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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 487 records · Page 27
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

Equilibrium concentrations of N2H4 and its decomposition products at elevated temperatures and pressures

Liquid hydrazine is considered as a convenient source of hydrogen rather than just as a rocket fuel. For such purposes, the hydrogen is usually obtained by passing the hydrazine through a heated catalytic bed. One convenient measure of the effectiveness of a catalytic decomposition device as a whole is to compare the quantity of hydrogen produced with the equilibrium concentration of the gaseous species N2H4, NH3, N3, and H2 which would exist at the temperature and pressure found in various parts of the device. Calculations of the concentrations were carried out and are reported here. Following presentation of the results in both tabular and graphical forms is a comparison between the computed equilibrium concentrations and available experimental data.

Smetana, F. O.↗
NASA NTRS1978

Determination of boron and lithium by recording the products from (n, alpha) reactions

Irradiation with thermal neutrons in the VVR-S reactor provides a nondestructive method for determining the presence of boron and lithium in solids. The charged particles produced in the reactions Li-6(n,alpha)H-3 and B-10(n,alpha)Li-7 were detected using CsI single crystal. For alpha-particle spectrometry in the boron determination, an ionization chamber (W and Sn electrodes, 99% Ar + 1% H2) was developed allowing both absolute and relative measurements. In determining boron in lithium-containing samples, both scintillation and ionization chambers are used. In determining lithium in minerals, the error was 1.5%, and the sensitivity 0.00005 wt.%. In the determination of boron in SiC with a concentration of boron approximately (3 plus or minus 2) the error given by the alpha-range uncertainty was 15%.

Lobanov, Y. M.↗
NASA NTRS1990

Gamma rays from giant molecular clouds

Giant Molecular Clouds (GMCs) are massive, bounded, cool, dense regions containing mostly H2, but also H I, CO, and other molecules. These clouds occupy less than 1 percent of the galactic volume, but are a substantial part of the interstellar mass. They are irradiated by the high energy cosmic rays which are possibly modulated by the matter and magnetic fields within the clouds. The product of cosmic-ray flux and matter density is traced by the emission of high energy gamma-rays. A spherical cloud model is considered and the gamma ray flux from several GMCs within 1 kpc of the sun which should be detectable by the EGRET (Energetic Gamma-Ray Experimental Telescope) instrument on GRO (Gamma Ray Observatory).

Hunter, Stanley D.↗
NASA NTRS1989

Photochemistry of CO and H2O - Analysis of laboratory experiments and applications to the prebiotic earth's atmosphere

The role photochemical reactions in the early earth's atmosphere played in the prebiotic synthesis of simple organic molecules was examined, extending an earlier calculation of formaldehyde production rates to more reduced carbon species, such as methanol, methane, and acetaldehyde. The experimental results of Bar-Nun and Chang (1983) are simulated as an aid in the construction of the photochemical scheme and as a way of validating the model. The results indicate that some fraction of CO2 and H2 present in the primitive atmosphere could have been converted to simple organic molecules. The exact amount is dependent on the partial pressure of CO2 and H2 in the atmosphere and on what assumptions are made concerning the shape of the absorption spectra of CO2 and H2O.

Wen, Jun-Shan↗
NASA NTRS1991

Three-dimensional calculations of supersonic reacting flows using an LU scheme

A 3-D numerical program that incorporates comprehensive real gas property models was developed to simulate supersonic reacting flows. The code employs an implicit, finite volume, Lower-Upper (LU), time-marching method to solve the complete Navier-Stokes and species equations in a fully-coupled and efficient manner. A chemistry model with 9 species and 18 reaction steps is adopted in the program to represent the chemical reactions of H2 and air. To demonstrate the capability of the program, flow fields of underexpanded hydrogen jets transversely injected into the supersonic airstream inside the combustors of scramjets are calculated. Results clearly depict the flow characteristics, including the shock structure, the separated flow regions around the injector, and the distribution of the combustion products.

