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At least 487 records · Page 27

Mass spectrometry in structural and stereochemical problems. CXCIX.

Electron-impact induced fragmentations of o-, m-, and p-hydroxyalkylphenones and their trimethylsilyl (TMS) ethers are studied by means of high-resolution mass spectrometry, metastable defocusing, and deuterium labeling of the TMS ether derivatives. A markedly increased methyl radical loss from the o-TMS ether is attributed to a proximity effect. Minor fragmentation was observed with m- and p-isomers. Significantly intense doubly-charged ions were formed from ketonic cleavage and by the loss of a TMS methyl radical. The sequence of fragmentation was found to depend on the size of the alkyl group attached to the ketone carbonyl.

Smith, G. G.↗

Quiet-time electron increases - A measure of conditions in the outer solar system.

Discussion of a possible explanation for the increases in the intensity range of 3- to 12-MeV interplanetary electrons that McDonald et al. (1972) have labeled as 'quiet-time electron increases.' It is argued that the electrons in quiet-time increases are galactic in origin but that the observed increases are not the result of any variation in the modulation of these particles in the inner solar system. It is suggested instead that quiet-time increases may occur when more electrons than normal penetrate a modulating region that lies far beyond the orbit of the earth. The number of electrons penetrating this region may increase when field lines that have experienced an unusually large random walk in the photosphere are carried by the solar wind out to the region. As evidence of this increased random walk, it is shown that five solar rotations before most of the quiet-time increases occur there is an extended period when the amplitude of the diurnal anisotropy (measured by the Deep River neutron monitor) is relatively low. A delay time of five rotations implies that the proposed modulating region lies at about 30 AU from the sun if the average solar-wind speed is assumed to be constant at about 400 km/sec over this distance. The implications for the correlation between periods of low-amplitude diurnal anisotropy and quiet-time increases on interplanetary conditions out to about 30 AU and some possible models for the proposed modulating region are also considered.

Fisk, L. A.↗

RF antenna-pattern visual aids for field use

Series of plots must be made of antenna pattern on polar-coordinate sheet depicting vertical planes. Separate sheets are plotted depicting antenna patterns in vertical plane at azimuth positions. After all polar plots are drawn, they are labeled according to their azimuthal positions. Transparencies are then stiffened with regular wire, cardboard, or molded plastic.

Williams, J. H.↗

Automated Microbial Metabolism Laboratory

The Automated Microbial Metabolism Laboratory (AMML) 1971-1972 program involved the investigation of three separate life detection schemes. The first was a continued further development of the labeled release experiment. The possibility of chamber reuse without inbetween sterilization, to provide comparative biochemical information was tested. Findings show that individual substrates or concentrations of antimetabolites may be sequentially added to a single test chamber. The second detection system which was investigated for possible inclusion in the AMML package of assays, was nitrogen fixation as detected by acetylene reduction. Thirdly, a series of preliminary steps were taken to investigate the feasibility of detecting biopolymers in soil. A strategy for the safe return to Earth of a Mars sample prior to manned landings on Mars is outlined. The program assumes that the probability of indigenous life on Mars is unity and then broadly presents the procedures for acquisition and analysis of the Mars sample in a manner to satisfy the scientific community and the public that adequate safeguards are being taken.

Source record↗

ADMAP (automatic data manipulation program)

Instructions are presented on the use of ADMAP, (automatic data manipulation program) an aerospace data manipulation computer program. The program was developed to aid in processing, reducing, plotting, and publishing electric propulsion trajectory data generated by the low thrust optimization program, HILTOP. The program has the option of generating SC4020 electric plots, and therefore requires the SC4020 routines to be available at excution time (even if not used). Several general routines are present, including a cubic spline interpolation routine, electric plotter dash line drawing routine, and single parameter and double parameter sorting routines. Many routines are tailored for the manipulation and plotting of electric propulsion data, including an automatic scale selection routine, an automatic curve labelling routine, and an automatic graph titling routine. Data are accepted from either punched cards or magnetic tape.

Mann, F. I.↗

Mass spectrometry.

Review of the current state of mass spectrometry, indicating its unique importance for advanced scientific research. Mass spectrometry applications in computer techniques, gas chromatography, ion cyclotron resonance, molecular fragmentation and ionization, and isotope labeling are covered. Details are given on mass spectrometry applications in bio-organic chemistry and biomedical research. As the subjects of these applications are indicated alkaloids, carbohydrates, lipids, terpenes, quinones, nucleic acid components, peptides, antibiotics, and human and animal metabolisms. Particular attention is given to the mass spectra of organo-inorganic compounds, inorganic mass spectrometry, surface phenomena such as secondary ion and electron emission, and elemental and isotope analysis. Further topics include mass spectrometry in organic geochemistry, applications in geochronology and cosmochemistry, and organic mass spectrometry.

