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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 487 records · Page 27
All sourcesNASA NTRSDOE OSTI
NASA NTRS2013

Interactions between Coronal Mass Ejections Viewed in Coordinated Imaging and In Situ Observations

The successive coronal mass ejections (CMEs) from 2010 July 30 - August 1 present us the first opportunity to study CME-CME interactions with unprecedented heliospheric imaging and in situ observations from multiple vantage points. We describe two cases of CME interactions: merging of two CMEs launched close in time and overtaking of a preceding CME by a shock wave. The first two CMEs on August 1 interact close to the Sun and form a merged front, which then overtakes the July 30 CME near 1 AU, as revealed by wide-angle imaging observations. Connections between imaging observations and in situ signatures at 1 AU suggest that the merged front is a shock wave, followed by two ejecta observed at Wind which seem to have already merged. In situ measurements show that the CME from July 30 is being overtaken by the shock at 1 AU and is significantly compressed, accelerated and heated. The interaction between the preceding ejecta and shock also results in variations in the shock strength and structure on a global scale, as shown by widely separated in situ measurements from Wind and STEREO B. These results indicate important implications of CME-CME interactions for shock propagation, particle acceleration and space weather forecasting.

Liu, Ying D.↗
NASA NTRS2007

Influence of Aerosols on the Shortwave Cloud Radiative Forcing from North Pacific Oceanic Clouds: Results from the Cloud Indirect Forcing Experiment (CIFEX)

Aerosols over the Northeastern Pacific Ocean enhance the cloud drop number concentration and reduce the drop size for marine stratocumulus and cumulus clouds. These microphysical effects result in brighter clouds, as evidenced by a combination of aircraft and satellite observations. In-situ measurements from the Cloud Indirect Forcing Experiment (CIFEX) indicate that the mean cloud drop number concentration in low clouds over the polluted marine boundary layer is greater by 53 cm(sup -3) compared to clean clouds, and the mean cloud drop effective radius is smaller by 4 micrometers. We link these in-situ measurements of cloud modification by aerosols, for the first time, with collocated satellite broadband radiative flux observations from the Clouds and the Earth s Radiant Energy System to show that these microphysical effects of aerosols enhance the top-of-atmosphere cooling by -.9.9 plus or minus 4.3 W m(sup -2) for overcast conditions.

Wilcox, Eric M.↗
NASA NTRS2005

Solar Probe: Report of the Science and Technology Definition Team

The Solar Probe mission of the Living With a Star program will be a historic mission, flying into one of the last unexplored regions of the solar system, the Sun's atmoshpere or corona, for the first time. Approaching as close as 3 Rs above the Sun's surface, Solar Probe will employ a combination of in-situ measurements and imaging to achieve the mission's primary scientific goal: to understand how the Sun's corona is heated and how the solar wind is accelerated. Solar Probe will revolutionize our knowledge of the physics of the origin and evolution of the solar wind. Moreover, by making the only direct, in-situ measurements of the region where some of the deadliest solar energetic particles are energized, Solar Probe will make unique and fundamental contributions to our ability to characterize and forecast the radiation environment in which future space explorers will work and live.

Source record↗
DOE OSTI2026

Cross-slip and easy-glide CRSS in titanium: Theoretical predictions and in-situ TEM measurements

This study investigates the mechanics of prismatic and first-order pyramidal $\langle$a$\rangle$ slip in titanium (Ti), elucidating the physics of easy-glide and cross-slip through a combination of theory and experiments. Screw-character prismatic (Pr) dislocations in Ti are of particular interest because their complex cores can be stable or unstable, leading to activation by either cross-slip or planar glide. To investigate these mechanisms, site-specific micro tensile samples were prepared using focused ion beam (FIB) milling and mounted on a push-to-pull (PTP) device for in-situ transmission electron microscopy (TEM) tensile testing. The in-situ experiments provide direct observations of the onset of dislocation motion and the precise determination of the critical resolved shear stress (CRSS) for the activated mechanisms, and its evolution with load cycling. A comprehensive theory has been developed to predict the CRSS values for easy glide, cross-slip, and multiplication of dislocations. Predicted critical stresses for pyramidal (π)-to-Pr and reverse cross-slip agree closely with the experimental measurements. The latter cross-slip stress is a factor of two higher than that of unobstructed planar slip. The model accounts for overlapping dislocation cores and employs a Wigner-Seitz based cell to evaluate misfit energies. By combining ab initio density functional theory (DFT) with anisotropic elasticity, the framework identifies minimum energy pathways for dislocation glide, which can be intermittent and zig-zag. A simplified expression utilizing (π) and Pr Schmid factor ratios is proposed for critical stress corresponding to (π)-to-Pr cross-slip transition. The results are strongly dependent on crystal orientation, underscoring non-Schmid behavior. Overall, this study explores key critical stress parameters essential for informing higher-scale simulations of plasticity in Ti.