Yu, Sheng-Tao↗
NASA NTRS1990

Identifying atmospheric monitoring needs for Space Station Freedom

The monitoring needs for Space Station Freedom were identified by examining: the experiences of past missions; ground based tests of proposed life support systems; a contaminant load model; metabolic production from an 8-person crew; and a fire scenario. Continuous monitoring is recommended for components critical for life support, and that intermittent analysis be provided for all agents that may exceed one-half the spacecraft maximum allowable concentration. The minimum monitoring effort recommended includes continuous monitoring for: N2, O2, CO2, CO, H2O, H2, CH4, nonmethane hydrocarbons, aromatic hydrocarbons, refrigerants, and halons. Information on over 70 compounds is presented on the rationale for monitoring the frequency of analysis, and concentration ranges.

Casserly, Dennis M.↗
NASA NTRS1993

Calculations on the competition between association and reaction for C3H(+) + H2

The ab initio results presently obtained for the potential energy surface of competing associative and reactive ion-molecule processes of the reactants H2 and C3H(+) show that the linear ion is able to directly access the deep potential well of the propargyl ion H2CCCH(+). Using the minimum energy potential pathway and properties of the stationary point structures determined via the ab initio methods, calculation results are obtained for both the association-rate coefficient for C3H3(+) production as a function of density, and the branching ratio between the propargyl and cyclic structures of the ion.

Maluendes, Sergio A.↗
NASA NTRS2001

Composition of Hydrothermal Vent Microbial Communities as Revealed by Analyses of Signature Lipids, Stable Carbon Isotopes and Aquificales Cultures

Extremely thermophilic microbial communities associated with the siliceous vent walls and outflow channel of Octopus Spring, Yellowstone National Park, have been examined for lipid biomarkers and carbon isotopic signatures. These data were compared with that obtained from representatives of three Aquificales genera. Thermocrinis ruber. "Thermocrinis sp. HI", Hydrogenobacter thermophilus TK-6, Aquifex pyrophilus and Aquifex aeolicus all contained phospholipids composed not only of the usual ester-linked fatty acids, but also ether-linked alkyls. The fatty acids of all cultured organisms were dominated by a very distinct pattern of n-C-20:1 and cy-C-21 compounds. The alkyl glycerol ethers were present primarily as CIS() monoethers with the expection of the Aquifex spp. in which dialkyl glycerol ethers with a boarder carbon-number distribution were also present. These Aquificales biomarker lipids were the major constituents in the lipid extracts of the Octopus Spring microbial samples. Two natural samples, a microbial biofilm growing in association with deposition of amorphous silica on the vent walls at 92 C, and the well-known 'pink-streamers community' (PSC), siliceous filaments of a microbial consortia growing in the upper outflow channel at 87 C were analyzed. Both the biofilm and PSC samples contained mono and dialkyl glycerol ethers with a prevalence of C-18 and C-20 alkyls. Phospholipid fatty acids were comprised of both the characteristic Aquificales n-C-20:1 and cy-C-21, and in addition, a series of iso-branched fatty acids from i-C-15:0 to i-C-21:0, With i-C-17:0 dominant in the PSC and i-C-19:0 in the biofilm, suggesting the presence of two major bacterial groups. Bacteriohopanepolyols were absent and the minute quantities of archaeol detected showed that Archaea were only minor constituents. Carbon isotopic compositions of the PSC yielded information about community structure and likely physiology. Biomass was C-13-depleted (10.9%) relative to available CO2 from the source water inorganic carbon pool with lipids further depleted by 6.3% relative to biomass The C-20-21 Aquificales fatty acids of the PSC were somewhat heavier than the iso-branched fatty acids. The carbon isotopic signatures of lipid biomarkers were also explored using a pure culture, T ruber, previously isolated from the PSC. Cells grown on C02 with O2 and both H2 and thiosulfate as electron donors were only slightly depleted (3.3%) relative to the C-source while cells grown on formate with O2 showed a major discrimination (19.7%), possibly the result of a metabolic branch point involving the assimilation of C-formate to biomass and the dissimilation to CO2 associated with energy production. T. ruber lipids were slightly heavier than biomass (+1.3%) whether cells were grown using CO2 or formate. Fatty acids from CO2 grown T. ruber cells were a so slightly heavier (average +2.1%) than biomass. The relatively depleted PSC C-20-21 fatty acids suggest that any associated Thermocrinis biomass would also be similarly depleted and much too light to be explained by growth on CO2. The C-fractionations determined with the pure culture suggest that growth of Thermocrinis in the PSC is more likely to occur on formate, presumably generated by geothermal activity. This study points to the value of the analysis of the structural and isotopic composition of lipid blomarkers both in pure culture studies, and in establishing community structure and physiology, as a complement to genomic profiles of microbial diversity. This is especially so when the members of the microbial community are novel and difficult to cultivate in the laboratory.

