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At least 487 records · Page 27

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NASA NTRS1972

Origin of organic matter in early solar system. V - Further studies of meteoritic hydrocarbons and a discussion of their origin.

The Murchison meteorite contains aliphatic and aromatic hydrocarbons similar to those made in static Fischer-Tropsch-type syntheses. Principal compound classes above C8 are n-alkanes, mono- and dimethylalkanes, alkenes, alkylbenzenes and -naphthalenes. Below C8, n-alkanes are virtually absent; instead, benzene, toluene, branched alkanes dominate. The CH4/C2H6 ratio is greater than 30, possibly greater than 700. Isoprenoids from C17 to C20 occur in a surface rinse but not in subsequent extracts and appear to be terrestrial contaminants. Thiophenes, porphyrin-like pigments, and chlorobenzenes were also found; the latter appear to be contaminants. In the Allende meteorite, only methane, benzene, toluene and an aromatic polymer seem to be indigeneous. A comprehensive review of current evidence shows that Fischer-Tropsch-type reactions can account for most principal features of meteorite organic matter.

Studier, M. H.↗

NASA NTRS1972

Evidence for amino-acids of extraterrestrial origin in the Orgueil meteorite.

The problems of separation of contaminant from indigenous amino-acids in meteorites can be largely overcome by applying gas chromatographic techniques for the separation of D,L enantiomers of amino-acids as their diastereomeric derivatives and the identification of these compounds by gas chromatographic retention times and mass spectral fragmentation patterns. Two samples of Orgueil meteorite were examined. The results show that there are amino-acids indigenous to the Orgueil meteorite in addition to those present as contaminants.

Lawless, J. G.↗

NASA NTRS1972

Thermal release characteristics of spallogenic He, Ne, and Ar from the Carbo iron meteorite.

Analysis of the thermal release patterns of He, Ne, and Ar from samples of the Carbo iron meteorite, showing that virtually no fractionation of He 3, He 4, Ne 21, and Ar 38 occurs. Thus conclusions about iron meteorites based on measured noble gas ratios will be unaffected by gas loss, and measurement of these ratios cannot yield information about possible loss. Further, noble gas loss cannot explain the abnormal elemental and isotopic patterns observed in some iron meteorites, notably hexahedrites. The release of He and Ne was continuously observed throughout the stepwise heating sequence, and ratios of diffusion coefficients at two consecutive temperatures have been determined from measurements of the relative degassing rates at these temperatures at the time of temperature increase. Effective activation energies of 100 plus or minus 20 kcal/mol for both He 3 and Ne 21 are calculated from the diffusion coefficient ratios at temperatures above 1050 C. A sharp maximum at 750 C in both the effective activation energy and the gas release is correlated with the alpha, gamma-phase transition.

Nyquist, L. E.↗

NASA NTRS1971

Transition element distribution in stony meteorites and in terrestrial and lunar rocks.

Discussion of the distribution of the transition elements (Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, and Zn) among the individual minerals of stony meteorites, and comparison with data on comparable lunar and terrestrial minerals. As an example of meteorite distribution patterns, data on the Modoc meteorite are presented. For the lunar rocks, microprobe data are used, along with published information from other investigators. For comparison with terrestrial igneous rocks, Skaergaard intrusion rocks are used. They present some striking analogies in mineralogy and petrology with the lunar igneous rocks and are thus peculiarly suitable for this cross comparison.

Mason, B.↗

NASA NTRS1972

The mineralogy of meteorites.

Of particular interest among minerals recently discovered in meteorites are five phosphate minerals, three of them unknown in terrestrial rocks; a chromium nitride and a silicon oxynitride; lonsdaleite and chaoite, new polymorphs of carbon; ringwoodite and majorite, the spinel and garnet analogs of olivine and pyroxene, respectively; a number of calcium- and aluminum-rich silicates in the Allende meteorite, a type III carbonaceous chondrite which fell in 1969; and several alkali-rich silicates found as inclusions in iron meteorites. Knowledge of the compositional range of the common minerals olivine, pyroxene, and plagioclase has also been greatly increased by recent researches.

Mason, B.↗

NASA NTRS1973

Photometric and polarimetric properties of the Bruderheim chondritic meteorite.

