Communications of the lunar and planetary laboratory, volume 7, part 4
Solar infrared spectra from solar photometer designed for CV-990 aircraft
Source record↗
SEARCH · Engineering Papers
Results for “INFRARED SPECTRA”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Reactions of technetium hexafluoride with nitric acid, nitrosyl fluoride, and nitryl fluoride
Stoichiometry of technetium hexafluoride reactions is studied. Magnetic properties and infrared spectra of reaction products are studied and compared with those of analogous complexes of the hexafluorides of tungsten, rhenium, and osmium.
Holloway, J. H.↗
A general survey of classical cepheid variable stars
Classical Cepheid variables and their spectra, infrared astronomy, and interstellar matter
Wilson, R. M.↗
Infrared and Raman spectroscopic studies of structural variations in minerals from Apollo 11, 12, 14 and 15 samples, volume 3
Infrared and Raman vibrational spectroscopic data, yielding direct information on molecular structure, were obtained for single grains ( 150 microns) of minerals, basalts, and glasses isolated from Apollo 11, 12, 14, and 15 rock and dust samples, and for grains in Apollo 14 polished butt samples. From the vibrational data, specification substitutions were determined for the predominant silicate minerals of plagioclase, pyroxene, and olivine. Unique spectral variations for grains of K-feldspar, orthopyroxene, pyroxenoid, and ilmenite were observed to exceed the ranges of terrestrial samples, and these variations may be correlatable with formation histories. Alpha-quartz was isolated as pure single grains, in granitic grains composited with sanidine, and in unique grains that were intimately mixed with varying amounts of glass. Accessory minerals of chromite and ulvospinel were isolated as pure grains and structurally characterized from their distinctive infrared spectra. Fundamental vibrations of the SiO4 tetrahedra in silicate minerals were used to classify bulk compositions in dust sieved fractions, basalt grains and glass particles, and to compare modal characteristics for maria, highland and rille samples. No hydrated minerals were found in any of the samples studied, indicating anhydrous formation conditions.
Estep, P. A.↗
Paschen beta emission in the spectrum of Omicron Ceti.
Evaluation of three infrared spectra of Omicron Ceti obtained on Aug. 7 to 11, 1969. The equivalent width of the Paschen beta emission line in these spectra was found to vary by a factor of 2 during this time period. The variation was similar to that for H gamma and H delta as measured by Odell et al. (1970) for the same time span. The equivalent widths of Paschen beta and H gamma on August 7 were used to estimate an opacity ratio of kappa (1.28 micron)/kappa (0.43 micron) about equal to 1:30 and a molecular/atomic hydrogen ratio of about 10. The variation in the strength of Paschen beta and H delta lines is considered to be intrinsic and to have a time scale of less than or about equal to 100,000 sec.
Kovar, R. P.↗
Development of a theory of the spectral reflectance of minerals, part 4
A theory of the spectral reflectance or emittance of particulate minerals was developed. The theory is expected to prove invaluable in the interpretation of the remote infrared spectra of planetary surfaces.
Aronson, J. R.↗
Chemical analysis of outgassing contaminants on spacecraft surfaces
Methods for analyzing and characterizing outgassing contaminants from such materials as RTV 501 potting compound and S 13 G paint are presented. Fractional distillation of a gross distillate from RTV 501 rubber was carried out and the distilled fractions examined as to their ultraviolet and infrared spectra by gas liquid chromatography. A sensitive technique for structural analysis and molecular identification was found to consist of a gas chromatography-mass spectroscopy system, which was determined to be economically unfeasible at present.
Mcnutt, R. C.↗
Water vapor in the atmosphere of Venus.
Infrared spectra of Venus produced by a Fourier spectrometer flown aboard the NASA CV 990 jet aircraft were analyzed for water-vapor content by comparison with calculated model spectra. The reflecting layer model gave an abundance of 1.6 plus or minus 0.4 micron of precipitable water for the two-way transmission of the Venus atmosphere. The scattering model resulted in a value of 0.25 plus or minus 0.10 micron of water per scattering mean free path. Neither is regarded as a definitive model, but derived mixing ratios will not be significantly in error. An abundance of CO2 using a number of bands, was determined for both models. The volume mixing ratios of H2O to CO2 obtained were 0.0000006 and 0.000001 for the reflecting layer and scattering model, respectively.
Fink, U.↗
Infrared observations of southern RV Tauri stars.
Photometric measurements from 2.2 to 18 microns are reported for six southern RV Tauri stars. Four of the six have anomalous infrared excess radiation similar to that observed in other RV Tauri stars. The infrared spectra of IW Car, AR Pup, and SX Cen resemble that of oxygen-rich RV Tau. RU Cen is similar to AC Her.
Gehrz, R. D.↗
Visible and near-infra-red transmission and reflectance measurements of the Luna 20 soil.
Visible and near-infrared spectra of chemically analyzed grains of glass and minerals from the Luna 20 sample were compared with diffuse reflectance spectra of the bulk soil. As in the spectra of soil samples from other localities on the moon, pyroxene contributes two broad absorption features near 1 and 2 microns. The soil has a high integral reflectance (or albedo) arising from plagioclase, which appears to be the dominant mineral in the lunar highlands. The Luna 20 soil curve is most similar to the reflectance curves of the non-rayed soils at Apollo 16, in agreement with the generally similar mineralogy of these samples. The average pyroxene composition in the Luna 20 soil, as determined from the absorption bands in the diffuse reflectance spectra, and analyses of single crystals, is more calcic than in the lithic fragments. Thus, the soil appears to have a few per cent of admixed material derived from mare basalts. Comparison of the soil spectrum with telescopic curves of nearby areas reveals a close similarity.
