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At least 487 records · Page 27

Ion reflection and downstream thermalization at the quasi-parallel bow shock

Using the results of ISEE 2 plasma and magnetic field measurements, two features related to the ion thermalization process at high-Mach-number (M above 2) quasi-parallel collisionless shocks are discussed. These are the presence of a coherent secondary beam of ions within the shock layer which is considered to be produced by reflection, and downstream ion distributions which contain both a relatively cold core of directly transmitted ions and a hotter 'shell' of ions, which appear to result from the disruption and scattering of ions initially reflected at the shock. Evidence is presented that coherent ion reflection is an important element of the ion energy dissipation process at high-Mach-number quasi-parallel shocks.

Gosling, J. T.↗

Interaction of minor ions with fast and slow shocks

The coronal slow shock was predicted to exist embedded in large coronal holes at 4 to 10 solar radii. A three-fluid model was used to study the jumps in minor ions propertes across the coronal slow shock. The jump conditions were formulated in the de Hoffmann-Teller frame of reference. The Rankine-Hugoniot solution determines the MHD flow and the magnetic field across the shocks. For each minor ion species, the fluid equations for the conservation of mass, momentum, and energy can be solved to determine the velocity and the temperature of the ions across the shock. A simularity solution was also obtained for heavy ions. The results show that on the downstream side of the coronal slow shock the ion temperatures are nearly proportional to the ion masses for He, O, Si, and Fe in agreement with observed ion temperatures in the inner solar wind. This indicates that the possibly existing coronal slow shock can be responsible for the observed heating of minor ions in the solar wind.

Whang, Y. C.↗

Surface modification using low energy ground state ion beams

A method of effecting modifications at the surfaces of materials using low energy ion beams of known quantum state, purity, flux, and energy is presented. The ion beam is obtained by bombarding ion-generating molecules with electrons which are also at low energy. The electrons used to bombard the ion generating molecules are separated from the ions thus obtained and the ion beam is directed at the material surface to be modified. Depending on the type of ion generating molecules used, different ions can be obtained for different types of surface modifications such as oxidation and diamond film formation. One area of application is in the manufacture of semiconductor devices from semiconductor wafers.

Chutjian, Ara↗

Unidentified ions in comets

Optical spectra were taken of comets Halley, West, and Brorsen-Metcalf in the wavelength region 3200 to 6400 A. These spectra were offset approximately 10(exp -5) to 10(exp -6) km tailward from the nucleus so that the features detected were all ions with the exception of a very small residual C2 emission at 5165 A. The full labeled tail spectrum of comet Halley is given. While most of the features detected are attributable to CO(+), H2O(+), CO2(+), CH(+), and OH(+), there are three moderately strong bands in the spectra of comets Halley and Brorsen-Metcalf which remain unidentified. These features were not detected in comet West. All three spectra in the 4800 to 5400 A region are presented, Brorsen-Metcalf is the gassiest of the three. The central wavelengths of the unidentified features are 4930, 5300, and 6000 A. In an effort to identify the ions responsible for these features as well as to confirm previous identifications, laboratory spectra of ions were compared with the comet spectra. H2O(+) and CO(+) are known to have extensive emission in the 4800 to 6200 A region. Therefore, the possibility that these unidentified features are due to H2O(+) and CO(+) was investigated. A search for the following bands was conducted: H2O(+) (11-0), H2O(+) (12-0), H2O(+) (13-1), CO(+) (1-1), and CO(+) (0-0). CO(+) (1-1) and CO(+) (0-0) were previously identified and are present in all the spectra examined. The H2O(+) (11-0) band was identified. Comparison of the H2O(+) (11-0) synthetic spectrum with comet Brorsen-Metcalf data is presented. The relative fluxes of the blended H2O(+) lines in the synthetic spectrum match those of the cometary data. After eliminating H2O(+) and CO(+) as significant contributors to the stronger unidentified features, spectra of ions which are not yet identified in the optical region of comets were compared to the data. These ions are NH(+), CS(+), and C2(+). None of these ions appears to be a significant contributor to the optical spectra of these three comets. In conclusion, H2O(+) (11-0) was unabiguously identified in cometary optical spectra. No other molecular ion for which there are laboratory spectra can explain the unidentified features found in the ion tails of comets Halley and Brorsen-Metcalf.