Jahnke, Linda L.↗
DOE OSTI2024

Bridging the Energy Future: The Role and Potential of Hydrogen Co-Firing with Natural Gas

In the transition toward sustainable energy systems, the co-firing of hydrogen (H2) with natural gas emerges as a critical technology for cleaner power generation. This study examines its benefits, including emissions reduction, enhanced efficiency, and compatibility with existing infrastructure. Concurrently, it addresses the inherent challenges, such as combustion dynamics, necessary infrastructure modifications, and economic considerations. Incorporating global case studies, the review explores recent advancements in hydrogen production and co-firing, evaluating their practicality and operational efficiency. It also provides a critical examination of the economic implications and societal acceptance, which are crucial for the adoption of hydrogen technologies. Moreover, the review investigates the synergy between hydrogen and renewable energy technologies, assessing potential impacts on energy policy and regulation. Ultimately, this comprehensive analysis underscores the essential role of hydrogen co-firing in the energy sector and advocates for a comprehensive strategy that synergizes technological progress, economic viability, regulatory support, and public engagement to promote a resilient and sustainable energy future.

hydrogen co-firing↗
NASA NTRS1975

High-energy galactic gamma radiation from cosmic rays concentrated in spiral arms

A model for the emission of high-energy (exceeding 100 Mev) gamma-rays from the galactic disk has been developed and compared with recent SAS-2 observations. In the calculation, it is assumed that (1) the high energy galactic gamma-rays result primarily from the interaction of cosmic rays with galactic matter, (2) the cosmic-ray density is proportional to the matter density on the scale of galactic arms, and (3) the matter in the Galaxy is distributed in a spiral pattern consistent with density-wave theory and experimental data on the matter distribution that is available, including the 21-cm H I line emission, continuum emission from H II regions, and data currently being used to estimate the H2 density. The calculated galactic-longitude distribution of gamma rays is in good agreement with the SAS-2 observations in relative shape and absolute flux. As a corollary, the nonuniform cosmic-ray distribution of this model tends to support the galactic origin of the fraction of cosmic rays which is important in the production of high-energy photons. Modifications of the basic model show that the gamma-ray flux is relatively sensitive to large variations of the assumed distribution of molecular hydrogen in the Galaxy.

Bignami, G. F.↗
NASA NTRS1987

Neutral upper atmospheres of the outer planets

The major characteristics of the neutral upper atmospheres of outer planets are discussed, with special attention given to the Uranus upper atmosphere, probed by Voyager 2. The composition, thermal structure, photochemistry, and vertical mixing of the Uranus atmosphere are compared with the respective features of other outer planets. Unlike the atmospheres of Jupiter and Saturn, which reflect the solar ratios of the elements, the Uranus atmosphere was found to have only few constituents, including NH3, CH4, H2, He, C2H2, and C2H6. The eddy diffusion coefficient of Uranus, determined from occultation experiments, was found to be in the range 10,000-100,000 sq cm/sec, the lowest value amongst the major planets; this implies relatively sluggish vertical mixing. Another major difference from Saturn and Jupiter is in the fact that stable hydrocarbon products (C2H2 and C2H6) in the Uranus atmosphere begin to condense at around 5-10 mb level, resulting in the production of haze in the lower stratosphere.

