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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 487 records · Page 27
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

In-beam γ -ray spectroscopy of negative-parity states of 37 K populated in dissipative reactions

In-beam γ-ray spectroscopy was used to study excited states of the neutron-deficient nucleus 37 K populated in fast-beam inelastic-scattering and proton-removal reactions at high-momentum loss. New γ-ray transitions and γγ coincidence relationships were established using the γ-ray tracking array GRETINA. The extension of the level scheme up to the first (13/2 – ) state highlights the potential of this recently demonstrated population pathway for studies of isospin symmetry involving mirror-energy differences. Furthermore, the nature of the newly identified states is discussed in comparison to shell-model calculations with the FSU cross-shell effective interaction. The calculated occupation numbers of individual orbitals are shown to offer a consistent explanation of the measured mirror-energy differences between 37 K and 37 Ar.

20 ≤ A ≤ 38↗
DOE OSTI2025

In-beam 𝛾-ray spectroscopy toward the proton dripline: The curious case of 32 Ar

High-resolution in-beam 𝛾-ray spectroscopy was used to study excited states of the neutron-deficient nucleus 32 Ar populated in fast-beam induced four- and six-nucleon removal reactions from 36,38 Ca. One new 𝛾-ray transition and indications for an additional two were found, allowing for a glimpse at the level scheme beyond the 2$^{+}_{1}$ state. The nature of the new 1900⁢(4)-keV transition is discussed in the context of the known energy spectrum of the mirror nucleus 32 Si and shell-model calculations using the FSU and SDPF-M cross-shell effective interactions. Its resulting parent state at 3767⁢(5)⁢keV, more than 1.3 MeV above the proton separation energy, is tentatively assigned to have mixed 𝑠⁢𝑑-shell and 2p-2h character. It might either be the mirror of the 𝐽 𝜋 = 2$^{+}_{2}$ state of 32 Si at 4230.8⁢(8)⁢keV, but with a decay branch favoring a transition to the 2$^{+}_{2}$ over the ground state, or the mirror of the 4983.9⁢(11)-keV state with quantum numbers 0 + . Furthermore, the resulting mirror-energy differences of −473⁢(5) and −1218⁢(5)⁢keV are both sizable when compared to systematics; in the latter case the result would, in fact, be among the largest reported to date in the nuclear chart or suggest the potential existence of an additional, hitherto unidentified, low-lying 0 + state of 32 Si.

20 ≤ A ≤ 38↗
DOE OSTI2025

Controlling magnetism and transport at perovskite cobaltite interfaces via strain-tuned oxygen vacancy ordering

Complex oxides such as perovskite cobaltites exhibit rich phenomena at interfaces due to the complex interplay between their structural, defect, electronic, and magnetic degrees of freedom. Here, we study this interplay here in the ferromagnetic metallic cobaltite La 1−𝑥 ⁢Sr 𝑥⁢ CoO 3−𝛿 , using specific substrates to vary both the heteroepitaxial strain (compressive vs tensile) and growth orientation ((001) vs (110)). Transmission electron microscopy, electron energy-loss spectroscopy, high-resolution X-ray diffraction, magnetometry, polarized neutron reflectometry, and electronic magnetotransport measurements are applied. Lattice mismatch and growth orientation are found to enable the precise control of interfacial oxygen vacancy ordering in La 1−𝑥⁢ Sr 𝑥 ⁢CoO 3−𝛿 , thus dictating strain relaxation and oxygen vacancy depth profiles, in turn controlling thickness-dependent magnetic and electronic properties. In particular, compressive strain and (110) orientations minimize deleterious magnetic/electronic dead layer effects, leading to the optimization of interfacial magnetism and transport. Strain and orientation tuning of oxygen vacancy ordering are thus established as powerful means to control physical properties at cobaltite-based interfaces, relevant to several fields.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Optimization Simulations for a Gamma-Ray Calibration Standard for a Cyclic Neutron Activation Analysis Pneumatic System at the Penn State Breazeale Reactor