Critical stress↗
NASA NTRS2003

Airborne Studies in the Arctic in Support of FIRE-III

This grant supported (i) the participation of the University of Washington's (UW) Cloud and Aerosol Research Group (CARG), with its Convair-580 research aircraft, in the FIRE-ACE field study in the Arctic; (ii) analyses of portions of the data collected; (iii) presentation of results at conferences and workshops; (iv) formal publication of results; and, (v) archiving of the data collected by the UW/CARG. The UW/CARG Convair-580 flew twenty-three research flights, totaling over 97 research hours, in the FIRE-ACE field study during the period 19 May through 24 June 1998. Six flights were beneath the NASA ER-2 aircraft, eight flights over the instrumented SHEBA ship, and eleven flights over the DOE ARM site in Barrow, Alaska. Measurements of cloud radiative properties and cloud structures were obtained in stratus, altocumulus and cirrus clouds. Aerosol measurements were obtained in polluted arctic haze, and in very clean conditions. Several new instruments were flown on the UW Convair-580, including the Gerber g-meter, the NASA/Goddard spectral full-scanning radiometer, and the SPEC cloud particle imager (CPI). A complete listing of all of the UW Convair-580 flights in FIRE-ACE is given in the report by Hobbs listed as (ii) in Section 3 below. The UW/CARG focussed its own analyses of these data on the airborne in situ measurements of clouds and aerosols. This resulted in five formal publications, covering topics ranging from the production of aerosols by clouds and aerosol effects on surface heating in the arctic, to the structures of arctic clouds and comparisons of in situ measurements of cloud structures with deductions from remote sensing measurements.

Hobbs, Peter V.↗
NASA NTRS2014

Amorphous Phases on the Surface of Mars

Both primary (volcanic/impact glasses) and secondary (opal/silica, allophane, hisingerite, npOx, S-bearing) amorphous phases appear to be major components of martian surface materials based on orbital and in-situ measurements. A key observation is that whereas regional/global scale amorphous components include altered glass and npOx, local scale amorphous phases include hydrated silica/opal. This suggests widespread alteration at low water-to-rock ratios, perhaps due to snow/ice melt with variable pH, and localized alteration at high water-to-rock ratios. Orbital and in-situ measurements of the regional/global amorphous component on Mars suggests that it is made up of at least three phases: npOx, amorphous silicate (likely altered glass), and an amorphous S-bearing phase. Fundamental questions regarding the composition and the formation of the regional/global amorphous component(s) still remain: Do the phases form locally or have they been homogenized through aeolian activity and derived from the global dust? Is the parent glass volcanic, impact, or both? Are the phases separate or intimately mixed (e.g., as in palagonite)? When did the amorphous phases form? To address the question of source (local and/or global), we need to look for variations in the different phases within the amorphous component through continued modeling of the chemical composition of the amorphous phases in samples from Gale using CheMin and APXS data. If we find variations (e.g., a lack of or enrichment in amorphous silicate in some samples), this may imply a local source for some phases. Furthermore, the chemical composition of the weathering products may give insight into the formation mechanisms of the parent glass (e.g., impact glasses contain higher Al and lower Si [30], so we might expect allophane as a weathering product of impact glass). To address the question of whether these phases are separate or intimately mixed, we need to do laboratory studies of naturally altered samples made up of mixed phases (e.g., palagonite) and synthetic single phases to determine their short-range order structures and calculate their XRD patterns to use in models of CheMin data. Finally, to address the timing of the alteration, we need to study rocks on the martian surface of different ages that may contain glass (volcanic or impact) with MSL and future rovers to better understand how glass alters on the martian surface, if that alteration mechanism is universal, and if alteration spans across long periods of time or if there is a time past which unaltered glass remains.