Atreya, S. K.↗
NASA NTRS1993

Single and double charge transfer of He(2+) ions with molecules at near-thermal energies

Rate coefficients were measured for charge-transfer reactions of He(2+) ions with H2, N2, O2, CO, CO2, and H2O. The experiments were carried out using a selected-ion drift-tube mass spectrometer. Total rate coefficients are found to be very large and are generally close to the limiting Langevin capture rate coefficients or the corresponding ADO-model (Su and Bowers, 1973) coefficients. The product-ion spectra indicate that both single and double charge transfer and possibly transfer ionization occur in these reactions.

Tosh, R. E.↗
NASA NTRS2003

Impact Melting of Ordinary Chondrite Regoliths and the Production of Fine-grained Fe(sup 0)

The detailed study of individual lunar soil grains provides evidence that the major optical properties of the lunar surface are primarily related to the production of fine-grained (< 20 nm, super-paramagnetic) Fe-particles in agglutinitic impact melts and to iron-rich vapor deposits on the surfaces of individual grains. These Fe-rich materials are derived from oxidized species due to high post-shock temperatures in the presence of solar-wind derived H2; part of the Fe-rich grain surfaces may also be due to sputtering processes. Identical processes were recently suggested for the optical maturation of S-type asteroid surfaces, the parent objects of ordinary chondrites (OCs). OCs, however, do not contain impact-produced soil melts, and should thus also be devoid of impact-triggered vapor condensates. The seeming disparity can only be understood if all OCs resemble relatively immature impact debris, akin to numerous lunar highland breccias. It is possible to assess this scenario by evaluating experimentally whether impact velocities of 5- 6 km/s, typical for the present day asteroid belt, suffice to produce both impact melts and fine-grained metallic iron. We used 125-250 m powders of the L6 chondrite ALH85017. These powders were aliquots from fines that were produced by collisionally disrupting a single, large (461g) chunk of this meteorite during nine impacts and by subjecting the resulting rubble to an additional 50 impacts. As a consequence, the present shock-recovery experiments employ target materials of exceptional fidelity (i.e., a real chondrite that was impact pulverized). The target powders were packed into tungsten-alloy containers to allow for the potential investigation of freshly produced, fine-grained iron and impacted by stainless-steel and tungsten flyer plates; the packing density varied between 38 and 45% porosity. Peak pressures ranged from 14.5 to 67 GPa and were attained after multiple reverberations of the shock wave at the interface of the silicate powder and metal container. Pressures in the 50 to 70 GPa range should be fairly typical for asteroid impacts at approx. 5-6 km/s, yet we note that these pressures refer to those at the projectile/target interface only and that most crater ejecta on OC parent-bodies will have experienced much lower stresses.

Hoerz, Friedrich↗
NASA NTRS1991

Ab initio study of C + H3+ reactions

The reaction C + H3+ --> CH(+) + H2 is frequently used in models of dense interstellar cloud chemistry with the assumption that it is fast, i.e. there are no potential energy barriers inhibiting it. Ab initio molecular orbital study of the triplet CH3+ potential energy surface (triplet because the reactant carbon atom is a ground state triplet) supports this hypothesis. The reaction product is 3 pi CH+; the reaction is to exothermic even though the product is not in its electronic ground state. No path has been found on the potential energy surface for C + H3+ --> CH2(+) + H reaction.

NASA Discipline Exobiology↗
DOE OSTI2026

Kinetics of Hydrogen Generation from In-Situ Methane Pyrolysis: Enhanced by Electromagnetic Heating and Natural Catalysts of Reservoir Rocks

Catalytic pyrolysis of methane (CH4) is a promising approach to generate hydrogen (H2). The apparent activation energy of this process has a significant influence on the efficiency and required temperature for H2 generation. Preliminary experiments indicate that minerals present in shales have catalytic effects during in-situ H2 generation from shale reservoirs under electromagnetic (EM) heating. However, the quantitative role of such natural catalysts on apparent activation energy is not explored yet. This research evaluated the role of reservoir rock (shale) in EM heating and on the apparent activation energy of methane pyrolysis (MP) for in-situ H2 generation. Experiments are conducted in a customized EM reactor with frequency 2.45 GHz, and reaction temperature and generated gases are measured by a real-time IR pyrometer and gas analyzer, respectively. It is found that shale samples experienced thermal runway (TR) at 420 ºC under 0.15 kW EM power without any artificial heating promoter. In the presence of spent shale, CH4 conversion started approximately at 600 ºC with negligible amount of carbon dioxide (CO2) generated during this process. We further calculated apparent reaction order and apparent activation energy for MP process in the presence of shale under EM heating, which are 0.4357 and 98.12 kJ/mol, respectively. This research paves a way for leveraging the role of minerals as natural catalysts for enhancing H2 generation under EM heating in petroleum reservoirs.

