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At least 487 records · Page 27
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NASA NTRS2019

Constraints on Martian Ancient Magmatic Processes Using Mineral Chemistry of Sedimentary Rocks in Gale Crater, Mars

If Mars has been assumed to be mostly basaltic for a long time, a series of recent discoveries have challenged this simplistic view. Orbital data indicated feldspar-rich rocks in Noachian terrains, likely supporting ancient evolved magmatism. The first indurated regolithic martian meteorite breccia NWA 7034, dated at 4.43 Gyr, contain several leucocratic felsic clasts identified as monzonitic and trachyandesitic, containing feldspars including K-spars and Na-rich plagioclases, pyroxenes, ilmenites and apatites. These clasts have been interpreted as the result of crystallization of a large impact pond. The Mars Science Laboratory rover (Curiosity), travelling within sedimentary bedrock on the floor of the Gale impact crater, discovered feldspar cumulates and a trachyandesite suggesting fractional crystallization of a basaltic melt. In addition, in the Bradbury group of fluvio-deltaic rocks (observed during the 1st 750 sols), sedimentary rocks are mostly comprised of secondary phases and detrital igneous minerals like feldspar, and pyroxene that are thought to come from Noachian-aged magmatic sources, although no definite origin and igneous processes have been inferred.

Payr, V.↗
NASA NTRSDate not supplied

Quantitative 3D Textural and Petrofabric Analysis of the Northwest Africa 10645 Nakhlite Using X-Ray Computed Tomography

Martian meteorites are currently the only samples available from Mars to study and are critical for elucidating variability in martian igneous processes over time [e.g., 1]. Quantifying igneous textures and fabrics can help us understand how rocks are formed and emplaced [e.g., 2]. These features are innately three dimensional (3D) and are often strongly heterogeneous in cumulate rocks, like the nakhlites and poikilitic shergottites [2–3], where there can be substantial textural variations between and within individual samples. However, most quantitative textural and fabric analyses on these samples have been limited to two dimensions through measurements made on polished petrographic thin sections. Thus, 3D petrographic measurements are imperative for both representative sample characterization and accurately interpreting magmatic processes. The emplacement of martian meteorites at or near the surface of Mars (i.e., extrusive or intrusive, respectively) remains enigmatic due to the innate lack of geologic context [e.g., 1], but conducting 3D quantitative textural and fabric analyses can help elucidate emplacement mechanisms and settings on Mars.

S. Ramsey↗
NASA NTRS1993

Polytopic vector analysis in igneous petrology: Application to lunar petrogenesis

Lunar samples represent a heterogeneous assemblage of rocks with complex inter-relationships that are difficult to decipher using standard petrogenetic approaches. These inter-relationships reflect several distinct petrogenetic trends as well as thermomechanical mixing of distinct components. Additional complications arise from the unequal quality of chemical analyses and from the fact that many samples (e.g., breccia clasts) are too small to be representative of the system from which they derived. Polytopic vector analysis (PVA) is a multi-variate procedure used as a tool for exploratory data analysis. PVA allows the analyst to classify samples and clarifies relationships among heterogenous samples with complex petrogenetic histories. It differs from orthogonal factor analysis in that it uses non-orthogonal multivariate sample vectors to extract sample endmember compositions. The output from a Q-mode (sample based) factor analysis is the initial step in PVA. The Q-mode analysis, using criteria established by Miesch and Klovan and Miesch, is used to determine the number of endmembers in the data system. The second step involves determination of endmembers and mixing proportions with all output expressed in the same geochemical variable as the input. The composition of endmembers is derived by analysis of the variability of the data set. Endmembers need not be present in the data set, nor is it necessary for their composition to be known a priori. A set of any endmembers defines a 'polytope' or classification figure (triangle for a three component system, tetrahedron for a four component system, a 'five-tope' in four dimensions for five component system, et cetera).

Shervais, John W.↗
NASA NTRS1979

The distribution of zirconium and hafnium in terrestrial rocks, meteorites and the moon

It is shown that Zr and Hf are not always fractionated in terrestrial igneous differentiation or regional metamorphism. Data do support a Zr-Hf fractionation in the differentiation of the alkali olivine magma at St. Helena Island. A strong Zr-Hf fractionation exists among lunar rocks and minerals. Ilmenite is an excellent concentrator of Zr and Hf and always exhibits high Zr/Hf ratios. Chondritic meteorites exhibit rather uniform Zr abundances and Zr/Hf ratios but a distinct Zr-Hf fractionation is observed among the eucrite and diogenite achondrites.