Rampe, E. B.↗
NASA NTRS1998

Mars Volatiles and Climate Surveyor (MVACS) Integrated Payload for the Mars Polar Lander Mission

The Mars Volatiles and Climate Surveyor (MVACS) integrated payload for the Mars Polar Lander will be launched in January 1999, with a scheduled landing on Mars' south-polar layered deposits in December 1999. Over the course of its 90-day nominal mission during the martian southern spring and summer seasons, it will make in situ measurements that will provide new insights into the behavior and distribution of martian volatiles, MVACS consists of four major instrument systems: a surface stereo imager (SSI), which will acquire multispectral stereo images of the surface and atmosphere; a 2-m robotic arm (RA), which will dig a O.5-m deep trench and acquire surface and subsurface samples that will be imaged by a focusable robotic arm camera (RAC), which will take close-up images of surface and subsurface samples at a spatial resolution of 21 micron; a meteorology package (MET), which will make the first measurements of surface pressure, temperature, and winds in Mars' southern hemisphere and employ a tunable diode laser (TDL) spectrometer to measure the water-vapor concentration and isotopic composition of CO2 in the martian atmosphere; and a thermal and evolved gas analyzer (TEGA), which will use differential scanning calorimetry and TDL-evolved gas analysis to determine the concentrations of ices, adsorbed volatiles, and volatile-bearing minerals in surface and subsurface soil samples. The unique in situ measurements made by MVACS at its high-latitude landing site will define a number of important aspects of the physical, isotopic, and chemical nature of the martian near-surface and subsurface environment that will be valuable in better understanding Mars meteorites and returned samples, as well as in the search for martian resources that could be utilized by humans.

Paige, D. A.↗
NASA NTRS2022

Soil Moisture Estimation in South Asia via Assimilation of SMAP Retrievals

A soil moisture retrieval assimilation framework is implemented across South Asia in an attempt to improve regional soil moisture estimation as well as to provide a consistent regional soil moisture dataset. This study aims to improve the spatiotemporal variability of soil moisture estimates by assimilating Soil Moisture Active Passive (SMAP) near-surface soil moisture retrievals into a land surface model. The Noah-MP (v4.0.1) land surface model is run within the NASA Land Information System software framework to model regional land surface processes. NASA Modern-Era Retrospective Analysis for Research and Applications (MERRA2) and Global Precipitation Measurement (GPM) Integrated Multi-satellitE Retrievals (IMERG) provide the meteorological boundary conditions to the land surface model. Assimilation is carried out using both cumulative distribution function (CDF)-corrected (DA-CDF) and uncorrected SMAP retrievals (DA-NoCDF). CDF matching is applied to correct the statistical moments of the SMAP soil moisture retrieval relative to the land surface model. Comparison of assimilated and model-only soil moisture estimates with publicly available in situ measurements highlights the relative improvement in soil moisture estimates by assimilating SMAP retrievals. Across the Tibetan Plateau, DA-NoCDF reduced the mean bias and RMSE by 8.4 % and 9.4 %, even though assimilation only occurred during less than 10 % of the study period due to frozen (or partially frozen) soil conditions. The best goodness-of-fit statistics were achieved for the IMERG DA-NoCDF soil moisture experiment. The general lack of publicly available in situ measurements across irrigated areas limited a domain-wide direct model validation. However, comparison with regional irrigation patterns suggested correction of biases associated with an unmodeled hydrologic phenomenon (i.e., anthropogenic influence via irrigation) as a result of SMAP soil moisture retrieval assimilation. The greatest sensitivity to assimilation was observed in cropland areas. Improvements in soil moisture potentially translate into improved spatiotemporal patterns of modeled evapotranspiration, although limited influence from soil moisture assimilation was observed on modeled processes within the carbon cycle such as gross primary production. Improvement in fine-scale modeled estimates by assimilating coarse-scale retrievals highlights the potential of this approach for soil moisture estimation over data-scarce regions.