Adams, J. B.↗
Dust particles and molecules in the extended atmospheres of carbon stars
It is shown that the absorption due to a circumstellar shell containing solid silicon carbide particles can very nicely explain the observed strong violet opacity in stars in which the carbon to oxygen ratio is greater than 1. It has been shown by Friedemann and Gilman that solid SiC particles can form in the cooler outer layers of such stars. Thermal re-emission from SiC particles is predicted to be in the 10-13 micron region, and recent infrared observations by Hackwell show an emission band in this region, thereby strongly supporting the SiC suggestion. It is also shown that the opacity due to C3 pseudocontinuum is not adequate to explain the observed violet opacity. It is suggested that the vibrational bands of C3 and SiC2 molecules should be among the major opacity sources in the infrared spectra of the late N-type carbon stars and some of the observed bands may be, at least in part, due to these molecules.
Gilra, D. P.↗
A new upper limit for an atmosphere of CO2, CO on Mercury
High-resolution infrared spectra of Mercury (1.9-2.7 microns, resolution limit 0.134 wavelength/cm) obtained with the original 'Connes' interferometer at the Steward Observatory 90-inch telescope have provided a very sensitive test for the possible presence of a CO2, CO atmosphere. An improved upper limit of 0.12 cm-atm has been set for CO2, and a new upper limit of 0.05 cm-atm has been set for CO. Upper limits of similar magnitude can be established for CH4 and NH3. From the separation of the Mercury signal into reflected sunlight and thermal emission, we determine that the reflectivity decreases toward longer wavelengths and has a value of about 0.06 at 2.25 microns. Implications for the possible evolution of an atmosphere on Mercury are discussed.
Fink, U.↗
The hard start phenomena in hypergolic engines. Volume 3: Physical and combustion characteristics of engine residuals
An investigation was conducted to determine the cause of starting problems in the hypergolic rocket engines of the Apollo reaction control (RCS) engines. The scope of the investigation was as follows: (1) to establish that chemical reactions occurred during the preignition and post combustion periods, (2) to identify the chemical species of the products of preignition and post combustion reaction, and (3) to determine the explosive nature of the identified species. The methods used in identifying the chemical products are described species. The infrared spectra, X-ray spectra, and other signatures of the compounds are presented. The physical and explosion characteristics of various hypergolic agents are reported.
Miron, Y.↗
A practical multi-spectrum Hadamard Transform Spectrometer
A Hadamard Transform Spectrometer (HTS) which simultaneously obtains fifteen infrared spectra, each having 255 spectral elements was constructed. Spectra are obtained essentially in real time through use of a minicomputer with 8K words of memory and a CRT display. This permits operation of the instrument in the field.
Tai, M. H.↗
Techniques for carrying out radiative transfer calculations for the Martian atmospheric dust
A description is given of the modification of a theory on the reflectance of particulate media so as to apply it to analysis of the infrared spectra obtained by the IRIS instrument on Mariner 9. With the aid of this theory and the optical constants of muscovite mica, quartz, andesite, anorthosite, diopside pyroxenite, and dunite, modeling calculations were made to refine previous estimates of the mineralogical composition of the Martian dust particles. These calculations suggest that a feldspar rich mixture is a very likely composition for the dust particles. The optical constants used for anorthosite and diopside pyroxenite were derived during this program from reflectance measurements. Those for the mica were derived from literature reflectance data. Finally, a computer program was written to invert the measured radiance data so as to obtain the absorption coefficient spectrum which should then be independent of the temperature profile and gaseous component effects.
Aronson, J. R.↗
The spectral energy distribution of NGC 1275
An analysis of absolute spectral energy distributions of interstellar gas for a galaxy (NGC 1275) is presented. Infrared spectra data shows heavy reddening. It is proposed that the interstellar gas may be ionized by shock waves or by nonthermal or stellar radiation. It is suggested, that high velocity, emission-line knots are H2 regions in a Perseus cluster galaxy or intergalactic gas cloud seen in projection against NGC 1275.
Shields, G. A.↗
The spectrum of Mars in the region 1800-3200 per cm
During the 1971 opposition of Mars, new infrared spectra covering the region 1800-3200 per cm were taken at a resolution of 0.095 per cm using a Connes'-type Fourier spectrometer on a 2.7 m telescope. No new trace constituents have, as yet, been found in the spectra, but several previously unobserved combination of isotopic bands of CO2 are visible. It has also been found possible to fit fairly well defined kinetic temperatures and Bond albedos to the data. The kinetic temperatures have been determined by a new technique. It is found that the albedo at 33 deg phase, which was determined a few days after the onset of the great dust storm of 1971, was significantly higher than for the clear atmosphere. The explanation for this phenomenon must await detailed radiative transfer calculations for a dust-laden atmosphere.
Beer, R.↗
Surfaces and interfaces of glass and ceramics; Proceedings of the International Symposium on Special Topics in Ceramics, Alfred University, Alfred, N.Y., August 27-29, 1973
The characterization of surfaces and interfaces is considered along with the infrared spectra of several N-containing compounds absorbed on montmorillonites, applications of surface characterization techniques to glasses, the observation of electronic spectra in glass and ceramic surfaces, a method for determining the preferred orientation of crystallites normal to a surface, and the friction and wear behavior of glasses and ceramics. Attention is given to the wear behavior of cast surface composites, an experimental investigation of the dynamic and thermal characteristics of the ceramic stock removal process, a dynamic elastic model of ceramic stock removal, and the structure and properties of solid surfaces. Individual items are announced in this issue.
Frechette, V. D.↗