Study of the spectral, photometric, and polarimetric properties of the Bruderheim olivine-hypersthene chondritic meteorite. This meteorite is representative of the most common meteoritic material recovered on earth, and, hence, could also be the most common in interplanetary space. Yet, comparison with astronomical data indicates that none of the asteroids in the main belt for which adequate observations exist can be matched with Bruderheim properties. Only the surface of the Apollo asteroid Icarus does, in light of polarization and photometry data, appear to be consistent with an ordinary chondrite composition. This suggests the possibility that this material, although common in earth-crossing orbits, is rare as a surface constituent in the main asteroid belt.

Egan, W. G.↗

NASA NTRS1974

Constraints of magnetic field which magnetized the Farmington meteorite parant body

Analysis indicates the following: (1) the parent body of the Farmington meteorite experienced sufficient heating (probably from shock accompanying a major collision occurring 520 million years ago) to erase the record of any magnetization acquired prior to that event; therefore, (2)the observed magnetization in the Farmington meteorite must have been acquired after the collision; and (3)shockproduced magnetization is unlikely, because of the finite cooling time indicated by the burial depth of approximately several meters. The possibility of shock or irradiation-produced magnetizations is proposed as an experimental study, even though neither appears likely to have produced the magnetic field which produced the magnetization in the parent body of the Farmington meteorite.

Rowe, M. W.↗

NASA NTRS1974

The Magnetization of Carbonaceous Meteorites

Alternating field demagnetization experiments have been conducted on representative samples of the carbonaceous meteorites (carbonaceous chondrites and ureilites). The results indicate that many, if not all, of these meteorites possess an intense and stable magnetic moment of extraterrestrial origin. Thermomagnetic analyses have been conducted on samples of all known carbonaceous meteorites. In addition to yielding quantitative magnetite estimates, these studies indicate the presence of a thermally unstable component, troilite, which reacts with gaseous oxygen to form magnetite. It is proposed that the magnetite found in some carbonaceous chondrites resulted from the oxidation of troilite during the early history of the solar system. The formation of pyrrhotite is expected as a natural consequence of magnetite formation via this reaction. Consideration is given to the implications of magnetite formation on paleointensity studies.

Herndon, James Herndon↗

NASA NTRS1974

The Ellicott meteorite

Two medium octahedrite iron meteorites recently found near Ellicott, Colorado, are described and compared to a medium octahedrite iron meteorite discovered in 1902 at nearby Franceville, Colo. Based on the Ni, Ga, Ge, and Ir contents, the pronounced differences in shock history, and the differences in average kamacite bandwidth, it is clear that Ellicott is a new meteorite, distinct from the Franceville find.

Olsen, E. J.↗

NASA NTRS1975

Constraints on magnetic field which magnetized the Farmington meteorite parent body

The parent body of the Farmington meteorite experienced sufficient heating, probably from shock accompanying a major collision occurring 520 million years ago, to erase the record of any magnetization acquired prior to that event. Therefore, the observed magnetization in the Farmington meteorite must have been acquired after the collision. Shock-produced magnetization is unlikely because of the finite cooling time indicated by the burial depth of over several meters. The possibility of shock or irradiation-produced magnetizations should be studied experimentally, even though neither appears likely to have produced the magnetic field which produced the magnetization in the parent body of the Farmington meteorite.

Rowe, M. W.↗

NASA NTRS1975

Stereoisomers of isovaline in the Murchison meteorite

Isovaline is present in the Murchison meteorite as a racemic mixture (about equal concentrations of the R and S enantiomers). Since isovaline does not have a hydrogen atom on its asymmetric alpha-carbon atom, the racemic mixture could not have formed by commonly accepted mechanisms of racemization. Thus, isovaline in the meteorite most probably was synthesized as a racemic mixture and is not the result of the racemization of either the R or S enantiomer. Other chiral amino acids in the meteorite are present as racemic mixtures, and were probably synthesized in a similar manner by abiotic, extraterrestrial processes.

Pollock, G. E.↗

NASA NTRS1975

The low-temperature electrical properties of carbonaceous meteorites

Electrical conductivities and dielectric constants have been measured over the temperature range 90-300 K on several carbonaceous chondrites and some terrestrial analogues. The conductivities of meteorites of different petrologic subtypes range over many orders of magnitude and the low-temperature activation energies are typically much smaller than those observed in terrestrial materials at higher temperatures. The electrical properties of carbonaceous chondrites vary systematically with chemical-mineralogical characteristics in that: (1) activation energy at low temperature is greater in the more volatile-rich meteorites containing hydrated silicates, and (2) conductivity is greater in the more reduced meteorites of higher petrologic subtype. These new data on the electrical properties of chondrites hold important implications for both the thermal and magnetic histories of small bodies in the early solar system.