Engel, Lisa↗

Empirical modeling of ion composition in the middle and topside ionosphere

The paper reviews the efforts to represent the global and temporal variations of the ionospheric ion composition in the altitude range from 100 km to 1000 km. The ground and space data sets that have been collected for the ion densities over the past decades are listed. Empirical models are discussed including models for the densities and compositions of O(+), H(+), He(+), O(2+), and NO(+) ions, and for the characteristic transition heights from light ions to atomic oxygen ions and from atomic oxygen ions to molecular ions. The status of the ion composition model in the International Reference Ionosphere (IRI) is reviewed, and shortcomings are pointed out. Possible improvements of IRI with the help of recent modeling studies are summarized.

Bilitza, Dieter↗

Ion mass spectrometer measurements from the Space Shuttle

Ion-mass-spectrometer measurements made, as part of the University of Iowa's Plasma Diagnostic Package, on the STS-3 and Spacelab 2 missions, sampled a variety of positive ion composition perturbations in response to gas emissions from the vehicle. A background of contaminant ion species (mostly relating to water) always exists in the vicinity of the Shuttle. The measured number fluxes of the contaminant ions vary differently from those of the ambient ions in response to changes in the spectrometer and spacecraft angles of attack. There is a near-Shuttle wake cavity in the contaminant ion distributions which has a different spatial configuration than the wake of the ambient ions. Although water dumps produce the longest term ion perturbations, the most well defined effects were observed from measurements taken during the short firings of the reaction-control-system thrusters.

Grebowsky, J. M.↗

Heating of minor ions by the coronal slow shock

The coronal slow shock has been predicted to exist embedded in large coronal holes at 4-10 solar radii. In this paper, a three-fluid model is used to study the jumps in minor ion properties across a slow shock such as the coronal slow shock. The jump conditions are formulated in the de Hoffmann-Teller frame of reference. The Rankine-Hugoniot solution determines the MHD flow and the magnetic field across the shocks. For each minor ion species, the fluid equations for the conservation of mass, momentum, and energy can be solved to determine the velocity and the temperature of the ions across the shock. Also obtained is a similarity solution for heavy ions. The results show that, on the downstream side of the slow shock, the ion temperatures are nearly proportional to the ion masses for He, O, Si, and Fe, in agreement with observed ion temperatures in the inner solar wind. This indicates that the possibly existing coronal slow shock can be responsible for the observed heating of minor ions in the solar wind.

Whang, Y. C.↗

Heating of the polar wind due to ion beam instabilities

Recent DE 1 observations (Chen et al., 1990) in the polar cap region have detected upflowing field-aligned O(+) and H(+) beams of about 10 eV energy; it was suggested that these beams may interact with the polar wind and provide free energy to the polar wind which will alter its 'classical' description. This paper investigates both the linear and the nonlinear effects of upflowing O(+) and H(+) ion beams on an O(+) and H(+) polar wind by applying isotropic Maxwellian distributions for modeling the O(+) and H(+) polar-wind ions and using drifting Maxwellian distributions for the electrons, O(+), and H(+) beam ions. It is shown that, in the presence of O(+) and H(+) beams, the slow ion acoustic and slow ion cyclotron modes can couple to the normal modes of the plasma and be driven unstable. The O(+) ions are preferentially heated over the H(+) ions; this preferential heating couses enhanced outflow of O(+) ions along polar cap field lines by effectively increasing the O(+) scale height.

Chen, Margaret W.↗

Negative ions in the coma of Comet Halley

The detection of negatively charged cometary ions in the inner coma of Comet Halley is reported. These ions are observed in three broad mass peaks at 7-19, 22-65, and 85-110 AMU, with densities reaching greater than about 1/cu cm, about 0.05/cu cm, and about 0.04/cu cm, respectively, at a distance of about 2300 km from the nucleus. The ion species thought to be present include O(-), OH(-), C(-), CH(-), CN(-) and heavier complex CHO molecular ions. As negative ions are easily destroyed by solar radiation at about 1 AU, an efficient production mechanism, so far unidentified, is required to account for the observed densities. The detection of negative ions in the coma near 1 AU implies that negative ions should also be present in similar neutral gas and dust environment farther away from the sun. If the negative-ion densities are large enough, they could play an important part in physical processes such as radiative transfer or charge exchange.

