifications for the majority of the O-type stars.

Walborn, N. R.↗
NASA NTRS1986

Lower thermosphere densities of N2, O and Ar under high latitude winter conditions

Measurements of the neutral thermosphere were conducted in northern Scandinavia during the Energy Budget Campaign. These measurements included determinations of N2, O, and Ar densities using rocket-borne experiments. The results obtained in the experiments are presented, taking into account also details regarding the employed experimental methods, and an evaluation of the significance of the data. It is found that there are striking differences in thermospheric distributions of the neutral constituents under different geomagnetic conditions. Under quiet geomagnetic conditions there was reasonable agreement with the United States Standard Atmosphere. The concentrations of N2 and Ar were about 70 percent of the predicted values, while the O concentration was about 2.5 times greater.

Dickinson, P. H. G.↗
NASA NTRS1985

Analysis of O(7+)/O(6+) observations in the solar wind

The ratio of O(7+)/O(6+) in the solar wind can be used to deduce the temperature at the point in the corona where the charge states become 'frozen' in the flow, and its determination therefore depends both upon the characteristics of the instrument and those of the source. The apparent increase of the ratio O(7+)/O(6+) observed in the solar wind by Ogilvie and Vogt (1980) at speeds above 450 km/s has been reevaluated using a greatly expanded data set. The ratio observed for solar wind speeds less than 450 km/s corresponds to an electron temperature of (1.7 + or - 0.2) x 10 to the 6th K in the region of 'freezing in' of the flow, as was previously reported. At higher speeds, when the kinetic temperature of the solar wind often exceeds (2-3) x 10 to the 5th K, instrumental effects become large and corrections difficult to determine.

Ogilvie, K. W.↗
NASA NTRS1985

IUE observations of phase-dependent variations in WN + O systems

IUE observations of six WN + O Wolf-Rayet (W-R) systems are reported. The periodic variations in five of the systems are shown to result primarily from selective atmospheric eclipses of the O star continuum by the W-R wind. An optical depth distribution of the form tau inversely proportional to radius is suggested for radii greater than 14 solar radii. Phase-dependent variations in the C IV 1550 absorption components in V444 Cyg, HD 90657, and HD 211853 are interpreted as wind-wind collision effects.

Koenigsberger, G.↗
NASA NTRS1986

The role of energetic O(+) precipitation in a mid-latitude aurora

It is shown that fluxes of precipitating energetic O(+) that have been observed by satellites in the topside ionosphere can explain the magnitude of the N2+(1 N) (first negative) 3914-angstroms and N2(2 P) (second positive) 3371-angstroms emission rate observed during a mid-latitude aurora over Logan, Utah (41 degrees N, 111 degrees W), on 21-22 September 1982. Heavy particle precipitation has previously been invoked to explain the anomalously high populations in the upper vibrational levels of the N2+(1 N) system that are evident in the observed emissions. An improved model is used to investigate the impact of precipitating heavy ions on the atmosphere. The nocturnal thermospheric heating rate and ionization rate during one of these events can be equivalent to the daytime EUV heating and ionization rates. The observed spectrum can be explained by energetic O(+) precipitation to within the uncertainties of the inputs to the model.

Ishimoto, M.↗
NASA NTRS1986

Future directions for H sub x O sub y detection

The activities and recommendations of the NASA workshop on the Future Directions for H sub x O sub y detection are given. The objective of this workshop was to access future directions for the measurement of the OH radical as well as other H sub x O sub y species. The workshop discussions were focused by two broad questions: (1) What are the capabilities of potential measurement methods? and (2) Will the results from the most promising method be useful in furthering understanding of tropospheric chemistry?

Crosley, David R.↗
NASA NTRS1986

Future directions for H sub x O sub y detection, executive summary

New methods for the measurement of OH radicals were assessed as were currently available and possible future methods for the other H sub x O sub y species, HO2 and H2O2. The workshop participants were invited from different groups: modelers of atmospheric photochemistry, experimentalists measuring H sub x O y species with laser and nonlaser methods, and chemists and physicists familiar with such experiments but not involved in atmospheric monitoring. There were three major conclusions from the workshop concerning the OH radical. First, it was felt that local measurements made by laser techniques would be ready within 2 or 3 years to furnish reliable measurements at the level of 1,000,000 cu. cm. Second, measurements at this level of sensitivity and with attainable levels of precision could indeed be used to make useful and interesting tests of the fast photochemistry of the troposphere. It is important, however, that the measurements be carefully designed, with respect to spatial and temporal averaging, if there is to be a meaningful comparison between results from two experimental methods or a measurement and a model. Third, nonlocal measurements using released reactants and tracers would also be very useful. These could be made on a regional or global basis, although they still require experimental design including choice of compounds.

Source record↗
NASA NTRS1986

Extended active space CASSCF/MRSD CI calculations of the barrier height for the reaction: O + H2 yields OH + H

The convergence of the barrier height for the O + H2 yields OH + H reaction was studied as a function of the size of the active space and basis set completeness. The barrier height is rapidly convergent with respect to expansion of the active space. Addition of 2p yields 2p' correlation terms to the active space lowers the barrier to the O + H2 reaction by about 2.0 kcal/mole, but addition of 3d and other terms has little additional effect. Multireference singles and doubles contracted CI plus Davidson's correction calculations using a (5s5p3d2f1g/4s3p2d1f) basis set with a 5 sigma 2 pi active space lead to a barrier height of 12.7 kcal/mole. Including an estimate of the CI contraction error and basis set superposition error leads to 12.4 kcal/mole as the best estimate of the barrier height.