For new experimental setups, the initial testing and calibrations can be expensive and time consuming without prior optimization. However, these issues can be mitigated using realistic modeling and simulation studies of the proposed system a priori. Specifically, an experiment can be performed virtually using realistic simulations and the expected results evaluated to inform adjustments of the experimental setup to achieve optimum results. At the Penn State Breazeale Reactor, a new pneumatic transfer system has been developed for the detection and characterization of short-lived fission fragments to enhance and complement existing nuclear data. The system accomplishes this task by transporting samples cyclically between an assortment of gamma-ray/neutron detectors and the reactor-core vicinity with sub-second transit times. The measured neutron flux paired with simulations of detector response using Geant4 and a custom module for estimating cascade summing effects and corrections were used to select sample-material masses for system characterization. With the optimized sample masses, an experimental counting plan for characterizing the repeatability of the newly developed pneumatic system was developed. Finally, the predictions made with these simulations allowed for optimization of the irradiation sample characteristics and gamma-ray detection system.

cyclic neutron activation, gamma-ray spectroscopy↗
DOE OSTI2022

Erratum to: The LUX-ZEPLIN (LZ) radioactivity and cleanliness control programs

LUX-ZEPLIN (LZ) is a second-generation direct dark matter experiment with spin-independent WIMP-nucleon scattering sensitivity above 1.4 × 10 -48 cm 2 for a WIMP mass of 40 GeV/c 2 and a 1000 d exposure. LZ achieves this sensitivity through a combination of a large 5.6 t fiducial volume, active inner and outer veto systems, and radio-pure construction using materials with inherently low radioactivity content. The LZ collaboration performed an extensive radioassay campaign over a period of six years to inform material selection for construction and provide an input to the experimental background model against which any possible signal excess may be evaluated. The campaign and its results are described in this paper. We present assays of dust and radon daughters depositing on the surface of components as well as cleanliness controls necessary to maintain background expectations through detector construction and assembly. Finally, examples from the campaign to highlight fixed contaminant radioassays for the LZ photomultiplier tubes, quality control and quality assurance procedures through fabrication, radon emanation measurements of major sub-systems, and be spoke detector systems to assay scintillator are presented.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2025

Charge Radii of Neutron-Rich Scandium Isotopes and the Seniority Symmetry in the 0⁢𝑓 7/2 Shell

Nuclear charge radii of neutron-rich 47–49 Sc isotopes were measured using collinear laser spectroscopy at CERN-ISOLDE. The new data reveal that the charge radii of scandium isotopes exhibit a distinct trend between 𝑁 = 20 and 𝑁 = 28, with 41 Sc and 49 Sc isotopes having similar values, mirroring the closeness of the charge radii of 40 Ca and 48 Ca. Theoretical models that successfully interpret the radii of calcium isotopes could not account for the observed behavior in scandium radii, in particular the reduced odd-even staggering. Remarkably, the inclusion of the new 49 Sc radius data has unveiled a similar trend in the charge radii of 𝑁 = 28 isotones and 𝑍 = 20 isotopes when adding the protons atop the 48 Ca core and the neutrons atop the 40 Ca core, respectively. We demonstrate that this trend is consistent with the prediction of the seniority model.

Nuclear charge distribution↗
DOE OSTI2021

In-beam γ-ray spectroscopy of 68 Fe from charge exchange on 68 Co projectiles

Excited states in the neutron-rich nucleus 68 Fe were populated using a 9 Be( 68 Co, 68 Fe + γ)X charge-exchange reaction at 95 MeV/u. The new γ-ray transitions reported here for the first time complement data from β-decay studies and nucleon knockout reactions. In comparison to shell-model calculations with the LNPS effective interaction, two candidate states for the $6$$^{+}_{1}$ level emerge. Here, the distinct population pattern of excited states and the magnitude of the cross section, σ inc = 0.51(6) mb, make this reaction a promising one for future in-beam γ -ray spectroscopy. Reaction calculations with nuclear structure input from a new, locally optimized Hamiltonian, f7j4a, together with general considerations for heavy-ion-induced charge-exchange reactions appear consistent with most of the observations, although challenges remain.