Jawairia Ahmad↗
NASA NTRS2000

An Examination of the Inorganic Chlorine Budget in the Lower Stratosphere

We use the first simultaneous in situ measurements of ClONO2, ClO, and HCl acquired using the NASA ER-2 aircraft during the Photochemistry of Ozone Loss in the Arctic Region in Summer (POLARIS) mission to test whether these three compounds quantitatively account for total inorganic chlorine (Cly) in the lower stratosphere in 1997. We find (ClO + ClONO2 + HCl)/Cly = 0.92 +/- 0.10, where Cly is inferred from in situ measurements of organic chlorine source gases. These observations are consistent with our current understanding of the budget and partitioning of Cly in the lower stratosphere. We find no evidence in support of missing inorganic chlorine species that compose a significant fraction of Cly. We apply the analysis to earlier ER-2 observations dating from 1991 to investigate possible causes of previously observed discrepancies in the inorganic chlorine budget. Using space shuttle, satellite, balloon, and aircraft measurements in combination with ER-2 data, we find that the discrepancy is unlikely to have been caused by missing chlorine species or an error in the photolysis rate of chlorine nitrate. We also find that HCl/Cly is not significantly controlled by aerosol surface area density in the lower stratosphere.

Bonne, G. P.↗
NASA NTRS2016

On the Susceptibility of Cold Tropical Cirrus to Ice Nuclei Abundance

Numerical simulations of cirrus formation in the tropical tropopause layer (TTL) are used to evaluate the impact heterogeneous ice nuclei (IN) abundance on cold cloud microphysical properties. The model includes homogeneous and heterogeneous ice nucleation, deposition growthsublimation, and sedimentation. Reanalysis temperature and wind fields are used to force the simulations, with addition of high-frequency wave temperature variability based on in situ measurements. The model results are constrained by recent in situ observations of TTL cirrus and relative humidity, as well as satellite measurements of cirrus bulk properties and occurrence frequencies. Temperature variability driven by high-frequency waves has a dominant influence on TTL cirrus microphysical properties and occurrence frequencies, and inclusion of these waves is required to produce agreement between the simulated and observed cloud properties as well as the abundance of TTL cirrus. With a composition-independent supersaturation threshold for homogeneous freezing of aqueous aerosols, the model produces excessive ice concentrations compared with in situ observations. Inclusion of relatively numerous heterogeneous nuclei ( 100L) in the simulations improves the agreement with observed ice concentrations. However, when IN contribute significantly to TTL cirrus ice nucleation, the occurrence frequency of large supersaturations with respect to ice is less than indicated by in situ measurements. The simulated TTL cirrus extinction statistics agree with observations (within uncertainties) from both in situ and remote-sensing measurements. We find that the sensitivity of TTL cirrus extinction and ice water content statistics to heterogeneous ice nuclei abundance is relatively weak. Likewise, the simulated occurrence frequencies of TTL cirrus are insensitive to ice nuclei abundance, both in terms of cloud frequency height distribution and regional distribution throughout the tropics.

occurences↗
NASA NTRS2023

Large-Eddy Simulations of Marine Boundary Layer Clouds Associated with Cold-Air Outbreaks during the ACTIVATE Campaign. Part II: Aerosol–Meteorology–Cloud Interaction