Ehmann, W. D.↗
NASA NTRS2020

Mineralogy and Geochemistry of Sedimentary Rocks and Eolian Sediments in Gale Crater, Mars: A Review After Six Earth Years of Exploration with Curiosity

The Mars Science Laboratory Curiosity rover arrived at Mars in August 2012 with a primary goal of characterizing the habitability of ancient and modern environments. Curiosity was sent to Gale crater to study a sequence of ∼3.5 Ga old sedimentary rocks that, based on orbital visible and near- to short-wave infrared reflectance spectra, contain secondary minerals that suggest deposition and/or alteration in liquid water. The sedimentary sequence in the lower slopes of Mount Sharp in Gale crater preserves a dramatic shift on early Mars from a relatively warm and wet climate to a cold and dry climate, based on a transition from smectite-bearing strata to sulfate-bearing strata. The rover is equipped with instruments to examine the sedimentology and identify compositional changes in the stratigraphy. The Chemistry and Mineralogy (CheMin) instrument is one of two internal laboratories on Curiosity and includes a transmission X-ray diffractometer (XRD) and X-ray fluorescence (XRF) spectrometer. CheMin measures loose sediment samples scooped from the surface and drilled rock powders, and the XRD provides quantitative mineralogy to a detection limit of ∼1 wt.% for crystalline phases. Curiosity has traversed>20 km since landing and has primarily been exploring an ancient lake environment fed by streams and groundwater. Of the 19 drilled rock samples analyzed by CheMin as of sol 2300 (January 2019), 15 are from fluvio-lacustrine deposits that comprise the Bradbury and Murray formations. Most of these samples were drilled from units that did not have a clear mineralogical signature from orbit. Results from CheMin demonstrate an astounding diversity in the mineralogy of these rocks that signifies geochemical variations in source rocks, transportation mechanisms, and depositional and diagenetic fluids. Most detrital igneous minerals are basaltic, but the discovery in a few samples of abundant silicate minerals that usually crystallize from evolved magmas on Earth remains enigmatic. Trioctahedral smectite and magnetite at the base of the section may have formed from low-salinity pore waters with a circumneutral pH in lake sediments. A transition to dioctahedral smectite, hematite, and Ca-sulfate going up section suggests a change to more saline and oxidative aqueous conditions in the lake waters themselves and/or in diagenetic fluids. Perhaps one of the biggest mysteries revealed by CheMin is the high abundance of X-ray amorphous materials (15–73 wt.%) in all samples drilled or scooped to date. CheMin has analyzed three modern eolian sands, which have helped constrain sediment transport and mineral segregation across the active Bagnold Dune Field. Ancient eolian sandstones drilled from the Stimson formation differ from modern eolian sands in that they contain abundant magnetite but no olivine, suggesting that diagenetic processes led to the alteration of olivine to release Fe(II) and precipitate magnetite. Fracture-associated halos in the Stimson and the Murray formations are evidence for complex aqueous processes long after the streams and lakes vanished from Gale crater. The sedimentology and composition of the rocks analyzed by Curiosity demonstrate that habitable environments persisted intermittently on the surface or in the subsurface of Gale crater for perhaps more than a billion years.

E.B. Rampe↗
NASA NTRS2012

Multiple Smaller Missions as a Direct Pathway to Mars Sample Return

Recent discoveries by the Mars Exploration Rovers, Mars Express, Mars Odyssey, and Mars Reconnaissance Orbiter spacecraft include multiple, tantalizing astrobiological targets representing both past and present environments on Mars. The most desirable path to Mars Sample Return (MSR) would be to collect and return samples from that site which provides the clearest examples of the variety of rock types considered a high priority for sample return (pristine igneous, sedimentary, and hydrothermal). Here we propose an MSR architecture in which the next steps (potentially launched in 2018) would entail a series of smaller missions, including caching, to multiple landing sites to verify the presence of high priority sample return targets through in situ analyses. This alternative architecture to one flagship-class sample caching mission to a single site would preserve a direct path to MSR as stipulated by the Planetary Decadal Survey, while permitting investigation of diverse deposit types and providing comparison of the site of returned samples to other aqueous environments on early Mars