02 PETROLEUM↗
DOE OSTI2022

Controlling Selectivity in Plasmonic Catalysis: Switching Reaction Pathway from Hydrogenation to Homocoupling Under Visible–Light Irradiation

Plasmonic catalysis enables the use of light to accelerate molecular transformations. Its application to the control reaction selectivity is highly attractive but remains challenging. Here, we have found that the plasmonic properties in AgPd nanoparticles allowed different reaction pathways for tunable product formation under visible-light irradiation. By employing the hydrogenation of phenylacetylene as a model transformation, we demonstrate that visible-light irradiation can be employed to steer the reaction pathway from hydrogenation to homocoupling. Our data showed that the decrease in the concentration of H species at the surface due to plasmon-enhanced H2 desorption led to the control in selectivity. Furthermore, these results provide important insights into the understanding of reaction selectivity with light, paving the way for the application of plasmonic catalysis to the synthesis of 1,3-diynes, and bringing the vision of light-driven transformations with target selectivity one step closer to reality.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1988

Performance of lightweight nickel electrodes

The NASA Lewis Research Center is currently developing nickel electrodes for nickel-hydrogen (Ni-H2) batteries. These electrodes are lighter in weight and have higher energy densities than the heavier state-of-the-art (SOA) sintered nickel electrodes. In the present approach, lightweight materials or plaques are used as conductive supports for the nickel hydroxide active material. These plaques (fiber and felt, nickel plated plastic and graphite) are commercial products that are fabricated into nickel electrodes by electrochemically impregnating them with active material. Evaluation is performed in half cells structured in the bipolar configuration. Initial performance tests include capacity measurements at five discharge levels, C/2, 1.0C 1.37C, 2.0C and 2.74C. The electrodes that pass the initial tests are life cycle tested in a low Earth orbit regime at 80 percent depth of discharge. Different formulations of nickel fiber materials obtained from several manufacturers are currently being tested as possible candidates for nickel electrodes. One particular lightweight fiber mat electrode has accumulated over 3000 cycles to date, with stable capacity and voltage. Life and performance data of this electrode were investigated and presented. Good dimensional stability and active material adherence have been demonstrated in electrodes made from this lightweight plaque.

Britton, Doris L.↗
NASA NTRS1988

Performance of lightweight nickel electrodes

The NASA Lewis Research Center is currently developing nickel electrodes for nickel-hydrogen (Ni-H2) batteries. These electrodes are lighter in weight and have higher energy densities than the heavier state-of-the-art (SOA) sintered nickel electrodes. In the present approach, lightweight materials or plaques are used as conductive supports for the nickel hydroxide active material. These plaques (fiber and felt, nickel plated plastic and graphite) are commercial products that are fabricated into nickel electrodes by electrochemically impregnating them with active material. Evaluation is performed in half cells structured in the bipolar configuration. Initial performance tests include capacity measurements at five discharge levels, C/2, 1.0C, 1.37C, 2.0C and 2.74C. The electrodes that pass the initial tests are life cycle tested in a low earth orbit regime at 80 percent depth of discharge. Different formulations of nickel fiber materials obtained from several manufacturers are currently being tested as possible candidates for nickel electrodes. One particular lightweight fiber mat electrode has accumulated over 3000 cycles to date, with stable capacity and voltage. Life and performance data of this electrode were investigated and presented. Good dimensional stability and active material adherence have been demonstrated in electrodes made from this lightweight plaque.

Britton, Doris L.↗