Aerosol effects on micro/macrophysical properties of marine stratocumulus clouds over the western North Atlantic Ocean (WNAO) are investigated using in situ measurements and large-eddy simulations (LES) for two cold-air outbreak (CAO) cases (28 February and 1 March 2020) during the Aerosol Cloud Meteorology Interactions over the Western Atlantic Experiment (ACTIVATE). The LES is able to reproduce the vertical profiles of liquid water content (LWC), effective radius reff and cloud droplet number concentration Nc from fast cloud droplet probe (FCDP) in situ measurements for both cases. Furthermore, we show that aerosols affect cloud properties (N c , r eff , and LWC) via the prescribed bulk hygroscopicity of aerosols (¯k) and aerosol size distribution characteristics. N c , r eff , and liquid water path (LWP) are positively correlated to ¯κ and aerosol number concentration (N a ) while cloud fractional cover (CFC) is insensitive to ¯κ and aerosol size distributions for the two cases. The realistic changes to aerosol size distribution (number concentration, width, and the geometrical diameter) with the same meteorology state allow us to investigate aerosol effects on cloud properties without meteorological feedback. We also use the LES results to evaluate cloud properties from two reanalysis products, ERA5 and MERRA-2. Compared to LES, the ERA5 is able to capture the time evolution of LWP and total cloud coverage within the study domain during both CAO cases while MERRA-2 underestimates them.

Cloud forcing↗
DOE OSTI2023

Large-Eddy Simulations of Marine Boundary Layer Clouds Associated with Cold-Air Outbreaks during the ACTIVATE Campaign. Part II: Aerosol–Meteorology–Cloud Interaction

Aerosol effects on micro/macrophysical properties of marine stratocumulus clouds over the western North Atlantic Ocean (WNAO) are investigated using in situ measurements and large-eddy simulations (LES) for two cold-air outbreak (CAO) cases (28 February and 1 March 2020) during the Aerosol Cloud Meteorology Interactions over the Western Atlantic Experiment (ACTIVATE). The LES is able to reproduce the vertical profiles of liquid water content (LWC), effective radius r eff and cloud droplet number concentration N c from fast cloud droplet probe (FCDP) in situ measurements for both cases. Furthermore, we show that aerosols affect cloud properties (N c , r eff , and LWC) via the prescribed bulk hygroscopicity of aerosols ($\bar{κ}$) and aerosol size distribution characteristics. N c , r eff , and liquid water path (LWP) are positively correlated to $\bar{κ}$ and aerosol number concentration (N a ) while cloud fractional cover (CFC) is insensitive to $\bar{κ}$ and aerosol size distributions for the two cases. The realistic changes to aerosol size distribution (number concentration, width, and the geometrical diameter) with the same meteorology state allow us to investigate aerosol effects on cloud properties without meteorological feedback. We also use the LES results to evaluate cloud properties from two reanalysis products, ERA5 and MERRA-2. Compared to LES, the ERA5 is able to capture the time evolution of LWP and total cloud coverage within the study domain during both CAO cases while MERRA-2 underestimates them.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2021

Observation of absorbing aerosols above clouds over the South-East Atlantic Ocean from the geostationary satellite SEVIRI - Part 2: Comparison with MODIS and aircraft measurements from the CLARIFY-2017 field campaign

To evaluate the SEVIRI retrieval for aerosols above clouds presented in Part 1 of the companion paper, the algorithm is applied over the south-east Atlantic Ocean during the CLARIFY-2017 field campaign period. The first step of our analysis compares the retrieved aerosol and cloud properties against equivalent products from the MODIS MOD06ACAERO retrieval (Meyer et al., 2015). While the correlation between the two satellite retrievals of the above-cloud aerosol optical thickness (AOT) is good (R = 0.78), the AOT retrieved by SEVIRI is 20.3 % smaller than that obtained from the MODIS retrieval. This difference in AOT is attributed mainly to the more absorbing aerosol model assumed for the SEVIRI retrieval compared to MODIS. The underlying cloud optical thickness (COT) derived from the two satellites is in good agreement (R = 0.90). The cloud droplet effective radius (CER) retrieved by SEVIRI is consistently smaller than MODIS by 2.2 µm, which is mainly caused by the use of different spectral bands of the satellite instruments. In the second part of our analysis, we compare the forecast water vapour profiles used for the SEVIRI atmospheric correction as well as the aforementioned aerosol and cloud products with in situ measurements made from the Facility for Airborne Atmospheric Measurements (FAAM) aircraft platform during the CLARIFY-2017 campaign. Around Ascension Island, the column water vapour used to correct the SEVIRI signal is overestimated by 3.1 mm in the forecast compared to that measured by dropsondes. However, the evidence suggests that the accuracy of the atmospheric correction improves closer to the African coast. Consistency is observed between the SEVIRI above-cloud AOT and in situ measurements (from cavity ring-down spectroscopy instruments) when the measured single-scattering albedo is close to that assumed in the retrieval algorithm. On the other hand, the satellite retrieval overestimates the AOT when the assumed aerosol model is not absorbing enough. Consistency is also found between the cloud properties retrieved by SEVIRI and the CER measured by a cloud droplet probe and the liquid water path derived from a microwave radiometer. Despite the instrumental limitations of the geostationary satellite, the consistency obtained between SEVIRI, MODIS and the aircraft measurements demonstrates the ability of the retrieval in providing additional information on the temporal evolution of the aerosol properties above clouds.