Burlingame, A. L.↗

Generalized m series in tree enumeration.

Consideration of a particular series formed by deleting certain branches of the complete graph K sub t with t vertices. A class of graphs which contains the m series as a special case is considered, and a new formula is given for the m series itself (an m series graph is obtained from K sub t by removing m branches forming a closed loop). A formula is derived for the number of labeled spanning trees in the graph obtained by deleting certain branches from K sub t.

O'Neil, P. V.↗

Compounds of the organogenic elements in Apollo 11 and 12 lunar samples - A review.

Investigations of low molecular weight compounds of the organogenic elements on lunar samples are reviewed. The three general techniques of vacuum pyrolysis, acid hydrolysis, and crushing have been employed by most investigators. Vacuum pyrolysis of lunar fines produce a variety of gaseous species which are either: (1) indigenous, (2) solar wind products and/or (3) chemical reaction products of mineral phases found in the lunar samples. Acid hydrolysis of lunar fines using deuterium-labeled acids yields evidence for indigenous methane and ethane. Methane and ethane found in the lunar fines are largely derived from the solar wind with only trace amounts indigenous to the samples. Crushing experiments with lunar fines and breccias produce methane, ethane, hydrogen, nitrogen, hydrogen sulfide and the rare gases.

Gibson, E. K., Jr.↗

Outline of a new approach to the analysis of complex systems and decision processes.

Development of a conceptual framework for dealing with systems which are too complex or too ill-defined to admit of precise quantitative analysis. The approach outlined is based on the premise that the key elements in human thinking are not numbers, but labels of fuzzy sets - i.e., classes of objects in which the transition from membership to nonmembership is gradual rather than abrupt. The approach in question has three main distinguishing features - namely, the use of so-called 'linguistic' variables in place of or in addition to numerical variables, the characterization of simple relations between variables by conditional fuzzy statements, and the characterization of complex relations by fuzzy algorithms.

Zadeh, L. A.↗

Polymerization of amino acids under primitive earth conditions.

Small amounts of peptides were obtained when equal amounts of methane and ammonia were reacted with vaporized aqueous solutions of C14-labeled glycine, L-alanine, L-aspartic acid, L-glutamic acid and L-threonine in the presence of a continuous spark discharge in a 24-hr cyclic process. The experiment was designed to demonstrate the possibility of peptide synthesis under simulated primeval earth conditions. It is theorized that some dehydration-condensation processes may have taken place, with ammonium cyanide, the hydrogencyanide tetramer or aminonitriles as intermediate products, during the early chemical evolution of the earth.

Flores, J. J.↗

Evidence of hyperbolic cosmic dust particles.

Cosmic dust data from the helicentric Pioneers 8 and 9 have been gathered for more than 7 years. A review and detailed study of these data are given and show that events which were previously labeled solar disturbance events and assumed to be noise generated by solar effects are, logically, true cosmic dust impact events. They are shown as an extension of the range of particle parameters exhibited by the time-of-flight measurements. The effects of accepting the sun-oriented events as authentic impact events are discussed.

Berg, O. E.↗

Identification, definition and mapping of terrestrial ecosystems in interior Alaska

The author has identified the following significant results. The vegetation map in preparation at the time of the last report was refined and labeled. This map is presented as an indication of the spatial and classificatory detail possible from interpretations of enlarged ERTS-1 color photographs. Using this map, areas covered by the several vegetation types characterized by white spruce were determined by planimetry. A 1:63,360 scale land use map of the Juneau area was drawn. This map incorporates the land use classification system now under development by the U.S. Geological Survey. The ERTS-1 images used in making the Juneau map were used to determine changes in surface area of the terminal zones of advancing and receding glaciers, the Taku, Norris, and Mendenhall. A new 1:63,360 scale land use map of the Bonanza Creek Experimental Forest and vicinity was drawn. Several excellent new sciences of test areas were received from NASA in color-infrared transparency format. These are being used for making photographic prints for analysis and mapping according to procedures outlined in this report.