59 ≤ A ≤ 89↗
DOE OSTI2021

High Ammonia Adsorption in MFM-300 Materials: Dynamics and Charge Transfer in Host–Guest Binding

Ammonia (NH 3 ) is a promising energy resource owing to its high hydrogen density. However, its widespread application is restricted by the lack of efficient and corrosion-resistant storage materials. In this work, we report high NH 3 adsorption in a series of robust metal-organic framework (MOF) materials, MFM-300(M) (M = Fe, V, Cr, In). MFM-300(M) (M = Fe, V III , Cr) show fully reversible capacity for >20 cycles, reaching capacities of 16.1, 15.6, and 14.0 mmol g -1 , respectively, at 273 K and 1 bar. Under the same conditions, MFM-300(V IV ) exhibits the highest uptake among this series of MOFs of 17.3 mmol g -1 . In situ neutron powder diffraction, single-crystal X-ray diffraction, and electron paramagnetic resonance spectroscopy confirm that the redox-active V center enables host-guest charge transfer, with V IV being reduced to V III and NH 3 being oxidized to hydrazine (N 2 H 4 ). A combination of in situ inelastic neutron scattering and DFT modeling has revealed the binding dynamics of adsorbed NH 3 within these MOFs to afford a comprehensive insight into the application of MOF materials to the adsorption and conversion of NH 3 .

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Structure of high-lying excited states in 47 Ca with ℓ ≥ 3 populated in fast-beam 𝛾-ray-tagged one-neutron pickup reactions

Located just one neutron removed from doubly magic, stable 48 Ca, the adjacent isotope 47 Ca has been studied extensively with neutron-removing transfer reactions and interpreted within a shell-model picture. Neutron-adding transfer reactions onto the stable 46 Ca, however, have not been performed in nearly 60 years and never with the aid of high-resolution 𝛾-ray spectroscopy. Here, we report on the 12 C⁡( 46 , Ca 47 Ca+𝛾)⁢𝑋 one-neutron pickup reaction from 12 C onto 46 Ca at more than 50 MeV/nucleon, a regime of orbital angular momentum mismatch that selectively populates 47 Ca final states based on ℓ ≥ 3 neutron configurations. Newly observed excited states and 𝛾-ray transitions are discussed in comparison to 𝑓⁡𝑝 shell-model calculations in a variety of configuration spaces. Furthermore, it is shown that the nature of the observed spectrum of final states can be well interpreted, albeit with a significant fragmentation of the 𝜈⁢0⁢𝑓 5/2 strength observed in the measurement that is not borne out in the structure calculations.

39 ≤ A ≤ 58↗
DOE OSTI2021

Broadband X-ray burst spectroscopy of the fast-radio-burst-emitting Galactic magnetar

Magnetars are young, magnetically powered neutron stars that possess the strongest magnetic fields in the Universe. Fast radio bursts (FRBs) are extremely intense millisecond-long radio pulses of primarily extragalactic origin, and a leading attribution for their genesis focuses on magnetars. A hallmark signature of magnetars is their emission of bright, hard X-ray bursts of sub-second duration. On 27 April 2020, the Galactic magnetar SGR J1935+2154 emitted hundreds of X-ray bursts within a few hours. One of these temporally coincided with an FRB, the first known detection of an FRB from the Milky Way. Here, we present spectral and temporal analyses of 24 X-ray bursts emitted 13 hours prior to the FRB and seen simultaneously with the Neutron Star Interior Composition Explorer (NICER) mission of the National Aeronautics and Space Administration and with the Fermi Gamma-ray Burst Monitor (GBM) mission in their combined energy range of 0.2 keV to 30 MeV. These broadband spectra permit direct comparison with the spectrum of the FRB-associated X-ray burst (FRB-X). We demonstrate that all 24 NICER and GBM bursts are very similar temporally to the FRB-X, but strikingly different spectrally. The singularity of the FRB-X burst is perhaps indicative of an uncommon locale for its origin. We suggest that this event originated in quasi-polar open or closed magnetic field lines that extend to high altitudes.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Investigation of the ground-state spin inversion in the neutron-rich Cl 47 , 49 isotopes