Chaizy, P.↗

Near-term, 100-kW class ion engines

A design approach for large area, high power ion engines is presented. This approach conceptually divides a single engine into a combination of smaller discharge chambers (or segments) configured to operate as a single large area engine. This segmented ion thruster (SIT) approach is shown to enable the immediate development of 100-kW class argon ion engines for operation at a specific impulse of 10,000 s. A combination of six 30-cm diameter ion chambers operating as a single engine can process over 100 kW. Such a segmented ion engine could be built today and would operate from a single power processor unit. The segmented engine design approach may also enable the development of megawatt class ion engines. Potential benefits of the segmented ion thruster design include: mitigation of the span-to-gap problem central to the development of large area, high power ion engines; reduction in hollow cathode emission current requirements; improved fault tolerance; and reduced vacuum system pumping speed requirements for engine development testing.

Brophy, John R.↗

The use of transition heights for the representation of ion composition

Several characteristic transition heights can be found in ionospheric ion-composition profiles. These are the boundaries between the regions dominated by light ions, atomic oxygen ions, molecular ions, and cluster ions, respectively. Ion-composition modeling can benefit from the use of these transition heights. Special emphasis is given to the 'upper' transition height H sub T (light ions to atomic oxygen) and to the 'lower' transition height h sub t (atomic oxygen to molecular ions). Transition-height models deduced from rocket and satellite measurements are compared with the heights predicted by the International Reference Ionosphere. Considerable discrepancies are found between the different models as well as between the models and independent measurements.

Bilitza, Dieter↗

O(+) and He(+) restricted and extended (bi-modal) ion conic distributions

An automated procedure using standard image processing techniques has been developed that finds and characterizes energetic ion conic events in the data acquired by the Energetic Ion Composition Spectrometer on DE-1 in the altitude range 8000 to 24000 km. The algorithm discriminates between the two types of ion conic distribution, those restricted to a narrow angular range and those extended in angle. Extended (bimodal) ion conic distributions also have a significant flux of field-aligned energetic ions. Extended ion conics constitute more than one third of the ion conics found. The two types of ion conic distribution have different altitude dependences. The average properties of energetic conic distributions suggest that conic formation by localized, explosive, transverse energization is not the dominant mechanism responsible for producing energetic conic distributions above 8000 km.

Peterson, W. K.↗

Densities and abundances of hot cometary ions in the coma of P/Halley

On its flight by P/Halley, the Giotto spacecraft carried a High Energy Range Spectrometer (HERS) for measuring the properties of cometary ions picked up by the solar wind in the nearly collisionless regions of the coma. Preliminary estimates of the ion densities observed by HERS were reevaluated and extended; density profiles along the Giotto trajectory are presented for 13 values of ion mass/charge. Comparison with the physical-chemical model of the interaction of sunlight and the solar wind with the comet by other researchers reveals that, with the exception of protons and H2(+), all ion densities were at least an order of magnitude higher than predicted. The high ion densities cannot be explained on the basis of compression of the plasma, but require additional or stronger ionization mechanisms. Ratios of the densities of different ion species reveal an overabundance of carbonaceous material and an underabundance of H2(+) compared to the predictions of the Schmidt. While the densities of solar wind ions (H(+) and He(++)) changed sharply across a magnetic discontinuity located 1.35(10)(exp 5) km from the comet, this feature, which has been called both the 'cometopause' and the 'magnetic pileup boundary' was barely distinguishable in the density profiles of hot cometary ions. This result is consistent with the interpretation that the magnetic pileup boundary detected by Giotto was caused by a discontinuity in the solar wind and is not an intrinsic feature of the interaction of the solar wind with an active comet.

Neugebauer, M.↗

Negative-ion formation in the explosives RDX, PETN, and TNT using the Reversal Electron Attachment Detection (READ) technique