Niles, P. B.↗
NASA NTRSDate not supplied

The Scientific Significance of Potential Samples From the Jezero Crater Rim

The Mars 2020 Perseverance rover has been exploring Jezero crater, Mars to characterize the geology,assess the potential for rocks to represent ancient habitable environments and/or preserve biosignatures, and collect a suite of scientifically compelling samples for return to Earth (Farleyet al.,2020).Thus far, Perseverance has collected samples that represent the diversity of igneous materials encountered on the crater floor and a suite of aqueously deposited sedimentary rocks from the fanand margin units(Simon et al., 2023; Bosak et al., 2024). When the rover ascendsthe crater rimit will encounter rocktypesthat are not included in the current sample cache. These include rocks fromthe Noachian whose mineralogical, geochemical, and geochronological recordswould greatly expand our understanding of early Mars. Some of the exposures are understood to come from subsurface aquifers that may represent the most ancient potentially habitablesubsurfaceenvironmentson Mars(Ehlmann et al., 2024). Samples ofthese rocks will add uniquescientific value tothe sample cache and to the Mars sample returnprogramby addressing outstanding questions in Mars science including potential habitability and how the climate and the interior of the planet evolved through time.

Mars 2020↗
NASA NTRS1988

Significance of elevated K/Rb ratios in lower crustal rocks

The granulite uncertainty principle, which states that it is difficult or impossible to determine with certainty the maximum geopressure and geotemperature that a granulite has experienced, is addressed. Also, geochemical fingerprinting cannot always be used reliably in the nebulous region that is transitional between metamorphic and igneous environments. Ion exchange thermometers are typically useful to approximately 800 C in slowly cooled plutonic rocks unless one uses a reintegration technique on unmixed minerals, or unless a metastable mineral assemblage can be observed. It is argued that in most granulites, fossil temperatures are typically obliterated by reequilibration and/or deformation during slow cooling. Granulite metamorphism may be further complicated by the common association with igneous activity. The previously-used geochemical indicators such as high K/Rb ratios and LIL depletion may not be strictly the result of granulite facies metamorphic depletion, but also may result from igneous processes, which depend on bulk and mineral compositions and on the mineralogy of the protolith. Detailed geologic mapping will be the ultimate arbitrator of whether a given geochemical signature is the result of igneous or metamorphic processes.

Frost, B. Ronald↗
NASA NTRS1979

Mesosiderites and howardites - Igneous formation and possible genetic relationships

Neutron activation data are presented for major, minor, and trace elements in whole rock howardites and silicates from mesosiderites. Compositions of howardites and mesosiderites are similar and intermediate between those of eucrites and diogenites. It is indicated that mesosiderites have a higher normative silica component than howardites. It appears that this results partly from a higher content of a highly evolved igneous component and partly from in situ reduction of FeO to Fe followed by magnetic separation of metal prior to analysis. It is shown that light rare earth elements are enriched in some mesosiderites.

Mittlefehldt, D. W.↗
NASA NTRS1980

Lunar and Planetary Science Conference, 11th, Houston, TX, March 17-21, 1980, Proceedings. Volume 1 - Igneous processes and remote sensing

Topics discussed include basaltic studies, planetary differentiation (e.g., lunar highland rocks), and remote sensing studies of chemical composition, mineralogic composition, and physical surface properties. Particular attention is given to the petrology and chemistry of basaltic fragments from the Apollo 11 soil; a model of early lunar differentiation; rocks of the early lunar crust; refractory and moderately volatile element abundances in the earth, moon, and meteorites; the effects of overlapping optical absorption bands of pyroxene and glass on the reflectance spectra of lunar soils; and the characterization of Martian surface materials from earth-based radar.

Merrill, R. B.↗
NASA NTRS1984

Is phosphorus predictably incompatible in igneous processes?

Siderophile element abundances are central to recent models for core formation in the Earth and Moon and the origin of the Moon. It is important to identify siderophile elements whose behavior in igneous processes is predictable, so that primary mantle abundances can be deduced by subtracting out the effects of igneous processes. Newsom's model for core formation in the Moon requires subchondritic P, and suggests that P was depleted due to volatility. Experiments were conducted to determine P olivine/liquid distribution coefficients. Preliminary results indicate that P can be compatible with olivine during rapid cooling, but is not during isothermal crystallization with long growth times, and tends to be expelled during annealing. It is therefore not likely that P is compatible under any widespread igneous conditions, and the incompatible behavior of P in lunar crustal rocks can be safety assumed. In addition, low fO2 is insufficient to cause P compatibility, so it is unlikely that P-rich silicates formed during the early evolution of the Earth or Moon. These results indicate that P is depleted in the Moon.