Anderson, J. H.↗

NASTRAN data generation of helicopter fuselages using interactive graphics

The development and implementation of a preprocessor system for the finite element analysis of helicopter fuselages is described. The system utilizes interactive graphics for the generation, display, and editing of NASTRAN data for fuselage models. It is operated from an IBM 2250 cathode ray tube (CRT) console driven by an IBM 370/145 computer. Real time interaction plus automatic data generation reduces the nominal 6 to 10 week time for manual generation and checking of data to a few days. The interactive graphics system consists of a series of satellite programs operated from a central NASTRAN Systems Monitor. Fuselage structural models including the outer shell and internal structure may be rapidly generated. All numbering systems are automatically assigned. Hard copy plots of the model labeled with GRID or elements ID's are also available. General purpose programs for displaying and editing NASTRAN data are included in the system. Utilization of the NASTRAN interactive graphics system has made possible the multiple finite element analysis of complex helicopter fuselage structures within design schedules.

Sainsbury-Carter, J. B.↗

UV photography of the earth and the moon

The fundamental aim of this experiment was the acquisition of ultraviolet photographs of the earth and the moon that could be used to interpret similar imagery of Mars and Venus. Venus shows no markings whatever when viewed in visible light, a phenomenon that is in keeping with its immensely thick atmosphere and perpetual cloud cover, but in the near ultraviolet, the planet exhibits low contrast markings which vary in position and appearance with time. Mars posed just the opposite problem from Venus at wavelengths below 4500 A, Mars shows very little detail, sometimes none at all, whereas at longer wavelengths, the surface is clearly visible. Occasionally observers have reported that this obscuration has lifted and the ground has become visible at the shorter wavelengths as well. Such events have been labeled blue clearings and led to the suggestion that the ultraviolet obscuration was caused by an atmospheric haze. Mariner 6 and 7 observations of Mars failed to find such a haze and lent support to the alternative view that ascribed the absence of detail on UV photographs to a simple lack of contrast between Martian surface features at these wavelengths.

Source record↗

The Environmental Heat Flux Routine, Version 4 (EHFR-4) and Multiple Reflections Routine (MRR). Volume 2: Programmers reference manual

The EHFR program reference information which is presented consists of the following subprogram detailed data: purpose-description of the routine, a list of the calling programs, an argument list description, nomenclature definition, flow charts, and a compilation listing of each subprogram. Each of the EHFR subprograms were developed specifically for this routine and do not have an applicability of a general nature. Single precision accuracy available on the Univac 1108 is used exclusively in all but two of the 31 EHFR subprograms. The double precision variables required are identified in the nomenclature definition of the two subprograms that require them. A concise definition of the purpose, function, and capabilities is made in the subprogram description. The description references the appropriate Volume 1 sections of the report which contain the applicable detailed definitions, governing equations, and assumptions used. The compilation listing of each subprogram defines the program/data storage requirements, identifies the labeled block common data required, and identifies other subprograms called during execution. For Vol. 1, see N73-31842.

Dietz, J. B.↗

Geological mapping of the moon

Compilation and labelling of geological and morphological charts on a scale of 1:1,000,000 are discussed with emphasis on the regions of Maria Tranquilitatis, Crisium, Fecunditatis, Humorum and Nukium as well as certain prominent craters.

Markov, M. S.↗

Appendix A: Specimen 72275 documentation

The friability of the matrix of specimen 72275 caused numerous fragments and an abundance of fines to break away from the main mass during transport from the moon and handling in the lunar receiving laboratory. Samples 72275,1 to 72275,14 were labeled during PET examination. Samples 72275,1, 4, 6, 7, 8, and 9 were placed in storage, and the remainder were distributed.

Marvin, U. B.↗

Detection and analysis of Jupiter's decametric micropulses

The occurrence of Jupiter's decametric radio emission can be correlated with the central meridian longitude of Jupiter as if the active regions were radio transmitters placed at fixed longitudes on its surface. These active regions are commonly called sources and are labelled Source A, Jovian longitude = 200 deg, Source B = 100 deg and Source C =300 deg. These sources are not always active. However, they can be turned-on if Jupiter's innermost Galilean moon, Io, is in the right phase. In fact, if Io is found 90 deg from superior geocentric conjunction (maximum eastern elongation) and if source B is simultaneously on the central meridian, source B radiation is almost guaranteed, whereas source C radiation is highly likely when Io is found 240 deg from superior geocentric conjunction. Source A radiation is largely independent of Io's position. Interestingly, the Io-related radio storms contain unusually rapid events that can only be properly studied using wide-band techniques.

Lebo, G. R.↗