absorbing aerosols↗
NASA NTRS2018

A New Global Anthropogenic SO2 Emission Inventory for the Last Decade: A Mosaic of Satellite-Derived and Bottom-Up Emissions

Sulfur dioxide (SO2) measurements from the Ozone Monitoring Instrument (OMI) satellite sensor have been used to detect emissions from large point sources. Emissions from over 400 sources have been quantified individually based on OMI observations, accounting for about a half of total reported anthropogenic SO2 emissions. Here we report a newly developed emission inventory, OMI-HTAP, by combining these OMI-based emission estimates and the conventional bottom-up inventory, HTAP, for smaller sources that OMI is not able to detect. OMI-HTAP includes emissions from OMI-detected sources that are not captured in previous leading bottom-up inventories, enabling more accurate emission estimates for regions with such missing sources. In addition, our approach offers the possibility of rapid updates to emissions from large point sources that can be detected by satellites. Our methodology applied to OMI-HTAP can also be used to merge improved satellite-derived estimates with other multi-year bottom-up inventories, which may further improve the accuracy of the emission trends. OMI-HTAP SO2 emissions estimates for Persian Gulf, Mexico, and Russia are 59%, 65%, and 56% larger than HTAP estimates, respectively, in year 2010. We have evaluated the OMI-HTAP inventory by performing simulations with the Goddard Earth Observing System version 5 (GEOS-5) model. The GEOS-5 simulated SO2 concentrations driven by both HTAP and OMI-HTAP were compared against in situ measurements. We focus for the validation on year 2010 for which HTAP is most valid and for which a relatively large number of in situ measurements are available. Results show that the OMI-HTAP inventory improves the agreement between the model and observations, in particular over the US, with the normalized mean bias decreasing from 0.41 (HTAP) to -0.03 (OMI-HTAP) for year 2010. Simulations with the OMI-HTAP inventory capture the worldwide major trends of large anthropogenic SO2 emissions that are observed with OMI. Correlation coefficients of the observed and modelled surface SO2 in 2014 increase from 0.16 (HTAP) to 0.59 (OMI-HTAP) and the normalized mean bias dropped from 0.29 (HTAP) to 0.05 (OMI-HTAP), when we updated 2010 HTAP emissions with 2014 OMI-HTAP emissions in the model.

Sulfur dioxide (SO2)↗
NASA NTRSDate not supplied

OPTIMIZING MEASUREMENTS OF THE NEAR-SURFACE WATER CYCLE ON MARS: INSIGHTS FOR HABITABILITY.

The Martian regolith may act as a sink and source of water vapor for the lower atmosphere through processes such as frost formation, physisorption, solid-state hydration, and brine formation [e.g., 1- 12]. These processes are all dependent on temperature and humidity, as well as regolith properties such as porosity, tortuosity, and composition. In particular, the salty nature of the Martian regolith may increase its role in atmosphere-regolith interactions as hygroscopic salts interact with the ambient water vapor. Although to date experimental works near Mars-relevant conditions have constrained some of the potential effects of a salty regolith on water vapor exchange processes [e.g., 13-18], vital in situ measurements are lacking to link these to the near-surface water cycle on Mars. This is because previous and ongoing environmental payloads for landed Mars missions were not designed to investigate atmosphere-regolith exchange processes [12, 19-20]. Resolving the Martian near-surface water cycle is relevant to both climatic processes and astrobiology. There is the potential to presently form (meta)stable brines on Mars; their stability would be largely controlled by water vapor exchange processes [9, 21]. Here we argue for optimizing in situ measurements of water vapor exchange processes and regolith properties to advance our understanding of the local scale Martian water cycle and inform habitability studies.