Walch, Stephen P.↗
NASA NTRS1986

SRB O-ring free response analysis

The free response of viton O-rings were investigated. Two different response mechanisms of viton O-rings are identified and a theoretical representation of the two mechanisms is compared with experimental results for various temperatures.

Moore, Carleton J.↗
NASA NTRS1987

The production of O(1D) from dissociative recombination of O2(+)

The results of large scale ab initio calculations of the rates for production of O(1D) by dissociative combination of O2(+) are presented for electron temperatures in the range 100 to 3000 K. A 1-delta-u state is the dominant dissociative route from v = 0 and a 3-sigma-u(-) state is the most important route from v = 1 and v = 2. The calculated total rate for O(1D) production from v = 0 is 2.21(+0.21,-0.24) x 10(-7) x (T sub e/300) exp -.46 near room temperature. The v = 1 and v = 2 rates are about 17% and 47% smaller respectively, than the v = 0 rate at 300 K.

Guberman, Steven L.↗
NASA NTRS1987

Reactions of Atomic Oxygen (O(3P)) with Polybutadienes and Related Polymers

Thin films of the following polymers were exposed at ambient temperature to ground-state oxygen atoms (O(3P)), generated by a radio-frequency glow discharge in O2: cis- and trans-1,4-polybutadienes (CB and TB), amorphous 1,2-polybutadiene (VB), polybutadienes with different 1,4/1,2 contents, trans polypentenamer (TP), cis and trans polyoctenamers (CO and TO), and ethylene-propylene rubber (EPM). Transmission infrared spectra of CB and TB films revealed extensive surface recession, or etching, unaccompanied by any microstructural changes within the films, demonstrating that the reactions were confined to the surface layers. Contrary to the report by Rabek, Lucki, and Ranby (1979), there was no O(3P)-induced cis-trans isomerization in CB or TB. From weight-loss measurements, etch rates for polybutadienes were found to be markedly dependent on vinyl content, decreasing by two orders of magnitude from CB (2% 1,2) to structures with 30 to 40% 1,2 double bonds, thereafter increasing by half an order of magnitude to VB (97% 1,2). Relative etch rates for EMP and the polyalkenamers were in the order: EMP is greater than CO (or TO) is greater than TP is greater than CB. The sole non-elastomer examined, TB, had an etch rate about six times that of CB, ascribable to a morphology difference. Cis/trans content had a negligible effect on the etch rate of the polyalkenamers. Mechanisms involving crosslinking through units are proposed for the unexpected protection imparted to polybutadienes by the 1,2 double bonds.

Golub, Morton A.↗
NASA NTRS1986

On the direct and dissociative excitation of the O(3s 3S0) state by electron impact on atomic and molecular oxygen

The ratio of the cross sections for the direct and dissociative excitation of the OI(3s 3S0-2p 3P; 1304 A wavelength) transition, sigma A/sigma D, are accurately determined, and the sigma A/sigma D ratio is directly normalized to the ratio of the O(+) and O2(+) ionization cross sections using a high-density diffuse gas source, an electrostatically focused electron gun, a vacuum-ultraviolet monochromater, and a quadrupole mass spectrometer for simultaneous optical and composition measurements. Using revised sigma A(1304 A) values calculated with new calibration standards, the shape of the cross section for the excitation of the O(3s 3S0) state agrees well with previous results, though the absolute magnitude of sigma A(1304 A) is smaller than the results of Stone and Zipf (1974) by a factor of 2.8. The revised cross sections agree well with recent quantum calculations when cascade excitation of the 3s 3S0 state is taken into account.

Zipf, E. C.↗
NASA NTRS1987

Observation of the O I ultraviolet intercombination emissions in the terrestrial dayglow

The first measurement of the 1173-A O I intercombination line in emission in the terrestrial dayglow was performed using the EUV-FUV spectrometer designed to be flown with the Astro-1 observatory. The atmospheric conditions and viewing geometry were such as to suppress nitrogen emission relative to those from atomic oxygen, permitting the identification and measurement of the weak O I 1173-A intercombination multiplet and the 1641-A line as well as the strong 989-A and 1304-A emissions. At lower altitudes, the 1173-A emission rate increased while the 989-A emission, from the same upper level, decreased. This behavior is consistent with the radiative entrapment model of Meier (1982) and the laboratory value of the 1173-A/989-A branching ratio measured by Morrison (1985). The 1641-A/1304-A emission ratio is also consistent with a radiative entrapment model.

Bowers, C. W.↗
NASA NTRS1986

Excitation of O(1D) atoms in aurorae and emission of the forbidden OI 6300-A line

The electron aurora leads to six processes capable of exciting the O(1D2) metastable state of the atomic-oxygen ground-state configuration, the parent state of the 6300-A red line. Altitude profiles of the volume emission rate resulting from each process are computed for Maxwellian electron spectra with characteristic energies between 0.1 and 2.0 keV. Since each process peaks at a different altitude, the sum or total volume emission rate extends over a wide altitude range. Measurements of 6300-A emission obtained by rocket and satellite-borne instruments are summarized, and it is shown that the chemical reaction of N(2D) with O2 is the major source of O(1D) atoms in the electron aurora. New calculations of the 6300-A:4728-A column emission-rate ratio are presented for a range of characteristic energies in an assumed Maxwellian electron spectrum. An approximate equation for the red-line emission per unit energy input is given as a function of electron-spectrum characteristic energy.

Rees, M. H.↗