A first γ -ray study of Cl 47 , 49 spectroscopy was performed at the Radioactive Isotope Beam Factory with Ar 50 projectiles at 217 MeV/nucleon, impinging on the liquid hydrogen target of the MINOS device. Prompt deexcitation γ rays were measured with the NaI(Tl) array DALI2 + . Through the one-proton knockout reaction Ar 50 ( p , 2 p ) , a spin assignment could be determined for the low-lying states of Cl 49 from the momentum distribution obtained with the SAMURAI spectrometer. A spin-parity J π = 3 / 2 + is deduced for the ground state of Cl 49 , similar to the recently studied N = 32 isotope K 51 . The evolution of the energy difference E ( 1 / 2 1 + ) - E ( 3 / 2 1 + ) is compared to state-of-the-art theoretical predictions.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2021

Ab Initio Molecular Dynamics Simulations of Amorphous Calcium Carbonate: Interpretation of Pair Distribution Function and X-Ray Absorption Spectroscopy Data

The structure and transformation of hydrous amorphous calcium carbonate (ACC) are key to understanding biomineralization pathways and their relationship with the properties of the resulting material. Quantitative interpretation of scattering experiments aimed at elucidating the structure of ACC is challenging, due to the amorphous nature of this material, and, therefore, requires models for the structure and the scattering physics. Here, we generate physically realistic ensembles of hydrated ACC structures and their vibrational disorder from ab initio molecular dynamics (AIMD) simulations with an emphasis on enabling the consistent interpretation of the finer details of three complementary structural probes: neutron and x-ray pair distribution experiments and x-ray absorption spectroscopy (XAS). In each case, we simulate the signal directly in reciprocal space and then manipulate it into the real-space pair distribution function (PDF) or spectrum using the same procedures for the experimental and theoretical data. Good agreement with experiment was obtained across the three techniques with the simulations accounting well for all features in the spectra. Remaining small discrepancies pointed to differences between real samples and the idealized simulated systems such as deviations from the nominal CaCO3·nH2O stoichiometry. Additionally, the simulations offered a more accurate description of the local coordination environment of calcium than previous shell-by-shell fits to spectra of synthetic ACC and classical molecular dynamics simulations. This work demonstrates that AIMD is a powerful approach for extracting detailed structural information from neutron PDF, x-ray PDF, and XAS of amorphous carbonate phases.

Prange, Micah P.↗
DOE OSTI2024

Electromagnetic properties of indium isotopes illuminate the doubly magic character of 100 Sn

Understanding the nuclear properties in the vicinity of 100 Sn, which has been suggested to be the heaviest doubly magic nucleus with proton number Z equal to neutron number N, has been a long-standing challenge for experimental and theoretical nuclear physics. In particular, contradictory experimental evidence exists regarding the role of nuclear collectivity in this region of the nuclear chart. Here, we provide further evidence for the doubly magic character of 100 Sn by measuring the ground-state electromagnetic moments and nuclear charge radii of indium (Z = 49) isotopes as N approaches 50 from above using precision laser spectroscopy. Our results span almost the complete range between the two major closed neutron shells at N = 50 and N = 82 and reveal parabolic trends as a function of the neutron number, with a clear reduction towards these two closed neutron shells. Furthermore, a detailed comparison between our experimental results and numerical results from two complementary nuclear many-body frameworks (density functional theory and ab initio methods) exposes deficiencies in nuclear models and establishes a benchmark for future theoretical developments.