In the search for high sensitivity and direct atmospheric sampling of trace species, techniques have been developed such as atmospheric-sampling, glow-discharge ionization (ASGDI), corona discharge, atmospheric pressure ionization (API), electron-capture detection (ECD), and negative-ion chemical ionization (NICI) that are capable of detecting parts-per-billion to parts-per-trillion concentrations of trace species. These techniques are based on positive- or negative-ion formation via charge-transfer to the target, or electron capture under multiple-collision conditions in a Maxwellian distribution of electron energies at the source temperature. One drawback of the high-pressure, corona- or glow-discharge devices is that they are susceptible to interferences either through indistinguishable product masses, or through undesired ion-molecule reactions. The ASGDI technique is relatively immune from such interferences, since at target concentrations of less than 1 ppm the majority of negative ions arises via electron capture rather than through ion-molecule chemistry. A drawback of the conventional ECD, and possibly of the ASGDI, is that they exhibit vanishingly small densities of electrons with energies in the range 0-10 millielectron volts (meV), as can be seen from a typical Maxwellian electron energy distribution function at T = 300 K. Slowing the electrons to these subthermal (less than 10 meV) energies is crucial, since the cross section for attachment of several large classes of molecules is known to increase to values larger than 10(exp -12) sq cm at near-zero electron energies. In the limit of zero energy these cross sections are predicted to diverge as epsilon(exp -1/2), where epsilon is the electron energy. In order to provide a better 'match' between the electron energy distribution function and attachment cross section, a new concept of attachment in an electrostatic mirror was developed. In this scheme, electrons are brought to a momentary halt by reversing their direction with electrostatic fields. At this turning point the electrons have zero or near-zero energy. A beam of target molecules is introduced, and the resultant negative ions extracted. This basic idea has been recently improved to allow for better reversal geometry, higher electron currents, lower backgrounds, and increased negative-ion extraction efficiency. We present herein application of the so-called reversal electron attachment detector (READ) to the study of negative-ion formation in the explosives molecules RDX, PETN, and TNT under single-collision conditions.

Chutijian, Ara↗

Giotto data analysis: Electron plasma and heavy ion composition measurements at Comet Halley

This investigation involved the analysis of electron plasma and heavy ion composition measurements made by the COPERNIC (COmplete Positive ion, Electron, and Ram Negative Ion measurements near Comet Halley) plasma experiment during the close fly-by of Halley by the European Space Agency's Giotto spacecraft. The experiment provided measurements of the full 3-dimensional distribution of 10 eV-30 keV electrons, and mass analysis of cold cometary ions from 10-210 amu. The analysis of the COPERNIC data has yielded some remarkable results, including: The discovery of negatively charged ions in the inner coma; the discovery of far heavier (mass is greater than 50 amu) ions than predicted, dominated by complex molecular ions made up of C, H, O, and N; the discovery of an adiabatic heating effect on electrons from the compression of the solar wind plasma; the identification of several organic and sulfur bearing ions; and the discovery of a new 'mystery region' where electrons are accelerated to high energies. These discoveries were in addition to the detailed analysis of 'expected' features at Comet Halley. Although this grant has expired, analysis continues on the data at a low (unfunded) level, and it is expected that more significant results will be obtained. A bibliography of the papers resulting from this research is attached, and a copy of each paper is included.

Lin, Robert P.↗

Stormtime transport of ring current and radiation belt ions

This is an investigation of stormtime particle transport that leads to formation of the ring current. Our method is to trace the guiding-center motion of representative ions (having selected first adiabatic invariants mu) in response to model substorm-associated impulses in the convection electric field. We compare our simulation results qualitatively with existing analytically tractable idealizations of particle transport (direct convective access and radial diffusion) in order to assess the limits of validity of these approximations. For mu approximately less than 10 MeV/G (E approximately less than 10 keV at L equivalent to 3) the ion drift period on the final (ring-current) drift shell of interest (L equivalent to 3) exceeds the duration of the main phase of our model storm, and we find that the transport of ions to this drift shell is appropriately idealized as direct convective access, typically from open drift paths. Ion transport to a final closed drift path from an open (plasma-sheet) drift trajectory is possible for those portions of that drift path that lie outside the mean stormtime separatrix between closed and open drift trajectories, For mu approximately 10-25 MeV/G (110 keV approximately less than E approximately less than 280 keV at L equivalent to 3) the drift period at L equivalent to 3 is comparable to the postulated 3-hr duration of the storm, and the mode of transport is transitional between direct convective access and transport that resembles radial diffusion. (This particle population is transitional between the ring current and radiation belt). For mu approximately greater than 25 MeV/G (radiation-belt ions having E approximately greater than 280 keV at L equivalent to 3) the ion drift period is considerably shorter than the main phase of a typical storm, and ions gain access to the ring-current region essentially via radial diffusion. By computing the mean and mean-square cumulative changes in 1/L among (in this case) 12 representative ions equally spaced in drift time around the steady-state drift shell of interest (L equivalent to 3), we have estimated (from both our forward and our time-reversed simulations) the time-integrated radial-diffusion coefficients D(sup sim)(sub LL) for particles having selected values of mu approximately greater than 15 MeV/G. The results agree surprisingly well with the predictions (D(sup ql)(sub LL)) of quasilinear radial diffusion theory, despite the rather brief duration (approximately 3 hrs) of our model storm and despite the extreme variability (with frequency) of the spectral-density function that characterizes the applied electric field during our model storm. As expected, the values of D(sup sim)(sub LL) deduced (respectively) from our forward and time-reversed simulations agree even better with each other and with D(sup sim)(sub LL) when the impulse amplitudes which characterize the individual substorms of our model storm are systematically reduced.