Brecher, A.↗

NASA NTRS1976

Spectral reflectance characteristics of the meteorite classes

The results are presented of spectral reflectance measurements on more than 150 individual meteorite specimens representing essentially all types and subtypes of meteorites. A brief review is provided of the nature of the compositional information contained in a reflection spectrum of a natural material. Attention is given to the spectral reflectance characteristics of mineral assemblages, and to meteorite class spectral characteristics.

Gaffey, M. J.↗

NASA NTRS1976

Lafayette meteorite - Petrology and opaque mineralogy

The Lafayette meteorite is a calcium-rich achondrite composed predominantly of cumulus clinopyroxene with minor iron-rich olivine and rare interstitial feldspar. The opaque oxide minerals are magnetite-ilmenite intergrowths, an apparently homogenous Cr-rich titaniferous magnetite, and discrete ilmenite. Pyrite, the major sulfide mineral, occasionally displays lamellar intergrowths of marcasite that appear to be of primary origin. Troilite occurs as inclusions in ilmenite or interstitial to the silicate minerals. Bulk chemical composition of the glass in the fusion crust is comparable with that of the Nakhla meteorite. The glass contains abundant skeletal crystals of magnetite as well as very rare, zoned magnetite grains with rims enriched in Mg and depleted in Ti relative to the cores. Although no brecciation is visible in the Lafayette meteorite, the presence of deformed twin lamellae in the clinopyroxene indicates some deformation has occurred.

Boctor, N. Z.↗

NASA NTRS1977

Fluorine in meteorites

Microanalysis using a resonant nuclear reaction was used to measure F concentrations in USGS standard rocks and 21 meteorites. The F appears to be a moderately depleted element, but there were significant variations within each sample. Measurements on separated metal phases suggest that about 20% of meteoritic F is in the metal or in a phase closely associated with it. Simultaneous measurements of F, Mg, Na, Al and Si in the nonmagnetic fractions of meteorites suggest plagioclase as a F containing phase.

Allen, R. O., Jr.↗

NASA NTRS1977

Meteoritic material on the moon

Three types of meteoritic material are found on the moon: micrometeorites, ancient planetesimal debris from the "early intense bombardment," and debris of recent, craterforming projectiles. Their amounts and compositions have been determined from trace element studies. The micrometeorite component is uniformly distributed over the entire lunar surface, but is seen most clearly in mare soils. It has a primitive, C1-chondrite-like composition, and comprises 1 to 1.5 percent of mature soils. Apparently it represents cometary debris. The ancient component is seen in highland breccias and soils. Six varieties have been recognized, differing in their proportions of refractories (Ir, Re), volatiles (Ge, Sb), and Au. All have a fractionated composition, with volatiles depleted relative to siderophiles. The abundance patterns do not match those of the known meteorite classes. These ancient meteoritic components seem to represent the debris of an extinct population of bodies (planetisimals, moonlets) that produced the mare basins during the first 700 Myr of the moon's history. On the basis of their stratigraphy and geographic distribution, five of the six groups are tentatively assigned to specific mare basins: Imbrium, Serenitatis, Crisium, Nectaris, and Humorum or Nubium.

Morgan, J. W.↗

NASA NTRS1978

Meteorites and their parent bodies: Evidence from oxygen isotopes

Isotopic abundance variations among meteorites are used to establish genetic associations between meteorite classes. Oxygen isotope distributions between group II E irons with H-group ordinary chondrites and enstatic meteorites indicate that the parent bodies were formed out of pre-solar material that was not fully mixed at the time condensation occurred within the solar nebula.

Clayton, R. N.↗

NASA NTRS1977

Al-26 in stony meteorites with gas losses

The Al-26 content of a group of stony meteorites with low levels of He-3 (implying outgassing caused by near approach to the sun) was analyzed in a test of the possible role of cosmic radiation in determining the radionuclide concentration of meteorites. The Al-26 contents of the meteorites with He-3 losses were found to be indistinguishable from the Al-26 contents of L- and H-chondrites. It is concluded that if the He-3 outgassing occurred near the sun, the flux of particles producing Al-26 must have been nearly normal, or the diffusion process must have taken place very rapidly.

Herzog, G. F.↗