100Sn↗
DOE OSTI1969

Application of Nuclear Technology to Art Identification Problems: First Annual Report

Throughout the centuries, as man has become increasingly affluent, his interest in antiquities and objects of art, and the price he has been willing to pay for them, has increased. Inevitably, one result has been to attract the unscrupulous to the production and sale of counterfeit paintings, sculptures, and other works of art. The skill of forgers varies but often is highly sophisticated. However, dealers, museum curators, and other experts have also become more skillful in the detection of forgeries. Scientific tools of increasing sensitivity and sophistication have gradually been applied to the examination of the materials of art and archaeology. Such tools frequently support and render more reliable the judgment of the experts. The quality of forgeries may improve further as their makers become acquainted with the new methods of detection and in turn learn to circumvent or confound the methods. Therefore, the development of still more advanced methods of examination has great utility in the art world. This is particularly true if the ultimate effect is to make circumvention of the methods of examination so costly that the economic incentives for producing forgeries may be substantially reduced, if not eliminated.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

High Resolution Fission Fragment Spectroscopy with Superconducting Microcalorimeters

Sub-1 AMU mass determination is important for determining fission yields and neutron multiplicity, which are necessary inputs for fission models. Fission models can improve spent nuclear waste stream analysis and nuclear fuel burnup determination. Here, to achieve this goal, we have used superconducting microcalorimeter detectors to directly measure the energy of fission fragments from the spontaneous fission of 252 Cf. With a fiber coupled LED pulser setup we demonstrate that we can reach a relative energy resolution of 0.1% and better for photon pulses with energies above 60 MeV. This instrument, in conjunction with time-of-flight (TOF) measurement, would allow for sub-1 atomic mass unit (AMU) mass determination of fission fragments in a future beamline application.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2020

Ammonothermal Synthesis, Crystal Structure, and Vibrational Properties of the Doubly Deprotonated Calcium Guanidinate, CaC(NH) 3

We report the synthesis of the doubly deprotonated calcium guanidinate, CaC(NH) 3 , from liquid ammonia and its crystal structure as determined from powder X‐ray and neutron diffraction, and confirmed using CNH elemental analysis and infrared (IR) spectroscopy data. CaC(NH) 3 crystallizes in the hexagonal system with space group P 6 3 / m (no. 176) with Z = 2 and a = 5.2666(13) Å, c = 6.5881(6) Å and V = 158.25(4) Å 3 . We also compare the structural similarities and differences of this phase with the isotypical strontium and ytterbium compounds.

Ogutu, George↗
DOE OSTI2021

Preface to the Special Issue on Signal Processing, Data Acquisition and Front-end Systems for Radiation Detection and Measurements

This special issue of the Journal of Signal Processing Systems focuses on advancement of signal processing and data-acquisition for radiation detection and measurements. The seven articles included cover diverse topics within the scope of radiation detection ranging from understanding of fundamental fission process, instrumentation, and application of radiation interaction (e.g., tomography and imaging). The articles focus on signal processing for fission spectrometer, neutron and gamma-ray computed tomography and artificial intelligence methods, dynamic neutron imaging system, pulse-pileup correction in x-ray spectroscopy and calibration methods in radiation measurement.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗
DOE OSTI2023

Electrospraying deposition and characterization of potassium chloride targets for nuclear science measurements

Natural and isotopically enriched KCl targets were prepared using specially formulated KCl solutions, deposited by electrospraying on thin (1.5 μm) gold backings, followed by a short annealing in a preheated (350-450 °C) furnace. Various techniques, such as X-ray fluorescence (XRF), scanning electron microscopy (SEM) imaging, and energy-dispersive X-ray spectroscopy (EDS), were used to characterize the produced targets. A white neutron beam at the Los Alamos Neutron Science Center (LANSCE) facility was also used to verify the estimated atomic percentages of the enriched 40 KCl targets. KCl was deposited relatively uniformly as large particles rather than films on the gold surface. As a result, this method can be broadly extended to make stable targets that are difficult to produce with other methods and more exotic radioactive targets required for research in fundamental sciences and applications.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