Chen, Margaret W.↗

Physical and Tribological Characteristics of Ion-Implanted Diamond Films

Unidirectional sliding friction experiments were conducted with a natural, polished diamond pin in contact with both as-deposited and carbon-ion-implanted diamond films in ultrahigh vacuum. Diamond films were deposited on silicon, silicon carbide, and silicon nitride by microwave-plasma-assisted chemical vapor deposition. The as-deposited diamond films were impacted with carbon ions at an accelerating energy of 60 keV and a current density of 50 micron A/cm(exp 2) for approximately 6 min, resulting in a dose of 1.2 x 10(exp 17) carbon ions/cm(exp 2). The results indicate that the carbon ion implantation produced a thin surface layer of amorphous, nondiamond carbon. The nondiamond carbon greatly decreased both friction and wear of the diamond films. The coefficients of friction for the carbon-ion-implanted, fine-grain diamond films were less than 0.1, factors of 20 to 30 lower than those for the as-deposited, fine-grain diamond films. The coefficients of friction for the carbon-ion-implanted, coarse-grain diamond films were approximately 0.35, a factor of five lower than those for the as-deposited, coarse-grain diamond films. The wear rates for the carbon-ion-implanted, diamond films were on the order of 10(exp -6) mm(exp 3)/Nm, factors of 30 to 80 lower than that for the as-deposited diamond films, regardless of grain size. The friction of the carbon-ion-implanted diamond films was greatly reduced because the amorphous, nondiamond carbon, which had a low shear strength, was restricted to the surface layers (less than 0.1 micron thick) and because the underlying diamond materials retained their high hardness. In conclusion, the carbon-ion-implanted, fine-grain diamond films can be used effectively as wear resistant, self-lubricating coatings for ceramics, such as silicon nitride and silicon carbide, in ultrahigh vacuum.

Miyoshi, K.↗

Energization and transport of ions of ionospheric origin in the terrestrial magnetosphere

The work of this grant has been predominantly focused on ion outflows from two data sets: Prognoz 7 and Dynamics Explorer. The Prognoz analysis studied ion densities, temperatures, and flow velocities in the magnetotail. The work performed under this contract consisted of developing a program to load the raw data, computing the background subtraction of a strong sun pulse, and using the net count to calculate the low order moments of the distribution function. The study confirms the results of ISEE with regard to the supply of plasma from the cusp as a major source of plasmasheet plasma and goes beyond this to discuss the use of ion velocities as a way to examine the motions of the magnetotail. The abstract of the work to be reported is included as an appendix. The work on the DE/Retarding Ion Mass Spectrometer is separated into two categories: (1) classification of low-energy ion flows from high-latitudes, and (2) studies of the polar wind. Major publications resulting from this work are also included as an appendix to this report. The polar wind is in a category by itself as a result of the thermal escape of hydrogen and helium because of ambipolar diffusion through the heavier, oxygen-dominated topside ionosphere. The analysis of the polar wind reports the flux variability as a function of season, magnetic activity, etc. Much effort has been expended under this grant to complete a follow on study of the thermal structure of the polar wind. Extensive display tools and analysis software have been developed and used in an attempt to carry out this thermal analysis. The present work uses a constrained fit scheme that combines the ion densities and flow velocities derived from Chandler et al. and a spacecraft potential derived from an empirical relation to the total ion density to determine the remaining fit parameter, the ion temperature, via a least squares fit to the RIMS data.

Waite, J. Hunter JR.↗