E G Rivera-Valentin↗
NASA NTRS2011

In-Situ XRF Measurements in Lunar Surface Exploration Using Apollo Samples as a Standard

Samples collected during the Apollo lunar surface missions were sampled and returned to Earth by astronauts with varying degrees of geological experience. The technology used in these EVAs, or extravehicular activities, included nothing more advanced than traditional terrestrial field instruments: rock hammer, scoop, claw tool, and sample bags. 40 years after Apollo, technology is being developed that will allow for a high-resolution geochemical map to be created in the field real-time. Handheld x-ray fluorescence (XRF) technology is one such technology. We use handheld XRF to enable a broad in-situ characterization of a geologic site of interest based on fairly rapid techniques that can be implemented by either an astronaut or a robotic explorer. The handheld XRF instrument we used for this study was the Innov-X Systems Delta XRF spectrometer.

Young, Kelsey E.↗
NASA NTRS2021

Development and Validation of an Empirical Ocean Color Algorithm with Uncertainties: A Case Study with the Particulate Backscattering Coefficient

We explored how algorithm (model) and in situ measurement (observation) uncertainties can effectively be incorporated into empirical ocean color model development and assessment. In this study we focused on methods for deriving the particulate backscattering coefficient at 555 nm, b(bp)(555)/(m). We developed a simple empirical algorithm for deriving b(bp)(555) as a function of a remote sensing reflectance line height (LH) metric. Model training was performed using a high-quality bio-optical dataset that contains coincident in situ measurements of the spectral remote sensing reflectances, R(rs)(λ)/(sr), and the spectral particulate backscattering coefficients, b(bp)(λ). The LH metric used is defined as the magnitude of Rrs(555) relative to a linear baseline drawn between R(rs)(490) and R(rs)(670). Using an independent validation dataset, we compared the skill of the LH-based model with two other models. We used contemporary validation metrics, including bias and mean absolute error (MAE), that were corrected for model and observation uncertainties. The results demonstrated that measurement uncertainties do indeed impact contemporary validation metrics such as mean bias and MAE. Zeta-scores and z-tests for overlapping confidence intervals were also explored as potential methods for assessing model skill.

ocean color↗
NASA NTRS2005

Diffuse Attenuation Coefficient of Downwelling Irradiance: An Evaluation of Remote Sensing Methods

The propagation of downwelling irradiance at wavelength lambda from surface to a depth (z) in the ocean is governed by the diffuse attenuation coefficient, K(sup -)(sub d)(lambda). There are two standard methods for the derivation of K(sup -)(sub d)(lambda) in remote sensing, which both are based on empirical relationships involving the blue-to-green ratio of ocean color. Recently, a semianalytical method to derive K(sup -)(sub d)(lambda) from reflectance has also been developed. In this study, using K(sup -)(sub d)(490) and K(sup -)(sub d)(443) as examples, we compare the K(sup -)(sub d)(lambda) values derived from the three methods using data collected in three different regions that cover oceanic and coastal waters, with K(sup -)(sub d)(490) ranging from approximately 0.04 to 4.0 per meter. The derived values are compared with the data calculated from in situ measurements of the vertical profiles of downwelling irradiance. The comparisons show that the two standard methods produced satisfactory estimates of K(sup -)(sub d)(lambda) in oceanic waters where attenuation is relatively low but resulted in significant errors in coastal waters. The newly developed semianalytical method appears to have no such limitation as it performed well for both oceanic and coastal waters. For all data in this study the average of absolute percentage difference between the in situ measured and the semianalytically derived K(sup -)(sub d) is approximately 14% for lambda = 490 nm and approximately 11% for lambda = 443 nm.

Lee, Zhong-Ping↗