Goodrich, C. A.↗
NASA NTRS2011

In Situ Visible to Short Wavelength Imaging Spectroscopy with the Ultra Compact Imaging Spectrometer (UCIS): Case Studies from the Mars Exploration Rovers

In Situ imaging spectroscopy provides a way to address complex questions of geological evolution for both aqueous and igneous processes by mapping mineral composition at the spatial scale of rocks and outcrops. Examination of locations studied by the Mars Exploration Rovers Spirit and Opportunity can provide examples of the potential utility and define the needed measurement requirements. A compact instrument is needed to be able to adequately address these science questions from a rover platform. The Ultra Compact Imaging Spectrometer (UCIS) is an instrument designed to address the science need and implementation constraints.

mineralogy sampling↗
NASA NTRS1998

The History of Allan Hills 84001 Revised: Multiple Shock Events

The geologic history of Martian meteorite Allan Hills (ALH) 84001 is more complex than previously recognized, with evidence for four or five crater-forming impacts onto Mars. This history of repeated deformation and shock metamorphism appears to weaken some arguments that have been offered for and against the hypothesis of ancient Martian life in ALH 84001. Allan Hills 84001 formed originally from basaltic magma. Its first impact event (I1) is inferred from the deformation (D1) that produced the granular-textured bands ("crush zones") that transect the original igneous fabric. Deformation D1 is characterized by intense shear and may represent excavation or rebound flow of rock beneath a large impact crater. An intense thermal metamorphism followed D1 and may be related to it. The next impact (I2) produced fractures, (Fr2) in which carbonate "pancakes" were deposited and produced feldspathic glass from some of the igneous feldspars and silica. After I2, carbonate pancakes and globules were deposited in Fr2 fractures and replaced feldspathic glass and possibly crystalline silicates. Next, feldspars, feldspathic glass, and possibly some carbonates were mobilized and melted in the third impact (I3). Microfaulting, intense fracturing, and shear are also associated with 13. In the fourth impact (I4), the rock was fractured and deformed without significant heating, which permitted remnant magnetization directions to vary across fracture surfaces. Finally, ALH 84001 was ejected from Mars in event I5, which could be identical to I4. This history of multiple impacts is consistent with the photogeology of the Martian highlands and may help resolve some apparent contradictions among recent results on ALH 84001. For example, the submicron rounded magnetite grains in the carbonate globules could be contemporaneous with carbonate deposition, whereas the elongate magnetite grains, epitaxial on carbonates, could be ascribed to vapor-phase deposition during I3.

Treiman, Allan H.↗
DOE OSTI2021

Trace element geochemistry of coarse-grained angrites from Northwest Africa: Implications for their petrogenesis on the angrite parent body

The angrites are a class of achondrites that encompass a wide range of igneous textures from quenched, volcanic, and subvolcanic stones to slowly cooled, plutonic rocks. The compositions of the various geochemical reservoirs generating this variety of rocks have not been investigated fully because historically the numbers and masses of angrites available for study have been quite small. However, the rapid increase in meteorites from Northwest Africa (NWA) has enabled a renewed opportunity for such an investigation. In particular, three samples, NWA 2999, 4590, and 4801, have provided a new window into our understanding of the origin and petrogenesis of the coarse-grained (plutonic) angrites. We report here the trace element abundances in individual mineral grains of pyroxene, plagioclase, olivine/kirschsteinite, and phosphate and in the whole-rock samples. We utilize these data to constrain the petrogenetic history of each of these samples on the angrite parent body (e.g., parental melt compositions and oxygen fugacity conditions) and assess genetic relationships to previously investigated angrites. The trace element abundances in each of the three coarse-grained angrites studied here indicate a unique history for each. The observed trace element abundances and patterns in NWA 2999 show similarities with previously studied fine-grained, volcanic angrites and potentially indicate a common geochemical source reservoir, even though NWA 2999 is temporally distinct from the volcanic angrites. In contrast, NWA 4590 has trace element characteristics analogous to other coarse-grained angrites (e.g., Lewis Cliff [LEW] 86010), suggesting that these samples originated from geochemically similar source reservoirs. The third angrite, NWA 4801, exhibits geochemical characteristics most similar to the plutonic, coarse-grained angrites, but also appears to have some affinities in its trace element characteristics to the volcanic, fine-grained angrites. This suggests that NWA 4801 may represent a petrogenetic link between two distinct geochemical reservoirs on the angrite parent body. In aggregate, the trace element distributions in these three plutonic angrites suggest that while they may have originated up to several million years after the fine-grained angrites, they sampled a range of source reservoirs on the angrite parent body. Here, some of these source reservoirs were likely similar to those of the fine-grained angrites, but others had distinct geochemical characteristics.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1979

Allan Hills 77005 - A new meteorite type found in Antarctica

A unique 482.5 g meteorite found in Antarctica appears to be related by igneous differentiation to shergottite achondrites, which have close similarities with terrestrial basaltic rocks. Zoned maskelynite with similar compositional ranges and plagioclase of such intermediate compositions as are unknown in other achondrites occur in both shergottites and the Allan Hills meteorite. The degree of silica saturation, however, strongly distinguishes the two meteorite types. It is suggested that the Allan Hills meteorite may represent a cumulate rock formed earlier than the shergottites from the same or a similar parent magma.

Mcsween, H. Y., Jr.↗
NASA NTRS1991

Megaregolith insulation and the duration of cooling to isotopic closure within differential asteroids and the moon

Global cooling of the moon and large (R = 40-250 km) asterodis, was modeled, starting at or near the solidus. A crucial factor in determining the prevailing interval (Ic) of cooling between igenous crystallization and isotopic closure, for any given depth in the crust, is the extent to which the body is insulated by a regolith/megaregolith layer of porous, fragmental impact debris. Given plausible assumptions regarding the thicknesses of such layers on the moon and the eucrite parent asteroid (and regarding the radius of the eucrite asteroid), the results indicate that deep-crustal regions tend to remain above the Nd and Sr isotopic closure temperature for intervals that are long in comparison to the precision of modern Nd- and Sr-based age measurements, and in comparison to suggested chronologic scenarios of global differentiation. Ic intervals of as long as 100 my may be common among available samples of primordial, deep-crustal cumulates from both bodies. Chronologies for the gross solidification of the moon and the eucrite asteroid should allow for the possibility that any single age for a coarse-grained 'plutonic' or cumulate-textured rock might be many tens of millions of years younger than the igneous crystallization age.

Warren, Paul H.↗
NASA NTRS1972

Elastic properties of Apollo 14 and 15 rocks.

Ultrasonic P- and S-wave velocities of lunar samples 14310,72 and 15418,43 and P-wave velocities of sample 15015,18 were measured at room temperature to 5 kb confining pressure. The velocities of both igneous and breccia samples increased sharply over this pressure range. At low confining pressures, the shape of velocity-pressure curves of rocks is determined by the distribution function of crack aspect ratios. We suggest that analogue studies on terrestrial rocks having a wide assortment of crack parameters may be used to infer the nature of cracks in lunar rocks.

Todd, T.↗
NASA NTRS2005

Mineral Composition and Abundance of the Rocks and Soils at Gusev and Meridiani from the Mars Exploration Rover Mini-TES Instruments

The Miniature Thermal Emission Spectrometer (Mini-TES) has provided remote measurements of mineralogy, thermophysical properties, and atmospheric temperature profile and composition of the outcrops, rocks, spherules, and soils surrounding the Spirit and Opportunity Rovers. The mineralogy of volcanic rocks provides insights into the composition of the source regions and the nature of martian igneous processes. Carbonates, sulfates, evaporites, and oxides provide information on the role of water in the surface evolution. Oxides, such as crystalline hematite, provide insight into aqueous weathering processes, as would the occurrence of clay minerals and other weathering products. Diurnal temperature measurements can be used to determine particle size and search for the effects of sub-surface layering, which in turn provide clues to the origin of surficial materials through rock disintegration, aeolian transport, atmospheric fallout, or induration. In addition to studying the surface properties, Mini-TES spectra have also been used to determine the temperature profile in the lower boundary layer, providing evidence for convective activity, and have determined the seasonal trends in atmospheric temperature and dust and cloud opacity.

Christensen, P. R.↗